WO2012055812A1

WO2012055812A1 - Cosmetic composition comprising a fatty-chain alkoxysilane and an antidandruff agent.

Info

Publication number: WO2012055812A1
Application number: PCT/EP2011/068531
Authority: WO
Inventors: Samira Khenniche; Grégory Plos
Original assignee: L'oreal
Priority date: 2010-10-26
Filing date: 2011-10-24
Publication date: 2012-05-03
Also published as: FR2966357A1

Abstract

The invention relates to a cosmetic composition comprising: - from 0.1% to 20% by weight, relative to the total weight of the composition, of one or more fatty-chain alkoxysilanes of formula (I) : R₁Si(OR₂)₃ in which R₁ represents a linear or branched alkyl or alkenyl group, comprising from 7 to 18 carbon atoms, and R₂ represents a linear or branched alkyl group comprising from 1 to 6 carbon atoms, and - one or more antidandruff agents. The invention also relates to an antidandruff and cosmetic treatment process using the said composition, and also to the use of the said composition as an antidandruff composition.

Description

Cosmetic composition comprising a fatty-chain alkoxysilane and an antidandruff agent

The present invention relates to a cosmetic composition compri sing one or more fatty-chain alkoxysilanes and one or more antidandruff agents .

The present invention al so relates to the use of the sai d composition for the cosmetic treatment of keratin fibres, such as human keratin fibres and in particular the hair, and al so to a cosmetic process for treating keratin fibres using such a composition.

In the field of cosmetic haircare, it i s common practice to care for keratin fibres subj ected to various external attacking factors. Specifically, these fibres may be subj ect to attacks of various origins, such as mechanical attack, for example linked to di sentangling or blow-drying, or alternatively chemical attack, for example following dyeing or permanent-waving.

These attacks have consequences on the qualities of the keratin fibre and may lead to difficult di sentangling at the time of washing the hair, on wet and/or dry hair, and al so to degradation of the surface properties of the fibres, which become rough, dry and irregular at the surface, more particularly when the hair is dry.

Moreover, dandruff problems affect up to 50% of the worldwide population. The appearance of dandruff i s an inconvenience, in particular from an aesthetic viewpoint.

Care products exi st that can limit these phenomena. However, these solutions are not always sufficiently effective and are not sufficiently shampoo-resistant.

The prior-art compositions that can facilitate di sentangling by softening the keratin fibre and that afford glo ss, softness and uniformity to dry hair essentially compri se cationic surfactants, fatty sub stances, silicones and cationic polymers.

After having been applied, these compositions are rinsed out, and the cosmetic conditioning agents and antidandruff agents, which are only lightly deposited on the keratin fibres, are generally removed at the time of the next wash.

Thus, the application of these compositi ons must be repeated after each wash, in order to treat the hair and the scalp and to facilitate their conditioning.

There i s thus a need for compositions that can form a material or for effecting the penetration of care active agents uniformly onto and/or into keratin fibres, in a manner that i s resi stant to shampooing several times, whil e at the same time depositing antidandruff agents uniformly onto the scalp and making these deposits resi stant to shampooing several times.

International patent application WO 2004/012 691 di scloses the cosmetic use of silanes for improving the condition of the hair.

Patent application EP 0 1 59 628 proposes compositions for reinforcing the elasticity of the hair, compri sing an alkyltrialkoxysilane.

Moreover, patent application EP 1 736 139 describes a hair treatment composition compri sing an alkoxysilane, an organic aci d and water, the pH of the composition being between 2 and 5.

Finally, patent application EP 0 877 027 di scloses a composition comprising an organosilane and a particular polyol.

The Applicant has now di scovered, surpri singly, that a combination of a particular fatty-chain alkoxysilane with at least one antidandruff agent can afford efficient and long-lasting treatment of the hair, and thus facilitate its conditioning.

In particular, such a composition makes it possible, firstly, to greatly limit, or even to prevent, the appearance of dandruff, and, secondly, to give the head of hair good cosmetic properties, in a manner that i s resi stant to shampooing several times.

One subj ect of the present invention is thus a cosmetic composition comprising :

- from 0. 1 % to 20% by weight, relative to the total weight of the composition, of one or more fatty-chain alkoxy silanes of formula (I) b elow : Ri Si(OR₂)₃ (I) in which Ri represents a linear or branched alkyl or alkenyl group, compri sing from 7 to 1 8 carbon atoms, and R₂ represents a linear or branched alkyl group compri sing from 1 to 6 carbon atoms, and

one or more antidandruff agents .

The present invention further concerns a cosmetic composition, obtainable by mixing the following ingredients :

- from 0. 1 % to 20% by weight, relative to the total weight of the composition, of one or more fatty-chain alkoxy silanes of formula

(I) b elow :

Ri Si(OR₂)₃ (I) in which Ri represents a linear or branched alkyl or alkenyl group, compri sing from 7 to 1 8 carbon atoms, and R₂ represents a linear or branched alkyl group compri sing from 1 to 6 carbon atoms, and

- one or more antidandruff agents.

Thi s particular combination proves to b e particularly suitable for caring for the hair and al so makes it possible to obtain very good working qualities such as particularly easy application and good rinseability.

The composition according to the invention allows the removal of dandruff and affords the head of hair excell ent cosmetic properties, and in particular promotes di sentangling, suppleness, lightness and smoothness of the hair, and also the homogeneity of the keratin fibre.

In addition, the feel of the hair after treatment using the composition according to the invention i s particularly pleasant.

Finally, the antidandruff properties obtained using the composition according to the invention are shampoo-resi stant.

Another subj ect of the invention consi sts of an antidandruff and cosmetic process for treating the hair using a composition according to the invention. In particular, the composition according to the invention may be rinsed out or left in, optionally applied under the effect of heat, and optionally combined with chemical and/or mechanical hair treatments .

A subj ect of the invention i s al so the use of the composition according to the invention as an antidandruff composition, especially for the antidandruff and cosmetic treatment of the hair.

Other subj ect-matters, characteristics, aspects and advantages of the invention will become even more clearly apparent on reading the description and examples which follow.

According to the invention, the composition compri ses from

0. 1 % to 20% by weight, relative to the total weight of the composition, of one or more fatty-chain alkoxysilanes and one or more antidandruff agents .

The fatty-chain alkoxysilane(s) that may be used in the composition according to the invention are those corresponding to formula (I) b elow :

Ri Si(OR₂)₃ (I) in which R¹ represents a linear or branched alkyl or alkenyl group compri sing from 7 to 1 8 carbon atoms, and R₂ represents a linear or branched alkyl group compri sing from 1 to 6 carb on atoms and preferably from 1 to 4 carbon atoms, and even more preferentially the ethyl group .

Said fatty-chain alkoxysilane can b e present in the composition under the form of a compound of formul a (I) ab ove, and/or under the form of one or more oligomer(s) of such a compound.

Ri being an alkyl or alkenyl group and R₂ being an alkyl group, these group s compri se only carbon and hydrogen atoms .

Preferably, R₂ denotes an alkyl group compri sing from 1 to 4 carbon atoms, better still a linear alkyl group compri sing from 1 to 4 carbon atoms, and better still the ethyl group .

Preferably, Ri represents an alkyl group and even more preferentially a linear alkyl group . Preferably, the fatty-chain alkoxysilane i s chosen from octyltriethoxysilane, dodecyltriethoxysilane, octadecyltriethoxysilane and hexadecyltriethoxysilane.

More particularly, the fatty-chain alkoxysilane according to the invention i s octyltriethoxy silane (OTES).

The alkoxysilane(s) of formula (I) are present in the composition according to the invention in proportions ranging from 0. 1 % to 20% by weight, more preferentially from 0.5% to 1 8% by weight and better still from 2% to 1 5% by weight, relative to the total weight of the composition.

According to the present invention, the composition compri ses one or more antidandruff agents .

The antidandruff agents that may b e used according to the invention are especially chosen from the families ( 1 ) to ( 10) below:

1 ) pyridinethione salts, especially the calcium, magnesium, barium, strontium, zinc, cadmium, tin and zirconium salts . The zinc salt of pyridinethione i s particularly preferred.

The zinc salt of pyridinethione i s sold especi ally under the name Omadine zinc by the company Arch Personal Care.

2) l -hydroxy-2-pyridone derivatives represented especially by formula (II);

in which R₉ represents an alkyl group containing from 1 to 1 7 carb on atoms, an alkenyl group containing from 2 to 17 carbon atoms, a cycloalkyl group containing from 5 to 8 carbon atoms, a bicycloalkyl group containing from 7 to 9 carbon atoms; a cycloalkylalkyl group, an aryl group, an aralkyl group with an alkyl containing from 1 to 4 carbon atoms, an arylalkenyl group with an alkenyl containing from 2 to 4 carbon atoms, aryloxyalkyl or arylmercaptoalkyl with an alkyl containing from 1 to 4 carbon atoms, a furylalkenyl group with an alkenyl containing from 2 to 4 carb on atoms, an alkoxy group containing from 1 to 4 carbon atoms, a nitro group, a cyano group or a halogen atom.

Ri o represents a hydrogen atom, a C ₁ -C₄ alkyl group, a C₂ - C 4 alkenyl group, a halogen atom, a phenyl group or a benzyl group;

Y represents an organic base, an alkali metal or alkaline-earth metal ion or an ammonium ion.

Examples of compounds of formula (II) include l -hydroxy-4- methyl-2-pyridone, 1 - hydroxy-6-methyl-2-pyridone, 1 - hydroxy- 4, 6 - dimethyl-2-pyridone, 1 -hydroxy-4-methyl -6-(2,4,4-trimethylpentyl)-2- pyridone, 1 -hydroxy-4-methyl-6-cyclohexyl-2-pyridone, l -hydroxy-4- methyl-6-(methylcyclohexyl)-2-pyridone, 1 -hydroxy-4-methyl-6-(2- bicyclo[2,2, 1 ]heptyl)-2-pyridone, 1 -hydroxy-4-methyl-6-(4-methyl- phenyl) -2 -pyridone, 1 - hydroxy-4-methyl-6- [ 1 - (4-nitrophenoxy)butyl] - 2 -pyridone, 1 - hydroxy-4-methyl-6-(4-cyanophenoxymethyl)-2- pyridone, 1 -hydroxy-4-methyl-6-(phenyl sulfonylmethyl)-2-pyridone and 1 -hydroxy-4-methyl-6-(4-bromo-benzyl)-2-pyridone.

The compounds of formula (II) may be used in the form of salts with organic or mineral bases.

Examples of organic bases are especially alkanolamines of low molecular weight such as ethanolamine, diethanolamine, N- ethylethanolamine, triethanolamine, diethylaminoethanol and 2-amino- 2-methylpropanediol; non-volatile b ases such as ethylenediamine, hexamethylenediamine, cyclohexylamine, benzylamine and N- methylpiperazine; quaternary ammonium hydroxides, e .g. trimethylbenzyl hydroxide; guanidine and derivatives thereof, and particularly alkyl derivatives thereof. Examples of mineral bases are especially salts of alkali metal s, e. g. sodium or potassium; ammonium salts, salts of an alkaline-earth metal, e .g . magnesium or calcium; salts of di-, tri- or tetravalent cationic metals, e.g. zinc, aluminium zirconium.

Alkanolamines, ethylenediamine and mineral bases such alkali metal salts are preferred.

A compound of formula (II) that is particularly preferred is one for which:

R-9 denotes a group

CH₃— C-CH₂-CH-CH₂- CH₃

Rio denotes a methyl group, and

X⁺ denotes N⁺H₃CH₂CH₂OH.

This compound is sold, for example, under the name Octopirox (1 -hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2-pyridone,

monoethanolamine salt) by the company Hoechst.

3) 2,2'-dithiobis(pyridine N-oxide) of formula (III):

The compounds of formula (III) may be introduced into the compositions in the form of mineral salts. An example of a mineral salt is magnesium sulfate.

4) the trihalocarbamides especially of formula (IV) below:

in which Z represents a halogen atom such as chlorine or a C₁-C₄ trihaloalkyl group such as CF₃; 5) triclo san, represented by formula (V) :

6) azole compounds such as climbazole, ketoconazole, clotrimazole, econazole, i soconazole and miconazole,

7) antifungal polymers such as amphotericin B or nystatin;

8) selenium sulfides, in particular those of formula S_xSes-x, x ranging from 1 to 7;

9) extracts of one or more non-photosynthetic, non-fruiting filamentous b acteria,

The b acteri al extracts that may be used according to the invention will be chosen from non-photosynthetic, non-fruiting filamentous bacteria as defined according to the classification in Bergey ' s Manual of Systemic Bacteriology, volume 3 , section 23 , 9th edition 1989.

Among the bacteria that may be used, mention will be made more particularly of bacteria b elonging to the order B eggiatoales, and especially bacteria belonging to the genus Beggiotoa, for instance various strains of Beggiotoa alba. According to the definition, B. alba corresponds to the former names Beggiotoa arachnoidea, B. gigantea, B. leptomiformis, B. minima and B. mirabilis of Bergey ' s manual, 8th edition. Mention may moreover be made of bacteria belonging to the genus Vitreoscilla, which i s known to be close to and often difficult to di stingui sh from the genus Beggiatoa. The bacteria that have j ust been defined, and several of which have been described, generally have an aquatic habitat, and may be found especially in spring water sources .

Among of bacteria that may be used, mention may be made, for example, of Vitreoscilla beggiatoides (ATCC 43 1 8 1 ) and Beggiatoa alba (ATCC33555) . Preferentially, according to the invention, the use of the extract of Vitreoscilla filiformi s, in particular the strain ATCC 1 555 1 , metabolites thereof and fractions thereof, are claimed.

Moreover, it i s known that culturing non-photosynthetic, non- fruiting filamentous bacteria i s relatively difficult, as i s the production of pure cultures . Use will preferentially be made of the culture described in patent application WO 94/021 58.

The term "non-photosynthetic, non-fruiting fil amentous bacteria" means not only the culture supernatant but al so the biomas s obtained after culturing the said b acteria, the envelopes or envelope fractions, or the extracts of the biomass obtained by treating thi s biomass.

To prepare the extract according to the invention, the said bacteria can be cultured and then separated from the biomass obtained, for example by filtration, centrifugation, coagulation and/or lyophilization.

The extracts that may be used may especially be prepared according to the process described in patent application WO-A- 93/00741 . Thus, after culturing, the bacteria are concentrated by centrifugation. The biomass obtained i s autoclaved. Thi s biomass may be lyophilized to constitute what is known as the lyophilized extract. Any lyophilization method known to those skilled in the art may be used to prepare this extract.

The supernatant fraction of this biomass may al so b e filtered in a sterile container to remove the particles in suspension.

The terms " envelopes" and " envelope fractions" refer herein to the bacterial wall and possibly the subj acent membranes .

