WO2004065536A1 - Cosmetic compositions comprising alkyl glycol alkoxylates or diglycol alkoxylates - Google Patents

Cosmetic compositions comprising alkyl glycol alkoxylates or diglycol alkoxylates Download PDF

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Publication number
WO2004065536A1
WO2004065536A1 PCT/EP2004/000326 EP2004000326W WO2004065536A1 WO 2004065536 A1 WO2004065536 A1 WO 2004065536A1 EP 2004000326 W EP2004000326 W EP 2004000326W WO 2004065536 A1 WO2004065536 A1 WO 2004065536A1
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alkyl
alkoxylates
hair
cosmetic
alkoxylation
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PCT/EP2004/000326
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German (de)
French (fr)
Inventor
Ralf NÖRENBERG
Claudia Wood
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Basf Aktiengesellschaft
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Publication of WO2004065536A1 publication Critical patent/WO2004065536A1/en

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • C11D1/831Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/45Derivatives containing from 2 to 10 oxyalkylene groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/06Preparations for styling the hair, e.g. by temporary shaping or colouring
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/002Aftershave preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143Sulfonic acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols

Definitions

  • the present invention relates to mixtures of alkyl glycol alkoxylates or diglycol alkoxylates with certain anionic surfactants, cosmetic and / or dermatological compositions containing these mixtures and methods for reducing the skin irritation of surfactants or surfactant mixtures and methods for solubilizing ingredients of cosmetic and / or dermatological compositions and methods for Improving the sprayability of cosmetic and / or dermatological compositions.
  • Cosmetic and / or dermatological compositions such as hair cosmetic preparations or skin cosmetic preparations or mouth and / or dental care preparations or pharmaceutical compositions, generally have surfactants or surfactant mixtures.
  • amphiphilic compounds are required that can emulsify and remove greasy and oily dirt.
  • highly effective surfactants such as sodium dodecyl sulfate also penetrate the skin and cause irritation due to the interaction with the cells, for example the phospholipids of the cell membrane. Since a painful reaction of the skin to the personal care products is not acceptable, the surfactant system of cosmetic cleaning formulations, for example shampoos or shower gels or bath additives, is milder, i.e. well-tolerated surfactants.
  • the anionic surfactant system is often built up with ether sulfates, or zwitterionic surfactants based on betaines or isethionates or nonionic surfactants such as glucamides or polyglycosides are used to make the detergent mixture milder to the skin and to support the cleansing effect.
  • ether sulfates or zwitterionic surfactants based on betaines or isethionates or nonionic surfactants such as glucamides or polyglycosides are used to make the detergent mixture milder to the skin and to support the cleansing effect.
  • poloxamers such as ethylene oxide-propylene oxide block copolymers
  • compositions which have a reduced skin irritation effect.
  • the compositions contain a combination of a nonionic surfactant based on an ethylene oxide / propylene oxide / ethylene oxide triblock copolymer and a polyvinylpyrrolidone.
  • the combination of these two ingredients leads to a reduction in the skin irritation of liquid skin cleaning formulations. Furthermore, the foaming properties and the hand feel of the formulations are improved.
  • the object of the present invention is to provide the aforementioned products.
  • the object is achieved according to the invention by a mixture of alkyl glycol alkoxylates or diglycol alkoxylates, obtainable by alkoxylation of. 8-alkyl glycols or diglycols with C 2 -5 alkoxides up to an average degree of alkoxylation of 1 to 8, based on the C 4 - 8 alkyl glycols or diglycols,
  • alkyl glycol alkoxylates their mixtures with surfactants and their use in different compositions are known from DE-A 102 02 007, which is older and not prepublished. However, mixtures of the alkyl glycol alkoxylates or diglycol alkoxylates with the above special anionic surfactants are not described.
  • alkyl glycol alkoxylates or diglycol alkoxylates as defined above leads to a significant reduction in the skin irritant effect of the surfactants or surfactant mixtures.
  • the effect is comparable to the effect of the betaines commonly used.
  • the alkyl glycol alkoxylates and diglycol alkoxylates used according to the invention enhance the cleaning action of the surfactants.
  • the alkyl glycol alkoxylates and diglycol alkoxylates also act as a solubilizer for hydrophobic ingredients in cosmetic compositions.
  • an effect of Alkyl glycol alkoxylates and diglycol alkoxylates used according to the invention to improve the sprayability and reduce the droplet sizes (distribution) found in cosmetic aerosol sprays and sprays.
  • the invention also relates to a method for reducing the skin irritation of surfactants or surfactant mixtures, in which the surfactant or the surfactant mixture in combination with alkyl glycol alkoxylates or diglycol alkoxylates, obtainable by alkoxylation of C 4 . 8 alkyl glycols or diglycols with C 2 - 5 - alkoxides to an average degree of alkoxylation of 1 to 8, based on the C - 8 - alkyl glycols or -diglykole, begins.
  • the invention also relates to a process for the solubilization of hydrophobic ingredients in cosmetic compositions, in which the ingredients are combined with alkyl glycol alkoxylates or diglycol alkoxylates, obtainable by alkoxylation of C 8 alkyl glycols or diglycols with C 2 5 alkoxides up to one average degree of alkoxylation from 1 to 8, based on the C. 8 alkyl glycols or diglycols.
  • the invention relates to a method for improving the sprayability by reducing the droplet size of cosmetic and / or dermatological spray compositions, in which -diglykolalkoxylaten the ingredients in combination with Alkylglykolalkoxylaten or obtainable by alkoxylating C 4-8 alkyl glycols or diglycols with C 2 -5-alkoxides up to an average degree of alkoxylation of 1 to 8, based on the C -s-alkyl glycols or diglycols, or in combination with the mixtures according to the invention.
  • the beneficial cleaning effects and reduced irritation and droplet size reduction effects are especially the inventive mixtures or of Alkylglykolalkoxylaten -diglykolalkoxylaten with alkyl sulfates, alkyl ether sulfates, alkyl sulfonates having a C 8 - having 3 o-alkyl radical, or mixtures thereof reached.
  • the alkyl group is preferably a C 8-22 -alkyl radical, in particular a Cio-IOE radical.
  • the alkyl radicals can be linear or branched or partially branched. There is preferably an average of 0 to 1.5, particularly preferably 0 to 1, branching in the alkyl radicals. In particular, it can be linear alkyl radicals.
  • the compounds are present as alkali or alkaline earth metal salts or as ammonium or triethanolamine salts.
  • Preferred alkali and alkaline earth metals are sodium, potassium, magnesium and calcium.
  • the alkyl ether sulfates can have from 1 to 10 ethylene oxide or propylene oxide units, preferably 1 to 3 ethylene oxide units, in the molecule.
  • Sodium lauryl sulfate, ammonium lauryl sulfate, sodium lauryl ether sulfate, ammonium lauryl ether sulfate, and similar compounds are suitable, for example.
  • the mixtures according to the invention contain as a component C 2 - 5 alkoxylates, i.e. alkoxylates with C 2 - 5 alkoxides, having from C-S-alkyl glycols on average a degree of alkoxylation of 1 to 8
  • the alkyl glycols can be linear or branched alkyl glycols.
  • the C 4 -s-alkyl radical can be attached to the glycol at the end or at another position along the alkyl chain. They are preferably linear alkyl glycols, in particular linear, terminal alkyl glycols.
  • the alkyl radicals of the alkyl glycols preferably have 4 to 6 carbon atoms.
  • the degree of alkoxylation is on average 1 to 8, preferably 2 to 6.
  • C 2 - 4 alkoxides can preferably be used for the alkoxylation.
  • Ethylene oxide, propylene oxide, butylene oxide or mixtures thereof are preferably used.
  • Ethylene oxide is particularly preferably used.
  • the preferred ranges also refer to the alkyl glycol alkoxylates and alkyl diglycol alkoxylates themselves.
  • the preparation takes place starting from alcohol-free, preferably pure alkyl glycols and alkyl diglycols and not, as is usually the case, starting from alkanols, by alkoxylation. Therefore, the product mixtures do not contain any remaining alkanols, but at most alkyl glycols.
  • the distribution of the degree of alkoxylation is specific for alkyl glycols. Due to the manufacturing process, the alkyl glycol alkoxylates are free of alcohols.
  • Alkoxylates are oligomeric or polymeric reaction products with alkoxides. Because of the kinetics of polymerizations known to the person skilled in the art, there is inevitably a statistical distribution of homologs, the mean value of which is usually given. The frequency distribution of the homologs contains the starting material, especially at low degrees of alkoxylation. By choosing the catalyst, the Distribution can be influenced to a certain extent, but nothing changes in the principle of the distribution curve. Pure alkyl oligoglycols can only be prepared by working up by distillation or chromatography and are therefore expensive. It has also been shown that the distribution of the homologs has a significant influence on the aggregation behavior.
  • alkoxylates claimed here have the homolog distribution important for the aggregation behavior and the other properties according to the invention, without containing alcohol.
  • the distribution of the degrees of alkoxylation can be determined by chromatographic methods.
  • the table below shows the distribution curves for a common n-hexanolefhoxylate (+ 3 EO), derived from n-hexanol, and an n-hexylglycol ethoxylate (+ 2 EO), derived from n-hexylglycol.
  • the first column shows how much ethylene oxide (0-6) is bound to the n-hexyl radical (C6). On average, both compounds contain the same number of EO units.
  • the samples were produced using KOH as a catalyst by introducing 2 or 3 mol / (mol of starting material) ethylene oxide into the respective starting material.
  • the analysis was carried out by gel permeation chromatography (GPC) in THF.
  • the hexanol signal was identified by adding hexanol, the higher homologues from the sequence of further signals.
  • the evaluation was carried out by integrating the signal areas.
  • the alkyl glycol alkoxylates are preferably used in an amount of 0.05 or 0.1 to 20, preferably 0.1 to 10% by weight, particularly preferably 0.5 to 7% by weight, in particular 0.8 to 5% by weight, based on the total weight of the mixture. The remaining proportion of the mixtures is accounted for by the surfactants. These quantities also apply to cosmetic products or other compositions produced from the mixtures or alkyl glycol alkoxylates.
  • the mixtures, compositions and formulations according to the invention are free from alcohols and preferably also from alkyl glycols or diglycols, in particular from C 4 to 8 -alkyl glycols and C 9 to 3 -alkanols.
  • the alkyl glycol alkoxylates or diglycol alkoxylates are obtainable by alkoxylation of C. 6 alkyl glycols or diglycols with C 2 . Alkoxides up to an average degree of alkoxylation of 2 to 6.
  • the mixtures can advantageously be used in cosmetic compositions.
  • the invention also relates to a cosmetic composition containing a mixture as described above.
  • the mixture preferably contains 0.1 to 20% by weight of the C 2 -5-alkoxylates of -s-alkyl glycols or -diglycols, based on the total weight of the mixture or of the agent.
  • the cosmetic compositions can contain a large number of further ingredients.
  • betaines, amine oxides, salts such as sodium chloride, water, polymers and surfactants or quaternized nitrogen atoms or mixtures thereof, alcohols, cosmetic oils and waxes, emulsifiers, silicone compounds, setting polymers such as nonionic, anionic, cationic, zwitterionic or amphoteric polymers, neutralizing agents come as further ingredients such as bases and acids, thickening and rheology modifiers, active ingredients and auxiliaries.
  • Suitable cosmetically and / or dermatologically active substances are, for example, coloring substances, skin and hair pigmentation agents, tinting agents, tanning agents, Bleaching agents, keratin-hardening substances, antimicrobial substances, light filter substances, repellent substances, hyperemising substances, keratolytic and keratoplastic substances, anti-dandruff substances, anti-inflammatory substances, keratinising substances, antioxidant or radical scavenger substances, skin moisturizing or re-moisturizing substances or anti-allergic active ingredients and mixtures thereof.
  • Suitable auxiliaries can be: lubricants, wetting agents, emulsifying and suspending agents, preserving agents, antioxidants, anti-irritants, chelating agents, emulsion stabilizers, film-forming agents, gel-forming agents, odor masking agents, resins, hydrocolloids, solvents, solubilizers, neutralizing agents, permeation compounds, accelerators, ammonium salts, pigments and superfatting agents, ointment, cream or oil base materials, silicone derivatives, stabilizers, sterilants, blowing agents, drying agents, opacifying agents, thickening agents, waxes, plasticizers, white oils.
  • a design in this regard is based on professional knowledge, such as that shown in Fiedler, HP Lexicon of auxiliary substances for pharmacy, cosmetics and related areas, 4th ed., Aulendorf: ECV-Editio-Kantor-Verlag, 1996.
  • Polymers containing betaines, amine oxides and quaternized nitrogen atoms are preferably used in amounts of 0.01 to 30% by weight.
  • Salts such as sodium chloride can preferably be used in amounts of 0.5 to 10% by weight.
  • Almost any amount of water can be used. Usual amounts of water are 3 to 90% by weight, particularly preferably 5 to 80% by weight, for example 10 to 90% by weight or 20 to 80% by weight.
  • Alcohols can be used from 0 to 95% by weight.
  • Cosmetic oils and waxes as well as emulsifiers are preferably used in amounts of 0.5 to 70% by weight.
  • Silicone compounds can be used in amounts of 0.05 to 30% by weight.
  • Fixing polymers such as nonionic, anionic, cationic or amphoteric polymers are usually used in styling formulations in amounts of 1 to 15% by weight.
  • Such setting polymers with acidic or basic functions are usually neutralized with bases or acids up to a certain degree of neutralization between 50 and 100%.
  • the usual amounts of the neutralizing agent required for this are between 0.1 and 20% by weight, depending on the molecular weight equivalent of the neutralizing agent.
  • Some cosmetic preparations also contain rheology modifiers in amounts of 0.05 to 50 Wt .-%.
  • Cosmetic and / or dermatological preparations usually contain active substances and auxiliary substances in quantities of 0.01 to 50% by weight.
  • the cosmetic compositions can be, for example, hair cosmetic preparations or skin cosmetic preparations or oral and dental care preparations.
  • Hair cosmetic preparations are, for example, hair shampoos, hair treatments, hair lotions, hair rinses, hair emulsions, tip fluids, leveling agents for perms, hair colorants, "hot oil treatment” preparations, conditioners, setting lotions, hair gels, hair waxes, hair foams or hair sprays.
  • the hair cosmetic preparations can be applied as a spray, foam, gel, gel spray, shampoo, conditioner or mousse.
  • the hair cosmetic preparations can also contain additives customary in cosmetics such as emulsifiers, preservatives, perfume oils, care substances such as panthenol, collagen, vitamins, protein hydrolyzates, stabilizers, pH regulators, Contain dyes, salts, consistency agents, silicones, humectants, lipid replenishers and other common additives.
  • emulsifiers such as emulsifiers, preservatives, perfume oils, care substances such as panthenol, collagen, vitamins, protein hydrolyzates, stabilizers, pH regulators, Contain dyes, salts, consistency agents, silicones, humectants, lipid replenishers and other common additives.
  • the mixtures according to the invention can be mixed with hair cosmetic polymers if very special properties are to be set.
  • anionic polymers are suitable as conventional cosmetic polymers.
  • Such anionic polymers are homopolymers and copolymers of acrylic acid and methacrylic acid or their salts, copolymers of acrylic acid and acrylamide and their salts; Sodium salts of polyhydroxycarboxylic acids, water-soluble or water-dispersible polyesters, polyurethanes (eg Luviset ® PUR from BASF AG) and polyureas.
  • Particularly suitable polymers are copolymers of t-butyl acrylate, ethyl acrylate, methacrylic acid (for example, Luvimer ® 100P from BASF AG), copolymers of N-tert-butyl acrylamide, ethyl acrylate, acrylic acid (eg, Ultrahold ® 8, Strong of BASF AG), copolymers of vinyl acetate, Crotonic acid and optionally other vinyl esters (e.g. Luviset ® brands from BASF AG), maleic anhydride copolymers, possibly reacted with alcohols, anionic polysiloxanes, e.g. carboxy-functional, copolymers from vinylpyrrolidone, t-butyl acrylate, methacrylic acid (e.g. Luviskol ® VBM from BASF AG).
  • Luvimer ® 100P from BASF AG
  • the group of polymers suitable for combination with the mixtures according to the invention further includes, for example, Balance CR (National Starch; acrylate copolymer), Balance 0/55 (National Starch; acrylate copolymer), Balance 47 (National Starch; octylacrylamide / acrylate / butylaminoethyl methacrylate copolymer), Aquaflex ® FX 64 (ISP; isobutylene / ethylmaleimide / hydroxyethylmaleimide copolymer), Aquaflex ® SF-40 (ISP / National Starch; VP / Yinyl Caprolactam / DMAPA acrylate copolymer), Allianz ® LT-120 (ISP / Rohm &Haas; Acrylate / Cl -2 succinate / hydroxyacrylate copolymer), Aquarez ® HS (Eastman; Polyester-1), Diaformer ® Z-400 (Clariant; methacryl
  • Acrylates with an acid number greater than or equal to 120 and copolymers of t-butyl acrylate, ethyl acrylate, methacrylic acid are very particularly preferably used as anionic polymers.
  • Further suitable cosmetic polymers are cationic polymers having the INCI name Polyquaternium, eg copolymers of vinylpyrrolidone / vinylimidazolium N- (Luviquat ® FC, Luviquat ® HM, Luviquat ® MS, Luviquat Care ® from BASF AG), copolymers of N-vinylpyrrolidone / dimethylaminoethyl methacrylate, quaternized with diethyl sulfate (Luviquat ® PQ 11 of BASF AG), copolymers of N-vinylcaprolactam N-vinylpyrrolidone / N-vinylimidazolium salts (Luviquat Hold ® of BASF AG);
  • Cationic guar derivatives such as guar hydroxypropyltrimonium chloride (INCI) can also be used.
  • Neutral polymers such as polyvinylpyrrolidones, copolymers of N-vinylpyrrolidone and vinyl acetate and / or vinyl propionate, copolymers of N-vinylpyrrolidone and dimethylaminopropylacrylamide or -methacrylamide (DMAPA), copolymers of N-vinylpyrrolidone acid and (meth) acrylic acid are also suitable as further cosmetic polymers , Polysiloxanes, polyvinylcaprolactam and copolymers with N-vinylpyrrolidone, polyethyleneimines and their salts, polyvinylamines and their salts, polyvinylformamide and its (partial) hydrolysis products, cellulose derivatives, polyaspartic acid salts and derivatives.
  • DMAPA dimethylaminopropylacrylamide or -methacrylamide
  • the preparations can also contain conditioning substances based on silicone compounds.
  • Suitable silicone compounds are, for example, polyalkylsiloxanes, polyarylsiloxanes, polyarylalkylsiloxanes, polyether siloxanes or silicone resins. Dimethicone copolyols (CTFA) and amino-functional silicone compounds such as amodimethicones (CTFA) are also suitable.
  • the shampoo formulations usually contain anionic surfactants as base surfactants and amphoteric and nonionic surfactants as cosurfactants.
  • the formulations in total contain, for example, 2 to 50% by weight of surfactants, preferably 5 to 40% by weight, particularly preferably 8 to 30% by weight of the mixtures according to the invention.
  • All neutral, amphoteric or cationic surfactants commonly used in shampoos can also be used in the shampoo formulations.
  • Suitable amphoteric surfactants are, for example, alkylbetaines, alkylamidopropylbetaines, alkylsulfobetaines, alkylglycinates, alkylcarboxyglycinates, alkylamphoacetates or propionates, alkylamphodiacetates or dipropionates.
  • cocodimethylsulfopropylbetaine laurylbetaine, cocamido propylbetaine or sodium cocamphopropionate can be used.
  • nonionic surfactants are the reaction products of aliphatic alcohols or alkylphenols with 6 to 20 carbon atoms in the alkyl chain, which can be linear or branched, with ethylene oxide and / or propylene oxide.
  • the amount of alkylene oxide is about 6 to 60 moles per mole of alcohol.
  • Alkylamine oxides, mono- or dialkylalkanolamides, fatty acid esters of polyethylene glycols, ethoxylated fatty acid amides, alkyl polyglycosides or sorbitan ether esters are also suitable.
  • the shampoo formulations can contain customary cationic surfactants, such as quaternary ammonium compounds, for example cetyltrimethylammonium chloride.
  • the polymers with quaternized nitrogen atoms are usually used in amounts of between 0.01 and 5% by weight, preferably between 0.05 and 2% by weight.
  • cationic polymers customary in shampoos can also be used, for example copolymers of acrylamide and dimethyldiallylammonium chloride (Polyquaternium-7), cationic cellulose derivatives (Polyquaternium-10), guar-hydroxypropyltrimethylammonium chloride (INCI: hydroxypropyl guar hydroxypropyltrimonium chloride ), Copolymers of N-vinyl-pyrrolidone and quaternized N-vinylimidazole (Polyquaterinium-16, -44, -46) and others.
  • the shampoo formulations can contain thickeners such as table salt, PEG-55, propylene glycol oleates, PEG-120 methyl glucose dioleates and others, and also preservatives, other active ingredients and auxiliaries and water.
  • the hair treatment preparations usually contain a polymer in an amount in the range from about 0.1 to 30% by weight, preferably 0.5 to 20% by weight, based on the total weight of the composition and 0.03 to 10% by weight.
  • % Surfactants preferably 0.05 to 5% by weight, particularly preferably 0.1 to 3% by weight, in particular of the mixtures according to the invention.
  • the hair treatment compositions according to the invention are preferably in the form of a foaming agent, hair mousse, hair gel, shampoo, hair spray or hair foam.
  • Hair sprays include both aerosol sprays and pump sprays without propellant.
  • Hair foams include both aerosol foams and pump foams without propellant.
  • the mixtures according to the invention can be used in skin cosmetic and dermatological preparations.
  • the mixtures according to the invention are used in cosmetic compositions for cleaning the skin.
  • cosmetic cleaning agents are selected from bar soaps such as toilet soaps, core soaps, transparent soaps, luxury soaps, deodorant soaps, cream soaps, baby soaps, skin protection soaps, abrasive soaps and syndets, liquid soaps such as pasty soaps, soft soaps and washing pastes and liquid washing, showering and bathing preparations such as washing lotions, shower baths and gels, foam baths, oil baths and scrub preparations.
