WO2004041224A1 - Hair conditioning agents having improved coating and olfactory properties - Google Patents

Hair conditioning agents having improved coating and olfactory properties Download PDF

Info

Publication number
WO2004041224A1
WO2004041224A1 PCT/EP2003/012135 EP0312135W WO2004041224A1 WO 2004041224 A1 WO2004041224 A1 WO 2004041224A1 EP 0312135 W EP0312135 W EP 0312135W WO 2004041224 A1 WO2004041224 A1 WO 2004041224A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
hair
agent
polymer
composition according
Prior art date
Application number
PCT/EP2003/012135
Other languages
German (de)
French (fr)
Inventor
Marion Detert
Thomas Döring
Kerstin Franck
Bettina Primmel
Original Assignee
Beiersdorf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beiersdorf Ag filed Critical Beiersdorf Ag
Priority to AU2003282063A priority Critical patent/AU2003282063A1/en
Publication of WO2004041224A1 publication Critical patent/WO2004041224A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8164Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/85Polyesters
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87Polyurethanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/06Preparations for styling the hair, e.g. by temporary shaping or colouring
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54Polymers characterized by specific structures/properties
    • A61K2800/542Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5424Polymers characterized by specific structures/properties characterized by the charge anionic
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54Polymers characterized by specific structures/properties
    • A61K2800/542Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5428Polymers characterized by specific structures/properties characterized by the charge amphoteric or zwitterionic
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/594Mixtures of polymers

