WO2016094973A1 - Cosmetic conditioning composition including a fixative - Google Patents
Cosmetic conditioning composition including a fixative Download PDFInfo
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- WO2016094973A1 WO2016094973A1 PCT/BR2014/050044 BR2014050044W WO2016094973A1 WO 2016094973 A1 WO2016094973 A1 WO 2016094973A1 BR 2014050044 W BR2014050044 W BR 2014050044W WO 2016094973 A1 WO2016094973 A1 WO 2016094973A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Definitions
- the present invention relates to cosmetic compositions comprising at least one fixative polymer and a vegetable butter. These compositions are particularly useful for providing discipline and control to hair, in particular curly hair, enhancing curl definition and curl retention and/or enhancing shine.
- Hair styling products often provide a shape, feel and/or color that are not natural, for example such as with the use of film-forming polymers. While there are several products to increase the manageability of hair, the performance of these products is still not optimal, especially for curly and wavy hair. It is thus an object of the invention to provide a cosmetic composition that is easy to apply to hair and affords long lasting manageability, volume control and increased shine without leaving the hair feeling and/or looking unnatural and stiff.
- the present invention is directed to an aqueous cosmetic composition for hair comprising:
- compositions optionally may also include other components appropriate for its intended use such as oils, antioxidants, preservatives, neutralizers, vitamins and the like.
- the invention is also directed to a method of improving the performance a leave-in hair treatment composition comprising adding to said composition a fixative polymer, in particular PQ-1 1 , and a plant butter.
- the present invention is also directed to a method of treating hair with a composition as defined above.
- Applicants have found that the addition of at least one fixative polymer and at least one plant butter having a hydrocarbon chain distribution C12:30- 55%/C14:10-40%/C16:4-15% to hair serums, conditioners, styling compositions, shots, biphasic compositions and/or monodoses vastly improves the performance of the composition, including providing long lasting manageability, volume control and increased shine of hair without leaving the hair feeling and/or looking unnatural and stiff.
- At least one means one or more and thus includes individual components as well as mixtures/combinations.
- Constanting means imparting to hair at least one property chosen from compatibility, manageability, moisture-retentivity, luster, shine, and softness. The state of conditioning is evaluated by measuring, and comparing the ease of combing of the treated hair in contrast with the untreated hair.
- “Free” or “devoid” of as it is used herein means that while it is preferred that no amount of the specific component be present in the composition, it is possible to have very small amounts of it in the compositions of the invention provided that these amounts do not materially affect at least one, preferably most, of the advantageous properties of the compositions of the invention.
- silicone free means that silicone is preferably omitted (that is 0% by weight), but can be present in the composition at an amount of less than about 0.25% by weight, typically less than about 0.1 % by weight, typically less than about 0.05% by weight, based on the total weight of the composition as a whole.
- INCI is an abbreviation of International Nomenclature of Cosmetic Ingredients, which is a system of names provided by the International Nomenclature Committee of the Personal Care Products Council to describe personal care ingredients.
- Polymers as defined herein, include homopolymers and copolymers formed from at least two different types of monomers.
- compositions and methods of the present invention can comprise, consist of, or consist essentially of the essential elements and limitations of the invention described herein, as well as any additional or optional ingredients, components, or limitations described herein or otherwise useful.
- ranges provided are meant to include every specific range within, and combination of subranges between, the given ranges.
- a range from 1 -5 includes specifically 1 , 2, 3, 4 and 5, as well as subranges such as 2- 5, 3-5, 2-3, 2-4, 1 -4, etc.
- ratios are meant to include every specific ratio within, and combination of subranges between, the given ranges.
- the present invention is directed to an aqueous cosmetic composition for hair comprising:
- the ratio of the fixative polymer to the at least one plant butter, by weight is from about 1 :1 to about 1 :10, typically from about 1 :1 to about 1 :5, including in particular about 1 :1 to about 1 :3.
- the composition includes at least one emollient or humectant, or a mixture thereof.
- composition further includes at least one silicone oil.