  • the mixtures according to the invention are preferably used in cosmetic compositions for the care and protection of the skin, in nail care compositions and in preparations for decorative cosmetics.
  • skin care products intimate care products, foot care products, light protection agents, repellents, shaving agents, hair removal agents, anti-acne agents, make-up, mascara, lipsticks, eye shadows, eye pencils, eyeliners, blushers, powders and eyebrow pencils is particularly preferred.
  • the skin care products are present in particular as W / O or O / W skin creams, day and night creams, eye creams, face creams, anti-wrinkle creams, moisturizing creams, bleaching creams, vitamin creams, skin lotions, care lotions and moisturizing lotions.
  • the compositions according to the invention can be applied in a form suitable for skin care, for example as a cream, foam, gel, stick, powder, mousse, milk or lotion.
  • the skin cosmetic preparations can also contain additives customary in cosmetics such as emulsifiers, preservatives, perfume oils, cosmetic active ingredients such as phytantriol, vitamins A, E and C, retinol, bisabolol, panthenol, light stabilizers, bleaching agents, colorants, tinting agents, Contain browning agents (e.g. dihydroxyacetone), collagen, protein hydrolyzates, stabilizers, pH regulators, dyes, salts, thickeners, gelling agents, consistency agents, silicones, humectants, refatting agents and other common additives.
  • additives customary in cosmetics such as emulsifiers, preservatives, perfume oils, cosmetic active ingredients such as phytantriol, vitamins A, E and C, retinol, bisabolol, panthenol, light stabilizers, bleaching agents, colorants, tinting agents, Contain browning agents (e.g. dihydroxyacetone), collagen, protein hydrolyzates, stabilize
  • Suitable solvents include water and lower monoalcohols or polyols with 1 to 6 carbon atoms or mixtures thereof; preferred monoalcohols or polyols are ethanol, i-propanol, propylene glycol, glycerin and sorbitol.
  • fatty substances such as mineral and synthetic oils such as paraffins, silicone oils and aliphatic hydrocarbons with more than 8 carbon atoms, animal and vegetable oils such as sunflower oil, coconut oil, avocado oil, olive oil, lanolin or waxes, fatty acids, fatty acid esters such as triglycerides of C 6 -C 3 o-fatty acids, wax esters such as jojoba oil, fatty alcohols, petroleum jelly, hydrogenated lanolin and acetylated lanolin. Mixtures of the same can of course also be used.
  • mineral and synthetic oils such as paraffins, silicone oils and aliphatic hydrocarbons with more than 8 carbon atoms
  • animal and vegetable oils such as sunflower oil, coconut oil, avocado oil, olive oil, lanolin or waxes
  • fatty acids such as triglycerides of C 6 -C 3 o-fatty acids
  • wax esters such as jojoba oil
  • fatty alcohols such as jojoba oil
  • petroleum jelly hydrogenated lanolin and
  • Typical thickeners in such formulations are crosslinked polyacrylic acids and their derivatives, polysaccharides such as xanthan gum, agar agar, alginates or tyloses, carboxymethyl cellulose or hydroxycarboxymethyl cellulose, fatty alcohols, monoglycerides and fatty acids, polyvinyl alcohol and polyvinyl pyrrolidone.
  • the mixtures according to the invention can also be mixed with conventional polymers or polymers according to EP-A 1 064 924 if special properties are to be set.
  • the mixtures according to the invention are used in cosmetic preparations, the preparation of which takes place according to the usual rules familiar to the person skilled in the art.
  • Such formulations are advantageously in the form of emulsions, preferably as water-in-oil (W / O) or oil-in-water (O / W) emulsions.
  • W / O water-in-oil
  • O / W oil-in-water
  • Emulsions which can be used according to the invention are prepared by known methods.
  • the emulsions contain conventional constituents such as fatty alcohols, fatty acid esters and in particular fatty acid triglycerides, fatty acids, lanolin and derivatives thereof, natural or synthetic oils or waxes and emulsifiers in the presence of water.
  • a skin cream which can be used according to the invention can be in the form of a W / O emulsion.
  • a W / O emulsion contains an aqueous phase which is emulsified in an oil or fat phase by means of a suitable emulsifier system.
  • the concentration of the emulsifier system in this type of emulsion is about 4 to 35% by weight, based on the total weight of the emulsion; the fat phase makes up about 20 to 60% by weight and the aqueous phases about 20 to 70% by weight, in each case based on the total weight of the emulsion.
  • the emulsifiers are those which are usually used in this type of emulsion.
  • C 12 -C 8 sorbitan fatty acid esters are selected from C 12 -C 8 sorbitan fatty acid esters; Esters of hydroxystearic acid and C 12 -C 3 o-fatty alcohols; Mono- and diesters of C 12 -C 8 fatty acids and glycerol or polyglycerol; Condensates of ethylene oxide and propylene glycols; oxypropylenated / oxyethylenated C 12 -C 2 o fatty alcohols; polycyclic alcohols such as sterols; high molecular weight aliphatic alcohols such as lanolin; Mixtures of oxypropylene / polyglycerolated alcohols and magnesium isostearate; Succhine esters of polyoxyethylenated or polyoxypropylenated fatty alcohols and mixtures of Magnesium, calcium, lithium, zinc or aluminum lanolate and hydrogenated lanolin or lanolin alcohol.
  • Suitable fat components which can be contained in the fat phase of the emulsions include hydrocarbon oils such as paraffin oil, purcellin oil, perhydrosqualene and solutions of microcrystalline waxes in these oils, animal or vegetable oils such as sweet almond oil, avocado oil, calophylum oil, lanolin and derivatives thereof, castor oil, sesame oil , Olive oil, jojoba oil, karite oil, hoplostethus oil, mineral oils whose distillation begins at atmospheric pressure at approx.
  • hydrocarbon oils such as paraffin oil, purcellin oil, perhydrosqualene and solutions of microcrystalline waxes in these oils
  • animal or vegetable oils such as sweet almond oil, avocado oil, calophylum oil, lanolin and derivatives thereof, castor oil, sesame oil , Olive oil, jojoba oil, karite oil, hoplostethus oil, mineral oils whose distillation begins at atmospheric pressure at approx.
  • esters of saturated or unsaturated fatty acids such as alkyl myristates, for example i-propyl, butyl or cetyl myristate, hexadecyl stearate, ethyl or i-propyl palmitate, octanoic or decanoic acid triglycerides and cetylricinoleate.
  • the fat phase can also contain silicone oils soluble in other oils, such as dimethylpolysiloxane, methylphenylpolysiloxane and the silicone glycol copolymer, fatty acids and fatty alcohols.
  • waxes can also be used, such as, for example, carnauba wax, candellila wax, beeswax, microcrystalline wax, ozokerite wax and calcium, magnesium and aluminum oleates, myristates, linoleates and stearates.
  • these water-in-oil emulsions are made by adding the fat phase and emulsifier to the batch container. It is heated at a temperature of 70 to 75 ° C., then the oil-soluble ingredients are added and, with stirring, water is added which has previously been heated to the same temperature and in which the water-soluble ingredients have been dissolved beforehand; the mixture is stirred until an emulsion of the desired fineness is obtained and then allowed to cool to room temperature, stirring less if necessary.
  • a care emulsion according to the invention can be present as an O / W emulsion.
  • Such an emulsion usually contains an oil phase, emulsifiers which stabilize the oil phase in the water phase and an aqueous phase which is usually present in a thickened state.
  • the aqueous phase of the O / W emulsion of the preparations according to the invention optionally contains Alcohols, diols or polyols and their ethers, preferably ethanol, isopropanol, propylene diglycol, glycerin, ethylene glycol monoethyl ether;
  • thickeners or gel formers such as crosslinked polyacrylic acids and their derivatives, polysaccharides such as xanthan gum or
  • Algjnate carboxymethyl cellulose or hydroxycarboxymethyl cellulose, fatty alcohols, polyvinyl alcohol and polyvinyl pyrrodlidone.
  • the oil phase contains common oil components in cosmetics such as:
  • Silicone oils such as cyclomethicone, dimethylpolysiloxane, diethylpolysiloxane, octamethylcyclotetrasiloxane and mixtures thereof;
  • Triglycerides of saturated and / or unsaturated, branched and / or unbranched C 8 -C 2 -alkane carboxylic acids can be selected from synthetic, semi-synthetic or natural oils such as olive oil, palm oil, almond oil or
  • Preferred emulsifiers are O / W emulsifiers such as polyglycerol esters, sorbitan esters or partially esterified glycerides. It can be produced by melting the oil phase at approx. 80 ° C; the water-soluble constituents are dissolved in hot water, added slowly and with stirring to the oil phase, homogenized and stirred cold.
  • the mixtures according to the invention are also suitable for use in washing and shower gel formulations and bath preparations.
  • such formulations optionally contain amphoteric and nonionic surfactants as cosurfactants, and also lipids, perfume oils, dyes, organic acids, preservatives and antioxidants, and also thickeners / gel formers, skin conditioners and humectants.
  • amphoteric and nonionic surfactants as cosurfactants, and also lipids, perfume oils, dyes, organic acids, preservatives and antioxidants, and also thickeners / gel formers, skin conditioners and humectants.
  • the mixtures and cosmetic compositions according to the invention show a reduction in skin irritation.
  • the skin irritation is usually checked after the zein test. This test is explained in more detail in the example.
  • the zein test is further explained in US 5,562,912.
  • the mixtures according to the invention show advantages in the solubilization of hydrophobic ingredients in the cosmetic compositions.
  • the hydrophobic ingredients or active ingredients can often be molecularly solubilized.
  • nonionic additives as described above, is particularly advantageous for reasons of compatibility of the formulation components with one another.
  • the betaines commonly used can be replaced by the alkyl glycol alkoxylates or diglycol alkoxylates described here.
  • the following table shows the effect of the alkoxylate on the skin irritation in comparison to the market standard, cocoamidopropyl betaine (GAB).
  • GAB cocoamidopropyl betaine
  • Hair cosmetic composition (general) a) 0.8 to 5% by weight of the mixture according to the invention b) 95 to 99.2% by weight of water and / or alcohol c) 0 to 95.2% by weight of further constituents
  • Alcohol is to be understood to mean all alcohols customary in cosmetics, e.g. Ethanol, isopropanol, n-propanol.
  • constituents are to be understood as the additives customary in cosmetics, for example blowing agents, defoamers, surface-active compounds, i.e. Surfactants, emulsifiers, foaming agents and solubilizers.
  • surface-active compounds i.e. Surfactants, emulsifiers, foaming agents and solubilizers.
  • the surface-active compounds used can be anionic, cationic, amphoteric or neutral.
  • Other common ingredients may also be e.g.
  • Preservatives perfume oils, opacifiers, active substances, UV filters, care substances such as panthenol, collagen, vitamins, protein hydrolyzates, alpha and beta hydroxycarboxylic acids, chitosan, protein hydrolyzates, cosmetic polymers, stabilizers, pH regulators, dyes, viscosity regulators , Gelling agents, dyes, salts, humectants, refatting agents, complexing agents and other common additives.
  • Example 1 Conditioner Shampoo with PO-10 35.70 g Sodium Laureth Sulfate
  • Example 2 Conditioner shampoo with GHTC
  • Example 3 Conditioner shampoo with Luviquat Care
  • phase A components Weigh in and dissolve phase A components; Set pH to 6-7. Add phase B and warm to 50 ° C. Allow to cool to room temperature while stirring.
  • the mixtures according to the invention are also suitable in hair styling preparations, in particular hair foams (aerosol foams with propellant gas and pump foams without propellant gas), hair sprays (aerosol sprays with propellant gas and pump sprays without propellant gas) and hair gels.
  • Blowing agents are the commonly used blowing agents. Mixtures of propane / butane, pentane, dimethyl ether, 1,1-difh ⁇ orethane (HFC-152 a), carbon dioxide, nitrogen or compressed air are preferred.
  • Aerosol hair foam a) 0.1 to 10% by weight of a cosmetic polymer b) 55 to 99.8% by weight of water and / or alcohol c) 5 to 20% by weight of a blowing agent d) 0.1 to 5 %
  • mixture e) according to the invention 0 to 10% by weight of further constituents
  • emulsifiers commonly used in hair foams can be used as further constituents.
  • Suitable emulsifiers can be nonionic, cationic or anionic or amphoteric.
  • nonionic emulsifiers are Laurethe, for example Laureth-4; Cetethe, for example cetheth-1, polyethylene glycol cetyl ether; Cetearethe, for example cetheareth-25, polyglycol fatty acid glycerides, hydroxylated lecithin, lactyl esters of fatty acids, alkyl polyglycosides.
  • cationic emulsifiers are cetyldimethyl-2-hydroxyethylammonium dihydrogen phosphate, cetyltrimonium chloride, cetyltrimmonium bromide, cocotrimonium methyl sulfate, quaternium-1 to x (LNC ⁇ ).
  • Anionic emulsifiers may for example be selected from the group of alkyl sulfates, alkyl ether sulfates, alkylsulfonates, alkylarylsulfonates, alkyl succinates, alkyl sulphosuccinates, N-Alkoylsarkosinate, acyl taurates, acyl isethionates, alkyl phosphates, Alkylethe triphosphate, alkyl ether carboxylates, alpha-olefin sulfonates, especially the alkali metal and alkaline earth metal salts, e.g. Sodium, potassium, magnesium, calcium, as well as ammonium and triethanolamine salts.
  • the alkyl ether sulfates, alkyl ether phosphates and alkyl ether carboxylates can have between 1 and 10 ethylene oxide or propylene oxide units, preferably 1 to 3 ethylene oxide units in the molecule.
  • a preparation suitable according to the invention for styling gels can be composed, for example, as follows:
  • Example 9 Aerosol hair foam 2.00 g cocotrimonium methosulfate q.s. Perfume 3.50 g setting polymer e.g. Polyquaternium-46, PQ-44, VP / methacrylamide /
  • Styling gel a) 0.1 to 10% by weight of a cosmetic polymer b) 60 to 99.85% by weight of water and / or alcohol c) 0.05 to 10% by weight of a gelling agent d) 0.1 up to 5% by weight of the mixture e) according to the invention 0 to 20% by weight of further constituents
  • gel formers customary in cosmetics can be used as gel formers. These include slightly cross-linked polyacrylic acid, e.g. carbomer (INCI), cellulose derivatives, e.g. Hydroxypropyl cellulose, hydroxyethyl cellulose, cationically modified celluloses,
  • slightly cross-linked polyacrylic acid e.g. carbomer (INCI)
  • cellulose derivatives e.g. Hydroxypropyl cellulose, hydroxyethyl cellulose, cationically modified celluloses
  • Polysaccharides e.g. xanthum gum, caprylic / capric triglycerides, sodium acrylates Copolymer, Polyquaternium-32 (and) Paraffinum Liquidum (J-NCI), Sodium Acrylates Copolymer (and) Paraffinum Liquidum (and) PPG-1 Trideceth-6, Acrylamidopropyl Trimomum Chloride / Acrylamide Copolymer, Steareth-10 Allyl Ether Acrylates Copolymer, Polyquaternium -37 (and) Paraffinum Liquidum (and) PPG-1 Trideceth-6, Polyquaternium 37 (and) Propylene Glycole Dicaprate Dicaprylate (and) PPG-1 Trideceth-6, Polyquaternium-7, Polyquaternium-44.
  • J-NCI Paraffinum Liquidum
  • PPG-1 Trideceth-6 Acrylamidopropyl Trimomum Chloride / Acrylamide Cop
  • setting polymer e.g. VP / methacrylamide / vinyl imidazole copolymer
  • a preparation suitable according to the invention for styling sprays can be composed, for example, as follows:
  • Aerosol styling spray a) 0.1 to 10% by weight of a cosmetic polymer b) 55 to 99.8% by weight of water and / or alcohol c) 5 to 20% by weight of a propellant d) 0.1 to 5 %
  • a cosmetic polymer b) 55 to 99.8% by weight of water and / or alcohol c) 5 to 20% by weight of a propellant d) 0.1 to 5 %
  • a propellant d
  • Example 16 Aerosol hairspray VOC55
  • panthenol 0.10 g benzophenone-3
  • Example 18 Aerosol hairspring VOC80 5.00 g acrylate copolymer
  • Example 19 Aerosol hairspray VOC80 3.00 g PEG / PPG-25/25 Dimethicone / Acrylates Copolymer
  • Example 20 Aerosol hairspray VOC95 0.95 g aminomethyl propanol 0.60 g alkyl glycol alkoxylates according to the invention 0.10 g dimethicone copolyol
  • Example 21 Pump hair spray 11.20 g PEG / PPG-25/25 Dimethicone / Acrylates Copolymer
  • Example 22 Pump hair spray VOC55 2.00 g VP / methacrylamide / vinyl imidazole copolymer
  • the droplet size distribution of the sprays is advantageously influenced in the direction of smaller droplets, so that finer spray mists are formed or even formulations which are difficult to spray are brought into a sprayable application at all ,
  • Example 23 Liquid makeup phase A 1.70 g glyceryl stearate 1.70 g cetyl alcohol
  • iron oxide / AI powder / silica e.g. Sicoj BASF
  • setting polymer e.g. polyurethane-1 or
  • Example 26 Sun protection emulsion with TiO 2 and ZnO?
  • Example 30 Facial cleansing milk Tvp O / W
  • alkyl glycol alkoxylates according to the invention 35.00 g of PVP (20% solution in water)

Abstract

The invention relates to a mixture of alkyl glycol alkoxylates or diglycol alkoxylates, obtained by means of alkoxylation of C4-8 alkyl glycols or diglycols with C2-5 alkoxides up to a mean degree of alkoxylation of 1 to 8, based on the C4-8 alkyl glycols or diglycols and alkyl sulphates, alkyl ether sulphates, alkyl sulphonates, which have a C8-30 alkyl group, or mixtures thereof which find application in cosmetic compositions.

Description

Alkylglykolalkoxylate oder -diglykolalkoxylate enthaltende kosmetische Zusammensetzungen Cosmetic compositions containing alkyl glycol alkoxylates or diglycol alkoxylates
Die vorliegende Erfindung betrifft Mischungen von Alkylglykolalkoxylaten oder -diglykolalkoxylaten mit bestimmten anionischen Tensiden, diese Mischungen enthaltende kosmetische und/oder dermatologische Zusammensetzungen sowie Verfahren zur Verminderung der Hautreizwirkung von Tensiden oder Tensidmischungen und Verfahren zur Solubilisierung von Inhaltsstoffen von kosmetischen und/oder dermatologischen Zusammensetzungen und Verfahren zur Verbesserung der Versprühbarkeit von kosmetischen und/oder dermatologischen Zusammensetzungen.The present invention relates to mixtures of alkyl glycol alkoxylates or diglycol alkoxylates with certain anionic surfactants, cosmetic and / or dermatological compositions containing these mixtures and methods for reducing the skin irritation of surfactants or surfactant mixtures and methods for solubilizing ingredients of cosmetic and / or dermatological compositions and methods for Improving the sprayability of cosmetic and / or dermatological compositions.
Kosmetische und/oder dermatologische Zusammensetzungen, wie haarkosmetische Zubereitungen oder hautkosmetische Zubereitungen oder Mund- und/oder Zahnpflegezubereitungen oder pharmazeutische Zusammensetzungen, weisen in aller Regel Tenside oder Tensidmischungen auf. Zur Reinigung von Haut und Haaren sind amphiphile Verbindungen erforderlich, die fettigen und öligen Schmutz emulgieren und abtransportieren können. Gut wirksame Tenside wie Natriumdodecylsulfat dringen allerdings auch in die Haut ein und sorgen dort durch die Wechselwirkung mit den Zellen, beispielsweise den Phospholipiden der Zellmembran, zu Irritationen. Da eine schmerzhafte Reaktion der Haut auf die Körperpflegemittel nicht akzeptabel ist, wird das Tensidsystem kosmetischer Reinigungsformulierungen, beispielsweise von Shampoos oder Duschgelen oder Badezusätzen auf Basis milder, d.h. gut hautverträglicher Tenside aufgebaut. Häufig wird dabei das anionische Tensidsystem mit Ethersulfaten aufgebaut, oder zwitterionische Tenside auf Basis von Betainen oder Isethionaten oder nichtionische Tenside wie Glucamide oder Polyglycoside werden mit verwendet, um im Reinigungsmittel die Tensidmischung milder zur Haut zu machen und die Reinigungswirkung zu unterstützen. Auch der Einsatz von Poloxameren, wie Ethylenoxid-Propylenoxid-Blockcopolymeren, als Zusatzstoff zu den Tensidformulierungen führt zu einer Abmilderung der Hautreizwirkung.Cosmetic and / or dermatological compositions, such as hair cosmetic preparations or skin cosmetic preparations or mouth and / or dental care preparations or pharmaceutical compositions, generally have surfactants or surfactant mixtures. To clean skin and hair, amphiphilic compounds are required that can emulsify and remove greasy and oily dirt. However, highly effective surfactants such as sodium dodecyl sulfate also penetrate the skin and cause irritation due to the interaction with the cells, for example the phospholipids of the cell membrane. Since a painful reaction of the skin to the personal care products is not acceptable, the surfactant system of cosmetic cleaning formulations, for example shampoos or shower gels or bath additives, is milder, i.e. well-tolerated surfactants. The anionic surfactant system is often built up with ether sulfates, or zwitterionic surfactants based on betaines or isethionates or nonionic surfactants such as glucamides or polyglycosides are used to make the detergent mixture milder to the skin and to support the cleansing effect. The use of poloxamers, such as ethylene oxide-propylene oxide block copolymers, as an additive to the surfactant formulations also leads to a reduction in the skin irritation effect.
In der US 5,562,912 sind flüssige Hautreinigungszusammensetzungen beschrieben, die eine verminderte Hautreizwirkung aufweisen. Die Zusammensetzungen enthalten eine Kombination eines nichtionischen Tensids auf Basis eines Ethylenoxid/Propylen- oxid/Ethylenoxid-Triblockcopolymers und eines Polyvinylpyrrolidons. Die Kombination dieser beiden Inhaltsstoffe führt zur Verminderung der Hautreizwirkung von flüssigen Hautreinigungsformulierungen. Ferner werden die Schäumeigenschaften und das Handgefühl der Formulierungen verbessert.No. 5,562,912 describes liquid skin cleaning compositions which have a reduced skin irritation effect. The compositions contain a combination of a nonionic surfactant based on an ethylene oxide / propylene oxide / ethylene oxide triblock copolymer and a polyvinylpyrrolidone. The combination of these two ingredients leads to a reduction in the skin irritation of liquid skin cleaning formulations. Furthermore, the foaming properties and the hand feel of the formulations are improved.