Definitions

  • the invention comprises hair treatment compositions containing at least one polymer with acidic or amphoteric groups and. at least one polyhydroxyalkylamine.
  • the hair treatment composition according to the invention shows good sensors and improved odor properties.
  • the hair treated with the preparation according to the invention has a natural, permanent bounce.
  • hair treatment products such as shampoos, cures, conditioners, and top fluids for cleaning and maintaining the hair, which are used in a wide variety of applications, for example as leave on or rinse off products.
  • hair care products such as shampoos, cures, conditioners, and top fluids for cleaning and maintaining the hair, which are used in a wide variety of applications, for example as leave on or rinse off products.
  • three other product categories are used in hair care and treatment; namely permanent or temporary hair colorants, permanent hair shaping agents as well as agents that only allow temporary shaping and stabilization of the hairstyle and are generally known as styling agents.
  • These include products such as hair sprays, hair lacquers, setting lotions, setting foams, hair gels, glossy products, hairstyle creams, etc. All these agents have in common that they usually consist of a large number of individual substances or components that perform a wide variety of tasks within the formulation.
  • the formulations are varied, and the components of the hair treatment agent must be compatible in an ethanolic, aqueous-ethanolic or aqueous medium.
  • Styling agents with anionic or amphoteric polymers mostly equipped with carboxy functionalities, require a neutralizing agent to achieve their optimal performance.
  • the neutralization improves the solubility of the film, the viscous elasticity, the film formation property and the KW propellant compatibility.
  • Common neutralizing agents have the disadvantage that they are either volatile and have an undesirable odor such as ammonia, etha . nolamine or aminomethylpropanol or adversely affect the quality of the film (sodium hydroxide or ammonia).
  • the films show a lack of flexibility, the hair has an unnatural feel, residues in the form of fine or coarse scales can be formed.
  • DE 19808824 describes a hair treatment composition containing at least one polymer with acidic groups and at least one N-unsubstituted or N-substituted polyhydroxyamine in a suitable cosmetic base.
  • the polyhydroxyamine has at least 4, particularly preferably 4 to 6, hydroxyl groups.
  • the object of the present invention is to provide a hair treatment composition which overcomes the disadvantages of the prior art, in particular to provide an composition with good film-forming properties and improved odor properties. Furthermore, it is an object of the present invention to provide an alternative hair treatment agent to the prior art.
  • the tasks are solved by a hair treatment agent according to claim 1.
  • the subclaims relate to advantageous embodiments of the agents according to the invention.
  • the invention further comprises the use of such agents.
  • a hair treatment composition comprising at least one polymer with acidic and / or amphoteric groups in alcoholic, aqueous-alcoholic or aqueous medium and at least one polyhydroxyalkylamine of the formula
  • R mono-, di- or trihydroxyalkyl radical with a carbon chain C 2 - C 6 ,
  • R 2 , R 3 H, alkyl radical with a carbon chain Ci - C 18 or mono-, di- or
  • the agent according to the invention contains 0.01 to 5% by weight of polyhydroxyalkylamine, preferably 0.01 to 2% by weight, in each case based on the total weight of the preparation.
  • the preferred polyhydroxyalkylamine is 1-amino-2,3-propanediol and / or 2-amino-1,3-propanediol (serinol).
  • the salts of the polyhydroxyalkylamines, in particular the lactates, can likewise be regarded as particularly preferred.
  • Other hydroxyalkylamines, which belong to the class of compounds according to the invention, have also made possible good film-forming properties and improved odor properties in the cosmetic composition.
  • the film formed by the agent becomes highly elastic, the hair has a natural, permanent bounce without impairing the good firmness of the hair in high humidity and without stickiness of the film.
  • the film shows a good one
  • the polymers with acidic or amphoteric groups can be partially or completely neutralized with the polyhydroxyalkylamine in the hair treatment composition according to the invention. Preference is given to agents in which 20 to 100%, particularly preferably 50 to 100%, of the acid groups in the polymer are neutralized with the amine of the neutralizing agent.
  • the polymer with acid groups can be a natural or a synthetic homo- or copolymer with monomer units containing acid groups, which is optionally copolymerized with comonomers which do not contain acid groups.
  • Suitable acid groups are sulfonic acid, phosphoric acid and carboxylic acid groups, of which the carboxylic acid groups are preferred.
  • Suitable monomers containing acid groups are, for example, acrylic acid, methacrylic acid, crotonic acid, maleic acid or maleic anhydride, aldehydocarboxylic acids or ketocarboxylic acids.
  • comonomers are for example acrylamide, methacrylamide, alkyl- and dialkylacrylamide, alkyl- and dialkylmethacrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone, vinyl pyrrolidone, Vinylester, vinyl alcohol, propylene glycol or ethylene glycol, amine substituted vinyl monomers such as dialkylaminoalkyl acrylate, dialkylaminoalkyl methacrylate, monoalkylaminoalkyl acrylate and
  • Monoalkylaminoalkyl methacrylate with the alkyl groups of these monomers preferably C1 to C7 alkyl groups, particularly preferably C1 to C3 alkyl groups.
  • Suitable polymers with acid groups are in particular uncrosslinked or crosslinked with polyfunctional agents, homopolymers of acrylic acid or methacrylic acid, copolymers of acrylic acid or methacrylic acid with monomers selected from acrylic acid or methacrylic acid esters, acrylamides, methacrylamides and vinylpyrrolidone, homopolymers of crotonic acid and copolymers of crotonic acid with monomers selected from Vinyl esters, acrylic or methacrylic acid esters, acrylamides and methacrylamides.