10) other antidandruff agents are sulfur in its various forms, cadmium sulfide, allantoin, coal or wood tars and derivatives thereof, in particular cade oil, salicylic acid, undecylenic acid, fumaric acid, ellagic acid, ellagic acid tannins, and allylamines such as terbinafine.

Even more preferentially, the antidandruff agents that may be used in the invention are chosen from pyridinethione salts, 1 -hydroxy- 2-pyridone derivatives, 2,2'-dithiobi s(pyridine N-oxide) and sel enium sulfides, and mixtures thereof.

Zinc pyridinethione, 1 -hydroxy-4-methyl-6-(2,4,4- trimethylpentyl)-2-pyridone and salts thereof and selenium sulfides are particularly preferred.

The antidandruff agent(s) are present in the composition according to the invention in proportions ranging from 0.001 % to 10% by weight, more preferentially from 0. 1 % to 5% by weight and better still from 0.2% to 2% by weight, relative to the total weight of the composition.

Preferably, the antidandruff agent(s) are present in the compositions according to the invention such that the weight ratio between the amount of fatty-chain alkoxysilane(s), on the one hand, and the amount of antidandruff agent(s), on the other hand, i s preferably greater than or equal to 0. 1 .

In one preferred embodiment, the weight ratio between the amount of fatty-chain alkoxysilane(s), on the one hand, and the amount of antidandruff agent(s), on the other hand, ranges from 0. 1 to 50, preferably from 1 to 50 and better still from 1 to 20.

The composition according to the invention may al so compri se one or more organic or mineral acids .

The term "organic acid" means any non-polymeric organi c compound comprising two or more than two carbon atoms and one or more acid functions chosen from carboxylic acid, sulfonic acid and phosphoric acid functions.

Preferentially, the organic acid i s not a surfactant.

Even more preferentially, the molecular weight of the organi c acid is less than 250 and better still less than 200.

Even more preferentially, the organic acids according to the invention are carboxylic acids and a-hydroxylated carboxylic acids or AHAs.

The organic acids may be amino acids.

The organic acid(s) are preferably chosen from acetic acid, propanoic acid, butanoic aci d, lactic acid, malic acid, glycolic acid, ascorbic acid, maleic acid, phthalic acid, succinic acid, aspartic acid, taurine, tartaric acid, arginine, glycine, glucuronic acid, gluconic acid and citric acid.

Even more preferentially still, the organic acid used in the composition according to the invention is chosen from acetic acid, citric acid, lactic acid, malic acid, succinic acid and aspartic acid, and i s preferably lactic acid.

In the composition, the organic aci d(s) may be in free or salified form .

The term "mineral acid" means any acid derived from a mineral compound. Among the mineral acids, mention may be made especially of hydrochloric acid, orthophosphoric acid, sulfuric acid, sulfonic acids and nitric acid.

Preferably, the organic or mineral acid(s) used in the present invention are chosen from lactic acid, citric acid, malic acid, acetic acid, succinic acid, aspartic acid, phosphoric acid and hydrochloric acid.

The mineral or organic acid(s) that may be used in the composition according to the present invention may be present in a content, expressed as free acids, ranging from 0.01 % to 10% by weight, preferably in a content ranging from 0.01 % to 5% by weight and even more preferentially in a content ranging from 0.01 % to 3 % by weight relative to the total weight of the composition.

According to one preferred embodiment, the composition according to the invention al so compri ses one or more thickeners .

For the purposes of the present invention, the term "thickener" means an agent which, when introduced at 1 % by weight in an aqueous solution or an aqueous-alcoholic solution containing 30% ethanol, and at pH 7, makes it possible to achieve a vi scosity of at least 100 mPa. s ( 100 cPs) and preferably of at least 500 mPa. s (500 cPs), at 25 °C and at a shear rate of 1 s^{" 1}. Thi s vi scosity may be measured using a cone/plate vi scometer (Haake R600 rheometer or the like) .

The thickener or thickeners may be selected from fatty acid amides obtained from C 10 - C30 carboxylic acid such as monoi sopropanolamide, diethanolamide or monoethanolamide of coconut acids, monoethanolamide of ethoxylated carboxylic alkyl ether acid, nonionic cellulo se-based thickeners (hydroxyethylcellulo se, hydroxypropylcellulose, carb oxymethylcellulose), guar gum and its nonionic derivatives such as hydroxypropyl guar, gums of microbial origin such as xanthan gum, scleroglucan gum, crosslinked homopolymers and copolymers b ased on acrylic acid, methacrylic acid or acrylamidopropanesulfonic acid, and associative polymers, especially acrylic associative polymers or polyurethanes, as described below.

The associative polymer(s) that can be used according to the invention are water-soluble or water-dispersible polymers which, in an aqueous medium, are capable of reversible association with one another or with other molecules.

Their chemical structure compri ses hydrophilic zones and hydrophobic zones characterized by at least one fatty chain preferably compri sing from 10 to 30 carbon atoms .

The associative polymer(s) that may be used according to the invention may be of anionic, cationic, amphoteric or nonionic type, for instance the polymers sold under the names Pemulen TR1 or TR2 by the company Goodrich, the INCI name of which i s Acrylates/C 10-30 Alkyl Acrylate Crosspolymer, Salcare SC90 by the company Ciba, Aculyn 22, 28, 33 , 44 or 46 by the company Rohm & Haas, and Elfacos T210 and T212 by the company Akzo.

Among the cited thickeners, use i s preferably made of nonioni c cellulo se-based thickeners, such as hydroxyethylcellulo se, guar gum and xanthan gum, and associative polymers such as acrylic acid/stearyl methacrylate copolymers, crosslinked acrylic acid/ alkyl acrylate s copolymers, and copolymers of dicyclohexylmethane dii socyanate (SMDI)/alkyl-terminated polyethylene glycol.

Preferably, the composition according to the invention compri ses from 0. 1 % to 20% by weight and better still from 0.2% to 10%) by weight of thickener(s) relative to the total weight of the composition. The composition according to the invention may al so compri se one or more anionic surfactants .

The term "anionic surfactant" means a surfactant compri sing, as ionic or ionizable groups, only anionic groups . These anionic groups are preferably chosen from -C0₂H, -C0₂ ^", - S O₃H, - S O₃ ^", -O S O3H, -O S O3 ^", -H2-PO3 , -HPO3 ^", -PO3^{2 "}, -H2PO2, =HP0₂, -HP0₂ ^", =P0₂ ^", =POH and =PO^" groups .

Mention may be made, as examples of anionic surfactants that may be used in the composition according to the invention, of alkyl sulfates, alkyl ether sulfates, alkylamido ether sulfates, alkylaryl polyether sulfates, monoglyceride sulfates, alkyl sulfonates, alkylamidesulfonates, alkylaryl sulfonates, a-olefin sulfonates, paraffin sulfonates, alkyl sulfosuccinates, alkyl ether sulfosuccinates, alkylamide sulfosuccinates, alkyl sulfoacetates, acyl sarcosinates, acylglutamates, alkyl sulfosuccinamates, acyli sethionates and N- acyltaurates, polyglycoside polycarb oxylic acid and alkyl monoester salts, acyl lactylates, salts of D-gal actoside uronic acids, salts of alkyl ether carboxylic acids, salts of alkylaryl ether carboxylic acids, salt s of alkylamido ether carboxylic acids; and the corresponding non- salified forms of all these compounds; the alkyl and acyl groups of all these compounds comprising from 6 to 24 carbon atoms and the aryl group denoting a phenyl group .

These compounds may be oxyethylenated and then preferably compri se from 1 to 50 ethylene oxide units.

The salts of C₆-C₂4 alkyl monoesters of polyglycoside- polycarboxylic acids can be selected from C₆-C₂4 alkyl polyglycoside- citrates, C₆-C₂4 alkyl polyglycoside-tartrates and C₆-C₂4 alkyl poly glycoside- sulfo succinates .

When the anionic surfactant(s) are in salt form, they may be chosen from alkali metal salts such as the sodium or potassium salt and preferably the sodium salt, the ammonium salts, the amine salts and in particular amino alcohol salts or the alkaline-earth metal salt s such as the magnesium salts . Examples of amino alcohol salts that may especially b e mentioned include monoethanolamine, diethanolamine and triethanolamine salts, monoisopropanolamine, dii sopropanolamine or triisopropanolamine salts, 2-amino-2-methyl- 1 -propanol salts, 2- amino-2-methyl- l , 3 -propanediol salts and tri s(hydroxymethyl)aminomethane salts.

Alkali metal or alkaline-earth metal salts and in particular the sodium or magnesium salts are preferably used.

Among the anionic surfactants mentioned, use i s preferably made of (C₆ - C24)alkyl sulfates, (C₆ - C24)alkyl ether sulfates compri sing from 2 to 50 ethylene oxide units, especially in the form of alkali metal, ammonium, amino alcohol and alkaline-earth metal salts, or a mixture of these compounds.

It i s particularly preferred to use (C i 2 - C2o)alkyl sulfates, (C ₁₂- C2o)alkyl ether sulfates comprising from 2 to 20 ethylene oxide units, especially in the form of alkali metal, ammonium, amino alcohol and alkaline-earth metal salts, or a mixture of these compounds . B etter still, use is made of sodium lauryl ether sulfate containing 2.2 mol of ethylene oxide.

When they are present, the amount of the anionic surfactant(s) preferably ranges from 0.01 % to 20% by weight, more preferably from 0.2% to 10%) by weight, relative to the total weight of the composition.

In one particular embodiment, the composition according to the invention may al so compri se one or more additives chosen from cationic, nonionic, amphoteric and zwitterionic surfactants, alkoxysilanes other than those of formula (I), non-siliceous fatty sub stances, silicones, cationic polymers, solid particl es other than antidandruff agents, reducing agents and oxidizing agents .

The cationic surfactant(s) that can be used in the compositions of the present invention compri se, for example, salts of optionally polyoxyalkylenated primary, secondary or tertiary fatty amines, quaternary ammonium salts, and mixtures thereof.

Exampl es of quaternary ammonium salts that may especially b e mentioned include : - those corresponding to the general formula (VI) below:

in which the groups R₈ to Rn, which may be identical or different, represent a linear or branched aliphatic group comprising from 1 to 30 carbon atoms or an aromatic group such as aryl or alkylaryl, at least one of the groups R₈ to Rn comprising from 8 to 30 carbon atoms and preferably from 12 to 24 carbon atoms. The aliphatic groups may comprise heteroatoms such as, in particular, oxygen, nitrogen, sulfur and halogens.

The aliphatic groups are chosen, for example, from C₁-C30 alkyl, C1-C30 alkoxy, polyoxy(C2-Ce)alkylene, C1-C30 alkylamide, (Ci₂-C₂₂)alkyl ami do(C₂-C₆)alkyl , (Ci₂-C₂₂)alkylacetate, C₁-C30 hydroxyalkyl, X^" is an anionic counterion chosen from halides, phosphates, acetates, lactates, (Ci-C₄)alkyl sulfates, and (Ci-C₄)alkyl- or (Ci-C₄)alkylarylsulfonates.

Preference is given, among the quaternary ammonium salts of formula (VI), on the one hand, to tetraalkylammonium chlorides, such as, for example, dialkyldimethylammonium or alkyltrimethylammonium chlorides in which the alkyl group comprises approximately from 12 to 22 carbon atoms, in particular behenyltrimethylammonium chloride, distearyldimethylammonium chloride, cetyltrimethylammonium chloride or benzyldimethylstearyl- ammonium chloride, or also, on the other hand, to distearoylethylhydroxyethylmethylammonium methosulfate, dipalmitoylethylhydroxyethylammonium methosulfate or distearoylethylhydroxyethylammonium methosulfate, or also, finally, to palmitylamidopropyltrimethylammonium chloride or stearamidopropyldimethyl(myristyl acetate)ammonium chloride, sold under the name Ceraphyl^® 70 by Van Dyk. - quaternary ammonium salts of imidazoline, such as, for example, those of formula (VII) below:

(VII) in which Ri₂ represents an alkyl or alkenyl group compri sing from 8 to 30 carb on atoms, for example fatty acid derivatives of tallow, Rn represents a hydrogen atom, a C ₁ -C₄ alkyl group or an alkyl or alkenyl group comprising from 8 to 30 carbon atoms, Ri₄ represents a C ₁ -C₄ alkyl group, R15 represents a hydrogen atom or a C ₁ -C₄ alkyl group, X^" i s an anion chosen from the group of halides, phosphates, acetates, lactates, (C ₁ -C₄)alkyl sulfates and (C ₁ -C₄)alkyl- or (C i -C₄)alkylaryl- sulfonates . R₁₂ and Rn preferably denote a mixture of alkyl or alkenyl group s comprising from 12 to 21 carbon atoms, for example tallow fatty acid derivatives, Ri₄ denotes a methyl group, and R15 denotes a hydrogen atom. Such a product is, for example, sold under the name Rewoquat® W 75 by the company Rewo,

- quaternary diammonium or triammonium salts, in particular of formula (VIII) b elow:

(VIII) in which R₁₆ denotes an alkyl group compri sing about 16 to 30 carbon atoms, optionally hydroxylated and/or interrupted with one or more oxygen atoms; Ri₇ is chosen from hydrogen, an alkyl group comprising from 1 to 4 carbon atoms or a group -(CH₂)3-N⁺(Ri6a)(Ri7a)(Ri8a); Riea, Ri7a, Ri8a, Ri8, Ri9, R₂o and R₂1 , which may be identical or different, are chosen from hydrogen and an alkyl group comprising from 1 to 4 carbon atoms, and X^" is an anion chosen from the group of halides, acetates, phosphates, nitrates, (Ci-C4)alkyl sulfates and (Ci- C4)alkyl- or (Ci-C4)alkylaryl-sulfonates, in particular methyl sulfate and ethyl sulfate. Such compounds are, for example, Finquat CT-P, sold by the company Finetex (Quaternium 89), and Finquat CT, sold by the company Finetex (Quaternium 75);

- quaternary ammonium salts comprising one or more ester functions, for instance those of formula (IX) below:

(IX) in which:

R₂₂ is chosen from Ci-C₆ alkyl and Ci-C₆ hydroxyalkyl or dihydroxyalkyl groups;

R₂3 is chosen from:

O

- the group f¾— C—

linear or branched, saturated or unsaturated Ci-C₂₂ hydrocarbon-based groups R₂₇,

- a hydrogen atom,

R₂5 is chosen from:

o

- the group ^R2 C

linear or branched, saturated or unsaturated hydrocarbon-based groups R₂g,

- a hydrogen atom, R24, R26 and R₂8, which may be identical or different, are chosen from linear or branched, saturated or unsaturated C7-C21 hydrocarbon-based groups;

r, s and t, which may be identical or different, are integers ranging from 2 to 6,

rl and tl, which may be identical or different, are equal to 0 or

1,

r2+rl=2r and tl+t2=2t,

y is an integer ranging from 1 to 10,

x and z, which may be identical or different, are integers ranging from 0 to 10,

X^" is a simple or complex, organic or mineral anion,

with the proviso that the sum x + y + z is from 1 to 15, that when x is 0, then R₂3 denotes R27 and that when z is 0, then R₂₅ denotes R29- The alkyl groups R22 may be linear or branched, and more particularly linear.