Es besteht jedoch weiterhin große Nachfrage nach Produkten, die die Hautreizwirkung von Tensiden oder Tensidmischungen in kosmetischen Zusammensetzungen vermindern. Die Produkte sollen vorzugsweise wirksamer als die üblicherweise eingesetzten Betaine sein und sollen die Reinigungswirkung der Tenside oder Tensidmischungen verstärken. Ferner besteht auch Nachfrage an Zusatzstoffen, die als Solubilisator für hydrophobe Wirkstoffe wirken.However, there continues to be a great demand for products which reduce the skin irritation of surfactants or surfactant mixtures in cosmetic compositions. The products should preferably be more effective than the betaines commonly used and should increase the cleaning action of the surfactants or surfactant mixtures. There is also a demand for additives that act as solubilizers for hydrophobic active ingredients.
Aufgabe der vorliegenden Erfindung ist die Bereitstellung der vorstehend genannten Produkte.The object of the present invention is to provide the aforementioned products.
Die Aufgabe wird erfindungsgemäß gelöst durch eine Mischung aus Alkylglykolalkoxylaten oder -diglykolalkoxylaten, erhältlich durch Alkoxylierung von . 8-Alkylglykolen oder -diglykolen mit C2-5-Alkoxiden bis zu einem mittleren Alkoxylierungsgrad von 1 bis 8, bezogen auf die C4-8-Alkylglykole oder -diglykole,The object is achieved according to the invention by a mixture of alkyl glycol alkoxylates or diglycol alkoxylates, obtainable by alkoxylation of. 8-alkyl glycols or diglycols with C 2 -5 alkoxides up to an average degree of alkoxylation of 1 to 8, based on the C 4 - 8 alkyl glycols or diglycols,
und Alkylsulfaten, Alkylethersulfaten, Alkylsulfonaten, die einen C8-3o-Alkylrest aufweisen, oder Gemischen davon.and alkyl sulfates, alkyl ether sulfates, alkyl sulfonates having a C 8 - having 3 o-alkyl radical, or mixtures thereof.
Aus der prioritätsälteren, nicht vorveröffentlichten DE-A 102 02 007 sind derartige Alkylglykolalkoxylate, ihre Mischungen mit Tensiden und ihre Verwendung in unterschiedlichen Zusammensetzungen bekannt. Mischungen der Alkylglykolalkoxylate oder -diglykolalkoxylate mit den vorstehenden speziellen anionischen Tensiden sind jedoch nicht beschrieben.Such alkyl glycol alkoxylates, their mixtures with surfactants and their use in different compositions are known from DE-A 102 02 007, which is older and not prepublished. However, mixtures of the alkyl glycol alkoxylates or diglycol alkoxylates with the above special anionic surfactants are not described.
Es wurde erfindungsgemäß gefunden, dass eine Kombination der Alkylglykolalkoxylate oder -diglykolalkoxylate, wie sie vorstehend definiert sind, mit Tensiden oder Tensidmischungen zu einer signifikanten Verminderung der Hautreizwirkung der Tenside oder Tensidmischungen führt. Die Wirkung ist dabei vergleichbar mit der Wirkung der üblicherweise eingesetzten Betaine. Zudem verstärken die erfindungsgemäß eingesetzten Alkylglykolalkoxylate und -diglykolalkoxylate die Reinigungswirkung der Tenside. Ferner wirken die Alkylglykolalkoxylate und -diglykolalkoxylate als Solubilisator für hydrophobe Inhaltsstoffe von kosmetischen Zusammensetzungen. Zudem wurde eine Wirkung der erfindungsgemäß eingesetzten Alkylglykolalkoxylate und -diglykolalkoxylate auf die Verbesserung der Sprühbarkeit und Verminderung der Tröpfchengrößen(verteilung) in kosmetischen Aerosolsprays und Sprays gefunden.It has been found according to the invention that a combination of the alkyl glycol alkoxylates or diglycol alkoxylates as defined above with surfactants or surfactant mixtures leads to a significant reduction in the skin irritant effect of the surfactants or surfactant mixtures. The effect is comparable to the effect of the betaines commonly used. In addition, the alkyl glycol alkoxylates and diglycol alkoxylates used according to the invention enhance the cleaning action of the surfactants. The alkyl glycol alkoxylates and diglycol alkoxylates also act as a solubilizer for hydrophobic ingredients in cosmetic compositions. In addition, an effect of Alkyl glycol alkoxylates and diglycol alkoxylates used according to the invention to improve the sprayability and reduce the droplet sizes (distribution) found in cosmetic aerosol sprays and sprays.
Entsprechend betrifft die Erfindung auch ein Verfahren zur Vermindung der Hautreizwirkung von Tensiden oder Tensidmischungen, bei dem man das Tensid oder die Tensidmischung in Kombination mit Alkylglykolalkoxylaten oder -diglykolalkoxylaten, erhältlich durch Alkoxylierung von C4.8-Alkylglykolen oder -diglykolen mit C2-5- Alkoxiden bis zu einem mittleren Alkoxylierungsgrad von 1 bis 8, bezogen auf die C -8- Alkylglykole oder -diglykole, einsetzt.Accordingly, the invention also relates to a method for reducing the skin irritation of surfactants or surfactant mixtures, in which the surfactant or the surfactant mixture in combination with alkyl glycol alkoxylates or diglycol alkoxylates, obtainable by alkoxylation of C 4 . 8 alkyl glycols or diglycols with C 2 - 5 - alkoxides to an average degree of alkoxylation of 1 to 8, based on the C - 8 - alkyl glycols or -diglykole, begins.
Ebenso betrifft die Erfindung ein Verfahren zur Solubilisierung von hydrophoben Inhaltsstoffen von kosmetischen Zusammensetzungen, bei dem man die Inhaltsstoffe in Kombination mit Alkylglykolalkoxylaten oder -diglykolalkoxylaten, erhältlich durch Alkoxylierung von C -8-Alkylglykolen oder -diglykolen mit C2-5-Alkoxiden bis zu einem mittleren Alkoxylierungsgrad von 1 bis 8, bezogen auf die C .8-Alkylglykole oder -diglykole, einsetzt.The invention also relates to a process for the solubilization of hydrophobic ingredients in cosmetic compositions, in which the ingredients are combined with alkyl glycol alkoxylates or diglycol alkoxylates, obtainable by alkoxylation of C 8 alkyl glycols or diglycols with C 2 5 alkoxides up to one average degree of alkoxylation from 1 to 8, based on the C. 8 alkyl glycols or diglycols.
Weiterhin betrifft die Erfindung ein Verfahren zur Verbesserung der Versprühbarkeit durch Vermindern der Tröpfchengröße von kosmetischen und/oder dermatologischen Sprayzusammensetzungen, bei dem man die Inhaltsstoffe in Kombination mit Alkylglykolalkoxylaten oder -diglykolalkoxylaten, erhältlich durch Alkoxylierung von C4- 8-Alkylglykolen oder -diglykolen mit C2-5-Alkoxiden bis zu einem mittleren Alkoxylierungsgrad von 1 bis 8, bezogen auf die C -s-Alkylglykole oder -diglykole, oder in Kombination mit den erfindungsgemäßen Mischungen einsetzt.Furthermore, the invention relates to a method for improving the sprayability by reducing the droplet size of cosmetic and / or dermatological spray compositions, in which -diglykolalkoxylaten the ingredients in combination with Alkylglykolalkoxylaten or obtainable by alkoxylating C 4-8 alkyl glycols or diglycols with C 2 -5-alkoxides up to an average degree of alkoxylation of 1 to 8, based on the C -s-alkyl glycols or diglycols, or in combination with the mixtures according to the invention.
Die vorteilhaften Reinigungswirkungen und verminderten Reizwirkungen und Tröpfchengrößenverminderungswirkungen werden insbesondere mit den erfindungsgemäßen Mischungen aus Alkylglykolalkoxylaten oder -diglykolalkoxylaten mit Alkylsulfaten, Alkylethersulfaten, Alkylsulfonaten, die einen C8-3o-Alkylrest aufweisen, oder Gemischen davon erreicht. Der Alkylrest ist vorzugsweise ein C8-22-Alkylrest, insbesondere ein Cio-iö-Alkylrest. Die Alkylreste können dabei linear oder verzweigt oder teilweise verzweigt sein. Vorzugsweise liegen in den Alkylresten im Mittel 0 bis 1,5, besonders bevorzugt 0 bis 1 Verzweigung vor. Insbesondere kann es sich um lineare Alkylreste handeln. Insbesondere liegen die Verbindungen als Alkali- oder Erdalkalimetallsalze oder als Ammonium- oder Triethanolarnin-Salze vor. Bevorzugte Alkali- und Erdalkalimetalle sind Natrium, Kalium, Magnesium und Calcium. Die Alkylethersulfate können von 1 bis 10 Ethylenoxid- oder Propylenoxid-Einheiten, bevorzugt 1 bis 3 Ethylenoxid-Einheiten im Molekül aufweisen.The beneficial cleaning effects and reduced irritation and droplet size reduction effects are especially the inventive mixtures or of Alkylglykolalkoxylaten -diglykolalkoxylaten with alkyl sulfates, alkyl ether sulfates, alkyl sulfonates having a C 8 - having 3 o-alkyl radical, or mixtures thereof reached. The alkyl group is preferably a C 8-22 -alkyl radical, in particular a Cio-IOE radical. The alkyl radicals can be linear or branched or partially branched. There is preferably an average of 0 to 1.5, particularly preferably 0 to 1, branching in the alkyl radicals. In particular, it can be linear alkyl radicals. In particular, the compounds are present as alkali or alkaline earth metal salts or as ammonium or triethanolamine salts. Preferred alkali and alkaline earth metals are sodium, potassium, magnesium and calcium. The alkyl ether sulfates can have from 1 to 10 ethylene oxide or propylene oxide units, preferably 1 to 3 ethylene oxide units, in the molecule.
Geeignet sind beispielsweise Natriumlaurylsulfat, Ammoniumlaurylsulfat, Natrium- laurylethersulfat, Ammomumlaurylethersulfat, und ähnliche Verbindungen.Sodium lauryl sulfate, ammonium lauryl sulfate, sodium lauryl ether sulfate, ammonium lauryl ether sulfate, and similar compounds are suitable, for example.
Die nachstehenden Ausführungen beziehen sich ebenso auf Alkyldiglykole wie auf Alkylglykole bzw. deren Alkoxylate.The statements below relate to alkyl diglycols as well as to alkyl glycols or their alkoxylates.
Die erfindungsgemäßen Mischungen enthalten als eine Komponente C2-5-Alkoxylate, das heißt Alkoxylate mit C2-5-Alkoxiden, von C -s-Alkylglykolen, die im Mittel einen Alkoxylierungsgrad von 1 bis 8 aufweisen. Bei den Alkylglykolen kann es sich um lineare oder verzweigte Alkylglykole handeln. Die Anbindung des C4-s-Alkylrestes an den Glykol kann endständig oder an einer anderen Position entlang der Alkylkette erfolgen. Vorzugsweise handelt es sich um lineare Alkylglykole, insbesondere um lineare, endständige Alkylglykole. Vorzugsweise weisen die Alkylreste der Alkylglykole 4 bis 6 Kohlenstoffatome auf. Der Alkoxylierungsgrad beträgt im Mittel 1 bis 8, vorzugsweise 2 bis 6. Zur Alkoxylierung können dabei vorzugsweise C2-4-Alkoxide eingesetzt werden. Vorzugsweise werden Ethylenoxid, Propylenoxid, Butylenoxid oder Gemische davon eingesetzt. Besonders bevorzugt wird Ethylenoxid eingesetzt. Die bevorzugten Bereiche beziehen sich auch auf die Alkylglykolalkoxylate und Alkyldiglykolalkoxylate an sich.The mixtures according to the invention contain as a component C 2 - 5 alkoxylates, i.e. alkoxylates with C 2 - 5 alkoxides, having from C-S-alkyl glycols on average a degree of alkoxylation of 1 to 8 The alkyl glycols can be linear or branched alkyl glycols. The C 4 -s-alkyl radical can be attached to the glycol at the end or at another position along the alkyl chain. They are preferably linear alkyl glycols, in particular linear, terminal alkyl glycols. The alkyl radicals of the alkyl glycols preferably have 4 to 6 carbon atoms. The degree of alkoxylation is on average 1 to 8, preferably 2 to 6. C 2 - 4 alkoxides can preferably be used for the alkoxylation. Ethylene oxide, propylene oxide, butylene oxide or mixtures thereof are preferably used. Ethylene oxide is particularly preferably used. The preferred ranges also refer to the alkyl glycol alkoxylates and alkyl diglycol alkoxylates themselves.
Die Herstellung erfolgt, ausgehend von alkoholfreien, vorzugsweise reinen Alkylglykolen und Alkyldiglykolen und nicht, wie sonst üblich, ausgehend von Alkanolen, durch Alkoxylierung. Daher enthalten die Produktgemische auch keine verbleibenden Alkanole, sondern höchstens Alkylglykole. Es ergibt sich eine für Alkylglykole spezifische Verteilung des Alkoxylierungsgrades. Durch das Herstellungsverfahren sind die Alkylglykolalkoxylate frei von Alkoholen.The preparation takes place starting from alcohol-free, preferably pure alkyl glycols and alkyl diglycols and not, as is usually the case, starting from alkanols, by alkoxylation. Therefore, the product mixtures do not contain any remaining alkanols, but at most alkyl glycols. The distribution of the degree of alkoxylation is specific for alkyl glycols. Due to the manufacturing process, the alkyl glycol alkoxylates are free of alcohols.
Alkoxylate sind oligomere oder polymere Umsetzungsprodukte mit Alkoxiden. Aufgrund der dem Fachmann bekannten Kinetik von Polymerisationen kommt es zwangsläufig zu einer statistischen Verteilung von Homologen, deren Mittelwert üblicherweise angegeben wird. Die Häufigkeitsverteilung der Homologen beinhaltet insbesondere bei niedrigen Alkoxylierungsgraden den Ausgangsstoff. Durch die Wahl des Katalysators kann zwar die Verteilung in gewissem Umfang beeinflußt werden, am Prinzip der Verteilungskurve ändert sich aber nichts. Reine Alkyloligoglykole lassen sich nur durch destillative oder chromatographische Aufarbeitung herstellen und sind daher teuer. Außerdem hat sich gezeigt, daß die Verteilung der Homologen einen deutlichen Einfluß auf das Aggregationsverhalten hat.Alkoxylates are oligomeric or polymeric reaction products with alkoxides. Because of the kinetics of polymerizations known to the person skilled in the art, there is inevitably a statistical distribution of homologs, the mean value of which is usually given. The frequency distribution of the homologs contains the starting material, especially at low degrees of alkoxylation. By choosing the catalyst, the Distribution can be influenced to a certain extent, but nothing changes in the principle of the distribution curve. Pure alkyl oligoglycols can only be prepared by working up by distillation or chromatography and are therefore expensive. It has also been shown that the distribution of the homologs has a significant influence on the aggregation behavior.
Die hier beanspruchten Alkoxylate besitzen die für das Aggregationsverhalten und die anderen erfindungsgemäßen Eigenschaften wichtige Homologenverteilung, ohne Alkohol zu enthalten.The alkoxylates claimed here have the homolog distribution important for the aggregation behavior and the other properties according to the invention, without containing alcohol.
Die Bestimmung der Verteilung der Alkoxylierungsgrade kann durch chromatographische Verfahren erfolgen.The distribution of the degrees of alkoxylation can be determined by chromatographic methods.
Nachstehend sind die Verteilungskurven für ein übliches n-Hexanolefhoxylat (+ 3 EO), abgeleitet von n-Hexanol, und ein n-Hexylglykolethoxylat (+ 2 EO), abgeleitet von n-Hexylglykol, einander tabellarisch gegenübergestellt. In der ersten Spalte ist angegeben, wieviel Ethylenoxid (0 - 6) an den n-Hexylrest (C6) gebunden vorliegt. Im Mittel enthalten beide Verbindungen gleichviele EO-Einheiten.The table below shows the distribution curves for a common n-hexanolefhoxylate (+ 3 EO), derived from n-hexanol, and an n-hexylglycol ethoxylate (+ 2 EO), derived from n-hexylglycol. The first column shows how much ethylene oxide (0-6) is bound to the n-hexyl radical (C6). On average, both compounds contain the same number of EO units.
Figure imgf000006_0001
Figure imgf000006_0001
Die Muster wurden hergestellt mit KOH als Katalysator durch Einleiten von 2 oder 3 mol/ (mol Ausgangsstoff) Ethylenoxid zum jeweiligen Ausgangsstoff. Die Analyse erfolgte durch Gelpermeationschromatographie (GPC) in THF. Das Hexanolsignal wurde durch Aufstocken mit Hexanol identifiziert, die höheren Homologen aus der Abfolge der weiteren Signale. Die Auswertung erfolgte durch die Integration der Signalflächen. In den erfindungsgemäßen Mischungen werden die Alkylglykolalkoxylate vorzugsweise in einer Menge von 0,05 oder 0,1 bis 20, bevorzugt 0,1 bis 10 Gew.-%, besonders bevorzugt 0,5 bis 7 Gew.-%, insbesondere 0,8 bis 5 Gew.- eingesetzt, bezogen auf das Gesamtgewicht der Mischung. Der verbleibende Anteil der Mischungen entfällt auf die Tenside. Diese Mengenangaben gelten auch für aus den Mischungen oder Alkylglykolalkoxylaten hergestellte kosmetische Mittel oder andere Zusammensetzungen.The samples were produced using KOH as a catalyst by introducing 2 or 3 mol / (mol of starting material) ethylene oxide into the respective starting material. The analysis was carried out by gel permeation chromatography (GPC) in THF. The hexanol signal was identified by adding hexanol, the higher homologues from the sequence of further signals. The evaluation was carried out by integrating the signal areas. In the mixtures according to the invention, the alkyl glycol alkoxylates are preferably used in an amount of 0.05 or 0.1 to 20, preferably 0.1 to 10% by weight, particularly preferably 0.5 to 7% by weight, in particular 0.8 to 5% by weight, based on the total weight of the mixture. The remaining proportion of the mixtures is accounted for by the surfactants. These quantities also apply to cosmetic products or other compositions produced from the mixtures or alkyl glycol alkoxylates.
Es ist erfindungsgemäß nicht notwendig und aufgrund des physiologischen Potentials der Alkohole auch nicht erwünscht, dass ein Restgehalt an Alkohol in den erfindungsgemäßen Mischungen oder Formulierungen vorliegt. Gemäß einer Ausführungsform sind die erfindungsgemäßen Mischungen, Mittel und Formulierungen frei von Alkoholen und bevorzugt auch von Alkylglykolen bzw. Diglykolen, insbesondere von C4-8-Alkylglykolen und C93-Alkanolen. Erfindungsgemäß wurde gefunden, dass ohne einen Restgehalt an Alkohol, der üblicherweise bei niedrigen Alkoholalkoxylaten herstellungsbedingt im Produkt enthalten ist, durch Einsatz der erfindungsgemäßen Alkylglykolalkoxylate Tensidformulierungen mit geringer Hautreizung und hoher Reinigungswirkung und Tröpfchengrößenvermindeungswirkung formuliert werden können.According to the invention, it is not necessary and, because of the physiological potential of the alcohols, it is also undesirable for a residual alcohol content to be present in the mixtures or formulations according to the invention. According to one embodiment, the mixtures, compositions and formulations according to the invention are free from alcohols and preferably also from alkyl glycols or diglycols, in particular from C 4 to 8 -alkyl glycols and C 9 to 3 -alkanols. According to the invention, it was found that without a residual alcohol content, which is usually contained in the product in the case of low alcohol alkoxylates due to the production process, by using the alkyl glycol alkoxylates according to the invention, surfactant formulations with little skin irritation and high cleansing action and droplet size reduction effect can be formulated.
In erfindungsgemäß bevorzugten Mischungen sind die Alkylglykolalkoxylate oder -diglykolalkoxylate erhältlich durch Alkoxylierung von C .6-Alkylglykolen oder -diglykolen mit C2. -Alkoxiden bis zu einem mittleren Alkoxylierungsgrad von 2 bis 6.In mixtures preferred according to the invention, the alkyl glycol alkoxylates or diglycol alkoxylates are obtainable by alkoxylation of C. 6 alkyl glycols or diglycols with C 2 . Alkoxides up to an average degree of alkoxylation of 2 to 6.
Die Mischungen können vorteilhaft in kosmetischen Zusammensetzungen eingesetzt werden. Die Erfindung betrifft auch eine kosmetische Zusammensetzung, die eine wie vorstehend beschriebene Mischung enthält. Die Mischung enthält dabei vorzugsweise 0,1 bis 20 Gew.-% der C2-5-Alkoxylate von -s-Alkylglykolen oder -diglykolen, bezogen auf das Gesamtgewicht der Mischung oder des Mittels.The mixtures can advantageously be used in cosmetic compositions. The invention also relates to a cosmetic composition containing a mixture as described above. The mixture preferably contains 0.1 to 20% by weight of the C 2 -5-alkoxylates of -s-alkyl glycols or -diglycols, based on the total weight of the mixture or of the agent.