- viscosity measurement referred to herein were made with a Rheomat RM 200 instrument (measured at 25 Q C, 1 atmosphere), spindle M3/30.
- the foregoing cosmetic composition including a fixative polymer and a plant butter have a viscosity from about 15 cP to about 55 cP (centipoises), including all ranges and sub ranges there between.
- the cosmetic composition has a viscosity from about 20 cP to about 45 cP, including all ranges and sub ranges there between.
- compositions have a pH at 25 Q C of from about 4 to about 5.
- the present invention is directed to an aqueous cosmetic composition for hair comprising:
- the ratio of the fixative polymer to the at least one plant butter is from about 1 :1 to about 1 :10; said composition having a viscosity from about 15 cP to about 55 cP; all weights and ratios being relative to the weight of the final composition.
- the present invention is directed to an aqueous cosmetic composition for hair comprising:
- (f) optionally from about 0.05% to about 40%, particularly 0.1 % to about 5%, more particularly from about 0.3% to about 1 % of at least one emollient, humectant or a mixture thereof;
- the ratio of the fixative polymer to the at least one plant butter, by weight is from about 1 :1 to about 1 :2.5; said composition having a viscosity from about 20 cP to about 45 cP and a pH at 25 Q C of from about 4 to about 5, all weights and ratios being relative to the weight of the final composition.
- the present invention is directed to a method caring for, conditioning, and/or styling hair by the application to the hair a composition
- a composition comprising:
- composition of the invention is clear gives the hair manageability, good curl retention, and soft feel and sheen.
- the invention is also directed to a method of improving the performance a leave-in hair treatment composition comprising adding to said composition a fixative polymer, in particular PQ-1 1 , and a plant butter.
- compositions of the invention comprise at least one fixative polymer.
- Fixatives including in particular fixative polymers for hair, are known in the hair care industry. See, e.g., US2040/0129307, WO13186486 and WO14023675.
- Non-limiting examples of such polymers that may be used in the current compositions include polyvinylpyrrolidone, vinylpyrrolidone/vinyl acetate copolymers, acrylates/vinylpyrrolidone copolymers, polyquaternium-4, polyquaternium-6, polyquaternium-7 polyquaternium-10 polyquaternium-1 1 , polyquaternium-16, polyquaternium-22, polyquaternium-28, polyquaternium-32, polyquaternium-55, and mixtures thereof.
- the fixative is selected from polyquaternimum-1 1 (PQ-1 1 ) (which is also known as copolymer vinylpyrrolidone/dimethylaminoethyl methacrylate quaternized, such as the product Gafquat ® 734, which is commercially available from ISP/Ashland) and polyquaternimum-55 (PQ-55) (such as the product Styleze ® W-17L, commercially available from ISP/Ashland).
- PQ-1 1 polyquaternimum-1 1
- PQ-55 polyquaternimum-55
- compositions of the invention comprise at least one fixative polymer (a) in an amount preferably ranging from about 0.1 % to about 3%, typically from about 0.15% to about 1 .5%, most typically from about 0.2% to about 0.6%, by weight, relative to the weight of the composition.
- compositions of the invention comprise at least one plant butter hydrocarbon chain distribution C12:30-55%/C14:10-40%/C16:4-15%.
- a “butter” is a fat that is solid at room temperature (25° C).
- a plant butter often also referred to as a “vegetable butter,” is a butter derived from a natural plant source.
- Fats such a butters, are generally characterized by their hydrocarbon chain length. See, e.g. US Pat. No. 5,554,408. Plant fats often have mixtures of different hydrocarbon lengths. Thus, a fat having a hydrocarbon chain distribution of C12:30-55%/C14:10-40% means the fat has two hydrocarbon chains, one having 12 carbons and being present in the fat in an amount from 30-55%, and a second hydrocarbon chain having 14 carbons and being present in the fat from 10-40%.
- Non-limiting plant butters useful in the current compositions include, murumuru butter (Astrocaryum murumuru), cupuacu butter (Theobroma grandiflorum), babassu butter (Corbignya), and mixtures thereof.