Preferably, R22 denotes a methyl, ethyl, hydroxyethyl or dihydroxypropyl group, and more particularly a methyl or ethyl group.

Advantageously, the sum x + y + z is from 1 to 10.

When R₂₃ is a hydrocarbon-based group R27, it may be long and contain from 12 to 22 carbon atoms, or may be short and contain from 1 to 3 carbon atoms.

When R25 is a hydrocarbon-based group R29, it preferably contains 1 to 3 carbon atoms.

Advantageously, R24, R26 and R28, which may be identical or different, are chosen from linear or branched, saturated or unsaturated C₁₁-C₂₁ hydrocarbon-based groups, and more particularly from linear or branched, saturated or unsaturated Cn-C₂₁ alkyl and alkenyl groups.

Preferably, x and z, which may be identical or different, have values of 0 or 1.

Advantageously, y is equal to 1.

Preferably, r, s and t, which may be identical or different, are equal to 2 or 3, and even more particularly are equal to 2. The anion X^" is preferably a halide, preferably chloride, bromide or iodide, a (Ci-C4)alkyl sulfate or a (Ci-C4)alkyl- or (Ci- C4)alkylaryl-sulfonate. However, methanesulfonate, phosphate, nitrate, tosylate, an anion derived from an organic acid, such as acetate or lactate, or any other anion that is compatible with the ammonium containing an ester function, may be used.

The anion X^" is even more particularly chloride, methyl sulfate or ethyl sulfate.

Use is made more particularly in the composition according to the invention of the ammonium salts of formula (IX) in which:

- R22 denotes a methyl or ethyl group,

- x and y are equal to 1,

- z is equal to 0 or 1,

- r, s and t are equal to 2,

- R23 is chosen from:

O

• the group R ^x2^■6

· methyl, ethyl or C14-C₂₂ hydrocarbon-based groups,

• a hydrogen atom,

- R25 is chosen from:

• - the group

II

^R28 ^C

• a hydrogen atom,

- R24, R26 and R28, which may be identical or different, are chosen from linear or branched, saturated or unsaturated C₁₃-C₁₇ hydrocarbon-based groups, and more particularly from linear or branched, saturated or unsaturated C₁₃-C₁₇ alkyl and alkenyl groups.

Advantageously, the hydrocarbon-based groups are linear.

Among the compounds of formula (IX), examples that may be mentioned include salts, especially the chloride or methyl sulfate, of diacyloxy ethyl dimethyl ammonium, diacyloxyethylhydroxy- ethyl methyl ammonium, mo noacyloxy ethyl di hydroxy ethyl methyl- ammonium, triacyloxyethylmethylammonium or monoacyloxyethyl- hydroxyethyldimethylammonium, and mixtures thereof. The acyl groups preferably contain 14 to 1 8 carbon atoms and are obtained more particularly from a pl ant oil such as palm oil or sunflower oil. When the compound contains several acyl groups, these groups may b e identical or different.

These products are obtained, for example, by direct esterification of triethanolamine, trii sopropanolamine, an alkyldiethanolamine or an alkyldii sopropanolamine, which are optionally oxyalkylenated, with fatty acids or with fatty acid mixtures of plant or animal origin, or by transesterification of the methyl esters thereof. This esterification is followed by a quaternization by means of an alkylating agent such as an alkyl halide, preferably methyl or ethyl halide, a dialkyl sulfate, preferably methyl or ethyl sulfate, methyl methanesulfonate, methyl para-toluenesulfonate, glycol chlorohydrin or glycerol chlorohydrin.

Such compounds are, for example, sold under the names Dehyquart^® by Henkel, Stepanquat^® by Stepan, Noxamium^® by Ceca or Rewoquat^® WE 1 8 by Rewo-Witco.

The composition according to the invention may contain, for example, a mixture of quaternary ammonium salts of mono-, di- and triesters with a weight maj ority of diester salts.

Mixtures of ammonium salts that can be used include, for example, the mixture containing 1 5% to 30% by weight of acyloxyethyldihydroxyethylmethylammonium methyl sulfate, 45% to 60% of diacyloxy ethylhydroxyethylmethylammonium methyl sulfate and 1 5%) to 30%> of triacyloxyethylmethylammonium methyl sulfate, the acyl groups having from 14 to 1 8 carbon atoms and originating from palm oil, which i s optionally partially hydrogenated.

It is al so possible to use the ammonium salts containing at least one ester function that are described in patents US-A-4 874 554 and US-A-4 137 1 80. Use may be made of behenoylhydroxypropyltrimethyl- ammonium chloride sold by Kao under the name Quartamin BTC 131.

Preferably, the ammonium salts containing at least one ester function contain two ester functions.

Among the cationic surfactants that may be present in the composition according to the invention, it is more particularly preferred to choose cetyltrimethylammonium, behenyltrimethyl- ammonium and dipalmitoylethylhydroxyethylmethylammonium salts, and mixtures thereof, and more particularly behenyltrimethyl- ammonium chloride, cetyltrimethylammonium chloride, and dipalmitoylethylhydroxyethylammonium methosulfate, and mixtures thereof.

When they are present, the amount of the cationic surfactant(s) preferably ranges from 0.01% to 20% by weight and better still from 0.2% to 10%) by weight, relative to the total weight of the composition.

Examples of nonionic surfactants that may be used in the composition used according to the invention are described, for example, in the Handbook of Surfactants by M.R. Porter, published by Blackie & Son (Glasgow and London), 1991, pp. 116-178. They are especially chosen from polyethoxylated, polypropoxylated or polyglycerolated alcohols, a-diols and (Ci-C2o)alkylphenols, containing at least one fatty chain comprising, for example, from 8 to 18 carbon atoms, the number of ethylene oxide and/or propylene oxide groups possibly ranging especially from 2 to 50, and the number of glycerol groups possibly ranging especially from 2 to 30.

Mention may also be made of copolymers of ethylene oxide and propylene oxide, optionally oxyethylenated fatty acid esters of sorbitan, fatty acid esters of sucrose, polyoxyalkylenated fatty acid esters, optionally oxyalkylenated alkylpolyglycosides, alkylglucoside esters, derivatives of N-alkylglucamine and of N- acylmethylglucamine, aldobionamides and amine oxides.

Unless otherwise mentioned, the term "fatty" compound (for example a fatty acid) denotes a compound comprising, in its main chain, at least one saturated or unsaturated hydrocarbon-based chain, such as alkyl or alkenyl containing at least 8 carbon atoms, preferably from 8 to 30 carbon atoms, and even better still from 10 to 22 carbon atoms.

The mono- or polyglycosides that may be used in the invention are well known and may be represented more particularly by the general formula (AO) below:

Ri O-(R₂0)_t (G)v (AO) in which :

Ri represents a linear or branched alkyl and/or alkenyl group, compri sing from about 8 to 24 carb on atoms, or an alkylphenyl group whose linear or branched alkyl group compri ses from 8 to 24 carbon atoms,

R₂ represents an alkylene group compri sing from about 2 to 4 carbon atoms,

G represents a sugar unit compri sing from 5 to 6 carbon atoms, t denotes a value ranging from 0 to 10 and preferably 0 to 4, preferably 0 to 4, and

v denotes an integer ranging from 1 to 1 5.

Mono- or polyglycosides that are preferred in the present invention are (C₈-C i ₈)alkyl mono- or polyglycosides and are compounds of formula (AO) in which :

Ri more particularly denotes a saturated or unsaturated, linear or branched alkyl group comprising from 8 to 1 8 carbon atoms,

t denotes a value ranging from 0 to 3 and even more particularly i s equal to 0,

G may denote glucose, fructose or galactose, preferably glucose.

The degree of polymerization, i. e. the value of v in formula

(AO), may range from 1 to 1 5 and preferably from 1 to 4. The average degree of polymerization i s more particularly between 1 and 2 and even more preferentially from 1 . 1 to 1 .5. The glycoside bonds between the sugar units are of 1-6 or 1-4 type and preferably of 1-4 type.

Examples of compounds of formula (AO) are especially caprylylglucoside, decylglucoside or caprylglucoside, laurylglucoside, cetearylglucoside and cocoglucoside, and mixtures thereof. These preferred compounds of formula (AO) are especially represented by the products sold by the company Cognis under the names Plantaren® (600 CS/U, 1200 and 2000) or Plantacare® (818, 1200 and 2000). It is also possible to use the products sold by the company SEPPIC under the names Triton CG 110 or Oramix CG 110 and Triton CG 312 or Oramix® NS 10, the products sold by the company BASF under the name Lutensol GD 70 or those sold by the company Chem Y under the name AGIO LK.

It is also possible to use, for example, (C₈-Ci₆)alkyl-1,4- polyglucoside as an aqueous 53% solution, sold by the company Cognis under the reference Plantacare® 818 UP.

When they are present, the amount of the nonionic surfactant or surfactants varies preferably from 0.01% to 20% by weight, more preferably from 0.2% to 10% by weight, relative to the total weight of the composition.

The amphoteric or zwitterionic surfactant(s), which are preferably nonsilicone, which can be used in the present invention may especially be derivatives of optionally quaternized aliphatic secondary or tertiary amines, in which the aliphatic group is a linear or branched chain comprising from 8 to 22 carbon atoms, said amine derivatives containing at least one anionic group, for instance a carboxylate, sulfonate, sulfate, phosphate or phosphonate group. Mention may be made in particular of (C8-C2o)alkylbetaines, sulfobetaines, (C₈- C2o)alkylamido(C3-C₈)alkylbetaines and (C₈-C2o)alkylamido(C6- C₈)alkylsulfobetaines.

Among the optionally quaternized secondary or tertiary aliphatic amine derivatives that can be used, as defined above, mention may also be made of the compounds of respective structures (Al) and (A2): R_aCONHCH2CH2N⁺(Rb)(Rc)(CH₂COO^") (Al) in which:

R_a represents a C10-C30 alkyl or alkenyl group derived from an acid R_aCOOH preferably present in hydrolysed coconut oil, or a heptyl, nonyl or undecyl group;

Rb represents a β-hydroxyethyl group, and

R_c represents a carboxymethyl group;

and

R_a>CONHCH₂CH2N(B)(B') (A2) in which:

B represents the group -CH₂CH₂OX',

B' represents the group -(CH₂)_ZY', with z = 1 or 2,

X' represents the group -CH₂COOH, CH₂COOZ', -CH2CH2COOH, -CH2CH2COOZ', or a hydrogen atom,

Y' represents the group -COOH, -COOZ', the group -CH2-CHOHSO₃H or the group -CH₂CHOHS0₃Z' ,

Z' represents an ion resulting from an alkali metal or alkaline earth metal, such as sodium, an ammonium ion or an ion resulting from an organic amine,

R_a' represents a C10-C30 alkyl or alkenyl group of an acid Ra_'COOH preferably present in coconut oil or in hydrolysed linseed oil, an alkyl group, especially of C₁₇ and its iso form, or an unsaturated C₁₇ group.

These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the names disodium cocoamphodiacetate, disodium lauroamphodiacetate, disodium caprylamphodiacetate, disodium capryloamphodiacetate, disodium cocoamphodipropionate, disodium lauroamphodipropionate, disodium caprylamphodipropionate, disodium capryloamphodipropionate, lauroamphodipropionic acid and cocoamphodipropionic acid. By way of example, mention may be made of the cocoamphodiacetate sol d by the company Rhodia under the trade name Miranol^® C2M Concentrate.

Among the amphoteric or zwitterionic surfactants mentioned above, use is preferably made of (C ₈ - C2o)alkylb etaines such as cocoylbetaine, and (C₈ - C2o)alkylamido(C3 -C₈)alkylbetaines such as cocamidopropylbetaine, and mixtures thereof. More preferentially, the amphoteric or zwitterionic surfactant(s) are chosen from cocamidopropylbetaine and cocoylbetaine.

When they are present, the amount of the amphoteric or zwitterionic surfactant(s) preferably ranges from 0.0 1 % to 20% by weight and better still from 0.2% to 10% by weight, relative to the total weight of the composition.

Other alkoxysilanes, other than those of formula (I), may b e used in the composition and are preferably compounds of formula (G) 4-_xS i(OR)_x, with x denoting an integer ranging from 1 to 3 , G denoting identical or different monovalent group s and R denoting a monovalent hydrocarbon-based group compri sing one or more carbon atoms and optionally one or more heteroatoms .

Preferably, the alkoxysilane(s), other than the alkoxy silanes of the invention, contain two or three alkoxy functions.

Preferably, the alkoxy function(s) are cho sen from methoxy and ethoxy functions.

According to one particul ar embodiment, the additional alkoxysilane(s) compri se one or more solubilizing functional groups.

For the purposes of the present invention, the term " solubilizing functional group " means any chemical functional group that facilitates the di ssolution of the alkoxysilane in the medium of the composition, i . e. in the solvent or the solvent mixture of the composition, in particular in water or in aqueous-alcoholic mixtures.

As solubilizing functional groups that may be used according to the present invention, mention may be made of primary, secondary and tertiary amine, aromatic amine, alcohol, carboxylic acid, sulfoni c acid, anhydri de, carbamate, urea, guani dine, aldehyde, ester, amide, epoxy, pyrrole, dihydroimidazole, gluconamide, pyridyl and polyether groups.

This or these alkoxysilane(s) containing one or more solubilizing functional groups may contain one or more silicon atoms.

The alkoxysilane(s) containing one or more solubilizing functional groups generally contain two or three alkoxy functions. Preferably, the alkoxy functions are methoxy or ethoxy functions.

According to one particular embodiment, the alkoxysilane(s), other than the alkoxysilanes of the invention, are chosen from the compounds of formula (X) below:

(X) which:

R-6 represents a halogen or a group OR' or R'₆,

R₇ represents a halogen or a group OR" or R'₇,

R₈ represents a halogen or a group OR'" or R'₈,

R₃, R₄, Rs, R\ R", R"\ R'e, R'₇ and R'₈ represent, independently of each other, a saturated or unsaturated, linear or branched hydrocarbon-based group, optionally bearing additional chemical groups, R₃, R₄, R', R" and R'" also possibly denoting hydrogen, at least two of the groups R₆, R₇ and R₈ being different from the groups R'₆, R'7 and R'₈, at least two of the groups R', R" and R'" being other than hydrogen.

Preferably, the groups R₃, R₄, R', R'e, R'7, R'₈, R" and R'" are chosen from C₁-C₁₂ alkyl, C₆-Ci₄ aryl, (Ci-C₈)alkyl(C₆-Ci₄)aryl and (C₆-Ci₄)aryl(Ci-C₈)alkyl groups.