Die kosmetischen Zusammensetzungen können eine Vielzahl weiterer Inhaltsstoffe enthalten. Beispielsweise kommen als weitere Inhaltsstoffe Betaine, Aminoxide, Salze wie Natriumchlorid, Wasser, quaternisierte Stickstoffatome enthaltende Polymere und Tenside oder Gemische davon, Alkohole, kosmetische Öle und Wachse, Emulgatoren, Silikonverbindungen, Festigerpolymere wie nichtionische, anionische, kationische, zwitterionische oder amphotere Polymerisate, Neutralisationsmittel wie Basen und Säuren, Verdickungs- und Rheologiemodifizierungsmittel, Wirkstoffe und Hilfmittel in Betracht. Geeignete kosmetisch und/oder dermatologisch aktive Wirkstoffe sind z.B. färbende Wirkstoffe, Haut- und Haarpigmentierungsmittel, Tönungsmittel, Bräunungsmittel, Bleichmittel, Keratin-härtende Stoffe, antimikrobielle Wirkstoffe, Lichtfilterwirkstoffe, Repellentwirkstoffe, hyperemisierend wirkende Stoffe, keratolytisch und keratoplastisch wirkende Stoffe, Antischuppenwirkstoffe, Antiphlogistika, keratinisierend wirkende Stoffe, antioxidativ bzw. als Radikalfänger aktive Wirkstoffe, hautbefeuchtende oder - feuchthaltende Stoffe, rückfettende Wirkstoffe, antierythimatös oder antiallergisch aktive Wirkstoffe und Mischungen davon. Geeignete Hilfsstoffe können sein: Gleitmittel, Netzmittel, emulgierende und suspendierende Mittel, konservierende Mittel, Antioxidantien, Antireizstoffe, Chelatbildner, Emulsionsstabilisatoren, Filmbildner, Gelbildner, Geruchsmaskierungsmittel, Harze, Hydrokolloide, Lösemittel, Lösungsvermittler, Neutralisierungsmittel, Permeationsbeschleuniger, Pigmente, quaternäre Ammoniumverbindungen, Rückfettungs- und Überfettungsmittel, Salben-, Creme- oder Öl-Grundstoffe, Siliconderivate, Stabilisatoren, Sterilantien, Treibmittel, Trocknungsmittel, Trübungsmittel, Verdickungsmittel, Wachse, Weichmacher, Weißöle. Eine diesbezügliche Ausgestaltung beruht auf fachmännischem Wissen, wie sie beispielsweise in Fiedler, H. P. Lexikon der Hilfsstoffe für Pharmazie, Kosmetik und angrenzende Gebiete, 4. Aufl., Aulendorf: ECV-Editio-Kantor- Verlag, 1996, dargestellt sind.The cosmetic compositions can contain a large number of further ingredients. For example, betaines, amine oxides, salts such as sodium chloride, water, polymers and surfactants or quaternized nitrogen atoms or mixtures thereof, alcohols, cosmetic oils and waxes, emulsifiers, silicone compounds, setting polymers such as nonionic, anionic, cationic, zwitterionic or amphoteric polymers, neutralizing agents come as further ingredients such as bases and acids, thickening and rheology modifiers, active ingredients and auxiliaries. Suitable cosmetically and / or dermatologically active substances are, for example, coloring substances, skin and hair pigmentation agents, tinting agents, tanning agents, Bleaching agents, keratin-hardening substances, antimicrobial substances, light filter substances, repellent substances, hyperemising substances, keratolytic and keratoplastic substances, anti-dandruff substances, anti-inflammatory substances, keratinising substances, antioxidant or radical scavenger substances, skin moisturizing or re-moisturizing substances or anti-allergic active ingredients and mixtures thereof. Suitable auxiliaries can be: lubricants, wetting agents, emulsifying and suspending agents, preserving agents, antioxidants, anti-irritants, chelating agents, emulsion stabilizers, film-forming agents, gel-forming agents, odor masking agents, resins, hydrocolloids, solvents, solubilizers, neutralizing agents, permeation compounds, accelerators, ammonium salts, pigments and superfatting agents, ointment, cream or oil base materials, silicone derivatives, stabilizers, sterilants, blowing agents, drying agents, opacifying agents, thickening agents, waxes, plasticizers, white oils. A design in this regard is based on professional knowledge, such as that shown in Fiedler, HP Lexicon of auxiliary substances for pharmacy, cosmetics and related areas, 4th ed., Aulendorf: ECV-Editio-Kantor-Verlag, 1996.
Je nach Formulierungtyp der kosmetischen und/oder dermatologischen Zubereitung kommen unterschiedliche Inhaltsstoffe und unterschiedliche übliche Mengen derselben in Betracht.Depending on the type of formulation of the cosmetic and / or dermatological preparation, different ingredients and different customary amounts of the same come into consideration.
Betaine, Aminoxide und quaternisierte Stickstoffatome enthaltende Polymere werden vorzugsweise in Mengen von 0,01 bis 30 Gew.-% eingesetzt. Salze wie Natriumchlorid können vorzugsweise in Mengen von 0,5 bis 10 Gew.-% eingesetzt werden. Wasser kann in nahezu beliebiger Menge eingesetzt werden. Übliche Mengen an Wasser betragen 3 bis 90 Gew.- , besonders bevorzugt 5 bis 80 Gew.-%, z.B. 10 bis 90 Gew.-% oder 20 bis 80 Gew.-%. Alkohole können von 0 bis 95 Gew.-% eingesetzt werden. Kosmetische Öle und Wachse sowie Emulgtoren werden vorzugsweise in Mengen von 0,5 bis 70 Gew.-% verwendet. Silikonverbindungen können in Mengen von 0,05 bis 30 Gew.-% eingesetzt werden. Festigerpolymere wie nichtionische, anionische, kationische oder amphotere Polymerisate werden üblicherweise in Stylingformulierungen in Mengen von 1 bis 15 Gew.-% verwendet. Solche Festigerpolymere mit sauren oder basischen Funktionen werden darin üblicherweise mit Basen oder Säuren bis zu einem gewissen Neutralisationsgrad zwischen 50 und 100% neutralisiert. Die üblichen dafür notwendigen Mengen der Neutralisationsmittel liegen zwischen 0,1 und 20 Gew.-%, je nach Molekulargewichtsequivalent des Neutralisationsmittels. Manche kosmetischen Zubereitungen enthalten zudem Rheologiemodifizierungsmittel in Mengen von 0,05 bis 50 Gew.-%. Üblicherweise sind in kosmetischen und/oder dermatologischen Zubereitungen Wirkstoffe und Hifsstoffe in Mengen von 0,01 bis 50 Gew.-% enthalten.Polymers containing betaines, amine oxides and quaternized nitrogen atoms are preferably used in amounts of 0.01 to 30% by weight. Salts such as sodium chloride can preferably be used in amounts of 0.5 to 10% by weight. Almost any amount of water can be used. Usual amounts of water are 3 to 90% by weight, particularly preferably 5 to 80% by weight, for example 10 to 90% by weight or 20 to 80% by weight. Alcohols can be used from 0 to 95% by weight. Cosmetic oils and waxes as well as emulsifiers are preferably used in amounts of 0.5 to 70% by weight. Silicone compounds can be used in amounts of 0.05 to 30% by weight. Fixing polymers such as nonionic, anionic, cationic or amphoteric polymers are usually used in styling formulations in amounts of 1 to 15% by weight. Such setting polymers with acidic or basic functions are usually neutralized with bases or acids up to a certain degree of neutralization between 50 and 100%. The usual amounts of the neutralizing agent required for this are between 0.1 and 20% by weight, depending on the molecular weight equivalent of the neutralizing agent. Some cosmetic preparations also contain rheology modifiers in amounts of 0.05 to 50 Wt .-%. Cosmetic and / or dermatological preparations usually contain active substances and auxiliary substances in quantities of 0.01 to 50% by weight.
Bei den kosmetischen Zusammensetzungen kann es sich beispielsweise um haarkosmetische Zubereitungen oder um hautkosmetische Zubereitungen oder um Mund- und Zahnpflegezubereitungen handeln. Haarkosmetische Zubereitungen sind beispielsweise Haarshampoos, Haarkuren, Haarlotionen, Haarspülungen, Haaremulsionen, Spitzenfluids, Egalisierungsmittel für Dauerwellen, Haarfärbemittel, "Hot-Oil-Treatment"- Präparate, Conditioner, Festigerlotionen, Haargelen, Haarwachsen, Haarschäumen oder Haarsprays.The cosmetic compositions can be, for example, hair cosmetic preparations or skin cosmetic preparations or oral and dental care preparations. Hair cosmetic preparations are, for example, hair shampoos, hair treatments, hair lotions, hair rinses, hair emulsions, tip fluids, leveling agents for perms, hair colorants, "hot oil treatment" preparations, conditioners, setting lotions, hair gels, hair waxes, hair foams or hair sprays.
Je nach Anwendungsgebiet können die haarkosmetischen Zubereitungen als Spray, Schaum, Gel, Gelspray, Shampoo, Spülung oder Mousse appliziert werden. Man unterscheidet zwischen sogenannten Nachspülanwendungen (engl. rinse-off) und sogenannten im Haar verbleibenden Anwendungen (engl. leave-on).Depending on the area of application, the hair cosmetic preparations can be applied as a spray, foam, gel, gel spray, shampoo, conditioner or mousse. A distinction is made between so-called rinse-off applications and so-called leave-on applications that remain in the hair.
Die haarkosmetischen Zubereitungen können neben den erfindungsgemäßen Mischungen und geeigneten Lösungsmitteln wie Wasser oder Wasser/Alkohol-Gemischen noch in der Kosmetik übliche Zusätze wie Emulgatoren, Konservierungsmittel, Parfümöle, Pflegestoffe wie Panthenol, Collagen, Vitamine, Eiweißhydrolysate, Stabilisatoren, pH- Wert-Regulatoren, Farbstoffe, Salze, Konsistenzgeber, Silikone, Feuchthaltemittel, Rückfetter und weitere übliche Additive enthalten.In addition to the mixtures according to the invention and suitable solvents such as water or water / alcohol mixtures, the hair cosmetic preparations can also contain additives customary in cosmetics such as emulsifiers, preservatives, perfume oils, care substances such as panthenol, collagen, vitamins, protein hydrolyzates, stabilizers, pH regulators, Contain dyes, salts, consistency agents, silicones, humectants, lipid replenishers and other common additives.
Man kann die erfindungsgemäßen Mischungen mit Haarkosmetik-Polymeren abmischen, falls ganz spezielle Eigenschaften eingestellt werden sollen.The mixtures according to the invention can be mixed with hair cosmetic polymers if very special properties are to be set.
Als herkömmliche Kosmetik-Polymere eignen sich beispielsweise anionische Polymere. Solche anionischen Polymere sind Homo- und Copolymerisate von Acrylsäure und Meth- acrylsäure oder deren Salze, Copolymere von Acrylsäure und Acrylamid und deren Salze; Natriumsalze von Polyhydroxycarbonsäuren, wasserlösliche oder wasserdispergierbare Polyester, Polyurethane (z.B. Luviset® P.U.R. der BASF AG) und Polyharnstoffe. Besonders geeignete Polymere sind Copolymere aus t-Butylacrylat, Ethylacrylat, Methacrylsäure (z.B. Luvimer® 100P der BASF AG), Copolymere aus N-tert- Butylacrylamid, Ethylacrylat, Acrylsäure (z.B. Ultrahold® 8, Strong der BASF AG), Copolymere aus Vinylacetat, Crotonsäure und gegebenenfalls weiteren Vinylestern (z.B. Luviset® Marken der BASF AG), Maleinsäureanhydridcopolymere, ggf. mit Alkoholen umgesetzt, anionische Polysiloxane, z.B. carboxyfunktionelle, Copolymere aus Vinylpyrrolidon, t-Butylacrylat, Methacrylsäure (z.B Luviskol® VBM der BASF AG).For example, anionic polymers are suitable as conventional cosmetic polymers. Such anionic polymers are homopolymers and copolymers of acrylic acid and methacrylic acid or their salts, copolymers of acrylic acid and acrylamide and their salts; Sodium salts of polyhydroxycarboxylic acids, water-soluble or water-dispersible polyesters, polyurethanes (eg Luviset ® PUR from BASF AG) and polyureas. Particularly suitable polymers are copolymers of t-butyl acrylate, ethyl acrylate, methacrylic acid (for example, Luvimer ® 100P from BASF AG), copolymers of N-tert-butyl acrylamide, ethyl acrylate, acrylic acid (eg, Ultrahold ® 8, Strong of BASF AG), copolymers of vinyl acetate, Crotonic acid and optionally other vinyl esters (e.g. Luviset ® brands from BASF AG), maleic anhydride copolymers, possibly reacted with alcohols, anionic polysiloxanes, e.g. carboxy-functional, copolymers from vinylpyrrolidone, t-butyl acrylate, methacrylic acid (e.g. Luviskol ® VBM from BASF AG).
Weiterhin umfasst die Gruppe der zur Kombination mit den erfindungsgemäßen Mischungen geeigneten Polymere beispielhaft Balance CR (National Starch; Acrylatcopolymer), Balance 0/55 (National Starch; Acrylatcopolymer), Balance 47 (National Starch; Octylacrylamid/Acrylat/Butylaminoethylmethacrylate-Copolymer), Aquaflex® FX 64 (ISP; Isobutylen/Ethylmaleimid/Hydroxyethylmaleimid-Copolymer), Aquaflex® SF-40 (ISP / National Starch; VP/Yinyl Caprolactam/DMAPA Acrylatcopolymer), Allianz® LT-120 (ISP / Rohm & Haas; Acrylat/Cl-2 Succinat/Hydroxyacrylat-Copolymer), Aquarez® HS (Eastman; Polyester-1), Diaformer® Z-400 (Clariant; Methacryloylethylbetain/Methacrylat-Copolymer), Diaformer® Z-711 (Clariant; Methacryloylethyl N-oxid/Methacrylat-Copolymer), Diaformer® Z-712 (Clariant; Methacryloylethyl N-oxid/Methacrylat-Copolymer), Omnirez® 2000 (ISP; Monoethylester von Poly(Methylvinylether/Maleinsäure in Ethanol), Amphomer® HC oder Resyn® XP (National Starch; Acrylat/ Octylacrylamid-Copolymer), Amphomer® 28-4910 (National Starch; Octyl-acrylamid/Acrylat/Butylaminoethylmethacrylat-Copolymer), Amphomer® LV-71 (National Starch; Octylacrylamide/Acrylates/Butylaminoethyl Methacrylate Copolymer), Luviset® CAN (BASF) oder Resyn® 28-2930 (National Starch; VA/Crotonates/Vinyl Neodecanoate Copolymer),Advantage® HC 37 (ISP; Terpolymer aus Vinylcaprolactam/Vinylpyrrolidon/Dimethyl-aminoethylmethacrylat), Acudyne 258 (Rohm & Haas; Acrylat/ Hydroxyesteracrylat-Copolymer), Luviset® P.U.R. oder Luviset® Si-P.U.R. A (BASF; Polyurethane-1, Polyurethane-6), Luviflex® Silk (BASF; PEG/PPG- 25/25 Dimethicone/Acrylates Copolymer), Eastman® AQ Polymer (Eastman; Diglycol/CHDM/Isophthalates/SIP Copolymer), DynamX® (National Starch; Polyurethane- 14 (and) AMP-Acrylates Copolymer).The group of polymers suitable for combination with the mixtures according to the invention further includes, for example, Balance CR (National Starch; acrylate copolymer), Balance 0/55 (National Starch; acrylate copolymer), Balance 47 (National Starch; octylacrylamide / acrylate / butylaminoethyl methacrylate copolymer), Aquaflex ® FX 64 (ISP; isobutylene / ethylmaleimide / hydroxyethylmaleimide copolymer), Aquaflex ® SF-40 (ISP / National Starch; VP / Yinyl Caprolactam / DMAPA acrylate copolymer), Allianz ® LT-120 (ISP / Rohm &Haas; Acrylate / Cl -2 succinate / hydroxyacrylate copolymer), Aquarez ® HS (Eastman; Polyester-1), Diaformer ® Z-400 (Clariant; methacryloylethylbetaine / methacrylate copolymer), Diaformer ® Z-711 (Clariant; methacryloylethyl N-oxide / methacrylate- Copolymer), Diaformer ® Z-712 (Clariant; methacryloylethyl N-oxide / methacrylate copolymer), Omnirez ® 2000 (ISP; monoethyl ester of poly (methyl vinyl ether / maleic acid in ethanol), Amphomer ® HC or Resyn ® XP (National Starch; acrylate / Octyl acrylic amide copolymer), Amphomer ® 28-4910 (National Starch; Octyl acrylamide / acrylate / butylaminoethyl methacrylate copolymer), Amphomer ® LV-71 (National Starch; Octylacrylamide / Acrylates / Butylaminoethyl Methacrylate Copolymer), Luviset ® CAN (BASF) or Resyn ® 28-2930 (National Starch; VA / Crotonates / Vinyl Neodecanoate Copolymer), Advantage ® HC 37 (ISP; terpolymer made from vinyl caprolactam / vinyl pyrrolidone / dimethylaminoethyl methacrylate), Acudyne 258 (Rohm &Haas; acrylate / hydroxy ester acrylate copolymer), Luviset ® PUR or Luviset ® Si-PUR A (BASF; polyurethanes -1, Polyurethane-6), Luviflex ® Silk (BASF; PEG / PPG- 25/25 Dimethicone / Acrylates Copolymer), Eastman ® AQ Polymer (Eastman; Diglycol / CHDM / Isophthalates / SIP Copolymer), DynamX ® (National Starch; Polyurethane- 14 (and) AMP-Acrylates Copolymer).
Ganz besonders bevorzugt werden als anionische Polymere Acrylate mit einer Säurezahl größer gleich 120 und Copolymere aus t-Butylacrylat, Ethylacrylat, Methacrylsäure eingesetzt. Weitere geeignete Kosmetik-Polymere sind kationische Polymere mit der Bezeichnung Polyquaternium nach INCI, z.B. Copolymere aus Vinylpyrrolidon/N- Vinylimidazoliumsalzen (Luviquat® FC, Luviquat® HM, Luviquat® MS, Luviquat® Care der BASF AG), Copolymere aus N-Vinylpyrrolidon/Dimethylaminoethylmethacrylat, quaternisiert mit Diethylsulfat (Luviquat® PQ 11 der BASF AG), Copolymere aus N- Vinylcaprolactam N-Vinylpyrrolidon/N-Vinylimidazoliumsalzen (Luviquat® Hold der BASF AG); Copolymere aus N-Vinylpyrrolidon/Dimethylaminopropylmethacrylamid/ Methacryloylaminopropyllauryldimoniumchlorid (Polyquaternium-55), kationische Cellulose-derivate (Polyquaternium-4 und -10), Acrylamid-copolymere (Polyquaternium- 7).Acrylates with an acid number greater than or equal to 120 and copolymers of t-butyl acrylate, ethyl acrylate, methacrylic acid are very particularly preferably used as anionic polymers. Further suitable cosmetic polymers are cationic polymers having the INCI name Polyquaternium, eg copolymers of vinylpyrrolidone / vinylimidazolium N- (Luviquat ® FC, Luviquat ® HM, Luviquat ® MS, Luviquat Care ® from BASF AG), copolymers of N-vinylpyrrolidone / dimethylaminoethyl methacrylate, quaternized with diethyl sulfate (Luviquat ® PQ 11 of BASF AG), copolymers of N-vinylcaprolactam N-vinylpyrrolidone / N-vinylimidazolium salts (Luviquat Hold ® of BASF AG); Copolymers of N-vinylpyrrolidone / dimethylaminopropylmethacrylamide / methacryloylaminopropyllauryldimonium chloride (Polyquaternium-55), cationic cellulose derivatives (Polyquaternium-4 and -10), acrylamide copolymers (Polyquaternium-7).
Ferner können kationische Guarderivate wie Guarhydroxypropyltrimoniumchlorid (INCI) verwendet werden.Cationic guar derivatives such as guar hydroxypropyltrimonium chloride (INCI) can also be used.
Als weitere Kosmetik-Polymere sind auch neutrale Polymere geeignet wie Polyvinylpyrrolidone, Copolymere aus N-Vinylpyrrolidon und Vinylacetat und/oder Vinylpropionat, Copolymere aus N-Vinylpyrrolidon und Dimethylaminopropylacrylamid or -methacrylamid (DMAPA), Copolymere aus N-Vinylpyrrolidon und (Meth-)Acrylsäureestern, Polysiloxane, Polyvinylcaprolactam und Copolymere mit N- Vinylpyrrolidon, Polyethylenimine und deren Salze, Polyvinylamine und deren Salze, Polyvinylformamid und dessen (Teil-)Hydrolyseprodukte, Cellulosederivate, Polyasparaginsäuresalze und Derivate.Neutral polymers such as polyvinylpyrrolidones, copolymers of N-vinylpyrrolidone and vinyl acetate and / or vinyl propionate, copolymers of N-vinylpyrrolidone and dimethylaminopropylacrylamide or -methacrylamide (DMAPA), copolymers of N-vinylpyrrolidone acid and (meth) acrylic acid are also suitable as further cosmetic polymers , Polysiloxanes, polyvinylcaprolactam and copolymers with N-vinylpyrrolidone, polyethyleneimines and their salts, polyvinylamines and their salts, polyvinylformamide and its (partial) hydrolysis products, cellulose derivatives, polyaspartic acid salts and derivatives.
Zur Einstellung bestimmter Eigenschaften können die Zubereitungen zusätzlich auch konditionierende Substanzen auf Basis von Silikonverbindungen enthalten. Geeignete Silikonverbindungen sind beispielsweise Polyalkylsiloxane, Polyarylsiloxane, Polyarylalkylsiloxane, Polyethersiloxane oder Silikonharze. Weiterhin geeignet sind Dimethicon Copolyole (CTFA) und aminofunktionelle Silikonverbindungen wie Amodimethicone (CTFA).To adjust certain properties, the preparations can also contain conditioning substances based on silicone compounds. Suitable silicone compounds are, for example, polyalkylsiloxanes, polyarylsiloxanes, polyarylalkylsiloxanes, polyether siloxanes or silicone resins. Dimethicone copolyols (CTFA) and amino-functional silicone compounds such as amodimethicones (CTFA) are also suitable.
Die Shampooformulierungen enthalten üblicherweise anionische Tenside als Basistenside und amphotere und nichtionische Tenside als Cotenside. Die Formulierungen enthalten insgesamt beispielsweise 2 bis 50 Gew.-% Tenside, bevorzugt 5 bis 40 Gew.-%, besonders bevorzugt 8 bis 30 Gew.-% der erfindungsgemäßen Mischungen.The shampoo formulations usually contain anionic surfactants as base surfactants and amphoteric and nonionic surfactants as cosurfactants. The formulations in total contain, for example, 2 to 50% by weight of surfactants, preferably 5 to 40% by weight, particularly preferably 8 to 30% by weight of the mixtures according to the invention.