- the plant butter having hydrocarbon chain distribution C12:30-55%/C14:10-40%/C16:4-15% is selected from murumuru seed butter, babassu butter, or a mixture thereof, most preferably murumuru seed butter.
- compositions of the invention comprise at least one plant butter (b) in an amount preferably ranging from about 0.01 % to about 20%, typically from about
- 0.1 % to about 3% most typically from about 0.4% to about 0.7%, by weight, relative to the weight of the composition.
- compositions of the invention comprise at least one agent selected from cationic agent, a conditioning agent, a non-ionic surfactant, and mixtures thereof.
- the cationic agent may be selected from cationic surfactants, cationic silicones and mixtures thereof.
- the cationic surfactant useful in the cosmetic compositions disclosed herein optionally is selected from mono and di-alkyl quaternary ammonium or diammonium salts.
- quaternary ammonium or diammonium salts described in US2005071933, incorporated by reference herein, may be chosen, such as, for example, those of the general formula (XXI):
- -R1 and R4 may independently be chosen from saturated or unsaturated, linear or branched, aliphatic hydrocarbon radicals comprising from 1 to about 30 carbon atoms, or an alkoxy, alkoxycarbonylalkyl, polyoxyalkylene, alkylamido, alkylamidoalkyl, hydroxyalkyl, aromatic, aryl or alkylaryl radical comprising from about 12 to about 30 carbon atoms, with at least one radical among R1 , R2, R3 and R4 denoting a radical comprising from 8 to 30 carbon atoms; and -X " is an anion chosen from the group comprising halides, phosphates, acetates, lactates and alkyl sulfates;
- -R6 denotes an aliphatic radical comprising from about 16 to 30 carbon atoms
- R7, R8, R9, R10 and R1 1 are independently chosen from hydrogen or an alkyl radical comprising from 1 to 4 carbon atoms, and
- -X " is an anion chosen from the group comprising halides, acetates, phosphates and sulfates.
- ammonium salts containing at least one ester function such as those described in WO14056962A3.
- the ammonium salts containing at least one ester function contain two ester functions.
- quaternary ammonium and diammonium salts include, for example, distearyldimethylammonium chloride, cetyltnmethylammonium chloride (such as, for example, the products sold under the trade name Dehyquart A by Cognis, or Quartamin 60 W25 by Kao, or Genamin CTAC 25 by Clariant), behenyltnmethylammonium chloride (such as the products sold for example by Clariant under the trade name Genamin KDMP or Genamin BTLF, or by Evonik Goldschmidt under the name Varisoft BT 85), behentrimonium chloride, cetrimonium chloride, oleocetyldimethylhydroxyethylammonium chloride, behenoylhydroxypropyltrimethylammonium chloride (such as the product sold by Kao under the name Quartamin BTC 131 ) stearamidopropyl
- the cationic surfactant is selected from behentrimonium chloride, cetrimonium chloride, ceterayl alcohol (and) dipalmitoylethyl hydroxyethylmonium methosulfate, and mixtures thereof.
- Cationic silicones include in particular amino silicones.
- amino silicone means any polyaminosiloxane, i.e. any polysiloxane comprising at least one primary, secondary or tertiary amine function or a quaternary ammonium group.
- amino silicone(s) used in the cosmetic composition according to the present invention are selected from (A) - (D) as described below.
- Amino silicones are described, for example, in US201 1 /0155163 and US201 1 /155164, both of which are herein incorporated by reference.
- T is a hydrogen atom or a phenyl, hydroxyl (-OH) or CrC 8 alkyl radical, and preferably methyl, or a CrC 8 alkoxy, preferably methoxy,
- a denotes the number 0 or an integer from 1 to 3, and preferably 0, b denotes 0 or 1 , and in particular 1 ,
- n and n are numbers such that the sum (n + m) can range especially from 1 to 2000 and in particular from 50 to 150, it being possible for n to denote a number from 0 to 1999 and in particular from 49 to 149, and for m to denote a number from 1 to 2000 and in particular from 1 to 10;
- R 1 is a monovalent radical of formula -CqH 2q L in which q is a number from 2 to 8 and L is an optionally quaternized amino group selected from the following groups:
- R 2 denotes a hydrogen atom, a phenyl, a benzyl or a saturated monovalent hydrocarbon-based radical, for example a CrC 20 alkyl radical
- Q " represents a halide ion, for instance fluoride, chloride, bromide or iodide.