According to one preferred implementation variant of this embodiment, the alkoxysilane(s) comprise a substituent comprising a primary amine function, and are chosen from the compounds of formula (XI) below: OR

/

H₂N(CH₂)_n Si— OR

OR (XI) in which the groups R, which may be identical or different, are chosen from Ci-C₆ alkyl groups, and n is an integer from 1 to 6 and preferably from 2 to 4.

An alkoxysilane that is particularly preferred according to this embodiment is γ-aminopropyl triethoxysilane. Such a product is sold, for example, under the name Z-6011 Silane by the company Dow Corning.

According to another embodiment of the invention, the alkoxysilane(s) are chosen from the compounds of formula (XII):

in which:

Rii represents a halogen or a group OR'n and R₁₂ represents a halogen or a group OR'₁₂, at least one of the groups Rn and R₁₂ being other than a halogen,

R'₁₁ and R'₁₂ represent, independently of each other, hydrogen or a saturated or unsaturated, linear or branched Ci-C , hydrocarbon- based group, at least one of the groups R'n and R'₁₂ being other than hydrogen,

R9 is a non-hydrolysable functional group with a cosmetic effect, and

Rio is a non-hydrolysable functional group bearing a function chosen from the following functions: amine, carboxylic acid and salts thereof, sulfonic acid and salts thereof, polyalcohols such as glycol, polyether such as polyalkene ether, and phosphoric acid and salts thereof.

The term "functional group with a cosmetic effect", means a group chosen from groups derived from a reducing agent, from an oxidizing agent, from a colouring agent, from a polymer, from a surfactant, from an antibacterial agent or from a UV-screening agent.

Examples of groups derived from a colouring agent are, inter alia, aromatic nitro, anthraquinone, naphthoquinone, benzoquinone, azo, xanthene, triarylmethane, azine, indoaniline, indophenol and indoamine groups; examples of groups with a reducing effect are, inter alia, thiol and sulfinic acid groups or a sulfinic acid salt.

An example of an alkoxysilane of formula (XII) that may be mentioned is aminopropyl-N-(4,2- dinitrophenyl)aminopropyldiethoxysilane. Such compounds are described, for example, in patent application EP-1216023.

The alkoxysilane(s), other than the alkoxysilanes of the invention, may also be chosen from the compounds of formula (XIII) below:

in which:

Ri4 represents a halogen or a group OR'_H or R₀,

Ri5 represents a halogen or a group OR'15 or R'₀,

Ri6 represents a halogen or a group OR'i₆ or R"₀,

at least two of the groups R14, R15 and Ri₆ being different from the groups Ro, R'o and R"o,

Ri3 is a group chosen from groups bearing at least one function chosen from the following functions: carboxylic acid and salts thereof, sulfonic acid and salts thereof, polyalkyl ethers (or polyoxyalkylenes).

Ro, R'o, R"o, R'i4, R'i5 and R'i₆ represent, independently of each other, a saturated or unsaturated, linear or branched C1-C14 hydrocarbon-based group, optionally bearing additional chemical functions chosen from the following functions: carboxylic acid and salts thereof, sulfonic acid and salts thereof, polyalkyl ethers, R'₁₄, R'i5 and R'₁₆ also possibly denoting hydrogen, at least two of the groups R'14, R'i5 and R'₁₆ being other than hydrogen,

Preferably, the groups R'14, R'15 and R'₁₆, Ro, R'o and R'O represent a C1-C12 alkyl, C₆-Ci4 aryl, (Ci-C8)alkyl(C6-Ci4)aryl or (C₆- Ci4)aryl(Ci-Cs)alkyl group.

According to another embodiment, the alkoxysilane(s), other than the alkoxysilanes of the invention, are chosen from the compounds of formula (XIV) below:

(R₂iO)_x(R₂₂)_ySi(B)p[NR₂3(B')p']_q[NR'₂₃(B")p"]_q'Si(R'₂₂)_y'(OR'₂i)_x'

(XIV) in which:

R₂i, R₂₂, R'21 and R'₂₂ each independently represent a saturated or unsaturated, linear or branched hydrocarbon-based chain, optionally containing one or more heteroatoms, optionally interrupted or substituted with one or more groups chosen from ether, ester, amine, amide, carboxyl, hydroxyl and carbonyl groups,

x is an integer ranging from 1 to 3, y = 3-x, x' is an integer ranging from 1 to 3, y' = 3-x', p = 0 or 1, p' = 0 or 1, p" = 0 or 1, q = 0 or 1, q' = 0 or 1, it being understood that at least q or q' is other than zero,

B, B' and B" each independently represent a linear or branched divalent Ci-C₂₀ alkylene radical,

R₂₃ and R'₂₃ each independently represent a hydrogen atom or a saturated or unsaturated, linear or branched hydrocarbon-based chain, optionally containing one or more heteroatoms, optionally interrupted or substituted with one or more ether, Ci-C₂₀ alcohol ester, amine, carboxyl, alcoxysilane, C₆-C₃o aryl, hydroxyl or carbonyl groups, or a heterocyclic or non-heterocyclic aromatic ring, optionally substituted with one or more C3-C20 alcohol ester, amine, amide, carboxyl, alcoxysilane, hydroxyl, carbonyl or acyl groups.

As explained previously, R21, R22, R'21 and R'22 each independently represent a hydrocarbon-based chain. The term "hydrocarbon-based chain" preferably means a chain comprising from 1 to 10 carbon atoms.

Similarly, R₂₃ and R'23 may represent a hydrocarbon-based chain. In this case, a chain comprising from 1 to 10 carbon atoms is preferably intended.

Preferably, the aromatic ring comprises from 6 to 30 carbon atoms. Even more preferentially, it denotes an optionally substituted phenyl group.

Preferably, R₂₁ = R'21, R22 = R'22, x = x\ y = y\ p = p\ A = A', q = 1 and q' = 0.

The alkoxysilane(s) of formula (XIV) may also have the following characteristics, taken alone or in combination:

- R21, R22, R'21 and R'22, which may be identical or different, represent a C₁-C₄ alkyl,

- p = p' = 1,

- B and B', which may be identical or different, represent a linear C₁-C₄ alkylene and

- R2₃ is hydrogen.

According to another embodiment of the invention, the alkoxysilane(s), other than the alkoxysilanes of the invention, are chosen from the compounds of formula (XV) below:

in which:

R24 and R25 each independently represent a saturated or unsaturated, linear or branched hydrocarbon-based chain, optionally containing one or more heteroatoms, optionally interrupted or substituted with one or more groups chosen from ether, ester, amine, amide, carboxyl, hydroxyl and carbonyl groups,

x" = 2 or 3,

y" = 3-x",

n^* = 0 or 1,

n" = 0 or 1,

E and E' each independently represent a linear or branched divalent C1-C20 alkylene group,

R₂6 and R₂₇ each independently represent a hydrogen atom or a saturated or unsaturated, linear or branched hydrocarbon-based chain, optionally containing one or more heteroatoms, optionally interrupted or substituted with one or more ether, C1-C20 alcohol ester, amine, carboxyl, alcoxysilane, C6-C30 aryl, hydroxyl or carbonyl groups, or a heterocyclic or non-heterocyclic aromatic ring, optionally substituted with one or more Ci-C₂₀ alcohol ester, amine, amide, carboxyl, alcoxysilane, hydroxyl, carbonyl or acyl groups,

r is an integer ranging from 0 to 4,

r^* = 0 or 1,

the group(s) R₂₈ each independently represent a hydrogen atom or a saturated or unsaturated, linear or branched preferably C1-C10 hydrocarbon-based chain, optionally containing one or more heteroatoms, optionally interrupted or substituted with one or more ether, Ci-C₂₀ alcohol ester, amine, carboxyl, alcoxysilane, C6-C30 aryl, hydroxyl or carbonyl groups, or a heterocyclic or non-heterocyclic aromatic ring, optionally substituted with one or more Ci-C₂₀ alcohol ester, amine, amide, carboxyl, alcoxysilane, hydroxyl, carbonyl or acyl groups.

As explained previously, R₂₄ and R₂₅ each independently represent a hydrocarbon-based chain. The term "hydrocarbon-based chain" preferably means a chain comprising from 1 to 10 carbon atoms. Similarly, R₂₆ and R₂₇ may represent a hydrocarbon-based chain. In this case, a chain comprising from 1 to 10 carbon atoms is preferably intended.

The alkoxysilane(s) of formula (XV) may have the following characteristics, taken alone or in combination:

- R₂4 is a C1-C4 alkyl,

- x" = 3, n'= n" = 1; r = r' = 0,

R₂6 and R₂₇ independently represent hydrogen or a group chosen from C₁-C₄ alkyl, C₁-C₄ hydroxyalkyl and C₁-C₄ aminoalkyl groups.

In particular, the alkoxysilane(s) of formula (XV) may be chosen from:

3-(m-aminophenoxy)propyltrimethoxysilane, of formula:

p-aminophenyltrimethoxysilane, of formula:

- N-(2-aminoethylaminomethyl)phenethyltrimethoxysilane, of formula:

The alkoxysilane(s), other than the alkoxysilanes of the invention, may also be chosen from the compounds of formula (XVI) below:

in which:

R₂9 and R₃₀ each independently represent a saturated or unsaturated, linear or branched hydrocarbon-based chain, optionally containing one or more heteroatoms, optionally interrupted or substituted with one or more groups chosen from ether, ester, amine, amide, carboxyl, hydroxyl and carbonyl groups,

xi = 2 or 3, yi = 3-xi,

Ai represents a linear or branched Ci-C₂₀ divalent alkylene group, optionally interrupted or substituted with one or more Ci-C₃₀ alcohol ester, amine, carboxyl, alkoxysilane, C₆-C₃o aryl, hydroxyl or carbonyl groups,

s = 0 or 1,

As explained previously, R₂g and R₃₀ each independently represent a hydrocarbon-based chain. The term "hydrocarbon-based chain" preferably means a chain comprising from 1 to 10 carbon atoms.

The alkoxysilane(s) of formula (XVI) may also have the following characteristics, taken alone or in combination:

R₂9 and R₃₀ are chosen from C1-C4 alkyls,

s=l,

Ai is a linear C1-C4 alkylene,

In particular, the alkoxysilane(s) of formula (XVI) may be chosen from: - triethoxysilylbutyraldehyde, of formula :

(CH₃ CH₂0)₃ S i(CH₂)3 CH=0

- triethoxysilylundecanal, of formula:

(CH₃ CH₂0)₃ Si(CH₂) ioCH=0 and - triethoxysilylundecanal ethylene glycol acetal, of formula:

(CH₃ CH₂O)₃ Si(CH₂) ₁₀CH(OCH₂)₂.

The preferred compound of formula (XVI) i s triethoxysilylbutyraldehyde . Such a product i s sold, for example, under the name SIT 8 1 85.3 by the company Gelest.

According to one particularly preferred embodiment of the invention, the alkoxysilane(s), other than the alkoxy silanes of the invention, are chosen from the di- and/or trialkoxysilanes bearing one or more sub stituents compri sing one or more amine functions.

According to an even more preferred embodiment, the alkoxysilane(s), other than the alkoxysilanes of the invention, are chosen from trialkoxysilanes bearing a sub stituent compri sing one or more amine functions, more particularly from the compounds of formula (XI) .

An additional alkoxysilane that i s most particularly preferred is γ-aminopropyltriethoxysilane cited previously .

The alkoxysilane(s), other than the alkoxysilanes of the invention, may be present in the compositions according to the invention in proportions preferably ranging from 0.01 % to 25% by weight, more preferentially from 0.05% to 20% by weight and more particularly from 0. 1 % to 10% by weight rel ative to the total weight of the composition. The composition according to the invention may also comprise one or more non-siliceous fatty substances.

The term "fatty substance" means an organic compound that is insoluble in water at standard temperature (25°C) and at atmospheric pressure (760 mmHg, i.e. 1.013xl0⁵ Pa), i.e. with a solubility of less than 5%, preferably of less than 1% and even more preferably of less than 0.1%. The non-siliceous fatty substances generally have in their structure a hydrocarbon-based chain comprising at least 6 carbon atoms and not comprising any siloxane groups. In addition, the fatty substances are generally soluble in organic solvents under the same temperature and pressure conditions, for instance chloroform, ethanol, benzene, liquid petroleum j elly or decamethylcyclopentasiloxane.

The term "non-siliceous fatty substance" means a fatty substance whose structure does not comprise any silicon atoms.

The fatty substances that may be used in the composition according to the invention are generally not oxyalkylenated and preferably do not contain any carboxylic acid COOH functions.

Preferably, the non-siliceous fatty substances of the invention are chosen from hydrocarbons, fatty alcohols, fatty esters, fatty ethers and non-siliceous waxes, and mixtures thereof.

Even more preferentially, they are chosen from hydrocarbons, fatty alcohols, fatty esters and ceramides, and mixtures thereof.

They may be liquid or non-liquid, at room temperature and at atmospheric pressure.

The liquid fatty substances of the invention preferably have a viscosity of less than or equal to 2 Pa.s, better still less than or equal to 1 Pa.s and even better still less than or equal to 0.1 Pa.s at a temperature of 25°C and at a shear rate of 1 s^"1.

The term "liquid hydrocarbon" means a hydrocarbon composed solely of carbon and hydrogen atoms, which is liquid at standard temperature (25°C) and at atmospheric pressure (760 mmHg, i.e. 1.013 x 10⁵ Pa), which is especially of mineral or plant origin, preferably of plant origin.

More particularly, the liquid hydrocarbons are chosen from: - linear or branched, optionally cyclic, C₆ - C i 6 alkanes . Examples that may be mentioned include hexane, undecane, dodecane, tridecane, and i soparaffins, for instance i sohexadecane, i sododecane and i sodecane,

- linear or branched hydrocarbons of mineral, animal or synthetic origin with more than 16 carbon atoms, such as volatile or non-volatile liquid paraffins, petroleum j elly, liquid petroleum j elly, polydecenes, hydrogenated polyi sobutene such as the product sold under the brand name Parleam® by the company NOF Corporation, and squalane.

In one preferred variant, the liquid hydrocarb on(s) are chosen from volatile or non-volatile liquid paraffins, and derivatives thereof, and liquid petroleum j elly .

The term "liquid fatty alcohol" means a non-glycerolated and non-oxyalkylenated fatty alcohol, whi ch i s liquid at standard temperature (25 °C) and at atmospheric pressure (760 mmHg, i . e . 1 .013 x 10⁵ Pa) .

Preferably, the liquid fatty alcohols of the invention compri se from 8 to 30 carbon atoms.

The liquid fatty alcohol s of the invention may be saturated or unsaturated.

The saturated liquid fatty alcohol s are preferably branched. They may optionally compri se in their structure at least one aromatic or non-aromatic ring. They are preferably acyclic.

More particularly, the liquid saturated fatty alcohol s of the invention are chosen from octyldodecanol, i sostearyl alcohol and 2- hexyldecanol.

Octyldodecanol is mo st particularly preferred.