In den Shampooformulierungen können alle in Shampoos üblicherweise eingesetzten neutralen, amphoteren oder kationischen Tenside zusätzlich verwendet werden.All neutral, amphoteric or cationic surfactants commonly used in shampoos can also be used in the shampoo formulations.
Geeignete amphotere Tenside sind zum Beispiel Alkylbetaine, Alkylamidopropylbetaine, Alkylsulfobetaine, Alkylglycinate, Alkylcarboxyglycinate, Alkylamphoacetate oder - propionate, Alkylamphodiacetate oder -dipropionate.Suitable amphoteric surfactants are, for example, alkylbetaines, alkylamidopropylbetaines, alkylsulfobetaines, alkylglycinates, alkylcarboxyglycinates, alkylamphoacetates or propionates, alkylamphodiacetates or dipropionates.
Beispielsweise können Cocodimethylsulfopropylbetain, Laurylbetain, Cocamido- propylbetain oder Natriumcocamphopropionat eingesetzt werden.For example, cocodimethylsulfopropylbetaine, laurylbetaine, cocamido propylbetaine or sodium cocamphopropionate can be used.
Als nichtionische Tenside sind beispielsweise die Umsetzungsprodukte von aliphatischen Alkoholen oder Alkylphenolen mit 6 bis 20 C-Atomen in der Alkylkette, die linear oder verzweigt sein kann, mit Ethylenoxid und/oder Propylenoxid geeignet. Die Menge an Alkylenoxid beträgt ca. 6 bis 60 Mole auf ein Mol Alkohol. Ferner sind Alkylaminoxide, Mono- oder Dialkylalkanolamide, Fettsäureester von Polyethylenglykolen, ethoxylierte Fettsäureamide, Alkylpolyglykoside oder Sorbitanetherester geeignet.Examples of suitable nonionic surfactants are the reaction products of aliphatic alcohols or alkylphenols with 6 to 20 carbon atoms in the alkyl chain, which can be linear or branched, with ethylene oxide and / or propylene oxide. The amount of alkylene oxide is about 6 to 60 moles per mole of alcohol. Alkylamine oxides, mono- or dialkylalkanolamides, fatty acid esters of polyethylene glycols, ethoxylated fatty acid amides, alkyl polyglycosides or sorbitan ether esters are also suitable.
Außerdem können die Shampooformulierungen übliche kationische Tenside enthalten, wie quaternäre Ammoniumverbindungen, beispielsweise Cetyltrimethyl-ammoniumchlorid.In addition, the shampoo formulations can contain customary cationic surfactants, such as quaternary ammonium compounds, for example cetyltrimethylammonium chloride.
Die Polymere mit quaternisierten Stickstoffatomen, wie in EP-A 0 895 117 beschrieben, werden üblicherweise in Mengen zwischen 0,01 bis 5 Gew.-% eingesetzt, bevorzugt zwischen 0,05 und 2 Gew.-%.The polymers with quaternized nitrogen atoms, as described in EP-A 0 895 117, are usually used in amounts of between 0.01 and 5% by weight, preferably between 0.05 and 2% by weight.
Zusätzlich können auch weitere in Shampoos übliche kationische Polymere eingesetzt werden, so zum Beispiel Copolymere aus Acrylamid und Dimethyldiallyl- ammoniumchlorid (Polyquaternium-7), katonische Cellulosederivate (Polyquaternium-10), Guar-hydroxypropyltrimethylammoniumchlorid (INCI: Hydroxy-propyl Guar Hydroxy- propyltrimonium Chloride), Copolymere aus N-Vinyl-pyrrolidon und quaternisiertem N-Vinylimidazol (Polyquaterinium-16, -44, -46) und andere. Weiterhin können die Shampooformulierungen Verdicker, wie Kochsalz, PEG-55, Propylene Glycol Oleate, PEG-120 Methyl Glucose Dioleate und andere, sowie Konservierungsmittel, weitere Wirk- und Hilfsstoffe und Wasser enthalten.In addition, other cationic polymers customary in shampoos can also be used, for example copolymers of acrylamide and dimethyldiallylammonium chloride (Polyquaternium-7), cationic cellulose derivatives (Polyquaternium-10), guar-hydroxypropyltrimethylammonium chloride (INCI: hydroxypropyl guar hydroxypropyltrimonium chloride ), Copolymers of N-vinyl-pyrrolidone and quaternized N-vinylimidazole (Polyquaterinium-16, -44, -46) and others. Furthermore, the shampoo formulations can contain thickeners such as table salt, PEG-55, propylene glycol oleates, PEG-120 methyl glucose dioleates and others, and also preservatives, other active ingredients and auxiliaries and water.
Die Zubereitungen zur Haarbehandlung enthalten üblicherweise ein Polymer in einer Menge im Bereich von etwa 0,1 bis 30 Gew.-%, bevorzugt 0,5 bis 20 Gew.-%, bezogen auf das Gesamtgewicht des Mittels und 0,03 bis 10 Gew.-% Tenside, bevorzugt 0,05 bis 5 Gew.-%, besonders bevorzugt 0,1 bis 3 Gew.-%, insbesondere der erfindungsgemäßen Mischungen. Vorzugsweise liegen die erfindungsgemäßen Haarbehandlungsmittel in Form eines Schaumfestigers, Haarmousses, Haargels, Shampoos, Haarsprays oder Haarschaums vor. Haarsprays umfassen dabei sowohl Aerosolsprays als auch Pumpsprays ohne Treibgas. Haarschäume umfassen sowohl Aerosolschäume wie auch Pumpschäume ohne Treibgas.The hair treatment preparations usually contain a polymer in an amount in the range from about 0.1 to 30% by weight, preferably 0.5 to 20% by weight, based on the total weight of the composition and 0.03 to 10% by weight. % Surfactants, preferably 0.05 to 5% by weight, particularly preferably 0.1 to 3% by weight, in particular of the mixtures according to the invention. The hair treatment compositions according to the invention are preferably in the form of a foaming agent, hair mousse, hair gel, shampoo, hair spray or hair foam. Hair sprays include both aerosol sprays and pump sprays without propellant. Hair foams include both aerosol foams and pump foams without propellant.
Die erfindungsgemäßen Mischungen können in hautkosmetischen und dermatologischen Zubereitungen eingesetzt werden.The mixtures according to the invention can be used in skin cosmetic and dermatological preparations.
Beispielsweise werden die erfindungsgemäßen Mischungen in kosmetischen Mitteln zur Reinigung der Haut verwendet. Solche kosmetischen Reinigungsmittel sind ausgewählt aus Stückseifen wie Toilettenseifen, Kernseifen, Transparentseifen, Luxusseifen, Deoseifen, Cremeseifen, Babyseifen, Hautschutzseifen, Abrasiveseifen und Syndets, flüssigen Seifen wie pastösen Seifen, Schmierseifen und Waschpasten und flüssigen Wasch-, Dusch-, und Badepräparaten wie Waschlotionen, Duschbädern und -gelen, Schaumbädern, Ölbädern und Scrub-Präparaten.For example, the mixtures according to the invention are used in cosmetic compositions for cleaning the skin. Such cosmetic cleaning agents are selected from bar soaps such as toilet soaps, core soaps, transparent soaps, luxury soaps, deodorant soaps, cream soaps, baby soaps, skin protection soaps, abrasive soaps and syndets, liquid soaps such as pasty soaps, soft soaps and washing pastes and liquid washing, showering and bathing preparations such as washing lotions, Shower baths and gels, foam baths, oil baths and scrub preparations.
Bevorzugt werden die erfindungsgemäßen Mischungen in kosmetischen Mitteln zur Pflege und zum Schutz der Haut, in Nagelpflegemitteln sowie in Zubereitungen für die dekorative Kosmetik angewendet.The mixtures according to the invention are preferably used in cosmetic compositions for the care and protection of the skin, in nail care compositions and in preparations for decorative cosmetics.
Besonders bevorzugt ist die Verwendung in Hautpflegemitteln, Intimpflegemitteln, Fußpflegemitteln, Lichtschutzmitteln, Repellents, Rasiermitteln, Haarentfernungsmitteln, Antiaknemitteln, Make-up, Maskara, Lippenstiften, Lidschatten, Kajalstiften, Eyelinern, Rouges, Pudern und Augenbrauenstiften.The use in skin care products, intimate care products, foot care products, light protection agents, repellents, shaving agents, hair removal agents, anti-acne agents, make-up, mascara, lipsticks, eye shadows, eye pencils, eyeliners, blushers, powders and eyebrow pencils is particularly preferred.
Die Hautpflegemittel liegen insbesondere als W/O- oder O/W-Hautcremes, Tag- und Nachtcremes, Augencremes, Gesichtscremes, Antifaltencrem.es, Feuchthaltecremes, Bleichcremes, Vitamincremes, Hautlotionen, Pflegelotionen und Feuchthaltelotionen vor. Je nach Anwendungsgebiet können die erfindungsgemäßen Zusammensetzungen in einer zur Hautpflege geeigneten Form, wie zum Beispiel als Creme, Schaum, Gel, Stift, Pulver, Mousse, Milch oder Lotion appliziert werden.The skin care products are present in particular as W / O or O / W skin creams, day and night creams, eye creams, face creams, anti-wrinkle creams, moisturizing creams, bleaching creams, vitamin creams, skin lotions, care lotions and moisturizing lotions. Depending on the field of application, the compositions according to the invention can be applied in a form suitable for skin care, for example as a cream, foam, gel, stick, powder, mousse, milk or lotion.
Die hautkosmetischen Zubereitungen können neben den erfindungsgemäßen Mischungen und geeigneten Lösungsmitteln noch in der Kosmetik übliche Zusätze wie Emulgatoren, Konservierungsmitteln, Parfümöle, kosmetische Wirkstoffe wie Phytantriol, Vitamin A, E und C, Retinol, Bisabolol, Panthenol, Lichtschutzmittel, Bleichmittel, Färbemittel, Tönungsmittel, Bräunungsmittel (z.B. Dihydroxyaceton), Collagen, Eiweißhydrolysate, Stabilisatoren, pH-Wert-Regulatoren, Farbstoffe, Salze, Verdicker, Gelbildner, Konsistenzgeber, Silikone, Feuchthaltemittel, Rückfetter und weitere übliche Additive enthalten.In addition to the mixtures and suitable solvents according to the invention, the skin cosmetic preparations can also contain additives customary in cosmetics such as emulsifiers, preservatives, perfume oils, cosmetic active ingredients such as phytantriol, vitamins A, E and C, retinol, bisabolol, panthenol, light stabilizers, bleaching agents, colorants, tinting agents, Contain browning agents (e.g. dihydroxyacetone), collagen, protein hydrolyzates, stabilizers, pH regulators, dyes, salts, thickeners, gelling agents, consistency agents, silicones, humectants, refatting agents and other common additives.
Als geeignete Lösungsmittel sind insbesondere zu nennen Wasser und niedrige Monoalkohole oder Polyole mit 1 bis 6 Kohlenstoffatomen oder Mischungen davon; bevorzugte Monoalkohole oder Polyole sind Ethanol, i-Propanol, Propylenglykol, Glycerin und Sorbit.Suitable solvents include water and lower monoalcohols or polyols with 1 to 6 carbon atoms or mixtures thereof; preferred monoalcohols or polyols are ethanol, i-propanol, propylene glycol, glycerin and sorbitol.
Als weitere übliche Zusätze können enthalten sein Fettkörper wie mineralische und synthetische Öle wie zum Beispiel Paraffine, Silikonöle und aliphatische Kohlenwasserstoffe mit mehr als 8 Kohlenstoffatomen, tierische und pflanzliche Öle wie zum Beispiel Sonnenblumenöl, Kokosöl, Avocadoöl, Olivenöl, Lanolin oder Wachse, Fettsäuren, Fettsäureester, wie zum Beispiel Triglyceride von C6- C3o-Fettsäuren, Wachsester wie zum Beispiel Jojobaöl, Fettalkohole, Vaseline, hydriertes Lanolin und azetyliertes Lanolin. Selbstverständlich können auch Mischungen derselben verwendet werden.Other common additives can include fatty substances such as mineral and synthetic oils such as paraffins, silicone oils and aliphatic hydrocarbons with more than 8 carbon atoms, animal and vegetable oils such as sunflower oil, coconut oil, avocado oil, olive oil, lanolin or waxes, fatty acids, fatty acid esters such as triglycerides of C 6 -C 3 o-fatty acids, wax esters such as jojoba oil, fatty alcohols, petroleum jelly, hydrogenated lanolin and acetylated lanolin. Mixtures of the same can of course also be used.
Übliche Verdickungsmittel in derartigen Formulierungen sind vernetzte Polyacrylsäuren und deren Derivate, Polysaccharide wie Xanthan-Gum, Agar-Agar, Alginate oder Tylosen, Carboxymethylcellulose oder Hydroxycarboxymethylcellulose, Fettalkohole, Monogly- ceride und Fettsäuren, Polyvinylalkohol und Polyvinylpyrrolidon.Typical thickeners in such formulations are crosslinked polyacrylic acids and their derivatives, polysaccharides such as xanthan gum, agar agar, alginates or tyloses, carboxymethyl cellulose or hydroxycarboxymethyl cellulose, fatty alcohols, monoglycerides and fatty acids, polyvinyl alcohol and polyvinyl pyrrolidone.
Man kann die erfindungsgemäßen Mischungen auch mit herkömmlichen Polymeren oder Polymeren gemäß EP-A 1 064 924 abmischen, falls spezielle Eigenschaften eingestellt werden sollen. Die erfindungsgemäßen Mischungen werden in kosmetischen Zubereitungen eingesetzt, deren Herstellung nach den üblichen, dem Fachmann geläufigen Regeln erfolgt.The mixtures according to the invention can also be mixed with conventional polymers or polymers according to EP-A 1 064 924 if special properties are to be set. The mixtures according to the invention are used in cosmetic preparations, the preparation of which takes place according to the usual rules familiar to the person skilled in the art.
Solche Formulierungen liegen vorteilhafterweise in Form von Emulsionen, bevorzugt als Wasser-in-Öl- (W/O) oder Öl-in- Wasser (O/W)-Emulsionen vor. Es ist aber auch erfindungsgemäß möglich und gegebenenfalls vorteilhaft, andere Formulierungsarten zu wählen, beispielsweise Hydrodispersionen, Gele, Öle, Oleogele, multiple Emulsionen, beispielsweise in Form von W/O/W- oder O/W/O-Emulsionen, wasserfreie Salben bzw. Salbengrundlagen usw.Such formulations are advantageously in the form of emulsions, preferably as water-in-oil (W / O) or oil-in-water (O / W) emulsions. However, it is also possible and advantageous according to the invention to select other types of formulation, for example hydrodispersions, gels, oils, oleogels, multiple emulsions, for example in the form of W / O / W or O / W / O emulsions, anhydrous ointments or Ointment bases etc.
Die Herstellung erfindungsgemäß brauchbarer Emulsionen erfolgt nach bekannten Methoden. Die Emulsionen enthalten neben der erfindungsgemäßen Mischung übliche Bestandteile wie Fettalkohole, Fettsäureester und insbesondere Fettsäuretriglyceride, Fettsäuren, Lanolin und Derivate davon, natürliche oder synthetische Öle oder Wachse und Emulgatoren in Anwesenheit von Wasser.Emulsions which can be used according to the invention are prepared by known methods. In addition to the mixture according to the invention, the emulsions contain conventional constituents such as fatty alcohols, fatty acid esters and in particular fatty acid triglycerides, fatty acids, lanolin and derivatives thereof, natural or synthetic oils or waxes and emulsifiers in the presence of water.
Die Auswahl der Emulsionstyp-spezifischen Zusätze und die Herstellung geeigneter Emulsionen ist beispielsweise in Schrader, Grundlagen und Rezepturen der Kosmetika, Hüthig Buch Verlag, Heidelberg, 2. Auflage, 1989, Dritter Teil, beschrieben.The selection of additives specific to the type of emulsion and the preparation of suitable emulsions is described, for example, in Schrader, Fundamentals and Recipes for Cosmetics, Hüthig Buch Verlag, Heidelberg, 2nd edition, 1989, third part.
So kann eine erfindungsgemäß brauchbare Hautcreme zum Beispiel als W/O-Emulsion vorliegen. Eine derartige Emulsion enthält eine wässrige Phase, die mittels eines geeigneten Emulgatorsystems in einer Öl- oder Fettphase emulgiert ist.For example, a skin cream which can be used according to the invention can be in the form of a W / O emulsion. Such an emulsion contains an aqueous phase which is emulsified in an oil or fat phase by means of a suitable emulsifier system.
Die Konzentration des Emulgatorsystems beträgt in diesem Emulsions-Typ etwa 4 bis 35 Gew.-%„ bezogen auf das Gesamtgewicht der Emulsion; die Fettphase macht etwa 20 bis 60 Gew.-% aus und die wässrigen Phasen etwa 20 bis 70 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Emulsion. Bei den Emulgatoren handelt es sich um diejenigen, welche in diesem Emulsionstyp üblicherweise verwendet werden. Sie werden zum Beispiel ausgewählt unter C12-Cι8-Sorbitan-Fettsäureestern; Estern von Hydroxystearinsäure und C12-C3o-Fettalkoholen; Mono- und Diestern von C12-Cι8-Fettsäuren und Glycerin oder Polyglycerin; Kondensaten von Ethylenoxid und Propylenglykolen; oxypropylenier- ten/oxyethylenierten C12-C2o-Fettalkoholen; polycyclischen Alkoholen wie Sterolen; aliphatischen Alkoholen mit einem hohen Molekulargewicht wie Lanolin; Mischungen von oxypropylenierten/polyglycerinierten Alkoholen und Magnesiumisostearat; Succhinestern von polyoxyethylenierten oder polyoxypropylenierten Fettalkoholen und Mischungen von Magnesium-, Calcium-, Lithium-, Zink- oder Aluminiumlanolat und hydriertem Lanolin oder Lanolinalkohol.The concentration of the emulsifier system in this type of emulsion is about 4 to 35% by weight, based on the total weight of the emulsion; the fat phase makes up about 20 to 60% by weight and the aqueous phases about 20 to 70% by weight, in each case based on the total weight of the emulsion. The emulsifiers are those which are usually used in this type of emulsion. For example, they are selected from C 12 -C 8 sorbitan fatty acid esters; Esters of hydroxystearic acid and C 12 -C 3 o-fatty alcohols; Mono- and diesters of C 12 -C 8 fatty acids and glycerol or polyglycerol; Condensates of ethylene oxide and propylene glycols; oxypropylenated / oxyethylenated C 12 -C 2 o fatty alcohols; polycyclic alcohols such as sterols; high molecular weight aliphatic alcohols such as lanolin; Mixtures of oxypropylene / polyglycerolated alcohols and magnesium isostearate; Succhine esters of polyoxyethylenated or polyoxypropylenated fatty alcohols and mixtures of Magnesium, calcium, lithium, zinc or aluminum lanolate and hydrogenated lanolin or lanolin alcohol.
Zu den geeigneten Fettkomponenten, welche in der Fettphase der Emulsionen enthalten sein können, zählen Kohlenwasserstofföle wie Paraffinöl, Purcellinöl, Perhydrosqualen und Lösungen mikrokristalliner Wachse in diesen Ölen, tierische oder pflanzliche Öle wie Süßmandelöl, Avocadoöl, Calophylumöl, Lanolin und Derivate davon, Rizinusöl, Sesamöl, Olivenöl, Jojobaöl, Karite-Öl, Hoplostethus-Öl, mineralische Öle, deren Destillationsbeginn unter Atmosphärendruck bei ca. 250°C und deren Destillationsendpunkt bei 410°C liegt, wie zum Beispiel Vaselinöl, Ester gesättigter oder ungesättigter Fettsäuren wie Alkylmyristate, zum Beispiel i-Propyl-, Butyl- oder Cetyl- myristat, Hexadecylstearat, Ethyl- oder i-Propylpalmitat, Octan- oder Decansäure- triglyceride und Cetylricinoleat.Suitable fat components which can be contained in the fat phase of the emulsions include hydrocarbon oils such as paraffin oil, purcellin oil, perhydrosqualene and solutions of microcrystalline waxes in these oils, animal or vegetable oils such as sweet almond oil, avocado oil, calophylum oil, lanolin and derivatives thereof, castor oil, sesame oil , Olive oil, jojoba oil, karite oil, hoplostethus oil, mineral oils whose distillation begins at atmospheric pressure at approx. 250 ° C and whose distillation end point is 410 ° C, such as petroleum jelly oil, esters of saturated or unsaturated fatty acids such as alkyl myristates, for example i-propyl, butyl or cetyl myristate, hexadecyl stearate, ethyl or i-propyl palmitate, octanoic or decanoic acid triglycerides and cetylricinoleate.
Die Fettphase kann auch in anderen Ölen lösliche Silikonöle, wie Dimethylpolysiloxan, Methylphenylpolysiloxan und das Silikonglykol-Copolymer, Fettsäuren und Fettalkohole enthalten.The fat phase can also contain silicone oils soluble in other oils, such as dimethylpolysiloxane, methylphenylpolysiloxane and the silicone glycol copolymer, fatty acids and fatty alcohols.
Um die Retention von Ölen zu begünstigen, kann man auch Wachse verwenden, wie zum Beispiel Carnauba-Wachs, Candellilawachs, Bienenwachs, mikrokristallines Wachs, Ozokeritwachs und Ca-, Mg- und Al-Oleate, - Myristate, -Linoleate und -Stearate.To promote the retention of oils, waxes can also be used, such as, for example, carnauba wax, candellila wax, beeswax, microcrystalline wax, ozokerite wax and calcium, magnesium and aluminum oleates, myristates, linoleates and stearates.