- amino silicones corresponding to the definition of formula (II) are selected from the compounds corresponding to formula (III) below:
- R, R' and R which may be identical or different, denote a Cr C 4 alkyl radical, preferably CH 3 ; a C C 4 alkoxy radical, preferably methoxy; or OH;
- A represents a linear or branched, C 3 -C 8 and preferably C 3 -C 6 alkylene radical;
- m and n are integers dependent on the molecular weight and whose sum is between 1 and 2000.
- R, R', R" which may be identical or different, represent a CrC 4 alkyl or hydroxyl radical
- A represents a C 3 alkylene radical
- m and n are such that the weight-average molecular weight of the compound is between 5000 and 500 000 approximately.
- Compounds of this type are referred to in the CTFA dictionary as "aminodimethicones".
- R, R' and R" which may be identical or different, represent a C C 4 alkoxy or hydroxyl radical, at least one of the radicals R or R" is an alkoxy radical and A represents a C 3 alkylene radical.
- the hydroxy/alkoxy molar ratio is preferably between 0.2/1 and 0.4/1 and advantageously equal to 0.3/1 .
- m and n are such that the weight-average molecular weight of the compound is between 2000 and 10 6 . More particularly, n is between 0 and 999 and m is between 1 and 1000, the sum of n and m being between 1 and 1000.
- R and R" which are different, represent a Ci-C 4 alkoxy or hydroxyl radical
- at least one of the radicals R or R" is an alkoxy radical
- R' represents a methyl radical
- A represents a C 3 alkylene radical.
- the hydroxy/alkoxy molar ratio is preferably between 1 /0.8 and 1 /1 .1 and advantageously equal to 1 /0.95.
- m and n are such that the weight-average molecular weight of the compound is between 2000 and 200 000. More particularly, n is between 0 and 999 and m is between 1 and 1000, the sum of n and m being between 1 and 1000.
- R and R" represent a hydroxyl radical
- R' represents a methyl radical
- A is a C 4 -C 8 and preferably C 4 alkylene radical.
- m and n are such that the weight-average molecular weight of the compound is between 2000 and 10 6 . More particularly, n is between 0 and 1999 and m is between 1 and 2000, the sum of n and m being between 1 and 2000.
- a product of this type is especially sold under the name DC 28299 by Dow Corning.
- the molecular weight of these silicones is determined by gel permeation chromatography (ambient temperature, polystyrene standard; ⁇ styragem columns; eluent THF; flow rate 1 mm/m; 200 ⁇ of a solution containing 0.5% by weight of silicone in THF are injected, and detection is performed using a refractometer and a UV meter).
- n and m have the meanings given above in accordance with formula (II) or (III) above.
- R 3 represents a C1 -C18 monovalent hydrocarbon-based radical, and in particular a C Ci 8 alkyl or C 2 -Ci 8 alkenyl radical, for example methyl;
- R 4 represents a divalent hydrocarbon-based radical, especially a C Ci 8 alkylene radical or a divalent C1 -C18, and for example C-pCs, alkylenoxy radical;
- Q " is a halide ion, in particular chloride
- r represents a mean statistical value from 2 to 20 and in particular from
- s represents a mean statistical value from 20 to 200 and in particular from 20 to 50.
- a compound falling within this class is the product sold by the company Union Carbide under the name Ucar Silicone ALE 56.