The unsaturated liquid fatty alcohols contain in their structure at least one double or triple bond, and preferably one or more double bonds. When several double bonds are present, there are preferably 2 or 3 of them, and they may be conj ugated or unconj ugated.

These unsaturated fatty alcohol s may be linear or branched. They may optionally comprise in their structure at least one aromatic or non-aromatic ring. They are preferably acyclic.

More particularly, the unsaturated liquid fatty alcohols of the invention are chosen from oleyl alcohol, linoleyl alcohol, linolenyl alcohol and undecylenyl alcohol.

Oleyl alcohol is mo st particularly preferred.

The term "liquid fatty esters" means an ester derived from a fatty acid and/or from a fatty alcohol that i s liquid at standard temperature (25 °C) and at atmospheric pressure (760 mmHg, i. e . 1 .01 3 10⁵ Pa) .

The esters are preferably liquid esters of saturated or unsaturated, linear or branched C i -C₂₆ aliphatic monoacids or polyacids and of saturated or unsaturated, linear or branched C i -C₂6 aliphatic monoalcohol s or polyalcohol s, the total number of carbon atoms of the esters being greater than or equal to 10.

Preferably, for the esters of monoalcohol s, at least one from among the alcohol and the acid from which the esters of the invention are derived i s branched.

Among the monoesters of monoacids and of monoalcohol s, mention may be made of ethyl palmitate, i sopropyl palmitate, alkyl myristates such as isopropyl myri state or ethyl myri state, i socetyl stearate, 2-ethylhexyl i sononanoate, isononyl i sononanoate, isodecyl neopentanoate and i sostearyl neopentanoate .

Esters of C₄-C₂₂ dicarboxylic or tricarb oxylic acids and of C i - C₂₂ alcohol s and esters of monocarboxylic, dicarboxylic or tricarboxylic acids and of C₄-C₂₆ dihydroxy, trihydroxy, tetrahydroxy or pentahydroxy non-sugar alcohol s may al so be used.

Mention may be made especially of: diethyl sebacate; dii sopropyl sebacate; bi s(2-ethylhexyl) sebacate; dii sopropyl adipate; di-n-propyl adipate; dioctyl adipate; bi s(2-ethylhexyl) adipate; dii so stearyl adipate; bi s(2-ethylhexyl) maleate; trii sopropyl citrate; trii socetyl citrate; trii sostearyl citrate; glyceryl trilactate; glyceryl trioctanoate; trioctyldodecyl citrate; trioleyl citrate; neopentyl glycol diheptanoate; diethylene glycol dii sononanoate. The composition may al so compri se, as liquid fatty ester, sugar esters and diesters of C6 - C30 and preferably C 12 - C22 fatty aci ds. It i s recalled that the term " sugar" means oxygen-bearing hydrocarbon- based compounds containing several alcohol functions, with or without al dehyde or ketone functions, and which compri se at least 4 carbon atoms. These sugars may be monosaccharides, oligosacchari des or polysaccharides .

Examples of suitabl e sugars that may be mentioned include sucrose, glucose, galactose, ribose, fucose, maltose, fructose, manno se, arabinose, xylose and lactose, and derivatives thereof, especially alkyl derivatives, such as methyl derivatives, for instance methylglucose.

The sugar esters of fatty acids may be chosen especially from the group compri sing the esters or mixtures of esters of sugars described previously and of linear or branched, saturated or unsaturated C6 - C30 and preferably C 12 - C22 fatty acids . If they are unsaturated, these compounds may compri se one to three conj ugated or unconj ugated carbon-carbon double bonds.

The esters according to this variant may al so be chosen from mono-, di-, tri- and tetraesters, and polyesters, and mixtures thereof.

These esters may be chosen, for example, from oleates, laurates, palmitates, myristates, behenates, cocoates, stearates, linoleates, linolenates, caprates and arachidonates, or mixtures thereof, such as, in particular, oleopalmitate, oleostearate or palmitostearate mixed esters .

More particularly, use i s made of monoesters and diesters and in particular of sucrose, glucose or methylglucose mono- or dioleates, stearates, behenates, oleopalmitates, linoleates, linolenates or oleostearates .

An example that may be mentioned i s the product sold under the name Glucate® DO by the company Amerchol, which i s a methylglucose dioleate .

Finally, use may al so b e made of natural or synthetic glycerol esters of mono-, di- or triacids . Among these, mention may be made of plant oil s.

As oils of plant origin or synthetic triglycerides that may b e used in the composition of the invention as liquid fatty esters, examples that may be mentioned include :

- triglyceride oil s of plant or synthetic origin, such as liquid triglycerides of fatty acids containing from 6 to 30 carbon atoms, for instance heptanoic or octanoic acid triglycerides, or alternatively, for example, sunflower oil, corn oil, soybean oil, marrow oil, grapeseed oil, sesame seed oil, hazelnut oil, apricot oil, macadamia oil, arara oil, castor oil, avocado oil, olive oil, rapeseed oil, coconut oil, wheatgerm oil, sweet almond oil, safflower oil, candlenut oil, camellina oil , tamanu oil, babassu oil and pracaxi oil, caprylic/capric acid triglycerides, for instance those sold by the company Stearineries Dubois or those sold under the names Miglyol^® 8 10, 8 12 and 8 1 8 by the company Dynamit Nobel, j oj oba oil and shea butter oil.

Liquid fatty esters derived from monoalcohols will preferably be used as esters according to the invention.

Isopropyl myri state and i sopropyl palmitate are particularly preferred.

The liquid fatty ethers are chosen from liquid dialkyl ethers such as dicaprylyl ether.

The fatty sub stance(s) used in the composition according to the invention may al so be fatty sub stances that are non-liquid at room temperature (25 °C) and at atmospheric pressure (760 mmHg, i. e . 1 .013 x 10^s Pa) .

The term " non-liquid" preferably means a solid compound or a compound that has a vi scosity of greater than 2 Pa. s at a temperature of 25 °C and at a shear rate of 1 s^{" 1}.

More particularly, the non-liquid fatty sub stances are chosen from fatty alcohol s, fatty acid and/or fatty alcohol esters, non- siliceous waxes and fatty ethers, which are non-liquid and preferably solid.

The non-liquid fatty alcohol s that are suitable for use in the invention are more particularly chosen from saturated or unsaturated, linear or branched alcohols comprising from 8 to 30 carbon atoms. Mention may be made, for example, of cetyl alcohol, stearyl alcohol and a mixture thereof (cetylstearyl alcohol).

As regards the non-liquid esters of fatty acids and/or of fatty alcohols, mention may be made especially of solid esters derived from C9-C26 fatty acids and from C9-C26 fatty alcohols.

Among these esters, mention may be made of octyldodecyl behenate, isocetyl behenate, cetyl lactate, stearyl octanoate, octyl octanoate, cetyl octanoate, decyl oleate, myristyl stearate, octyl palmitate, octyl pelargonate, octyl stearate, alkyl myristates such as cetyl myristate, myristyl myristate and stearyl myristate, and hexyl stearate.

Still within the context of this variant, esters of C4-C22 dicarboxylic or tricarboxylic acids and of C1-C22 alcohols and esters of monocarboxylic, dicarboxylic or tricarboxylic acids and of C2-C26 dihydroxy, trihydroxy, tetrahydroxy or pentahydroxy alcohols may also be used.

Mention may be made especially of diethyl sebacate, diisopropyl sebacate, diisopropyl adipate, di-n-propyl adipate, dioctyl adipate and dioctyl maleate.

Among all the esters mentioned above, it is preferred to use myristyl, cetyl or stearyl palmitates, and alkyl myristates such as cetyl myristate, stearyl myristate and myristyl myristate.

The non-siliceous wax(es) are chosen especially from carnauba wax, candelilla wax, esparto wax, paraffin wax, ozokerite, plant waxes, such as olive tree wax, rice wax, hydrogenated jojoba wax or absolute flower waxes, such as the blackcurrant blossom essential wax sold by Bertin (France), or animal waxes, such as beeswaxes or modified beeswaxes (cerabellina), and ceramides.

The ceramides or ceramide analogues, such as glycoceramides, that may be used in the compositions according to the invention are known per se and are natural or synthetic molecules that may correspond to the general formula (XVII) below:

(XVII) in which:

- Ri denotes a linear or branched, saturated or unsaturated alkyl group, derived from C14-C30 fatty acids, it being possible for this group to be substituted with a hydroxyl group in the alpha position, or a hydroxyl group in the omega position esterified with a saturated or unsaturated C16-C30 fatty acid;

- R-2 denotes a hydrogen atom or a (glycosyl)_n, (galactosyl)_m or sulfogalactosyl group, in which n is an integer ranging from 1 to 4 and m is an integer ranging from 1 to 8;

- R3 denotes a C15-C26 hydrocarbon-based group which is saturated or unsaturated in the alpha position, it being possible for this group to be substituted with one or more C₁-C14 alkyl groups;

it being understood that, in the case of natural ceramides or glycoceramides, R3 can also denote a C15-C26 alpha-hydroxyalkyl group, the hydroxyl group being optionally esterified with a C16-C30 alpha-hydroxy acid.

The ceramides that are preferred in the context of the present invention are those described by Downing in Arch. Dermatol., Vol. 123, 1381-1384, 1987, or those described in French patent FR 2 673 179.

The ceramide(s) that are more particularly preferred according to the invention are the compounds for which Ri denotes a saturated or unsaturated alkyl derived from C16-C22 fatty acids; R2 denotes a hydrogen atom; and R3 denotes a saturated linear C₁₅ group.

Such compounds are, for example:

- N-linoleoyldihydrosphingosine,

- N-oleoyldihydrosphingosine,

- N-palmitoyldihydrosphingosine, - N-stearoyldihydrosphingosine,

- N-behenoyldihydrosphingosine,

or mixtures of these compounds .

More preferably still, ceramides are used for which Ri denotes a saturated or unsaturated alkyl group derived from fatty acids; R₂ denotes a galactosyl or sulfogalactosyl group; and R₃ denotes a -CH=CH-(CH₂ ) i 2-CH₃ group .

Other waxes or waxy starting material s that may be used according to the invention are especially marine waxes such as those sold by the company Sophim under the reference M82, and waxes of polyethylene or of polyolefins in general .

The non-liqui d fatty ethers are chosen from dialkyl ethers and especially dicetyl ether and di stearyl ether, alone or as a mixture.

Preferably, the non- siliceous fatty sub stances according to the invention are chosen from hydrocarbons, fatty alcohol s, fatty esters and ceramides.

Even more preferably, the non- siliceous fatty sub stances are chosen from liquid petroleum j elly, stearyl alcohol, cetyl alcohol and a mixture thereof such as cetyl stearyl alcohol, octyldodecanol, oleyl alcohol, i sopropyl palmitate, i sopropyl myri state, N- oleoyldihydrosphingosine, N-behenoyldihydrosphingosine and N- linoleoyldihydrosphingosine.

The non-siliceous fatty sub stance(s) may b e present in an amount ranging from 0.01 % to 40% by weight and especially from 0. 1 %) to 5% by weight relative to the total weight of the composition.

The composition according to the invention may al so compri se one or more silicones .

The silicones present in the composition according to the invention are in particular polyorganosiloxanes that may be in the form of aqueous solutions, i . e . di ssolved, or optionally in the form of di spersions or microdi spersions, or of aqueous emul sions. The polyorganosiloxanes may al so be in the form of oils, waxes, resins or gums. Organopolysiloxanes are defined in greater detail in Walter Noll's Chemistry and Technology of Silicones (1968), Academic Press.

The silicones may be volatile or non-volatile.

When they are volatile, the silicones are more particularly chosen from those with a boiling point of between 60°C and 260°C, and even more particularly from:

(i) cyclic silicones comprising from 3 to 7 and preferably

4 to 5 silicon atoms.

These are, for example, octamethylcyclotetrasiloxane sold especially under the name Volatile Silicone 7207 by the company Union Carbide or Silbione 70045 V 2 by the company Rhodia, decamethylcyclopentasiloxane sold under the name Volatile Silicone 7158 by the company Union Carbide, and Silbione 70045 V 5 by the company Rhodia, and mixtures thereof.

Mention may also be made of cyclocopolymers of the dimethylsiloxane/methylalkylsiloxane type, such as Volatile Silicone FZ 3109 sold by the company Union Carbide, of chemical structure:

-D"— D' -D" -D'

CH CH₃

I I

with D" : ^— Si ~°— with D' : -Si -O—

CH₃ C₈H₁₇

Mention may also be made of mixtures of cyclic silicones with organosilicon compounds, such as the mixture of octamethyl-cyclotetrasiloxane and tetrakis(trimethylsilyl)- pentaerythritol (50/50) and the mixture of octamethylcyclotetrasiloxane and oxy-l,l'-bis(2,2,2',2',3,3'-hexatrimethyl- silyloxy)neopentane;

(ii) linear volatile silicones containing 2 to 9 silicon atoms and having a viscosity of less than or equal to 5 x 10^"6 m²/s at 25°C. An example is decamethyltetrasiloxane sold in particular under the name SH 200 by the company Toray Silicone. Silicones belonging to this category are also described in the article published in Cosmetics and Toiletries, Vol. 91, Jan. 76, pp. 27-32, Todd & Byers Volatile Silicone Fluids for Cosmetics .

When the silicones are non-volatile, use is preferably made of polyalkylsiloxanes, polyarylsiloxanes, polyalkylarylsiloxanes, silicone gums and resins, and polyorganosiloxanes modified with organofunctional groups, and mixtures thereof.

These silicones are more particularly chosen from polyalkylsiloxanes, among which mention may be made mainly of polydimethylsiloxanes containing trimethylsilyl end groups (Dimethicone according to the CTFA name) having a viscosity of from 5xl0^"6 to 2.5 m²/s at 25°C and preferably lxlO^"5 to 1 m²/s. The viscosity of the silicones is measured, for example, at 25°C according to standard ASTM 445 Appendix C.

Among these polyalkylsiloxanes, mention may be made, in a non-limiting manner, of the following commercial products:

- the Silbione oils of the 47 and 70 047 series or the Mirasil oils sold by the company Rhodia, for instance the oil 70 047 V 500 000,

- the oils of the Mirasil series sold by the company Rhodia, - the oils of the 200 series from the company Dow Corning, such as, more particularly, DC200 with a viscosity of 60000 cSt,

- the Viscasil oils from the company General Electric and certain oils of the SF series (SF 96, SF 18) from the company General Electric.

Mention may also be made of polydimethylsiloxanes containing dimethylsilanol end groups (Dimethiconol according to the CTFA name) such as the oils of the 48 series from the company Rhodia.

Mention may also be made of polydimethylsiloxanes containing aminoethyl, aminopropyl and α,ω-silanol groups.

In this category of polyalkylsiloxanes, mention may also be made of the products sold under the names Abil Wax 9800 and 9801 by the company Goldschmidt, which are poly(Ci-C2o)alkylsiloxanes.