Im Allgemeinen werden diese Wasser-in-Öl-Emulsionen so hergestellt, dass die Fettphase und der Emulgator in den Ansatzbehälter gegeben werden. Man erwärmt diesen bei einer Temperatur von 70 bis 75°C, gibt dann die in Öl löslichen Ingredienzien zu und fügt unter Rühren Wasser hinzu, welches vorher auf die gleiche Temperatur erwärmt wurde und worin man die wasserlöslichen Ingredienzien vorher gelöst hat; man rührt, bis man eine Emulsion der gewünschten Feinheit hat, lässt sie dann auf Raumtemperatur abkühlen, wobei gegebenenfalls weniger gerührt wird.Generally, these water-in-oil emulsions are made by adding the fat phase and emulsifier to the batch container. It is heated at a temperature of 70 to 75 ° C., then the oil-soluble ingredients are added and, with stirring, water is added which has previously been heated to the same temperature and in which the water-soluble ingredients have been dissolved beforehand; the mixture is stirred until an emulsion of the desired fineness is obtained and then allowed to cool to room temperature, stirring less if necessary.
Weiterhin kann eine erfindungsgemäße Pflegeemulsion als O/W-Emulsion vorliegen. Eine derartige Emulsion enthält üblicherweise eine Ölphase, Emulgatoren, die die Ölphase in der Wasserphase stabilisieren und eine wässrige Phase, die üblicherweise verdickt vorliegt.Furthermore, a care emulsion according to the invention can be present as an O / W emulsion. Such an emulsion usually contains an oil phase, emulsifiers which stabilize the oil phase in the water phase and an aqueous phase which is usually present in a thickened state.
Die wässrige Phase der O/W-Emulsion der erfindungsgemäßen Zubereitungen enthält gegebenenfalls Alkohole, Diole oder Polyole sowie deren Ether, vorzugsweise Ethanol, Isopropanol, Propylendiglykol, Glycerin, Ethylenglykolmonoethylether;The aqueous phase of the O / W emulsion of the preparations according to the invention optionally contains Alcohols, diols or polyols and their ethers, preferably ethanol, isopropanol, propylene diglycol, glycerin, ethylene glycol monoethyl ether;
übliche Verdickungsmittel bzw. Gelbildner wie zum Beispiel vernetzte Polyacrylsäuren und deren Derivate, Polysaccharide wie Xanthan Gum oderCommon thickeners or gel formers such as crosslinked polyacrylic acids and their derivatives, polysaccharides such as xanthan gum or
Algjnate, Carboxymethylcellulose oder Hydroxycarboxymethylcellulose, Fettalkohole, Polyvinylalkohol und Polyvinylpyrrodlidon.Algjnate, carboxymethyl cellulose or hydroxycarboxymethyl cellulose, fatty alcohols, polyvinyl alcohol and polyvinyl pyrrodlidone.
Die Ölphase enthält in der Kosmetik übliche Ölkomponenten wie beispielsweise:The oil phase contains common oil components in cosmetics such as:
Ester aus gesättigten und/oder ungesättigten, verzweigten und/oder unverzweigten C3-C30-Alkancarbonsäuren und gesättigten und/oder ungesättigten, verzweigten und/oder unverzweigten C3-C3o-Alkoholen, aus aromatischen Carbonsäuren und gesättigten und/oder ungesättigten, verzweigten und/oder unverzweigten C3-C3oAlkoholen, beispielhaft Isopropylmyristat, Isopropylstearat, Hexyldecyl- stearat, Oleyloleat; außerdem synthetische, halbsynthetische und natürliche Gemische solcher Ester, wie Jojobaöl;Esters from saturated and / or unsaturated, branched and / or unbranched C 3 -C 30 -alkanecarboxylic acids and saturated and / or unsaturated, branched and / or unbranched C 3 -C 3 o-alcohols, from aromatic carboxylic acids and saturated and / or unsaturated , branched and / or unbranched C 3 -C 3 alcohols, for example isopropyl myristate, isopropyl stearate, hexyldecyl stearate, oleyl oleate; also synthetic, semi-synthetic and natural mixtures of such esters as jojoba oil;
verzweigte und/oder unverzweigte Kohlenwasserstoffe und -wachse;branched and / or unbranched hydrocarbons and waxes;
Silikonöle wie Cyclomethicon, Dimethylpolysiloxan, Diethylpolysiloxan, Octamethylcyclotetrasiloxan sowie Mischungen daraus;Silicone oils such as cyclomethicone, dimethylpolysiloxane, diethylpolysiloxane, octamethylcyclotetrasiloxane and mixtures thereof;
Dialkylether;dialkyl;
Mineralöle und Mineralwachse;Mineral oils and mineral waxes;
Triglyceride gesättigter und/oder ungesättigter, verzweigter und/oder unverzweigter C8-C2 -Alkancarbonsäuren; sie können ausgewählt werden aus synthetischen, halbsynthetischen oder natürlichen Ölen wie Olivenöl, Palmöl, Mandelöl oderTriglycerides of saturated and / or unsaturated, branched and / or unbranched C 8 -C 2 -alkane carboxylic acids; they can be selected from synthetic, semi-synthetic or natural oils such as olive oil, palm oil, almond oil or
Mischungen.Mixtures.
Als Emulgatoren kommen vorzugsweise O/W-Emulgatoren wie Polyglycerinester, Sorbitanester oder teilveresterte Glyceride in Betracht. Die Herstellung kann durch Aufschmelzen der Ölphase bei ca. 80°C erfolgen; die wasserlöslichen Bestandteile werden in heißem Wasser gelöst, langsam und unter Rühren zur Ölphase zugegeben, homogenisiert und kaltgerührt. Die erfindungsgemäßen Mischungen eignen sich auch zur Verwendung in Wasch- und Duschgel-Formulierungen sowie Badepräparaten.Preferred emulsifiers are O / W emulsifiers such as polyglycerol esters, sorbitan esters or partially esterified glycerides. It can be produced by melting the oil phase at approx. 80 ° C; the water-soluble constituents are dissolved in hot water, added slowly and with stirring to the oil phase, homogenized and stirred cold. The mixtures according to the invention are also suitable for use in washing and shower gel formulations and bath preparations.
Solche Formulierungen enthalten neben den erfindungsgemäßen Mischungen gegebenenfalls amphotere und nichtionische Tenside als Cotenside sowie Lipide, Parfümöle, Farbstoffe, organische Säuren, Konservierungsstoffe und Antioxidantien sowie Verdicker/Gelbildner, Hautkonditioniermittel und Feuchthaltemittel.In addition to the mixtures according to the invention, such formulations optionally contain amphoteric and nonionic surfactants as cosurfactants, and also lipids, perfume oils, dyes, organic acids, preservatives and antioxidants, and also thickeners / gel formers, skin conditioners and humectants.
In den Wasch-, Dusch- und Badepräparaten können zusätzlich alle in Körperreinigungsmitteln üblicherweise eingesetzten neutralen, amphoteren oder kationischen Tenside verwendet werden, wie sie vorstehend beschrieben sind.In addition, all neutral, amphoteric or cationic surfactants commonly used in personal cleansing agents, as described above, can be used in the washing, showering and bathing preparations.
Die erfindungsgemäßen Mischungen und kosmetischen Zusammensetzungen zeigen eine Verminderung der Hautreizwirkung. Die Hautreizwirkung wird dabei üblicherweise nach dem Zein-Test überprüft. Dieser Test ist im Beispiel näher erläutert. Der Zein-Test ist ferner in der US 5,562,912 näher erläutert. Ferner zeigen die erfindungsgemäßen Mischungen Vorteile bei der Solubilisierung von hydrophoben Inhaltsstoffen der kosmetischen Zusammensetzungen. Die hydrophoben Inhaltsstoffe oder Wirkstoffe können dabei häufig molekular solubilisiert werden. Ferner wurde in vielen Systemen beobachtet, dass die Schaumstabilität zunimmt und in einigen Fällen auch das Schaumvolumen.The mixtures and cosmetic compositions according to the invention show a reduction in skin irritation. The skin irritation is usually checked after the zein test. This test is explained in more detail in the example. The zein test is further explained in US 5,562,912. Furthermore, the mixtures according to the invention show advantages in the solubilization of hydrophobic ingredients in the cosmetic compositions. The hydrophobic ingredients or active ingredients can often be molecularly solubilized. Furthermore, it has been observed in many systems that the foam stability increases and in some cases also the foam volume.
Die Verwendung nichtionischer Zusatzstoffe, wie sie vorstehend beschrieben sind, ist aus Gründen der Verträglichkeit der Formulierungskomponenten untereinander besonders vorteilhaft. Dabei können die üblicherweise eingesetzten Betaine durch die hier beschriebenen Alkylglykolalkoxylate oder -diglykolalkoxylate ersetzt werden.The use of nonionic additives, as described above, is particularly advantageous for reasons of compatibility of the formulation components with one another. The betaines commonly used can be replaced by the alkyl glycol alkoxylates or diglycol alkoxylates described here.
Die Erfindung wird durch die nachstehenden Beispiele näher erläutert:The invention is illustrated by the following examples:
Beispiel:Example:
Zein-Test [E. Gotte, Int. Cong. Surf, Active Substances (Brüssel 1964)3 (1967), 83]Zein test [E. Gotte, Int. Cong. Surf, Active Substances (Brussels 1964) 3 (1967), 83]
Als Maß für die Hautreizwirkung kann laut o.g. Literaturstelle und [I. Pezron, L. Galet, D. Clausse, J. Colloid Interface Science 180 (1996), 285] die Neigung eines Tensids zur Solubilisierung von Weizenprotein (Zein), das an sich nicht löslich ist, angenommen werden. Durch Trübungsmessung oder moderner, durch Extinktionsmessung nach Zugabe eines unter Farbänderung mit Aminfunktionen reagierenden Farbstoffs (BCA Protein Assay Reagent, Pierce Chemical Company, Rockford, IL, USA), kann die Menge solubilisierten Proteins im Screening-Verfahren zuverlässig quantifiziert werden. Je höher die Solubilisierung, desto stärker die Extinktion und desto aggressiver die Tenside.As a measure of skin irritation, according to the above-mentioned literature and [I. Pezron, L. Galet, D. Clausse, J. Colloid Interface Science 180 (1996), 285], the tendency of a surfactant to solubilize wheat protein (zein), which is not soluble per se, can be assumed. The amount of solubilized protein can be reliably quantified in the screening method by means of turbidity measurement or more modern, by absorbance measurement after adding a dye which reacts with amine functions and changes color (BCA Protein Assay Reagent, Pierce Chemical Company, Rockford, IL, USA). The higher the solubilization, the stronger the extinction and the more aggressive the surfactants.
Durchführung: 40 ml einer l%igen Tensidlösung (pH ca. 7) wird mit 2 g Zeinprotein versetzt und bei 30°C für 1 Stunde gerührt. Die Lösung wird dann 20 Minuten lang bei 2000 g zentrifugiert, und die Proteinkonzentration im Überstand wird bestimmt. Dazu entnimmt man 5 μl des Überstands, verdünnt mit 95 μl der Tensidlösung und gibt 2 ml des Farbstoffreagenzes hinzu. Nach 2 Stunden Lagerung bei Raumtemperatur wird die Absorbanz bei 562 nm gemessen. Durch eine Eichkurve mit bekannten Mengen BSA, einem wasserlöslichen Protein, kann daraus die Zein-Zahl (mg N/lOOOg Tensid) bestimmt werden.Procedure: 2 ml of zein protein are added to 40 ml of a 1% surfactant solution (pH approx. 7) and the mixture is stirred at 30 ° C. for 1 hour. The solution is then centrifuged at 2000 g for 20 minutes and the protein concentration in the supernatant is determined. To do this, take 5 μl of the supernatant, dilute with 95 μl of the surfactant solution and add 2 ml of the dye reagent. After storage for 2 hours at room temperature, the absorbance is measured at 562 nm. The zein number (mg N / lOOOg surfactant) can be determined from this using a calibration curve with known amounts of BSA, a water-soluble protein.
Die folgende Tabelle zeigt die Wirkung des Alkoxylats auf die Hautreizwirkung im Vergleich zu dem Marktstandard, Cocoamidopropylbetain (GAB). Je höher die Absorbanz ist, desto reizender ist das Tensid oder die Tensidmischung.The following table shows the effect of the alkoxylate on the skin irritation in comparison to the market standard, cocoamidopropyl betaine (GAB). The higher the absorbance, the more irritating is the surfactant or the surfactant mixture.
Figure imgf000019_0001
Figure imgf000019_0001
Aus den vorstehend aufgeführten Testergebnissen geht hervor, dass Hexylglykol + 4 EO gegenüber Cocoamidopropylbetain eine wesentlich verminderte Hautreizwirkung zeigt. Bei Kombination mit Natriumdodecylsulfat kann eine Wirkung erreicht werden, die mit der bekannten Kombination von Natriumdodecylsulfat und Cocoamido-propylbetain vergleichbar ist. Beispiele kosmetischer Zusammensetzungen:The test results listed above show that hexylglycol + 4 EO shows a significantly reduced skin irritation effect compared to cocoamidopropylbetaine. When combined with sodium dodecyl sulfate, an effect can be achieved which is comparable to the known combination of sodium dodecyl sulfate and cocoamido-propylbetaine. Examples of cosmetic compositions:
Haarkosmetische Zusammensetzung (allg.) a) 0,8 bis 5 Gew.-% erfindungsgemäße Mischung b) 95 bis 99,2 Gew.-% Wasser und/oder Alkohol c) 0 bis 95,2 Gew.-% weitere BestandteileHair cosmetic composition (general) a) 0.8 to 5% by weight of the mixture according to the invention b) 95 to 99.2% by weight of water and / or alcohol c) 0 to 95.2% by weight of further constituents
Unter Alkohol sind alle in der Kosmetik üblichen Alkohole zu verstehen, z.B. Ethanol, Isopropanol, n-Propanol.Alcohol is to be understood to mean all alcohols customary in cosmetics, e.g. Ethanol, isopropanol, n-propanol.
Unter weiteren Bestandteilen sind die in der Kosmetik üblichen Zusätze zu verstehen, beispielsweise Treibmittel, Entschäumer, grenzflächenaktive Verbindungen, d.h. Tenside, Emulgatoren, Schaumbildner und Solubilisatoren. Die eingesetzten grenzflächenaktiven Verbindungen können anionisch, kationisch, amphoter oder neutral sein. Weitere übliche Bestandteile können ferner sein z.B. Konservierungsmittel, Parfümöle, Trübungsmittel, Wirkstoffe, UV-Filter, Pflegestoffe wie Panthenol, Collagen, Vitamine, Eiweißhydrolysate, Alpha- und Beta-Hydroxycarbonsäuren, Chitosan, Eiweißhydrolysate, Kosmetik-Polymere, Stabilisatoren, pH-Wert-Regulatoren, Farbstoffe, Viskositäts- regulierer, Gelbildner, Farbstoffe, Salze, Feuchthaltemittel, Rückfetter, Komplexbildner und weitere übliche Additive.Other constituents are to be understood as the additives customary in cosmetics, for example blowing agents, defoamers, surface-active compounds, i.e. Surfactants, emulsifiers, foaming agents and solubilizers. The surface-active compounds used can be anionic, cationic, amphoteric or neutral. Other common ingredients may also be e.g. Preservatives, perfume oils, opacifiers, active substances, UV filters, care substances such as panthenol, collagen, vitamins, protein hydrolyzates, alpha and beta hydroxycarboxylic acids, chitosan, protein hydrolyzates, cosmetic polymers, stabilizers, pH regulators, dyes, viscosity regulators , Gelling agents, dyes, salts, humectants, refatting agents, complexing agents and other common additives.
Shampooformulierung/DuschgelformulierungShampoo formulation / shower gel formulation
Bevorzugte Shampooformulierungen oder Duschgelformulierungen enthaltenPreferred shampoo formulations or shower gel formulations included
a) 0,05 bis 10 Gew.-% eines Kosmetik-Polymers b) 25 bis 94,95 Gew.-% Wasser c) 5 - 50 Gew.-% der erfindungsgemäßen Mischung d) 0 - 5 Gew.-% eines weiteren Konditioniermittels e) 0 - 10 Gew.-% weitere kosmetische Bestandteilea) 0.05 to 10% by weight of a cosmetic polymer b) 25 to 94.95% by weight of water c) 5 to 50% by weight of the mixture according to the invention d) 0 to 5% by weight of another Conditioning agent e) 0-10% by weight of further cosmetic ingredients
In den Shampooformulierungen können zudem alle in Shampoos üblicherweise eingesetzten anionischen, neutralen, amphoteren oder kationischen Tenside verwendet werden mit den vorstehenden Maßgaben.In addition, all anionic, neutral, amphoteric or cationic surfactants usually used in shampoos can be used in the shampoo formulations with the above provisions.
Beispiel 1: Conditioner Shampoo mit PO-10 35,70 g Sodium Laureth SulfateExample 1: Conditioner Shampoo with PO-10 35.70 g Sodium Laureth Sulfate
6,50 g Cocamidopropyl Betaine 0,50 g erfindungsgemäße Alkylglykolalkoxylate6.50 g cocamidopropyl betaine 0.50 g of alkyl glycol alkoxylates according to the invention
0,40 g Polyquaternium-100.40 g polyquaternium-10
0,10 g Konservierungsmittel ad 100 g Aqua dem.0.10 g preservative ad 100 g Aqua dem.
Beispiel 2: Conditioner Shampoo mit GHTCExample 2: Conditioner shampoo with GHTC
35,70 g Sodium Laureth Sulfate35.70 g sodium laureth sulfate
6,50 g Cocamidopropyl Betaine6.50 g cocamidopropyl betaine
0,50 g erfindungsgemäße Alkylglykolalkoxylate0.50 g of alkyl glycol alkoxylates according to the invention
0,20 g Guarhydroxypropyltrimonium Chloride0.20 g guar hydroxypropyltrimonium chloride
0,10 g Konservierungsmittel ad 100 g Aqua dem.0.10 g preservative ad 100 g Aqua dem.
Beispiel 3: Conditioner Shampoo mit Luviquat CareExample 3: Conditioner shampoo with Luviquat Care
35,70 g Sodium Laureth Sulfate35.70 g sodium laureth sulfate
6,50 g Cocamidopropyl Betaine6.50 g cocamidopropyl betaine
0,50 g erfindungsgemäße Alkylglykolalkoxylate0.50 g of alkyl glycol alkoxylates according to the invention
0,50 g Polyquaternium-4400.50 g polyquaternium-440
0,10 g Konservierungsmittel ad 100 g Aqua dem.0.10 g preservative ad 100 g Aqua dem.
Beispiel 4: ShampooExample 4: Shampoo
Phase APhase A
15,00 g Cocamidopropyl Betaine15.00 g cocamidopropyl betaines
10,00 g Disodium Cocoamphodiacetate10.00 g disodium cocoamphodiacetate
5,00 g Polysorbate 205.00 g of polysorbate 20
5,00 g Decyl Glucoside5.00 g decyl glucoside
0,50 g erfindungsgemäße Alkylglykolalkoxylate q.s. Perfume q.s. Konservierungsmittel0.50 g of alkyl glycol alkoxylates q.s. Perfume q.s. preservative
2,00 g Laureth-3 ad 100 Aqua dem. q.s. Citric Acid2.00 g Laureth-3 ad 100 Aqua dem. q.s. Citric acid
Phase BPhase B
3,00 g PEG-150 Distearate Herstellung3.00 g PEG-150 distearate manufacturing
Komponenten der Phase A einwiegen und lösen; pH- Wert auf 6-7 einstellen. Phase B zugeben und auf 50°C erwärmen. Auf Raumtemperatur abkühlen lassen unter Rühren.Weigh in and dissolve phase A components; Set pH to 6-7. Add phase B and warm to 50 ° C. Allow to cool to room temperature while stirring.
Beispiel 5: ShampooExample 5: Shampoo
30,00 g Sodium Laureth Sulfate30.00 g sodium laureth sulfate
6,00 g Sodium Cocoamphoacetate6.00 g sodium cocoamphoacetate
6,00 g erfindungsgemäße Alkylglykolalkoxylate6.00 g of alkyl glycol alkoxylates according to the invention
3,00 g Sodium Laureth Sulfate, Glycol Distearate, Cocamide MEA, Laureth-103.00 g Sodium Laureth Sulfate, Glycol Distearate, Cocamide MEA, Laureth-10
2,00 g Dimefhicone q.s. Parfüm q.s. Konservierungsmittel q.s. Citric Acid2.00 g Dimefhicone q.s. Perfume q.s. Preservatives q.s. Citric acid
1,00 g Sodium Chloride ad 100 Aqua dem.1.00 g sodium chloride ad 100 aqua dem.
Beispiel 6: DuschgelExample 6: Shower gel
20,00 g Ammonium Laureth Sulfate20.00 g of ammonium laureth sulfate
15,00 g Ammonium Lauryl Sulfate 5,00 g erfindungsgemäße Alkylglykolalkoxylate15.00 g of ammonium lauryl sulfate 5.00 g of alkyl glycol alkoxylates according to the invention
2,50 g Sodium Laureth Sulfate, Glycol Distearate, Cocamide MEA, Laureth-10 q.s. Parfüm q.s. Konservierungsmittel2.50 g sodium laureth sulfate, glycol distearate, cocamide MEA, laureth-10 q.s. Perfume q.s. preservative
0,50 g Sodium Chloride ad 100 Aqua dem.0.50 g sodium chloride ad 100 Aqua dem.
Beispiel 7: DuschgelExample 7: Shower gel
40,00 g Sodium Laureth Sulfate40.00 g sodium laureth sulfate
5,00 g Decyl Glucoside 5,00 g erfindungsgemäße Alkylglykolalkoxylate5.00 g decyl glucoside 5.00 g alkyl glycol alkoxylates according to the invention
1,00 g Panthenol q.s. Parfüm q.s. Konservierungsmittel q.s. Citric Acid 2,00 g Sodium Chloride ad 100 Aqua dem. Beispiel 8: Shampoo1.00 g panthenol qs perfume qs preservative qs citric acid 2.00 g sodium chloride ad 100 Aqua dem. Example 8: Shampoo
12,00 g Sodium Laureth Sulfate12.00 g sodium laureth sulfate
1,50 g Decyl Clucoside1.50 g decyl clucoside
2,50 g erfindungsgemäße Alkylglykolalkoxylate2.50 g of alkyl glycol alkoxylates according to the invention
5,00 g Coco-Glucoside Glyceryl Oleate5.00 g coco-glucoside glyceryl oleate
2,00 g Sodium Laureth Sulfate, Glycol Distearate, Cocomide MEA, Laureth-10 q.s. Konservierungsmittel q.s. Sunset Yelow C. 1. 15 985 q.s. Parfüm2.00 g Sodium Laureth Sulfate, Glycol Distearate, Cocomide MEA, Laureth-10 q.s. Preservatives q.s. Sunset Yelow C. 1. 15 985 q.s. Perfume
1,00 g Sodium Chloride ad 100 Aqua dem.1.00 g sodium chloride ad 100 aqua dem.