- R 7 which may be identical or different, represent a monovalent hydrocarbon-based radical containing from 1 to 18 carbon atoms, and in particular a C1 -C18 alkyl radical, a C2-C18 alkenyl radical or a ring comprising 5 or 6 carbon atoms, for example methyl;
- R6 represents a divalent hydrocarbon-based radical, especially a C1 -C18 alkylene radical or a divalent C Ci 8 , and for example CrC 8 , alkylenoxy radical linked to the Si via an SiC bond;
- R 8 which may be identical or different, represent a hydrogen atom, a monovalent hydrocarbon-based radical containing from 1 to 18 carbon atoms, and in particular a C1-C18 alkyl radical, a C2-C18 alkenyl radical or a radical -R6-NHCOR7;
- X " is an anion such as a halide ion, especially chloride, or an organic acid salt (acetate, etc.);
- r represents a mean statistical value from 2 to 200 and in particular from
- R-i , R2, R3 and R 4 which may be identical or different, denote a CrC 4 alkyl radical or a phenyl group,
- R5 denotes a CrC 4 alkyl radical or a hydroxyl group
- - n is an integer ranging from 1 to 5
- - m is an integer ranging from 1 to 5
- x is selected such that the amine number is between 0.01 and 1 meq/g.
- Amino silicone(s) that are particularly useful in the invention include polysiloxanes containing amine groups, such as the compounds of formula (III) or of formula (IV), and even more particularly the silicones containing quaternary ammonium groups of formula (VI).
- Non-limiting examples of particularly useful silicones include aminodimethicones, such as the products available from the company Wacker under the name FLUID ® (for example FLUID ® WR 1300) and BELSIL ® (for example BELSIL ® ADM LOG1 ) and a product available from Momentive Performance Material under the name SILSOFT ® . Also useful is trimethylsilylamodimethicone (such as Q@- 8220 available from OSI).
- composition of the invention may include a conditioning agent chosen, from example, from a cationic polymer, including homopolymers and copolymers.
- Non- limiting examples of cationic conditions polymers that can be used in the current compositions include: cationic cellulose derivatives, such as for example polyquaternium-10 ("PQ-10"); cationic gum derivatives such as for example gum derivatives, including particularly guar hydroxypropyltrimonium chloride (such as the products Jaguar ® C13S from Rhodia and N-Hance ® CG13 form Ashland); polymer derivatives of diallyldimethyl ammonium chloride (“poly-DADMAs”) and of methacrylamidopropyltrimethylammonium chloride (“poly-MAPTACs”), and having the following formulas:
- Non-limiting examples of poly-DADMAs and poly- poly-MAPTACs include, polyquaternium-4 (PQ-4), polyquaternium-5 (PQ-5), polyquaternium-6 (PQ- 6), polyquaternium-7 (PQ-7), polyquaternium-22 (PQ-22), polyquaternium-37 (PQ-37), polyquaternium-39 (PQ-39), polyquaternium47 (PQ-47) and polyquaternium-53 (PQ- 53), particularly DADMAC-based polymers, specifically PQ-6 and PQ-22.
- Cationic proteins such as, for example, hydroxypropyltrimonium hydrolyzed wheat protein are also useful as cationic conditioning agents.
- the cationic conditioning polymer is selected from guar hydroxypropyltrimonium chloride.
- Nonionic surfactants useful in the cosmetic compositions disclosed herein is selected from: alkyl polyglucosides; ethylene glycol, propylene glycol, glycerol, polyglyceryl esters and their ethoxylated derivatives (herein jointly referred to as "glycol ethers"); as well as amine oxides; and mixtures the foregoing.
- Alkyl polyglucosides useful in the compositions of the invention include those having the following formula (I):
- R 1 is an alkyl group having 8-18 carbon atoms
- R 2 is an ethylene or propylene group
- Z is a saccharide group with 5 to 6 carbon atoms
- n is an integer from 0 to10;
- x is an integer from 1 to 5.
- alkyl poly glucoside compounds include lauryl glucoside, octyl glucoside, decyl glucoside, coco glucoside, sucrose laurate, caprylyl/capryl glucoside, and sodium lauryl glucose carboxylate, and mixtures thereof.