The polyalkylarylsiloxanes are particularly chosen from linear and/or branched polydimethylmethylphenylsiloxanes and polydimethyldiphenylsiloxanes with a viscosity of from lxlO^"5 to 5xl0^"2 m²/s at 25°C.

Among these polyalkylarylsiloxanes, examples that may be mentioned include the products sold under the following names:

- Silbione oils of the 70641 series from the company Rhodia,

- the oils of the Rhodorsil 70 633 and 763 series from the company Rhodia,

- the oil Dow Corning 556 Cosmetic Grade Fluid from the company Dow Corning,

- silicones of the PK series from the company Bayer, such as the product PK20,

- the silicones of the PN and PH series from the company Bayer, such as the products PN1000 and PH1000,

- certain oils of the SF series from the company General Electric, such as SF 1023, SF 1154, SF 1250 and SF 1265.

The silicone gums that may be present in the composition according to the invention are especially polydiorganosiloxanes having high number-average molecular masses of between 200000 and 1 000000, used alone or as a mixture in a solvent. This solvent can be chosen from volatile silicones, polydimethylsiloxane (PDMS) oils, polyphenylmethylsiloxane (PPMS) oils, isoparaffins, polyisobutylenes, methylene chloride, pentane, dodecane and tridecane, or mixtures thereof.

Mention may be made more particularly of the following products:

- polydimethylsiloxane gums,

- polydimethylsiloxane/methylvinylsiloxane gums,

- polydimethylsiloxane/diphenylsiloxane gums,

- polydimethylsiloxane/phenylmethylsiloxane gums,

- polydimethylsiloxane/diphenylsiloxane/methylvinylsiloxane gums.

Products that may be used more particularly are the following mixtures: - mixtures formed from a polydimethylsiloxane hydroxylated at the end of the chain (known as dimethiconol according to the nomenclature of the CTFA dictionary) and from a cyclic polydimethylsiloxane (known as cyclomethicone according to the nomenclature of the CTFA dictionary), such as the product Q2 1401 sold by the company Dow Corning,

- mixtures formed from a polydimethylsiloxane gum with a cyclic silicone, such as the product SF 1214 Silicone Fluid from the company General Electric, this product being an SF 30 gum corresponding to a dimethicone, having a number-average molecular weight of 500 000, dissolved in the oil SF 1202 Silicone Fluid corresponding to decamethylcyclopentasiloxane,

- mixtures of two PDMSs with different viscosities, and more particularly of a PDMS gum and a PDMS oil, such as the product SF 1236 from the company General Electric. The product SF 1236 is a mixture of a gum SE 30 defined above, with a viscosity of 20 m²/s and of an oil SF 96 with a viscosity of 5 x 10^"6 m²/s. This product preferably comprises 15% of gum SE 30 and 85% of an oil SF 96.

The organopolysiloxane resins that may be present in the composition according to the invention are crosslinked siloxane systems containing the following units: R2S1O2/2, R3S1O1/2, RS1O3/2 and S1O4/2 in which R represents a hydrocarbon group containing 1 to 16 carbon atoms or a phenyl group. Among these products, the ones that are particularly preferred are those in which R denotes a C1-C4 alkyl group, more particularly methyl, or a phenyl group.

Among these resins, mention may be made of the product sold under the name Dow Corning 593 or those sold under the names Silicone Fluid SS 4230 and SS 4267 by the company General Electric, which are silicones of dimethyl/trimethylsiloxane structure.

Mention may also be made of the trimethyl siloxy silicate type resins sold in particular under the names X22-4914, X21-5034 and X21-5037 by the company Shin-Etsu.

The organomodified silicones that may be present in the composition according to the invention are silicones as defined above and compri sing in their structure one or more organofunctional groups attached via a hydrocarbon-based group .

Among the organomodifi ed silicones, mention may be made of polyorganosiloxanes compri sing :

- polyethyleneoxy and/or polypropyleneoxy groups optionally compri sing C₆ - C24 alkyl groups, such as the products known as dimethicone copolyol sold by the company Dow Corning under the name DC 1248 or the oil s Silwet L 722, L 7500, L 77 and L 71 1 by the company Union Carbide, and the (C i 2)alkylmethicone copolyol sold by the company Dow Corning under the name Q2 5200,

- thiol group s, such as the products sold under the names GP 72 A and GP 71 from the company Genesee,

- alkoxylated groups, such as the product sold under the name Silicone Copolymer F-755 by SWS Silicones and Abil Wax 2428, 2434 and 2440 by the company Goldschmidt,

- hydroxylated groups, such as the polyorganosiloxanes containing a hydroxyalkyl function, described in French patent application FR-A-2 589 476,

- acyloxyalkyl groups, for instance the polyorganosiloxanes described in patent US-A-4 957 732,

- anionic groups of the carboxyli c acid type, for instance in the products described in patent EP 1 86 507 from the company Chi sso Corporation, or of the alkylcarboxylic type, such as those present in the product X-22-3701E from the company Shin-Etsu; 2-hydroxyalkyl sulfonate; 2-hydroxyalkyl thio sulfate such as the products sold by the company Goldschmidt under the names Abil S201 and Abil S255 ,

hydroxyacylamino groups, for instance the polyorganosiloxanes described in patent application EP 342 834. Mention may be made, for example, of the product Q2-8413 from the company Dow Corning.

Among the organomodified silicones, mention may al so be made of amino silicones. For the purposes of the present invention, the term "amino silicone" means any silicone comprising at least one primary, secondary or tertiary amine function or a quaternary ammonium group .

The amino silicones that may be used in the cosmetic composition according to the present invention are chosen from:

(a) the compounds corresponding to formula (XVIII) below:

(R¹)_a(T)₃ -a- Si[O Si(T)₂]_n- [O Si(T)_b(R¹)_{2 -b}] _m-O Si(T)₃ -a-(R¹)a (XVIII) in which :

T i s a hydrogen atom or a phenyl, hydroxyl (-OH) or C i -C₈ alkyl group, and preferably methyl , or a C i -C₈ alkoxy, preferably methoxy,

a denotes the numb er 0 or an integer from 1 to 3 , and preferably 0,

b denotes 0 or 1 , and in particular 1 ,

m and n are numbers such that the sum (n + m) can range especially from 1 to 2000 and in particular from 50 to 1 50, it being possible for n to denote a number from 0 to 1999 and in particular from 49 to 149, and for m to denote a number from 1 to 2000 and in particular from 1 to 10,

R¹ is a monovalent radical of formula -C_qH_{2 q}L in which q i s a number from 2 to 8 and L i s an optionally quaternized amino group chosen from the following groups :

-N(R₂)-CH₂-CH₂-N(R²)₂ ;

-N(R²)₂,

-N⁺(R²)₃ Q-,

-N⁺(R²) (H)₂ Q-,

-N⁺(R²)₂HQ\

-N(R²)-CH₂-CH₂-N⁺(R²)(H)₂ Q\

in which R² may denote a hydrogen atom, a phenyl, a benzyl or a saturated monovalent hydrocarbon-based group, for example a C i -C₂₀ alkyl group, and Q^" represents a halide ion, for instance fluoride, chloride, bromide or iodide. In particular, the amino silicones corresponding to the definition of formula (XVIII) are chosen from the compounds corresponding to formula (XIX) below:

NH.

(XIX) in which R, R' and R", which may be identical or different, denote a C1-C4 alkyl group, preferably CH₃; a C₁-C₄ alkoxy group, preferably methoxy; or OH; A represents a linear or branched, C₃-C₈ and preferably C₃-C₆ alkylene group; m and n are integers dependent on the molecular weight and whose sum is between 1 and 2000.

According to a first possibility, R, R' and R", which may be identical or different, represent a C₁-C₄ alkyl or hydroxyl group, A represents a C₃ alkylene group and m and n are such that the weight- average molecular mass of the compound is between 5000 and 500000 approximately. Compounds of this type are referred to in the CTFA dictionary as "amodimethicones".

According to a second possibility, R, R' and R", which may be identical or different, each represent a C₁-C₄ alkoxy or hydroxyl group, at least one of the groups R or R" is an alkoxy group and A represents a C₃ alkylene group. The hydroxy/alkoxy mole ratio is preferably between 0.2/1 and 0.4/1 and advantageously equal to 0.3/1. Moreover, m and n are such that the weight-average molecular mass of the compound is between 2000 and 10⁶. More particularly, n is between 0 and 999 and m i s between 1 and 1000, the sum of n and m being between 1 and 1000.

In thi s category of compounds, mention may be made, inter alia, of the product B el sil® ADM 652 sold by the company Wacker.

According to a third possibility, R and R", which are different, each represent a C ₁ -C₄ alkoxy or hydroxyl group, at least one of the group s R or R" being an alkoxy group, R' representing a methyl group and A representing a C₃ alkylene group . The hydroxy/alkoxy mol e ratio i s preferably between 1 /0.8 and 1 / 1 . 1 and advantageously equal to 1 /0.95. Moreover, m and n are such that the weight-average molecular mass of the compound i s b etween 2000 and 200 000. More particularly, n i s between 0 and 999 and m i s between 1 and 1000, the sum of n and m being between 1 and 1000.

More particularly, mention may be made of the product Fluid WR® 1300 sold by the company Wacker.

Note that the molecular mass of these silicones i s determined by gel permeation chromatography (ambient temperature, polystyrene standard; μ styragem columns; eluent THF ; flow rate 1 mm/minute; 200 μΐ of a solution containing 0.5% by weight of silicone in THF are inj ected, and detection i s performed by refractometry and UV-metry) .

A product corresponding to the definition of formula (XVIII) i s in particular the polymer known in the CTFA dictionary as "trimethyl silyl amodimethicone", corresponding to formul a (XX) below :

CH₃ CH,

I

(CH₃)₃ SiO- -SiO SiO— -Si(CH₃ 3)'3

I I

CH, CH,

I

CHCH

II

CH m

(CH₂)₂

NH₀

(XX) in which n and m have the meanings given above in accordance with formula (XVIII).

Such compounds are described, for example, in patent EP 0095 238. A compound of formula (XX) is sold, for example, under the name Q2-8220 by the company OSI.

(b) the compounds corresponding to formula (XXI) below:

in which:

R³ represents a Ci-Ci₈ monovalent hydrocarbon-based group, and in particular a Ci-Ci₈ alkyl or C₂-Ci₈ alkenyl group, for example methyl,

R⁴ represents a divalent hydrocarbon-based group, especially a Ci-Ci₈ alkylene group or a divalent Ci-Ci₈, and for example Ci-C₈, alkylenoxy group,

Q^" is a halide ion, in particular chloride; r represents a mean statistical value from 2 to 20 and in particular from 2 to 8,

s represents a mean statistical value from 20 to 200 and in particular from 20 to 50.

Such compounds are described more particularly in patent US 4 185 087.

A compound falling within this class is the product sold by the company Union Carbide under the name Ucar Silicone ALE 56.

(c) the quaternary ammonium silicones of formula (XXII):

Rc

in which:

R-7, which may be identical or different, represent a monovalent hydrocarbon-based group containing from 1 to 18 carbon atoms, and in particular a Ci-Ci₈ alkyl group, a C₂-Ci₈ alkenyl group or a ring comprising 5 or 6 carbon atoms, for example methyl,

R-6 represents a divalent hydrocarbon-based group, especially a Ci-Ci₈ alkylene group or a divalent Ci-Ci₈, and for example Ci-C₈, alkylenoxy group linked to the Si via an SiC bond,

R₈, which may be identical or different, represent a hydrogen atom, a monovalent hydrocarbon-based group containing from 1 to 18 carbon atoms, and in particular a Ci-Ci₈ alkyl group, a C₂-Ci₈ alkenyl group or a group -R6-NHCOR7;

X^" is an anion such as a halide ion, especially chloride, or an organic acid salt (acetate, etc.);

r represents a mean statistical value from 2 to 200 and in particular from 5 to 100.

These silicones are described, for example, in patent application EP-A-0 530 974.

(d) the amino silicones of formula (XXIII):

(C_mH_2m)

(XXIII) in which:

- Ri, R-2, R₃ and R₄, which may be identical or different, denote a C1-C4 alkyl group or a phenyl group,

- R₅ denotes a C1-C4 alkyl group or a hydroxyl group,

- n is an integer ranging from 1 to 5,

- m is an integer ranging from 1 to 5, and

- x is chosen such that the amine number is between 0.01 and 1 meq/g.

The silicones that are particularly preferred are polydimethylsiloxanes, dimethicones and amodimethicones.

When these compounds are used, one particularly advantageous embodiment involves their combined use with cationic and/or nonionic surfactants.

By way of example, use may be made of the product sold under the name Cationic Emulsion DC 939 by the company Dow Corning, which comprises, besides amodimethicone, a cationic surfactant which is trimethylcetylammonium chloride and a nonionic surfactant of formula: Ci₃H₂₇-(OC₂H₄)i₂-OH, known under the CTFA name "Trideceth-12".

Another commercial product that may be used according to the invention is the product sold under the name Dow Corning Q27224 by the company Dow Corning, comprising, in combination, the trimethylsilyl amodimethicone of formula (XXIII) described above, a nonionic surfactant of formula: C₈Hi₇-C₆H₄-(OCH₂CH₂)₄o-OH, known under the CTFA name " Octoxynol-40 " , a second nonionic surfactant of formula: C i 2H25-(OCH₂-CH₂)6-OH, known under the CTFA name "Isolaureth-6 " , and propylene glycol.

The silicones of the invention may al so be silicones grafted with anionic groups, such as the compounds VS 80 or VS 70 sold by the company 3M.

In a more preferred emb odiment, the silicone i s a chemically unmodified polydimethyl siloxane .

The silicone(s) may be present in contents ranging from 0.01 % to 40% by weight and preferably from 0. 1 % to 5% by weight relative to the total weight of the composition.

The composition may al so compri se one or more cationi c polymers.

The term " cationic polymer" means any polymer containing cationic groups and/or groups that can be ionized to cationi c group s, which are preferably non-siliceous .

The cationic polymers which can be used in accordance with the present invention may be selected from all of those already known per se to enhance the cosmetic properties of hair treated with detergent compositions, these being, in particul ar, the polymers described in Patent Application EP-A-0 337 354 and in French Patent Applications FR-A-2 270 846, 2 383 660, 2 598 61 1 , 2 470 596 and 2 5 19 863 .

The preferred cationic polymers are chosen from those that contain units compri sing primary, secondary, tertiary and/or quaternary amine groups that may either form part of the main polymer chain or may be borne by a side sub stituent directly connected thereto.

The cationic polymers used have a weight-average molecul ar mass of more than 10⁵, preferably more than 10⁶ and more preferably of between 10⁶ and 10⁸.

Among the cationic polymers that may be mentioned more particularly are polymers of the polyamine, polyamino amide and polyquaternary ammonium type. These are known products .