Die erfindungsgemäßen Mischungen eignen sich auch in Haarstyling-Zubereitungen, insbesondere Haarschäume (Aerosolschäume mit Treibgas und Pumpschäume ohne Treibgas), Haarsprays (Aerosolsprays mit Treibgas und Pumpssprays ohne Treibgas) und Haargele.The mixtures according to the invention are also suitable in hair styling preparations, in particular hair foams (aerosol foams with propellant gas and pump foams without propellant gas), hair sprays (aerosol sprays with propellant gas and pump sprays without propellant gas) and hair gels.
Treibmittel sind die üblich verwendeten Treibmittel. Bevorzugt sind Gemische aus Propan/Butan, Pentan, Dimethylether, 1,1-Difhιorethan (HFC-152 a), Kohlendioxid, Stickstoff oder Druckluft.Blowing agents are the commonly used blowing agents. Mixtures of propane / butane, pentane, dimethyl ether, 1,1-difhιorethane (HFC-152 a), carbon dioxide, nitrogen or compressed air are preferred.
Aerosolhaarschaum a) 0,1 bis 10 Gew.-% eines Kosmetik-Polymers b) 55 bis 99,8 Gew.-% Wasser und/oder Alkohol c) 5 bis 20 Gew.-% eines Treibmittels d) 0,1 bis 5 Gew.-% der erfindungsgemäßen Mischung e) 0 bis 10 Gew.-% weitere BestandteileAerosol hair foam a) 0.1 to 10% by weight of a cosmetic polymer b) 55 to 99.8% by weight of water and / or alcohol c) 5 to 20% by weight of a blowing agent d) 0.1 to 5 % By weight of mixture e) according to the invention 0 to 10% by weight of further constituents
Als weitere Bestandteile können unter anderem alle in Haarschäumen üblicherweise eingesetzten Emulgatoren verwendet werden. Geeignete Emulgatoren können nichtionisch, kationisch bzw. anionisch oder amphoter sein.All other emulsifiers commonly used in hair foams can be used as further constituents. Suitable emulsifiers can be nonionic, cationic or anionic or amphoteric.
Beispiele für nichtionische Emulgatoren (LNCI-Nomenklatur) sind Laurethe, z.B. Laureth- 4; Cetethe, z.B. Cetheth-1, Polyethylenglycolcetylether; Cetearethe, z.B. Cetheareth-25, Polyglycolfettsäureglyceride, hydroxyliertes Lecithin, Lactylester von Fettsäuren, Alkylpolyglycoside. Beispiele für kationische Emulgatoren sind Cetyldimethyl-2-hydroxyethyl- ammoniumdihydrogenphosphat, Cetyltrimoniumchlorid, Cetyltrimmoniumbromid, Cocotrimoniummethylsulfat, Quaternium-1 bis x (LNCΪ).Examples of nonionic emulsifiers (LNCI nomenclature) are Laurethe, for example Laureth-4; Cetethe, for example cetheth-1, polyethylene glycol cetyl ether; Cetearethe, for example cetheareth-25, polyglycol fatty acid glycerides, hydroxylated lecithin, lactyl esters of fatty acids, alkyl polyglycosides. Examples of cationic emulsifiers are cetyldimethyl-2-hydroxyethylammonium dihydrogen phosphate, cetyltrimonium chloride, cetyltrimmonium bromide, cocotrimonium methyl sulfate, quaternium-1 to x (LNCΪ).
Anionische Emulgatoren können beispielsweise ausgewählt werden aus der Gruppe der Alkylsulfate, Alkylethersulfate, Alkylsulfonate, Alkylarylsulfonate, Alkylsuccinate, Alkylsulfosuccinate, N-Alkoylsarkosinate, Acyltaurate, Acylisethionate, Alkylphosphate, Alkylethe hosphate, Alkylethercarboxylate, Alpha-Olefinsulfonate, insbesondere die Alkali- und Erdalkalimetallsalze, z.B. Natrium, Kalium, Magnesium, Calcium, sowie Ammonium- und Triethanolamin-Salze. Die Alkylethersulfate, Alkyletherphosphate und Alkylethercarboxylate können zwischen I bis 10 Ethylenoxid oder Propylenoxid- Einheiten, bevorzugt 1 bis 3 Ethylenoxid-Einheiten im Molekül aufweisen.Anionic emulsifiers may for example be selected from the group of alkyl sulfates, alkyl ether sulfates, alkylsulfonates, alkylarylsulfonates, alkyl succinates, alkyl sulphosuccinates, N-Alkoylsarkosinate, acyl taurates, acyl isethionates, alkyl phosphates, Alkylethe triphosphate, alkyl ether carboxylates, alpha-olefin sulfonates, especially the alkali metal and alkaline earth metal salts, e.g. Sodium, potassium, magnesium, calcium, as well as ammonium and triethanolamine salts. The alkyl ether sulfates, alkyl ether phosphates and alkyl ether carboxylates can have between 1 and 10 ethylene oxide or propylene oxide units, preferably 1 to 3 ethylene oxide units in the molecule.
Eine erfindungsgemäß für Styling-Gele geeignete Zubereitung kann beispielsweise wie folgt zusammengesetzt sein:A preparation suitable according to the invention for styling gels can be composed, for example, as follows:
Beispiel 9: Aerosolhaarschaum 2.00 g Cocotrimonium Methosulf ate q.s. Perfume 3,50 g Festigerpolymer z.B. Polyquaternium-46, PQ-44, VP/Methacrylamide/Example 9: Aerosol hair foam 2.00 g cocotrimonium methosulfate q.s. Perfume 3.50 g setting polymer e.g. Polyquaternium-46, PQ-44, VP / methacrylamide /
Vinyl Imidazole Copolymer, etc. 0,80 g erfindungsgemäße Alkylglykolalkoxylate q.s. PreservativeVinyl imidazole copolymer, etc. 0.80 g of alkyl glycol alkoxylates q.s. Preservative
75,00 g Wasser dem. 10,00 g Propane/Butane (3.5 bar)75.00 g water dem. 10.00 g propane / butane (3.5 bar)
Stylinggel a) 0,1 bis 10 Gew.-% eines Kosmetik-Polymers b) 60 bis 99,85 Gew.-% Wasser und/oder Alkohol c) 0,05 bis 10 Gew.-% eins Gelbildners d) 0,1 bis 5 Gew.-% der erfindungsgemäßen Mischung e) 0 bis 20 Gew.-% weitere BestandteileStyling gel a) 0.1 to 10% by weight of a cosmetic polymer b) 60 to 99.85% by weight of water and / or alcohol c) 0.05 to 10% by weight of a gelling agent d) 0.1 up to 5% by weight of the mixture e) according to the invention 0 to 20% by weight of further constituents
Als Gelbildner können alle in der Kosmetik üblichen Gelbildner eingesetzt werden. Hierzu zählen leicht vernetzte Polyacrylsäure, beispielsweise Carbomer (INCI), Cellulosederivate, z.B. Hydroxypropylcellulose, Hydroxyethylcellulose, kationisch modifizierte Cellulosen,All gel formers customary in cosmetics can be used as gel formers. These include slightly cross-linked polyacrylic acid, e.g. carbomer (INCI), cellulose derivatives, e.g. Hydroxypropyl cellulose, hydroxyethyl cellulose, cationically modified celluloses,
Polysaccharide, z.B. Xanthum Gummi, Caprylic/Capric Triglyceride, Sodium acrylates Copolymer, Polyquaternium-32 (and) Paraffinum Liquidum (J-NCI), Sodium Acrylates Copolymer (and) Paraffinum Liquidum (and) PPG-1 Trideceth-6, Acrylamidopropyl Trimomum Chloride/Acrylamide Copolymer, Steareth-10 Allyl Ether Acrylates Copolymer, Polyquaternium-37 (and) Paraffinum Liquidum (and) PPG-1 Trideceth-6, Polyquaternium 37 (and) Propylene Glycole Dicaprate Dicaprylate (and) PPG-1 Trideceth- 6, Polyquaternium-7, Polyquaternium-44.Polysaccharides, e.g. xanthum gum, caprylic / capric triglycerides, sodium acrylates Copolymer, Polyquaternium-32 (and) Paraffinum Liquidum (J-NCI), Sodium Acrylates Copolymer (and) Paraffinum Liquidum (and) PPG-1 Trideceth-6, Acrylamidopropyl Trimomum Chloride / Acrylamide Copolymer, Steareth-10 Allyl Ether Acrylates Copolymer, Polyquaternium -37 (and) Paraffinum Liquidum (and) PPG-1 Trideceth-6, Polyquaternium 37 (and) Propylene Glycole Dicaprate Dicaprylate (and) PPG-1 Trideceth-6, Polyquaternium-7, Polyquaternium-44.
Beispiel 10: : HaarstvlinggelExample 10:: Hair gel
Phase APhase A
0,50 g Carbomer oder Acrylates/C10-30 Alkyl Acrylate Crosspolymer0.50 g carbomer or acrylates / C10-30 alkyl acrylate cross polymer
86,40 g Wasser dem.86.40 g of water.
Phase BPhase B
0,70 g Triethanolamine0.70 g triethanolamine
Phase CPhase C
6,00 g Festigerpolymer z.B. VP/Methacrylamide/Vinyl Imidazole Copolymer6.00 g of setting polymer e.g. VP / methacrylamide / vinyl imidazole copolymer
5,00g PVP5.00g PVP
0,20 g PEG-25 PABA0.20 g PEG-25 PABA
0,50 g erfindungsgemäße Alkylglykolalkoxylate q.s. Parfümöl q.s. PEG-14 Dimethicone q.s. Konservierungsmittel0.50 g of alkyl glycol alkoxylates q.s. Perfume oil q.s. PEG-14 Dimethicone q.s. preservative
0,10 g Tocopheryl Acetate0.10 g tocopheryl acetate
Beispiel 11: HaarstvlinggelExample 11: Hair gel
Phase APhase A
0,50 g Carbomer oder Acrylates/C10-30 Alkyl Acrylate Crosspolymer0.50 g carbomer or acrylates / C10-30 alkyl acrylate cross polymer
91,20 g Wasser dem.91.20 g of water.
Phase BPhase B
0,90 g Tetrahydroxypropyl Ethylenediamine0.90 g tetrahydroxypropyl ethylenediamine
Phase CPhase C
7,00 g VP/VA Copolymer7.00 g VP / VA copolymer
0,40 g erfindungsgemäße Alkylglykolalkoxylate q.s. Parfümöl q.s. Konservierungsmittel0.40 g of alkyl glycol alkoxylates q.s. Perfume oil q.s. preservative
0,10 g Propylene Glycol Beispiel 12: Hair Wax Cream0.10 g propylene glycol Example 12: Hair Wax Cream
6,00 g Caprylic/Capric Triglyceride6.00 g caprylic / capric triglycerides
3,00 g Glyceryl Stearate3.00 g glyceryl stearate
2,00 g Cetyl Alcohol2.00 g cetyl alcohol
3,50 g erfindungsgemäße Alkylglykolalkoxylate3.50 g of alkyl glycol alkoxylates according to the invention
0,50 g Cremophoer A60.50 g Cremophoer A6
0,70 g Cremophor A250.70 g Cremophor A25
0,50 g Dimethicone0.50 g dimethicone
0,50 g Vitamin E Acetate0.50 g Vitamin E Acetate
2,00 g Caprylic/Capric Triglyceride and Sodiumacrylates Copolymer2.00 g Caprylic / Capric Triglyceride and Sodium Acrylates Copolymer
1,00 g D-Panthenol USP1.00 g D-panthenol USP
0,10 g EDTA0.10 g EDTA
10,00 g Festigerpolymer q.s. Konservierungsmittel ad 100 g Wasser dem.10.00 g setting polymer q.s. Preservative ad 100 g water dem.
Beispiel 13: HaarpuddingExample 13: Hair pudding
3,00 g Kollicoat T-R (BASF) q.s. Konservierungsmittel3.00 g Kollicoat T-R (BASF) q.s. preservative
2,00 g Festigerpolymer2.00 g of setting polymer
4,00 g Acrylates/beheneth-25 Methacrylate Copolymer4.00 g acrylates / beheneth-25 methacrylate copolymer
0,70 g erfindungsgemäße Alkylglykolalkoxylate0.70 g of alkyl glycol alkoxylates according to the invention
0,50 g Dimethicone Copolyol0.50 g dimethicone copolyol
0,10 g EDTA0.10 g EDTA
0,20 g Benzophenone-4 ad 100 g Wasser dem.0.20 g benzophenone-4 ad 100 g water dem.
Beispiel 14: SprühgelExample 14: Spray gel
Phase APhase A
1,25 g Festigerpolymer1.25 g of setting polymer
96,25 g Wasser dem.96.25 g of water.
Phase BPhase B
0,70 g Acrylates/Steareth-20 Itaconate Copolymer0.70 g acrylate / steareth-20 itaconate copolymer
0,10 g Propylene Glycol0.10 g propylene glycol
0,50 g erfindungsgemäße Alkylglykolalkoxylate0.50 g of alkyl glycol alkoxylates according to the invention
0,10 g Glycerin q.s. Konservierungsmittel Phase C 0,70 g Triethanolamine0.10 g glycerin qs preservative Phase C 0.70 g triethanolamine
Eine erfindungsgemäß für Styling-Sprays geeignete Zubereitung kann beispielsweise wie folgt zusammengesetzt sein:A preparation suitable according to the invention for styling sprays can be composed, for example, as follows:
Aerosolstylingspray a) 0,1 bis 10 Gew.-% eines Kosmetik-Polymers b) 55 bis 99,8 Gew.-% Wasser und/oder Alkohol c) 5 bis 20 Gew.-% eines Treibmittels d) 0,1 bis 5 Gew.-% der erfindungsgemäßen Mischung e) 0 bis 10 Gew.-% weitere BestandteileAerosol styling spray a) 0.1 to 10% by weight of a cosmetic polymer b) 55 to 99.8% by weight of water and / or alcohol c) 5 to 20% by weight of a propellant d) 0.1 to 5 % By weight of the mixture e) according to the invention 0 to 10% by weight of further constituents
Beispiel 15: Aerosolhaarspray VOC55Example 15: VOC55 aerosol hair spray
5,00 g Acrylates Copolymer5.00 g acrylate copolymer
0,95 g Aminomethyl Propanol0.95 g aminomethyl propanol
0,50 g erfindungsgemäße Alkylglykolalkoxylate q.s. Parfüm0.50 g of alkyl glycol alkoxylates q.s. Perfume
15,00 g Alcohol15.00 g alcohol
39,00 g Aqua dem.39.00 g Aqua dem.
40,00 g Dimtehyl Ether40.00 g dimethyl ether
Beispiel 16: : Aerosolhaarsprav VOC55Example 16:: Aerosol hairspray VOC55
2,50 g Octylacrylamide/Acrylates/Butylaminoethyl Methacrylate Copolymer 2,50 g VA/Crotonates/Vinyl Neodecanoate Copolymer2.50 g octylacrylamides / acrylates / butylaminoethyl methacrylate copolymer 2.50 g VA / crotonates / vinyl neodecanoate copolymer
0,30 g erfindungsgemäße Alkylglykolalkoxylate0.30 g of alkyl glycol alkoxylates according to the invention
0,80 g Aminomethyl Propanol0.80 g aminomethyl propanol
0,03 g PPG-3 Methyl Ether0.03 g PPG-3 methyl ether
0,10 g Panthenol 0,10 g Benzophenone-30.10 g panthenol 0.10 g benzophenone-3
0,10 g Niacinamide q.s. Parfüm0.10 g niacinamide q.s. Perfume
15,00 g Alcohol15.00 g alcohol
38,50 g Aqua dem. 40,00 g Dimethyl Ether Beispiel 17: Aerosolhaarsprav VOC5538.50 g Aqua dem. 40.00 g dimethyl ether Example 17: Aerosol hairspray VOC55
3,00 g Acrylates Copolymer3.00 g acrylate copolymer
1,50 g Acrylat/Octylacrylamide Copolymer1.50 g acrylate / octylacrylamide copolymer
0,52 g Aminomethyl Propanol 0,70 g erfindungsgemäße Alkylglykolalkoxylate0.52 g aminomethyl propanol 0.70 g alkyl glycol alkoxylates according to the invention
0,30 g Phenyltrimethicone q.s. Parfüm0.30 g phenyltrimethicone q.s. Perfume
15,00 g Alcohol15.00 g alcohol
39,00 g Aqua dem. 40,00 g Dimtehyl Ether39.00 g Aqua dem. 40.00 g dimethyl ether
Beispiel 18: Aerosolhaarsprav VOC80 5,00 g Acrylates CopolymerExample 18: Aerosol hairspring VOC80 5.00 g acrylate copolymer
1,56 g Aminomethyl Propanol 0,70 g erfindungsgemäße Alkylglykolalkoxylate1.56 g aminomethyl propanol 0.70 g alkyl glycol alkoxylates according to the invention
0,50 g Panthenol0.50 g panthenol
0,10 g Phytantriol0.10 g phytantriol
12,14 g Aqua dem.12.14 g Aqua dem.
55,00 g Alcohol q.s. Parfüm55.00 g Alcohol q.s. Perfume
10,00 g Butane10.00 g butanes
15,00 g Dimethyl Ether15.00 g dimethyl ether
Beispiel 19: Aerosolhaarsprav VOC80 3,00 g PEG/PPG-25/25 Dimethicone/Acrylates CopolymerExample 19: Aerosol hairspray VOC80 3.00 g PEG / PPG-25/25 Dimethicone / Acrylates Copolymer
5,00 g Polyurethane- 15.00 g polyurethane- 1
0,10 g erfindungsgemäße Alkylglykolalkoxylate0.10 g of alkyl glycol alkoxylates according to the invention
0,36 g Aminomethyl Propanol0.36 g of aminomethyl propanol
16,04 g Aqua dem. 35,50 g Alcohol16.04 g Aqua dem. 35.50 g alcohol
40,00 g Dimethyl Ether40.00 g dimethyl ether
Beispiel 20: Aerosolhaarsprav VOC95 0,95 g Aminomethyl Propanol 0,60 g erfindungsgemäße Alkylglykolalkoxylate 0,10 g Dimethicone CopolyolExample 20: Aerosol hairspray VOC95 0.95 g aminomethyl propanol 0.60 g alkyl glycol alkoxylates according to the invention 0.10 g dimethicone copolyol
0,10 g Cetearyl Octanoate0.10 g cetearyl octanoate
0,10 g Panthenol q.s. Parfüm 54,15 g Alcohol0.10 g panthenol q.s. Perfume 54.15 g alcohol
4,00 g Acrylates Copolymer4.00 g acrylate copolymer
40,00 g Propane/Butane40.00 g propane / butane
Beispiel 21: Pumphaarspray 11,20 g PEG/PPG-25/25 Dimethicone/Acrylates CopolymerExample 21: Pump hair spray 11.20 g PEG / PPG-25/25 Dimethicone / Acrylates Copolymer
2,80 g VP/NA Copolymer2.80 g VP / NA copolymer
1,34 g Aminomethyl Propanol1.34 g aminomethyl propanol
0,30 g erfindungsgemäße Alkylglykolalkoxylate0.30 g of alkyl glycol alkoxylates according to the invention
11,36 g Aqua dem. 73,00 g Alcohol11.36 g Aqua dem. 73.00 g alcohol
Beispiel 22: Pumphaarspray VOC55 2,00 g VP/Methacrylamide/ Vinyl Imidazole CopolymerExample 22: Pump hair spray VOC55 2.00 g VP / methacrylamide / vinyl imidazole copolymer
2,00 g Polyquaternium-46 2,00 g erfindungsgemäße Alkylglykolalkoxylate q.s. Parfüm2.00 g polyquaternium-46 2.00 g alkylglycol alkoxylates q.s. Perfume
55,00 g Alcohol55.00 g alcohol
39,00 g Aqua dem.39.00 g Aqua dem.
Durch den Zusatz der erfindungsgemäß eingesetzten Alkylglykolalkoxylate und - diglykolalkoxylate, insbesondere in Form der erfindungsgemäßen Mischungen wird die Tröpfchengrößenverteilung der Sprays in vorteilhafter Weise in Richtung kleinerer Tröpfchen beeinflußt, so dass feinere Sprühnebel entstehen oder sogar sonst nur schwer sprühbare Formulierungen überhaupt in eine sprühbare Anwendung gebracht werden.By adding the alkyl glycol alkoxylates and diglycol alkoxylates used according to the invention, in particular in the form of the mixtures according to the invention, the droplet size distribution of the sprays is advantageously influenced in the direction of smaller droplets, so that finer spray mists are formed or even formulations which are difficult to spray are brought into a sprayable application at all ,
Hautkosmetische ZusammensetzungenSkin cosmetic compositions
Beispiel 23: Flüssiges Makeup Phase A 1,70 g Glyceryl Stearate 1,70 g Cetyl AlcoholExample 23: Liquid makeup phase A 1.70 g glyceryl stearate 1.70 g cetyl alcohol
1,70 g Ceteareth-61.70 g ceteareth-6
1,70 g Ceteareth-251.70 g ceteareth-25
5,20 g Caprylic/Capric Triglyceride5.20 g caprylic / capric triglycerides
5,20 g Mineral Oil5.20 g mineral oil
Phase B q.s. KonservierungsmittelPhase B q.s. preservative
4,30 g Propylene Glycol4.30 g propylene glycol
2,50 g erfindungsgemäße Alkylglykolalkoxylate2.50 g of alkyl glycol alkoxylates according to the invention
59,50 g Aqua dem.59.50 g Aqua dem.