- the at least one alkyl poly glucoside compound is selected from the group consisting of lauryl glucoside, decyl glucoside and coco glucoside, and more typically lauryl glucoside.
- Non-limiting examples of glycol esters useful in the compositions of the invention include those described in M. R. Porter et al., Handbook of Surfactants, Ch. 7, ⁇ 7.12, pp. 231 -235 (2 nd Ed. 1994), which is herein incorporated by reference.
- Preferred glycol esters have HLB values between about 9 and about 18.
- Particular glycol esters useful in the compositions of the invention include PEG-8 glyceryl laurate, polysorbate-40, polyglyceryl-5 laurate, and mixtures thereof.
- Amine oxides useful in the compositions of the invention include those having the formulas (I I A) and (MB)
- R is an alkyl group having 8-18 carbon atoms; and n is an integer from 1 to 3.
- a non-limiting example of a particular amine oxide is lauramine oxide.
- the at least one cationic agent and/or conditioning agent and/or nonionic surfactant, or mixtures thereof, is present in the compositions of the invention in an amount of from about 0.5% to about 6% by weight, typically from about 0.6% to about 3.5% by weight, and more typically from about 0.75% to about 2%, by weight, including all ranges and sub ranges therebetween, based on the total weight of the composition as a whole.
- compositions of the invention at include at least one fatty alcohol.
- Fatty alcohols have the structure R-OH in which R is a saturated or unsaturated, linear or branched radical containing from 8 to 40, preferably from 8 to 30, carbon atoms.
- R preferably a C12-C24 alkyl or C12-C24 alkenyl group.
- R may be substituted with one or more hydroxyl groups.
- Non-limiting examples of fatty alcohols useful in the compositions of the invention include lauryl alcohol, myristyl alcohol, cetyl alcohol, dodecyl alcohol, decyl alcohol, stearyl alcohol, oleyl alcohol, behenyl alcohol, linoleyl alcohol, undecylenyl alcohol, palmitoleyl alcohol, arachidonyl alcohol, erucyl alcohol, and mixtures thereof.
- the fatty alcohol is itself a may be a mixture of several species of fatty alcohols.
- fatty alcohol mixtures include, for example, cetearyl alcohol (mixture of cetyl and strearyl alcohols) and cetylstearyl alcohol.
- the fatty alcohol is selected from cetyl alcohol, stearyl alcohol, cetearyl alcohol, and mixtures thereof.
- the at least one fatty alcohol is present in the compositions of the invention in an amount of from about 0.5% to about 10% by weight, typically from about 1 % to about 8% by weight, and more typically from about 2% to about 6%, by weight, including all ranges and sub ranges therebetween, based on the total weight of the composition as a whole.
- compositions of the invention include water.
- the compositions can be aqueous or oil-in-water emulsions or water-in-oil emulsions.
- the water is present in the compositions of the invention in an amount of from about 60% to about 98%, preferably from about 70% to about 97%, more particularly from about from about 80% to about 95%, by weight, including all ranges and subranges therebetween, all weights being based on the total weight of the composition.
- Emollient/Humectant (f) (Optional)
- compositions of the invention optionally may include one or more emollient and/or humectants and/or moisturizers (herein generally referred to as "emollients"). These compounds hydrate the keratinous substrate, and also provide a shiny look. Emollients are known to skilled artisan. See, e.g. International Cosmetic Ingredient Dictionary and Handbook Vol. 4 (9 th ed. 2002), more particularly the emollients disclosed on pages 2930-2936. The disclosure of the International Cosmetic Ingredient Dictionary and Handbook Vol. 4, pages 2930-2936, is hereby incorporated by reference.
- the emollients that may be used in the compositions of the invention include, for example: glycerin; glycerol; propylene glycol; butylene glycol; carnauba wax; beeswax; candelilla; ozokerite; paraffin; rice bran wax; microcrystalline wax; polyethylene wax; mineral oil; almond oil; castor oil; sesame oil; hydrogenated polyisobutene; butylene glycol dicaprylte dicaprate (commercially available from Sasol as Myglyol ® ); and mixtures thereof.