The polymers of polyamine, polyaminoamide and polyquaternary ammonium type that can be used in the composition of the present invention are those described in French patents 2 505 348 and 2 542 997.

Among these polymers, mention may be made of:

( 1 ) Homopolymers or copolymers derived from acrylic or methacrylic esters or ami des and compri sing at least one of the unit s of formula (XXIV), (XXV), (XXVI) or (XXVII) below:

R₅

CH₂- C—

0 =

0

N

\

R,' R.

(XXIV)

R_c

(XXV)

R₅

— CH₂- C - 0 =

NH

N

\

FL^' R.

(XXVI)

-

(XXVII) in which :

R₃ and R₄, which may be identical or different, represent a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms, and preferably a methyl or ethyl group,

R-5 , which may be identical or different, denote a hydrogen atom or a CH₃ group,

A, which may be identical or different, represent a linear or branched alkyl group of 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms, or a hydroxyalkyl group of 1 to 4 carbon atoms,

R-6 , R₇, R₈, which may be identical or different, represent an alkyl group having from 1 to 1 8 carbon atoms or a b enzyl group, and preferably an alkyl group having from 1 to 6 carbon atoms,

X^" denotes an anion derived from a mineral or organic acid, such as a methosulfate anion or a halide such as chloride or bromide. The copolymers of family (1) may also contain one or more units derived from comonomers which may be chosen from the family of acrylamides, methacrylamides, diacetone acrylamides, acrylamides and methacrylamides substituted on the nitrogen atom with lower (Ci- C₄) alkyls, acrylic or methacrylic acids or esters thereof, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, and vinyl esters.

Thus, among these copolymers of the family (1), mention may be made of:

copolymers of acrylamide and of dimethylaminoethyl methacrylate quaternized with dimethyl sulfate or with a dimethyl halide, such as the product sold under the name Hercofloc by the company Hercules,

- copolymers of acrylamide and of methacryloyloxyethyl- trimethylammonium chloride, described, for example, in Patent Application EP-A-080 976 and sold under the name Bina Quat P 100 by the company Ciba Geigy,

- the copolymer of acrylamide and of methacryloyloxyethyl- trimethylammonium methosulfate sold under the name Reten by the company Hercules,

- quaternized or non-quaternized vinylpyrrolidone/ dialkylaminoalkyl acrylate or methacrylate copolymers, such as the products sold under the name Gafquat by the company ISP, such as, for example, Gafquat 734 or Gafquat 755, or alternatively the products known as Copolymer 845, 958 and 937. These polymers are described in detail in French Patents 2077 143 and 2393 573,

dimethylaminoethyl methacrylate/ vinylcaprolactam/ vinylpyrrolidone terpolymers, such as the product sold under the name Gaffix VC 713 by the company ISP,

vinylpyrrolidone/methacryl ami dopropyl dimethyl amine copolymers sold in particular under the name Styleze CC 10 by ISP,

- quaternized vinylpyrrolidone/dimethylaminopropylmethacryl- amide copolymers such as the product sold under the name Gafquat HS 100 by the company ISP, and - crosslinked polymers of methacryloyloxy(C i -C₄)alkyltri(C i - C₄)alkylammonium salts, such as the polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride, or by copolymerization of acrylamide with dimethylaminoethyl methacrylate quaternized with methyl chloride, the homo- or copolymerization being followed by crosslinking with an olefinically unsaturated compound, more particularly methylenebi sacrylamide. A crosslinked acrylamide/methacryloyl oxy- ethyltrimethylammonium chloride copolymer (20/80 by weight) in the form of a di spersion containing 50% by weight of the said copolymer in mineral oil can be used more particularly . Thi s di spersion i s sold under the name Salcare® SC 92 by the company Ciba. A crosslinked methacryloyloxyethyltrimethylammonium chloride homopolymer (INCI name : Polyquaternium-37), for example as a di spersion in mineral oil or in a liquid ester, can al so be used. These di spersions are sold under the names Salcare® SC 95 and Salcare® SC 96 by the company Ciba.

(2) Polymers formed from piperazinyl units and divalent alkylene or hydroxyalkylene radical s containing straight or branched chains, optionally interrupted with oxygen, sulfur or nitrogen atom s or with aromatic or heterocyclic rings, and al so the oxidation and/or quaternization products of these polymers . Such polymers are described, in particular, in French patents 2 162 025 and 2 280 36 1 .

(3 ) water-soluble polyamino amides prepared in particular by polycondensation of an acidi c compound with a polyamine . These polyaminoami des can be crosslinked with an epihalohydrin, a diepoxide, a di anhydride, an unsaturated dianhydri de, a bi s- unsaturated derivative, a bi s-halohydrin, a bi s-azetidinium, a bi s- haloacyldi amine, a bi s-alkyl halide or alternatively with an oligomer resulting from the reaction of a difunctional compound which is reactive with a bis-halohydrin, a bi s-azetidinium, a bi s- haloacyldi amine, a bi s-alkyl halide, an epihalohydrin, a di epoxide or a bis-unsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.3 5 mol per amine group of the polyaminoamide. These polyaminoamides can b e alkylated or, if they compri se one or more tertiary amine functions, they can b e quaternized . Such polymers are described, in particular, in French patents 2 252 840 and 2 368 508.

(4) Polyaminoamide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with difunctional agents. Mention may be made, for example, of adipic acid/dialkylaminohydroxy- alkyldi alkylenetriamine polymers in which the alkyl radical contains from 1 to 4 carbon atoms and preferably denotes methyl, ethyl or propyl. Such polymers are especially described in French patent 1 583 363 .

Among these derivatives, mention may be made more particularly of the adipic acid/dimethylamino- hydroxypropyl/diethyl enetriamine polymers sold under the name Cartaretine F, F4 or F 8 by the company Sandoz.

(5) The polymers obtained by reaction of a polyalkylene polyamine containing two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms. The mole ratio between the polyalkylene polyamine and the dicarboxylic acid i s between 0.8 : 1 and 1 .4 : 1 ; the polyamino amide resulting therefrom i s reacted with epichlorohydrin in a mole ratio of epichlorohydrin relative to the secondary amine group of the polyamino amide of between 0.5 : 1 and 1 .8 : 1 . Such polymers are described in particular in US patents 3 227 61 5 and 2 961 347.

Polymers of this type are sold in particular under the name Hercosett 57 by the company Hercules Inc. or alternatively under the name PD 170 or Delsette 101 by the company Hercules in the case of the adipic acid/epoxypropyl/diethylenetriamine copolymer.

(6) Cyclopolymers of alkyldiallylamine or of dialkyldiallylammonium, such as the homopolymers or copolymers containing, as main constituent of the chain, units corresponding to formula (XXVIII) or (XXIX) :

(XXVIII)

in which formulae : k and t are equal to 0 or 1 , the sum k + t being equal to 1 ; R₁₂ denotes a hydrogen atom or a methyl group; Rio and R_{1 1} , independently of one another, denote an alkyl group having from 1 to 6 carbon atoms, a hydroxyalkyl group in which the alkyl group has preferably 1 to 5 carbon atoms, a lower (C ₁ - C4) ami doalkyl group, or else Rio and Rn may, together with the nitrogen atom to which they are attached, denote heterocyclic group s, such as piperidyl or morpholinyl ; Y^" i s an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bi sulfate, bi sulfite, sulfate or phosphate. These polymers are especially describ ed in French patent 2 080 759 and in its Certificate of Addition 2 190 406.

Rio and Rn , independently of one another, denote preferably an alkyl group having from 1 to 4 carbon atoms.

Among the polymers defined above, mention may be made more particularly of the dimethyldiallylammonium chloride homopolymer sold under the name Merquat 100 by the company Nalco and its homologues of low weight-average molecular weights, and the copolymers of diallyldimethylammonium chloride and of acrylamide sold under the name Merquat 550.

(7) The quaternary diammonium polymer containing repeating units corresponding to the formula (XXX):

in which:

Ri₃, Ri₄, Ri₅ and Ri₆, which may be identical or different, represent aliphatic, alicyclic or arylaliphatic groups containing from 1 to 20 carbon atoms or lower hydroxyalkylaliphatic radicals, or alternatively R₁₃, Ri₄, R15 and R₁₆, together or separately, constitute, with the nitrogen atoms to which they are attached, heterocycles optionally containing a second heteroatom other than nitrogen, or alternatively Rn, Ri4, Ris and R₁₆ represent a linear or branched Ci-C₆ alkyl group substituted with a nitrile, ester, acyl or amide group or a group -CO-O-R17-D or -CO-NH-R17-D where R17 is an alkylene and D is a quaternary ammonium group,

Ai and Bi represent polymethylene groups containing from 2 to

20 carbon atoms, which may be linear or branched and saturated or unsaturated and may contain, joined to or intercalated in the main chain, one or more aromatic rings, or one or more oxygen or sulfur atoms or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and

X^" denotes an anion derived from a mineral or organic acid, Ai, Rn and R15 can form, with the two nitrogen atoms to which they are attached, a piperazine ring. In addition, if Ai denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, Bi may also denote a group (CH₂)_n-CO-D-OC-(CH2)p-,

n and p are integers ranging from 2 to 20 approximately, in which D denotes :

a) a glycol residue of formula: -0-Z-0-, where Z denotes a linear or branched hydrocarbon-based radical or a group corresponding to one of the following formulae :

-(CH₂-CH₂-0)_x -CH₂-CH₂-,

- [CH₂-CH(CH₃)-0]_y-CH₂-CH(CH₃)-,

in which x and y denote an integer from 1 to 4, representing a defined and unique degree of polymerization or any numb er from 1 to 4 representing an average degree of polymerization,

b) a bi s-secondary diamine residue such as a piperazine derivative,

c) a bi s-primary diamine residue of formula: -NH-Y-NH-, where Y denotes a linear or branched hydrocarbon-based radical, or el se the divalent radical -CH₂-CH₂- S- S-CH₂-CH₂-,

d) a ureylene group of formula -NH-CO-NH- .

Preferably, X^" i s an anion such as chloride or bromide.

These polymers generally have a number-average molecul ar mass of between 1000 and 100 000.

Polymers of thi s type are describ ed in particular in French patents 2 320 330, 2 270 846, 2 3 16 271 , 2 336 434 and 2 4 13 907 and US patents 2 273 780, 2 375 853 , 2 388 614, 2 454 547, 3 206 462, 2 261 002, 2 271 378, 3 874 870, 4 001 432, 3 929 990, 3 966 904, 4 005 193 , 4 025 617, 4 025 627, 4 025 653 , 4 026 945 and 4 027 020.

Use may more particularly be made of polymers that are formed from repeating units corresponding to formula (XXXI) :

in which Ri ₈, R1 9 , R₂o and R_{2 1} , which are identical or different, denote an alkyl or hydroxyalkyl group having from 1 to 4 carbon atoms approximately, r and s are integers ranging from 2 to 20 approximately, and X^" is an anion derived from a mineral or organic acid.

One particularly preferred compound of formula (XXXI) is that for which Ri₈, R19, R20 and R21 represent a methyl group and r = 3, s = 6 and X = CI, which is called Hexadimethrine chloride according to INCI nomenclature (CTFA).

(8) Polyquaternary ammonium polymers formed especially from units of formula (XXXII):

R 22 R 24

-N— (CH₂)— NH— CO— (CH₂)— CO— NH— (CH₂)— N—A R₂₃ X R 25 ^X

(XXXII) in which:

R22, R23, R24 and R25, which may be identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, β-hydroxyethyl, β-hydroxypropyl or -CH₂CH₂(OCH₂CH₂)pOH group,

where p is equal to 0 or to an integer between 1 and 6, with the proviso that R22, R23, R24 and R25 do not simultaneously represent a hydrogen atom,

t and u, which may be identical or different, are integers between 1 and 6,

v is equal to 0 or to an integer between 1 and 34,

X^" denotes an anion such as a halide,

A denotes a dihalide group or preferably represents -CH₂-CH₂-

Such compounds are described especially in Patent Application EP-A-122324.

Among these, mention may be made, for example, of the products Mirapol® A 15, Mirapol® AD1, Mirapol® AZ1 and Mirapol® 175, sold by the company Miranol. (9) Quaternary polymers of vinylpyrrolidone and/or of vinylimi dazole, for instance the products sol d under the names Luviquat® FC 905 , FC 550 and FC 370 and Luviquat Excellence by the company BASF .

( 10) Cationic polysaccharides, especially cationic cellulo ses and galactomannan gums.

Among cationic polysaccharides, mention may be made more particularly of cellulose ether derivatives comprising quaternary ammonium groups, cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer and cationic galactomannan gums.

The cellulo se ether derivatives compri sing quaternary ammonium groups described in French Patent 1 492 597. These polymers are al so defined in the CTFA dictionary as quaternary ammoniums of hydroxyethyl cellulo se that have reacted with an epoxide sub stituted with a trimethylammonium group .

The cationic cellulo se copolymers or the cellulose derivatives grafted with a water-soluble quaternary ammonium monomer are described especially in patent US 4 13 1 576, such as hydroxyalkyl cellulo ses, for instance hydroxymethyl, hydroxyethyl or hydroxypropyl cellulo ses grafted especially with a methacryloylethyltrimethyl- ammonium, methacrylamidopropyltrimethylammonium or dimethyl- diallylammonium salt.

The cationic galactomannan gums are described more particularly in US patents 3 589 578 and 4 03 1 307, in particular guar gums containing cationi c trialkylammonium groups. Guar gums modified with a salt such as 2, 3 -epoxypropyltrimethylammonium chloride are used, for example.

( 1 1 ) Cationic proteins or cationic protein hydrolysates, polyalkyleneimines, in particular polyethyleneimines, polymers containing vinylpyridine or vinylpyridinium units, condensates of polyamines and of epi chlorohydrin, quaternary polyureylenes and chitin derivatives. The cationic proteins or protein hydrolysates are, in particular, chemically modified polypeptides bearing quaternary ammonium groups at the end of the chain, or grafted thereon. Their molecular mass may vary, for example, from 1 500 to 10 000 and in particular from 2000 to 5000 approximately . Among these compounds, mention may be made especially of:

- collagen hydrolysates bearing triethylammonium groups, such as the products sold under the name Quat-Pro E by the company Maybrook and referred to in the CTFA dictionary as Triethonium Hydrolyzed Collagen Ethosulfate;

- collagen hydrolysates bearing trimethylammonium chloride and trimethyl stearylammonium chloride groups, which are sold under the name Quat-Pro S by the company Maybrook and are referred to in the CTFA dictionary as Steartrimonium Hydrolyzed Collagen;

- animal protein hydrolysates bearing trimethylbenzylammonium groups, such as the products sold under the name Crotein BTA by the company Croda and referred to in the CTFA dictionary as B enzyltrimonium hydrolyzed animal protein;

- protein hydrolysates bearing quaternary ammonium groups on the polypeptide chain, the said ammonium groups containing at least one alkyl group having from 1 to 1 8 carbon atoms .