Phase C q.s. ParfümölPhase C q.s. perfume oil
Phase DPhase D
2,00 g Iron Oxides2.00 g of iron oxides
12,00 g Titanium Dioxide12.00 g titanium dioxide
Beispiel 24: EyelinerExample 24: Eyeliner
Phase APhase A
40,60 g dest. Wasser40.60 g dist. water
0,20 g Disodium EDTA q.s. Konservierungsmittel0.20 g disodium EDTA q.s. preservative
Phase BPhase B
0,60 g Xanthan Gum0.60 g xanthan gum
0,40 g Veegum0.40 g Veegum
3,00 g Butylene Glycol3.00 g of butylene glycol
0,20 g Polysorbate-200.20 g polysorbate-20
Phase CPhase C
15,00 g Iron oxide / AI Powder / Silica (z.B. Sicoj BASF)15.00 g iron oxide / AI powder / silica (e.g. Sicoj BASF)
Phase DPhase D
10,00 g Aqua dem.10.00 g aqua dem.
25,00 g Festigerpolymer (z.B. Polyurethane-1 ode25.00 g of setting polymer (e.g. polyurethane-1 or
I-midazole Copolymer, etc.)I-midazole copolymer, etc.)
5,00 g erfindungsgemäße Alkylglykolalkoxylate Beispiel 25: Sonnenschutz-Gel5.00 g of alkyl glycol alkoxylates according to the invention Example 25: Sun protection gel
Phase APhase A
0,50 g PEG-40 Hydrogenated Castor Oil0.50 g PEG-40 Hydrogenated Castor Oil
0,50 g erfindungsgemäße Alkylglykolalkoxylate0.50 g of alkyl glycol alkoxylates according to the invention
8,00 g Octyl Methoxycinnamate8.00 g octyl methoxycinnamate
5,00 g Octocrylene5.00 g octocrylene
0,80 g Octyl Triazone0.80 g octyl triazone
2,00 g Butyl Methoxydibenzoylmethane2.00 g butyl methoxydibenzoylmethane
2,00 g Tocopheryl Acetate q.s. Parfüm2.00 g tocopheryl acetate q.s. Perfume
Phase BPhase B
0,30 g Acrylates/C10-30 Alkyl Acrylate Crosspolymer0.30 g Acrylates / C10-30 Alkyl Acrylate Crosspolymer
0,20 g Carbomer0.20 g carbomer
5,00 g Glycerin5.00 g glycerin
0,20 g Disodium EDTA q.s. Konservierungsmittel0.20 g disodium EDTA q.s. preservative
75,30 g Aqua dem.75.30 g Aqua dem.
Phase CPhase C
0,20 g Sodium Hydroxide0.20 g sodium hydroxide
Beispiel 26: Sonnenschutzemulsion mit TiO2 und ZnO?Example 26: Sun protection emulsion with TiO 2 and ZnO?
Phase APhase A
3,00 g PEG-7 Hydrogenated Castor Oil3.00 g PEG-7 Hydrogenated Castor Oil
3,00 g erfindungsgemäße Alkylglykolalkoxylate3.00 g of alkyl glycol alkoxylates according to the invention
2,00 g PEG-45/Dodecyl Glycol Copolymer2.00 g PEG-45 / dodecyl glycol copolymer
3,00 g Isopropyl Myristate3.00 g isopropyl myristate
8,00 g Jojoba (Buxus Chinensis) Oil8.00 g jojoba (Buxus Chinensis) Oil
4,00 g Octyl Methoxycinnamate4.00 g octyl methoxycinnamate
2,00 g 4-Methylbenzylidene Camphor2.00 g of 4-methylbenzylidenes camphor
3,00 g Titanium Dioxide, Dimethicone3.00 g titanium dioxide, dimethicone
1,00 g Dimethicone1.00 g dimethicone
5,00 g Zinc Oxide, Dimethicone5.00 g zinc oxides, dimethicone
Phase BPhase B
0,20 g Disodium EDTA 5,00 g Glycerin q.s. Konservierungsmittel0.20 g disodium EDTA 5.00 g glycerin qs preservative
60,80 g Aqua dem.60.80 g Aqua dem.
Phase C q.s. ParfümPhase C q.s. Perfume
Beispiel 27: GesichtswasserExample 27: Facial Toner
Phase APhase A
2,00 g PEG-40 Hydrogenated Castor Oil2.00 g PEG-40 Hydrogenated Castor Oil
1,00 g erfindungsgemäße Alkylglykolalkoxylate q.s. Parfümöl1.00 g of alkyl glycol alkoxylates q.s. perfume oil
0,40 g Bisabolol0.40 g bisabolol
Phase BPhase B
3,00 g Glycerin3.00 g glycerin
1,00 g Hydroxyethyl Cetyldimonium Phosphate1.00 g of hydroxyethyl cetyldimonium phosphate
5,00 g Whitch Hazel (Hamamelis Virginiana) Distillate5.00 g Whitch Hazel (Hamamelis Virginiana) distillates
0,50 g Panthenol q.s. Konservierungsmittel0.50 g panthenol q.s. preservative
87,60 g Aqua dem.87.60 g aqua dem.
Beispiel 28: Gesichtswaschpaste mit PeelingeffektExample 28: Facial washing paste with peeling effect
Phase APhase A
73,00 g Aqua dem.73.00 g Aqua dem.
1,50 g Carbomer q.s. Konservierungsmittel1.50 g carbomer q.s. preservative
Phase B q.s. ParfümölPhase B q.s. perfume oil
7,00 g Potassium Cocoyl Hydrolyzed Protein7.00 g of Potassium Cocoyl Hydrolyzed Protein
4,00 g erfindungsgemäße Alkylglykolalkoxylate4.00 g of alkyl glycol alkoxylates according to the invention
Phase CPhase C
1,50 g Triethanolamine1.50 g triethanolamine
Phase DPhase D
13,00 g Polyethylene (Luwax A™ von BASF) Beispiel 29: Seife13.00 g of polyethylene (Luwax A ™ from BASF) Example 29: Soap
Phase APhase A
25,00 g Potassium Cocoate25.00 g of Potassium Cocoate
20,00 g Disodium Cocoamphodiacetate20.00 g disodium cocoamphodiacetate
2,00 g Lauramide DEA2.00 g lauramide DEA
1,0 g Glycol Stearate1.0 g glycol stearate
2,00 g erfindungsgemäße Alkylglykolalkoxylate2.00 g of alkyl glycol alkoxylates according to the invention
50,00 g Aqua dem. q.s. Citric Acid50.00 g of Aqua dem. q.s. Citric acid
Phase B q.s. Konservierungsmittel q.s. ParfümPhase B q.s. Preservatives q.s. Perfume
Beispiel 30: Gesichtsreinigungsmilch Tvp O/WExample 30: Facial cleansing milk Tvp O / W
Phase APhase A
1,50 g Ceteareth-61.50 g ceteareth-6
1,50 g Ceteareth-251.50 g ceteareth-25
2,00 g Glyceryl Stearate2.00 g glyceryl stearate
2,00 g Cetyl Alcohol2.00 g cetyl alcohol
10,00 g Mineral Oil10.00 g mineral oil
Phase BPhase B
5,00 g Propylene Glycol q.s. Konservierungsmittel5.00 g propylene glycol q.s. preservative
1,00 g erfindungsgemäße Alkylglykolalkoxylate1.00 g of alkyl glycol alkoxylates according to the invention
66,30 g Aqua dem.66.30 g Aqua dem.
Phase CPhase C
0,20 g Carbomer0.20 g carbomer
10,00 g Cetearyl Octanoate10.00 g cetearyl octanoate
Phase DPhase D
0,40 g Tetrahydroxypropyl Ethylenediamine0.40 g tetrahydroxypropyl ethylenediamine
Phase E q.s. ParfümPhase E q.s. Perfume
0,10 g Bisabolol Beispiel 31: Transparente Seife0.10 g bisabolol Example 31: Transparent soap
4,20 g Sodium Hydroxide4.20 g sodium hydroxide
3,60 g dest. Wasser3.60 g dist. water
10,00 g erfindungsgemäße Alkylglykolalkoxylate10.00 g of alkyl glycol alkoxylates according to the invention
22,60 g Propylene Glycol22.60 g propylene glycol
18,70 g Glycerin18.70 g glycerin
5,20 g Cocoamide DEA5.20 g of Cocoamide DEA
2,40 g Cocamine Oxide2.40 g cocamine oxides
4,20 g Sodium Lauryl Sulfate4.20 g sodium lauryl sulfate
7,30 g Myristic Acid7.30 g myristic acid
16,60 g Stearic Acid16.60 g stearic acid
5,20 g Tocopherol5.20 g tocopherol
Beispiel 32: RasierschaumExample 32: Shaving cream
6,00 g Ceteareth-256.00 g ceteareth-25
5,00 g Poloxamer 4075.00 g Poloxamer 407
52,00 g Aqua dem.52.00 g Aqua dem.
1,00 g Triethanolamine1.00 g triethanolamine
5,00 g Propylene Glycol5.00 g propylene glycol
1,00 g PEG-75 Lanolin Oil1.00 g PEG-75 Lanolin Oil
5,00 g erfindungsgemäße Alkylglykolalkoxylate q.s. Konservierungsmittel q.s. Parfüm5.00 g of alkyl glycol alkoxylates q.s. Preservatives q.s. Perfume
25,00 g Sodium Laureth Sulfate Abfüllung: 90 Teile Wirksubstanz und 10 Teile Propan/Butan-Mischung 25:75.25.00 g sodium laureth sulfate Bottling: 90 parts active substance and 10 parts propane / butane mixture 25:75.
Beispiel 33: After Shave Balsam Phase AExample 33: After Shave Balm Phase A
0,25 g Acrylates/C10-30 Alkyl Acrylate Crosspolymer 1,50 g Tocopheryl Acetate0.25 g Acrylates / C10-30 Alkyl Acrylate Crosspolymer 1.50 g Tocopheryl Acetate
0,20 g Bisabolol0.20 g bisabolol
10,00 g Caprylic/Capric Triglyceride q.s. Parfüm10.00 g Caprylic / Capric Triglyceride q.s. Perfume
1,00 g PEG-40 Hydrogenated Castor Oil Phase B1.00 g PEG-40 Hydrogenated Castor Oil Phase B
1,00 g Panthenol1.00 g panthenol
15,00 g Alcohol15.00 g alcohol
5,00 g Glycerin5.00 g glycerin
0,05 g Hydroxyethyl Cellulose0.05 g hydroxyethyl cellulose
1,90 g erfindungsgemäße Alkylglykolalkoxylate1.90 g of alkyl glycol alkoxylates according to the invention
64,02 g dest. Wasser64.02 g dist. water
Phase CPhase C
0,08 g Sodium Hydroxide0.08 g sodium hydroxide
Beispiel 34: PflegecremeExample 34: Care Cream
Phase APhase A
2,00 g Ceteareth-62.00 g ceteareth-6
2,00 g Ceteareth-252.00 g ceteareth-25
2,00 g Cetearyl Alcohol2.00 g cetearyl alcohol
3,00 g Glyceryl Stearate SE3.00 g glyceryl stearate SE
5,00 g Mineral Oil5.00 g mineral oil
4,00 g Jojoba (Buxus Chinensis) Oil4.00 g jojoba (Buxus Chinensis) Oil
3,00 g Cetearyl Octanoate3.00 g cetearyl octanoate
1,00 g Dimethicone1.00 g dimethicone
3,00 g Mineral Oil, Lanolin Alcohol3.00 g mineral oil, lanolin alcohol
Phase BPhase B
5,00 g Propylene Glycol5.00 g propylene glycol
0,50 g Veegum0.50 g Veegum
1,00 g Panthenol1.00 g panthenol
1,70 g erfindungsgemäße Alkylglykolalkoxylate1.70 g of alkyl glycol alkoxylates according to the invention
6,00 g Polyquaternium-44 q.s. Konservierungsmittel6.00 g polyquaternium-44 q.s. preservative
60,80 g Auqa dem.60.80 g Auqa dem.
Phase C q.s. Parfüm Mund- und ZahnpflegezubereitungPhase C qs perfume Oral and dental care preparation
Beispiel 35: ZahnpasteExample 35: Toothpaste
Phase APhase A
34,79 g Aqua dem.34.79 g Aqua dem.
3,00 g erfindungsgemäße Alkylglykolalkoxylate3.00 g of alkyl glycol alkoxylates according to the invention
20,00 g Glycerin20.00 g glycerin
0,76 g Sodium Monofluorophosphate0.76 g sodium monofluorophosphate
Phase BPhase B
1,20 g Sodium Carboxymethylcellulose1.20 g sodium carboxymethyl cellulose
Phase CPhase C
0,80 g Aromaöl0.80 g aromatic oil
0,06 g Saccharin q.s. Konservierungsmittel0.06 g saccharin q.s. preservative
0,05 g Bisabolol0.05 g bisabolol
1,00 g Panthenol1.00 g panthenol
0,50 g Tocopheryl Acetate0.50 g tocopheryl acetate
2,80 g Silica2.80 g silica
1,00 g Sodium Lauryl Sulfate1.00 g sodium lauryl sulfate
7,90 g Dicalciumphosphate Anhydrate7.90 g dicalcium phosphate anhydrates
25,29 g Dicalciumphosphate Dihydrate25.29 g of dicalcium phosphate dihydrates
0,45 g Titanium Dioxide0.45 g titanium dioxide
Beispiel 36: MundwasserExample 36: Mouthwash
Phase APhase A
2,00 g Aromaöl2.00 g aromatic oil
4,00 g PEG-40 Hydrogenated Castor Oil4.00 g PEG-40 Hydrogenated Castor Oil
1,00 g Bisabolol1.00 g bisabolol
30,00 g Alcohol30.00 g of alcohol
Phase BPhase B
0,20 g Saccharin0.20 g saccharin
5,00 g Glycerin q.s. Konservierungsmittel5.00 g glycerol q.s. preservative
5,00 g Poloxamer 407 0,50 g erfindungsgemäße Alkylglykolalkoxylate5.00 g Poloxamer 407 0.50 g of alkyl glycol alkoxylates according to the invention
52,30 g Aqua dem.52.30 g Aqua dem.
Beispiel 37: Prothesenhaftmittel Phase AExample 37: Prosthetic adhesive phase A
0,20 g Bisabolol0.20 g bisabolol
1,00 g Beta-Carotene q.s. Aromaöl 20,00 g Cetearyl Octanoate1.00 g beta carotenes q.s. Aromatic oil 20.00 g cetearyl octanoate
5,00 g Silica 33,80 g Mineral Oil Phase B5.00 g silica 33.80 g mineral oil phase B
5,00 g erfindungsgemäße Alkylglykolalkoxylate 35,00 g PVP (20%ige Lösung in Wasser) 5.00 g of alkyl glycol alkoxylates according to the invention 35.00 g of PVP (20% solution in water)

Claims

- 1 -Patentansprüche - 1 -patent claims
1. Mischung aus Alkylglykolalkoxylaten oder -diglykolalkoxylaten, erhältlich durch Alkoxylierung von C4.8-Alkylglykolen oder -diglykolen mit C2-5-Alkoxiden bis zu einem mittleren Alkoxylierungsgrad von 1 bis 8, bezogen auf die C -8-Alkylglykole oder -diglykole, und Alkylsulfaten, Alkylethersulfaten, Alkylsulfonaten, die einen C8.3o-Alkylrest aufweisen, oder Gemischen davon.1. Mixture of alkyl glycol alkoxylates or diglycol alkoxylates, obtainable by alkoxylation of C 4 . 8 alkyl glycols or diglycols with C 2 - 5 alkoxides to an average degree of alkoxylation of 1 to 8, based on the C - 8 or -Alkylglykole -diglykole, and alkyl sulfates, alkyl ether sulfates, alkyl sulfonates having a C. 8 3 have o-alkyl radical, or mixtures thereof.
2. Mischung nach Anspruch 1, dadurch gekennzeichnet, dass die Alkylglykolalkoxylate oder -diglykolalkoxylate erhältlich sind durch Alkoxylierung von C .6-Alkylglykolen oder -diglykolen mit C2.4-Alkoxiden bis zu einem mittleren Alkoxylierungsgrad von 2 bis 6.2. Mixture according to claim 1, characterized in that the alkyl glycol alkoxylates or diglycol alkoxylates are obtainable by alkoxylation of C. 6 alkyl glycols or diglycols with C 2 . 4 alkoxides up to an average degree of alkoxylation of 2 to 6.
3. Verwendung von Mischungen gemäß Anspruch 1 oder 2 in kosmetischen und/oder dermatologischen Zusammensetzungen und pflegenden Handgeschirrspülmitteln.3. Use of mixtures according to claim 1 or 2 in cosmetic and / or dermatological compositions and nourishing hand dishwashing detergents.
4. Kosmetische und/oder dermatologische Zusammensetzung, enthaltend eine Mischung gemäß Anspruch 1 oder 2.4. Cosmetic and / or dermatological composition containing a mixture according to claim 1 or 2.
5. Kosmetische Zusammensetzung nach Anspruch 4, enthaltend als weitere Inhaltsstoffe Betaine, Aminoxide, Salze, Wasser, quaternisierte Stickstoffatome enthaltende Polymere oder Gemische davon.5. Cosmetic composition according to claim 4, containing betaines, amine oxides, salts, water, polymers containing quaternized nitrogen atoms or mixtures thereof as further ingredients.
6. Kosmetische Zusammensetzung nach Anspruch 4 oder 5, enthaltend 0,1 bis 20 Gew.-% der C2-5-Alkoxylate von C4-s-Alkylglykolen oder -diglykolen, bezogen auf das Gesamtgewicht der kosmetischen Zusammensetzung.6. A cosmetic composition according to claim 4 or 5, containing 0.1 to 20 wt .-% of the C 2 - 5 alkoxylates of C 4 -s alkyl glycols or diglycols, based on the total weight of the cosmetic composition.
7. Kosmetische Zusammensetzung nach einem der Ansprüche 4 bis 6, dadurch gekennzeichnet, dass es sich um eine haarkosmetische Zubereitung, ausgewählt aus Haarshampoos, Haarkuren, Haarlotionen, Haarspülungen, Haaremulsionen, Spitzenfluids, Egalisierungsmitteln für Dauerwellen, Haarfärbemitteln, "Hot-Oil- Treatmenf'-Präparaten, Conditionern, Festigerlotionen, Haargelen, Haarwachsen, Haarschäumen oder Haarsprays handelt. 7. Cosmetic composition according to one of claims 4 to 6, characterized in that it is a hair cosmetic preparation, selected from hair shampoos, hair treatments, hair lotions, hair rinses, hair emulsions, tip fluids, leveling agents for perms, hair colorants, "hot oil treatmenf" Preparations, conditioners, setting lotions, hair gels, hair waxes, hair foams or hair sprays.
8. Kosmetische Zusammensetzung nach einem der Ansprüche 4 bis 6, dadurch gekennzeichnet, dass es sich um eine hautkosmetische Zubereitung, ausgewählt aus Hautreinigungsmitteln, Hautpflegemitteln, Hautschutzmitteln oder dekorativen Kosmetikmitteln handelt, oder um Mund- und/oder Zahnpflegezubereitungen.8. Cosmetic composition according to one of claims 4 to 6, characterized in that it is a skin cosmetic preparation selected from skin cleansing agents, skin care agents, skin protection agents or decorative cosmetic agents, or oral and / or dental care preparations.
9. Verfahren zur Verminderung der Hautreizwirkung von Tensiden oder Tensidmischungen, dadurch gekennzeichnet, dass man das Tensid oder die Tensidmischung in Kombination mit Alkylglykolalkoxylaten oder -diglykolalkoxylaten, erhältlich durch Alkoxylierung von C -8-Alkylglykolen oder -diglykolen mit C2-5-Alkoxiden bis zu einem mittleren Alkoxylierungsgrad von 1 bis 8, bezogen auf die C4-8-Alkylglykole oder -diglykole, einsetzt.9. A method for reducing the skin irritation of surfactants or surfactant mixtures, characterized in that the surfactant or the surfactant mixture in combination with alkyl glycol alkoxylates or diglycol alkoxylates, obtainable by alkoxylation of C 8 alkyl glycols or diglycols with C 2 to 5 alkoxides to an average degree of alkoxylation of 1 to 8, based on the C 4-8 -Alkylglykole or -diglykole, begins.
10. Verfahren zur Solubilisierung von hydrophoben Inhaltsstoffen von kosmetischen und/oder dermatologischen Zusammensetzungen, dadurch gekennzeichnet, dass man die Inhaltsstoffe in Kombination mit Alkylglykolalkoxylaten oder -diglykolalkoxylaten, erhältlich durch Alkoxylierung von C4-8-Alkylglykolen oder -diglykolen mit C -5-Alkoxiden bis zu einem mittleren Alkoxylierungsgrad von 1 bis 8, bezogen auf die C4-s-Alkylglykole oder -diglykole, einsetzt.10. A process for the solubilization of hydrophobic ingredients of cosmetic and / or dermatological compositions, characterized in that the ingredients in combination with alkyl glycol alkoxylates or diglycol alkoxylates, obtainable by alkoxylation of C 4 - 8 alkyl glycols or diglycols with C - 5 alkoxides up to an average degree of alkoxylation of 1 to 8, based on the C 4 -s-alkyl glycols or diglycols.
11. Verfahren zur Verbesserung der Sprühbarkeit von kosmetischen und/oder dermatologischen Sprayzusammensetzungen durch Vermindern der Tröpfchengröße, dadurch gekennzeichnet, dass man die Inhaltsstoffe in Kombination mit Alkylglykolalkoxylaten oder -diglykolalkoxylaten, erhältlich durch Alkoxylierung von C .8-Alkylglykolen oder -diglykolen mit C2-5-Alkoxiden bis zu einem mittleren Alkoxylierungsgrad von 1 bis 8, bezogen auf die C4.8-Alkylglykole oder -diglykole, einsetzt. 11. A method for improving the sprayability of cosmetic and / or dermatological spray compositions by reducing the droplet size, characterized in that the ingredients in combination with alkyl glycol alkoxylates or diglycol alkoxylates, obtainable by alkoxylation of C. 8 alkyl glycols or diglycols with C 2 -5 alkoxides up to an average degree of alkoxylation of 1 to 8, based on the C 4 . 8 alkyl glycols or diglycols.
PCT/EP2004/000326 2003-01-17 2004-01-16 Cosmetic compositions comprising alkyl glycol alkoxylates or diglycol alkoxylates WO2004065536A1 (en)

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