- glycerin glycerol
- propylene glycol butylene glycol
- carnauba wax beeswax
- candelilla candelilla
- ozokerite paraffin
- rice bran wax microcrystalline wax
- polyethylene wax mineral oil
- almond oil castor oil
- sesame oil hydrogenated polyisobutene
- butylene glycol dicaprylte dicaprate commercially
- the emollient is glycerin.
- the emollient is present in the composition of the invention in an amount of from about 0.05% to about 40%, preferably from about 0.1 % to about 5%, more particularly from about 0.3% to about 1 %, by weight, including all ranges and subranges therebetween, all weights being based on the total weight of the composition.
- composition of the present disclosure may optionally also include a silicone oil or a mixtures of such oils.
- Non-limiting examples of silicone oils include polydimethylsiloxanes (PDMS), phenylated polyorganosiloxanes such as phenyltrimethicones, phenyltrimethylsiloxy-diphenylsiloxanes, diphenylmethyldimethyltrisiloxanes, diphenyldimethicones, phenyldimethicones, polymethyl-phenylsiloxanes, optionally fluorinated; polysiloxanes modified with fatty acids, fatty alcohols or polyoxyalkylenes, fluorinated silicones, perfluorinated silicone oils, aminated silicone oils.
- PDMS polydimethylsiloxanes
- phenylated polyorganosiloxanes such as phenyltrimethicones, phenyltrimethylsiloxy-diphenylsiloxanes, diphenylmethyldimethyltrisiloxanes, diphenyldimethicones, pheny
- Preferred silicone oils include polydimethylsiloxanes, polymethylphenylsiloxanes, and mixtures thereof.
- silicone oils can optionally comprise alkyl, hydroxyl or alkoxy groups at the end of the silicone chain or pendant, for example polydimethylsiloxanes with trimethylsilyl end groups and polydimethylsiloxanes with dimethylsilanol end groups.
- polydimethylsiloxanes with trimethylsilyl end groups we may notably mention those having a viscosity from 5.10 "6 to 2.5 m 2 /s at 25 degrees centigrade and preferably 1 .10 "5 to 1 m 2 /s.
- the viscosity of the silicones is for example measured at 25 degrees centigrade according to standard ASTM 445 Appendix C.
- Non-liming examples of polyalkylsiloxanes include the following commercial products:
- oils of the 200 series from the company DOW CORNING such as more particularly DC200 of viscosity 60 000 cSt;
- polydimethylsiloxanes with dimethylsilanol end groups such as the oils of the 48 series from the company RHODIA.
- silicone oil usable in the invention we may also mention the linear or cyclic silicones, and in particular with from 2 to 7 silicon atoms.
- cyclic silicones include octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, hexadecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane and mixtures thereof.
- oils that are particularly preferred within the scope of the present invention are polydimethylsiloxanes and mixtures thereof.
- the polydimethyl siloxane oil is dimethicone, such as Belsil 60000 from Wacher.
- the silicone oil may be used in an amount from about 0.05% to about 3%, typically from about 0.5% to about 1 .5%, more particularly from about 0.2% to about 1 %, by weight, including all ranges and subranges therebetween, all weights being based on the total weight of the composition.
- composition of the present disclosure may additionally include any other adjuvant or additive that is usually used in the field of hair care.
- adjuvants and/or additives include pH adjusting agents, preserving agents, sequestrants and chelators , consistency regulators (e.g. isopropyl alcohol), thickeners, antioxidants, fragrances, dyestuffs such as soluble dyes and pigments, optical brighteners, electrolytes and stabilizers (e.g.
- compositions of the invention preferably do not include waxes.
- Non-limiting examples of pH adjusting agents include potassium acetate, potassium hydroxide, sodium carbonate, sodium hydroxide, phosphoric acid, succinic acid, sodium citrate, citric acid, boric acid, lactic acid, sodium hydrogen carbonate, ethanol amines, and mixtures thereof.
- the pH adjusting agent is selected from citric acid.