Among these protein hydrolysates, mention may be made, inter alia, of:

- Croquat L, in which the quaternary ammonium groups contain a C i 2 alkyl group;

- Croquat M, in which the quaternary ammonium groups contain C ₁₀-C _{1 8} alkyl groups;

- Croquat S, in which the quaternary ammonium group s contain a C _{1 8} alkyl group;

- Crotein Q, in which the quaternary ammonium groups contain at least one alkyl group having from 1 to 1 8 carb on atoms .

These various products are sold by the company Croda.

Other quaternized proteins or hydrolysates are, for example, those corresponding to formula (XXXIII) :

(XXXIII) in which X^" i s an anion of an organic or inorganic acid, A denotes a protein residue derived from collagen protein hydrolysates, R-29 denotes a lipophilic group containing up to 30 carbon atoms, and R-3 0 represents an alkylene group having 1 to 6 carbon atoms. Mention may be made, for example, of the products sold by the company Inolex, under the name Lexein QX 3000, referred to in the CTFA dictionary as Cocotrimonium Collagen Hydrolysate.

Mention may al so be made of quaternized plant proteins such as wheat, corn or soybean proteins, for instance quaternized wheat proteins . Mention may be made of those sold by the company Croda under the names Hydrotriticum WQ or QM, referred to in the CTFA dictionary as Cocodimonium hydrolysed wheat protein, Hydrotriticum QL, referred to in the CTFA dictionary as Laurdimonium hydrolysed wheat protein, or el se Hydrotriticum Q S, referred to in the CTFA dictionary as Steardimonium hydrolysed wheat protein.

Preferably, the cationi c polymer(s) are chosen from polymers of families ( 1 ), (6), (9) and ( 10) .

Among these preferred cationic polymers that may be used in the context of the present invention, it i s more particularly preferred to use cationic cyclopolymers, in particular dimethyldiallylammonium chloride homopolymers or copolymers, sold under the names Merquat 100, Merquat 550 and Merquat S by the company Nalco, quaternary polymers of vinylpyrrolidone and of vinylimidazole, such as the copolymer of vinylpyrrolidone and of methylvinylimidazolinium chloride sold under the name Luviquat Excellence by BASF, cationic polysaccharides, more particularly guar gums modified with 2,3 - epoxypropyltrimethylammonium chloride sold, for example, under the name Jaguar C 13 S by the company Rhodia or cellulo se ether derivatives comprising quaternary ammonium groups, for instance the cellulo se ethers sold under the name Ucare Polymer JR 400 LT by the company Amerchol (Dow Chemical), and crosslinked polymers of methacryloyloxy(C i - C4)alkyltri(C i - C4)alkylammonium salts, such as the crosslinked methacryloyloxyethyltrimethylammonium chloride homopolymer sold under the name Salcare S C 95 by the company Ciba, and mixtures thereof.

When they are present, the cationic polymer(s) are present in the composition according to the invention in preferential proportions of at least 0.01 % by weight, preferably ranging from 0.01 % to 1 5% by weight, more preferentially from 0.05% to 10% by weight and better still from 0. 1 % to 5% by weight, relative to the total weight of the composition.

The composition may al so compri se one or more solid particles other than the antidandruff agents. Among these solid particles, fillers, and especi ally silica, titanium dioxi de, pigments, dyes, abrasive powders such as pumice and apricot kernel powder may be present in the composition according to the invention.

The composition according to the present invention may al so contain one or more reducing agents, especially such as sulfureous reducing agents. These agents are preferably chosen from organic compounds comprising one or more mercapto groups (- SH), sulfite s and sulfite derivatives .

The term " sulfite derivatives" essentially denotes bi sulfites and sulfite diesters of formula RO S O₂R' , with R and R' denoting C ₁ - C _{1 0} alkyl groups .

The organi c compounds compri sing a mercapto group are preferably chosen from the following compounds : thioglycolic aci d, thiolactic acid, cysteine, homocysteine, glutathione, thioglycerol, thiomalic acid, 2-mercaptopropionic acid, 3 -mercaptopropioni c acid, thiodiglycol, 2-mercaptoethanol, dithiothreitol, thi oxanthine, thiosali cyli c acid, thiodiglycolic acid, lipoic acid, N-acetylcysteine, and thioglycolic or thiolactic acid esters, and mixtures of these compounds. The sulfureous reducing agent(s) may be used especially in the form of salts, in particular alkali metal salts such as sodium and potassium salts, alkaline-earth metal salts, for example magnesium and calcium salts, ammonium salts, amine salts and amino alcohol salts.

In a particularly preferred manner, the sulfureous reducing agent(s) are chosen from thioglycolic acid and salts thereof, thiolactic acid and salts thereof, alkali metal sulfites and especially sodium sulfite, alkali metal bi sulfites and especially sodium bi sulfite, and precursors of these sulfites or bi sulfites such as sodium metabi sulfite.

The sulfureous reducing agent(s) may b e present in an amount ranging from 0. 1 % to 5% by weight and especially from 0.3 % to 3 % by weight relative to the total weight of the composition.

The composition in accordance with the invention may al so compri se at least one oxidizing agent.

Such an oxidizing agent i s preferably chosen from the group formed by hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, and persalts such as perborates and persulfates.

The use of hydrogen peroxide i s particularly preferred.

The composition according to the invention may be aqueous or anhydrous .

The term " anhydrous" refers to a composition not containing any added water, i. e . a composition in which the water that may be present comes only from the water of crystallization or of adsorption of the starting material s. In any case, an anhydrous composition contains less than 5% by weight of water and b etter still less than 1 % by weight of water relative to the total weight of the composition.

Whether it i s anhydrous or aqueous, the composition according to the invention may contain one or more organic solvents that are liquid at room temperature (25 °C) and at atmospheric pressure (760 mmHg) . Preferably, the liquid organic solvent(s) are chosen from C i - C₄ lower alcohol s, such as ethanol, i sopropanol, tert-butanol or n- butanol, polyols such as propylene glycol, polyol ethers, C 5 - C 1 0 alkanes, C 3 - C 4 ketones such as acetone and methyl ethyl ketone, C ₁ -C₄ alkyl acetates such as methyl acetate, ethyl acetate and butyl acetate, dimethoxyethane, diethoxyethane, silicone oil s and the non-siliceous liquid fatty sub stances described above, and mixtures thereof.

When the composition of the invention is aqueous, its pH i s generally between 2 and 9 and in particular b etween 3 and 8. Preferably, the pH i s less than 7. Even more preferentially, it ranges from 3 to 6.

It may be adj usted to the desired value by means of acidifying or basifying agents usually used in cosmetics for this type of application, or alternatively using standard buffer systems .

Among the acidifying agents, examples that may be mentioned include the organic or mineral acids already mentioned previously .

Use may be made especially of mineral or organi c acids such as hydrochloric acid, orthophosphoric acid, sulfuric acid, carboxylic acids, for instance acetic acid, tartaric acid, citric acid or lactic aci d, and sulfonic acids.

Among the basifying agents, examples that may be mentioned include aqueous ammonia, alkali metal carbonates, alkanol amines, such as mono-, di- and triethanolamines and derivatives thereof, sodium hydroxide, potassium hydroxide and the compounds of the following formula:

in which W i s a propylene residue optionally sub stituted with a hydroxyl group or a C ₁ -C₄ alkyl radical ; and R_a, Rb, Rc and Rd, whi ch may be identical or different, represent a hydrogen atom or a C ₁ -C₄ alkyl or C ₁ -C₄ hydroxyalkyl radi cal.

Preferably, the pH adj usters can be chosen from alkaline agents, such as aqueous ammoni a, monoethanolamine, diethanolamine, triethanolamine, 1 , 3 -propanediamine or an alkaline hydroxide, such as 2-amino-2-methyl- l -propanol, or el se acidifying agents, such as phosphoric acid or hydrochloric acid. The compositions according to the invention may al so comprise one or more additives chosen from fixing polymers, pseudoceramides, vitamins and provitamins, including panthenol, water-solubl e or liposoluble, silicone or non-silicone sunscreens, nacreous agents and opacifiers, sequestrants, conditioning agents other than the silicones and cationic polymers mentioned above, solubilizers, antioxidants, antidandruff agents other than those mentioned above, anti- seborrhoei c agents, hair-lo ss counteractants and/or hair restorers, penetrants, fragrances, peptizers and preserving agents, and any other additive conventionally used in the cosmetics field.

These additives can be present in the composition according to the invention in an amount ranging from 0 to 20% by weight, with respect to the total weight of the composition.

A person skilled in the art will take care to select the optional additives and the amounts thereof such that they do not harm the properties of the compositions of the present invention.

The present invention al so relates to an antidandruff and cosmetic hair treatment process, which consi sts in applying to the hair an effective amount of a composition as described ab ove.

Thi s application may or may not be followed by a rinsing operation.

When the application of the compositi on is followed by a rinsing operation, the leave-in time of the composition on the keratin materi al s ranges from a few seconds to 60 minutes, better still from 5 seconds to 30 minutes, even better still from 10 seconds to 10 minutes.

Whether in rinsed mode or non-rinsed mode, the application of the composition may take place in the presence of heat. The heating device may be a hairdryer, a hood dryer, a curling iron or a flat iron. The heating temperature may be between 40°C and 220°C .

The application of the composition according to the invention to the hair may take place on dry hair or on wet hair. It may in particular b e carried out after a shampooing operation or after a pretreatment at acidic or b asic pH. The examples that follow serve to illustrate the invention without, however, being limiting in nature.

Examples

In the following examples, all the amounts are shown as percentage by weight of active material, with respect to the total weight of the composition.

Example 1

The following compositions are prepared with the compounds indicated in the table below.

¹ ' the alkoxysilane i s chosen from octyltriethoxy silane, octadecyltriethoxy silane, dodecyltriethoxysilane and hexadecyltriethoxysilane

⁽²⁾ the antidandruff agent i s zinc pyrithione or selenium di sulfide

^{(3 )} the anionic surfactant is sodium lauryl ether sulfate or sodium lauryl sulfate

⁽⁴⁾ the thickener i s chosen from cellulose derivatives (in particular hydroxyethylcellulose), guar gum, xanthan gum and associative polymers such as associative polyurethanes (acryli c acid/stearyl methacrylate copolymer, crosslinked acrylic acid/alkyl acrylates polymer, SMDI/alkyl-terminated polyethylene glycol copolymer) Example 2

The composition according to the invention is prepared from the ingredients li sted in the above table.

sold under the brand name Dynasylan Octeo by the company Evonik sold under the brand name Selenium Sulfide USP XXXI/EP6 by the company Ferro Metal and Chemical

sold under the trade name Texapon AO S 225 UP by the company

Cogni s

sold under the brand name Natrosol 250 HHR by the company PC Ashland

Claims

1 . Cosmetic composition comprising:

- from 0. 1 % to 20% by weight, relative to the total weight of the composition, of one or more fatty-chain alkoxy silanes of formula (I) b elow:

- one or more antidandruff agents.

2. Composition according to Claim 1 , characterized in that R₂ represents an alkyl group compri sing from 1 to 4 carbon atoms, better still a linear alkyl group comprising from 1 to 4 carbon atoms, and preferably the ethyl group .

3 . Composition according to Claim 1 or 2, characterized in that Ri represents an alkyl group and even more preferentially a linear alkyl group .

4. Composition according to Claims 1 to 3 , characterized in that the fatty-chain alkoxy silane of formula (I) i s chosen from octyltriethoxysilane, dodecyltriethoxysilane, octadecyltriethoxy si lane and hexadecyltriethoxysilane.

5. Composition according to Claim 4, characterized in that the alkoxysilane i s octyltriethoxysilane.

6. Composition according to any one of the preceding claims, characterized in that the fatty-chain alkoxysilane(s) of formula (I) are present in proportions ranging from 0.5% to 1 8% by weight and better still from 2% to 1 5% by weight relative to the total weight of the composition.

7. Composition according to any one of the preceding claims, characterized in that the antidandruff agent(s) are chosen from :

( 1 ) pyridinethione salts,

(2) l -hydroxy-2-pyridone derivatives, (3 ) 2,2 ' -dithiobi s(pyridine N-oxide),

(4) trihalocarbamides,

(5) triclo san,

(6) azole compounds such as climbazole, ketoconazole, clotrimazol e, econazole, i soconazole and miconazole,

(7) antifungal polymers,

(8) selenium sulfides,

(9) extracts of one or more non-photosynthetic, non-fruiting filamentous bacteria, and

( 10) sulfur in its various forms, cadmium sulfide, allantoin, coal or wood tars and derivatives thereof, salicylic acid, undecylenic aci d, fumaric acid, allylamines .

8. Composition according to Claim 7, characterized in that the antidandruff agent(s) are chosen from zinc pyridinethione, 1 -hydroxy- 4-methyl-6-(2,4,4-trimethylpentyl)-2-pyridone and salts thereof, and selenium di sulfide, and mixtures thereof.

9. Composition according to any one of the preceding claims, characterized in that the antidandruff agent(s) are present in proportions ranging from 0.001 % to 10% by weight, preferably from 0. 1 %) to 5% by weight and more preferentially from 0.2% to 2% by weight relative to the total weight of the composition.

10. Composition according to any one of the preceding claims, characterized in that the weight ratio between the amount of fatty- chain alkoxysilane(s), on the one hand, and the amount of antidandruff agent(s), on the other hand, i s greater than or equal to 0. 1 , and preferably ranges from 0. 1 to 50, more preferentially from 1 to 50 and better still from 1 to 20.

1 1 . Composition according to any one of the preceding claims, characterized in that it compri ses one or more organic or mineral acids .

12. Composition according to any one of the preceding claims, characterized in that it compri ses one or more anionic surfactants, which are preferably present in an amount ranging from 0.01 %> to 20% by weight relative to the total weight of the composition.

13 . Composition according to any one of the preceding claims, characterized in that it al so compri ses one or more thickeners, which are preferably present in an amount ranging from 0. 1 % to 20% by weight and better still from 0.2% to 1 0% by weight relative to the total weight of the composition.

14. Composition according to any one of the preceding claims, characterized in that it compri ses one or more additives chosen from cationic, nonionic, amphoteric and zwitterioni c surfactants, alkoxysilanes other than those of formula (I), non-siliceous fatty sub stances, silicones, cationic polymers, solid particl es other than antidandruff agents, reducing agents and oxidizing agents.

1 5. Composition according to any one of the preceding claims, characterized in that it i s anhydrous.

16. Composition according to any one of Claims 1 to 14, characterized in that it i s aqueous.

17. Antidandruff and cosmetic hair treatment process, characterized in that it consi sts in applying to the hair an effective amount of a composition according to any one of Claims 1 to 16 and then in optionally rinsing the hair after an optional leave-on time, in the presence or ab sence of heat.

1 8. Use of the cosmetic composition according to any one of Claims 1 to 16, as an antidandruff composition.