- Non-limiting examples of useful preservatives include ethanol, polyvinyl alcohol, phenoxyethanol, benzyl alcohol, salicylic acid, sodium benzoate, caprylyl glycol, methyl paraben, propyl paraben, ethylhexylglycerin, 1 ,3-propanediol, cholorphensin, methylchloroisothiazolinone, methylisothiazolinone, benzalkonium chloride, polyaminopropyl biguanide, chlorhexidine dihydrochloride, and mixtures thereof.
- the preservatives are selected from chlorhexidine dihydrochloride, sodium benzoate, and mixtures thereof.
- Chelating agents and antioxidants are ingredients which assist in preventing or retarding spoilage.
- antioxidants suitable for use in the present composition are potassium sulfite, sodium bisulfite, sodium erythrobate, sodium metabisulfite, sodium sulfite, propyl gallate, cysteine hydrochloride, butylated hydroxytoluene, butylated hydroxyanisole, and mixtures thereof.
- Suitable chelators include salts of ethylenediaminetetraacetic acid (“EDTA”), butylated hydroxytoluene (“BHT”), and mixtures thereof.
- the antioxidant/chelator is BHT.
- these additives may be present in the composition in a proportion from 0.005% to 15% (such as from 0.01 % to 10%) relative to the total weight of the composition and further such as from 0.01 % to 5%.
- compositions according to the invention can be manufactured by known processes used generally in the cosmetics, including the processes described in the examples below.
- composition in accordance with the present invention for the treatment of hair was prepared as described below.
- the materials and amounts employed in the example are provided in Table 1 below.
- phase A One quarter of the water was combined with phase A. The temperature was brought to 65 Q C and the composition was stirred at 3200 RMP for 10 minutes. 8% of the water was then added. The temperature was brought to 40 Q C and the components of phase B were added with mixing. Thereafter, the rest of the water and the remaining components (phases C and D) were added with mixing.
Abstract
Description
Claims
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BR112017008517-8A BR112017008517B1 (en) | 2014-12-16 | 2014-12-16 | cosmetic compositions, use of the composition and method for the improvement of at least one property selected from long-lasting handling capacity, volume control and hair shine |
PCT/BR2014/050044 WO2016094973A1 (en) | 2014-12-16 | 2014-12-16 | Cosmetic conditioning composition including a fixative |
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PCT/BR2014/050044 WO2016094973A1 (en) | 2014-12-16 | 2014-12-16 | Cosmetic conditioning composition including a fixative |
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Cited By (3)
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KR20190038396A (en) * | 2017-09-29 | 2019-04-08 | (주)아모레퍼시픽 | Cosmetic Composition for Hair and Scalp for Enhancing Hair Volume |
US20210069095A1 (en) * | 2017-12-15 | 2021-03-11 | L'oreal | Leave-on hair care compositions |
US20210128441A1 (en) * | 2019-10-31 | 2021-05-06 | L'oreal | Compositions and methods for curly hair |
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Cited By (6)
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KR20190038396A (en) * | 2017-09-29 | 2019-04-08 | (주)아모레퍼시픽 | Cosmetic Composition for Hair and Scalp for Enhancing Hair Volume |
CN111163754A (en) * | 2017-09-29 | 2020-05-15 | 株式会社爱茉莉太平洋 | Cosmetic composition for hair or scalp for enhancing fluffy feeling of hair |
CN111163754B (en) * | 2017-09-29 | 2023-04-07 | 株式会社爱茉莉太平洋 | Cosmetic composition for hair or scalp for enhancing fluffy feeling of hair |
KR102564638B1 (en) | 2017-09-29 | 2023-08-09 | (주)아모레퍼시픽 | Cosmetic Composition for Hair and Scalp for Enhancing Hair Volume |
US20210069095A1 (en) * | 2017-12-15 | 2021-03-11 | L'oreal | Leave-on hair care compositions |
US20210128441A1 (en) * | 2019-10-31 | 2021-05-06 | L'oreal | Compositions and methods for curly hair |
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BR112017008517A2 (en) | 2018-01-09 |
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