  • a suitable natural polymer is shellac, for example.
  • polymers are: cross-linked or uncross-linked vinyl acetate / crotonic acid copolymers (INCI VA / crotonates copolymer) e.g. Resyn 28-1310 from National Starch or Luviset CA66 from BASF; Terpolymers of vinyl acetate, crotonate and vinyl alkanoate, in particular vinyl acetate crotonate vinyl noedecanoate copolymers (INCI: VA / Crotonates /
  • Vinyl neodecanoate copolymer e.g. National Starch Resyn 28-2930; partially esterified copolymers between vinyl methyl ether and maleic anhydride (INCI: ethyl, isopropyl, butyl ester of PVM / MA copolymer) e.g.
  • Gantrez ES 225 or Gantrez ES 425 from ISP Copolymers of acrylic acid or methacrylic acid with alkyl acrylates and / or N-alkyl acrylamides, in particular copolymers of methacrylic acid and alkyl acrylates, and terpolymers of acrylic acid, alkyl acrylates and N-alkyl acrylamides such as acrylic acid / ethyl acrylate / N-tert.-butylacrylamide terpolymer (INCI: acrylates / acrylates Copolymer) e.g.
  • Ultrahold 8 from BASF or tert-butyl acrylate / ethyl acrylate / methacrylic acid terpolymer (INCI: Acrylates Copolymer), e.g. Luvimer from BASF; Polystyrene sulfonates (INCI: Sodium Polystyrene Sulfonate) e.g. Flexan 130 from National Starch.
  • Suitable anionic polymers are also water-soluble or dispersible anionic polyurethanes, e.g. Luviset PUR from BASF or polyester.
  • Suitable amphoteric polymers are octylacrylamides / acrylates / butylaminoethyl methacrylate copolymers (Amphomer 28-4910; National Starch) or methacryloyl ethyl betaines / methacrylates copolymers (Diaformer; Mitsubishi).
  • copolymers of monomers containing carboxyl groups or sulfone groups for example (meth) acrylic acid and itaconic acid with basic monomers containing in particular amino groups, such as, for example, mono- or dialkylaminoalkyl (meth) acrylates and / or mono- or dialkylaminoalkyl (meth) acrylamides, Copolymers of N- Octylacrylamide, methyl methacrylate, hydroxypropyl methacrylate, N-tert.-
  • the polymers according to the invention therefore include, in particular, polymers with carboxy, sulfonic acid, phosphoric acid, acid amide, anhydride and / or anionic polyurethane functionality.
  • the aforementioned polymers are among the polymers with acidic and / or amphoteric groups, the amphoteric polymers being composed of an anioic and a cationic functionality in the same molecule.
  • the polymers are preferably film-forming and hair-fixing polymers.
  • Film-forming, hair-fixing polymers are understood to mean those polymers which are used alone in 0.01 to 20%, preferably in 0.1 to 10%, particularly preferably in 1.0 to 5.0% aqueous, alcoholic or aqueous alcoholic solution used, are able to deposit a polymer film on the hair and in this way to strengthen the hair.
  • the agent according to the invention can, as a further component, 0.01 to 20% by weight, preferably 0.1 to 10% by weight, particularly preferably 1.0 to 5.0% by weight, of at least one synthetic or natural, film-forming, nonionic or contain cationic hair-fixing polymer.
  • the hair-fixing polymers can be used individually or in a mixture. Furthermore, polymers with a thickening effect can be used.
  • Suitable synthetic, nonionic, film-forming, hair-fixing polymers are, for example, homopolymers of vinylpyrrolidone, which are sold, for example, under the trade names LUVISKOL TM K by BASF, Germany or PVP-K by ISP, USA, and homopolymers of N-vinylformamide, which are sold, for example, under the trade name PVF by the company National Starch / USA.
  • Other suitable synthetic film-forming, nonionic hair-fixing polymers are, for example, copolymers of vinylpyrrolidone and vinyl acetate, which are sold, for example, under the trade names LUVISKOL TM VA by the company BASF / Germany; Terpolymers
  • Vinyl pyrrolidone, vinyl acetate and vinyl propionate for example, under the Trade name LUVISKOL TM VAP from BASF / Germany; Polyvinylcaprolactam, polyvinylamides and their salts and copolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate, terpolymers of vinylcaprolactam, vinylpyrrolidone and dimethylaminomethacrylate; Polyacrylamides, for example under
  • Suitable cationic polymers are e.g. Copolymers of amine-substituted vinyl monomers and non-amine-substituted, non-cationic monomers.
  • Amine-substituted vinyl monomers include dialkylaminoalkyl acrylate,
  • alkyl groups such as C1-C7 alkyl groups, particularly preferably C1-C3 alkyl groups.
  • Suitable ammonium substituted vinyl monomers are e.g. Trialkylmethacryloxy- alkylammonium, trialkylacryloxyalkylammonium, dialkyldiallylammonium and quaternary vinylammonium monomers with cyclic, cationic nitrogen-containing groups
  • alkyl groups of these monomers are preferably lower alkyl groups such as e.g. C1-C7 alkyl groups, particularly preferably C1-C3 alkyl groups.
  • Suitable polymers are polymers described under the names polyquaternium, such as quaternized copolymers of vinylimidazole, vinylpyrrolidone and / or vinylcaprolactam
  • Non-amine-substituted, non-cationic comonomers are e.g. acrylamide,
  • cationic polymers are: quaternized vinyl pyrrolidone / dialkylaminoalkyl methacrylate copolymers, in particular quaternized vinyl pyrrolidone / dimethylaminoethyl methyl acrylate copolymer (INCI: Polyquatemium-11), for example Gafquat 755 from ISP or Luviquat PQ11 from BASF; Methyl vinylimidazolium chlori ⁇ vinyl pyrrolidone.
  • Copolymer for example the Luviquat types FC 370, FC 550, FC 905 or HM552 from BASF; Methyl vinyl imidazolium methyl sulfate / vinyl pyrrolidone copolymer (I ⁇ CI: Polyquaternium-44), for example Luviquat Care or Luviquat MS 370 from BASF; or the copolymer of vinyl caprolactam, vinyl pyrrolidone and quaternized vinyl imidazole (I ⁇ CI Polyquatemium-46), for example Luviquat Hold from BASF.
  • Luviquat types FC 370, FC 550, FC 905 or HM552 from BASF
  • Methyl vinyl imidazolium methyl sulfate / vinyl pyrrolidone copolymer (I ⁇ CI: Polyquaternium-44), for example Luviquat Care or Luviquat MS 370 from BASF
  • Suitable natural film-forming polymers with hair-setting action are, for example, various types of saccharides such as, for example, polysaccharides or mixtures of oligo-, mono- and disaccharides, which are sold, for example, under the trade name C-PUR TM by the company Cerestar, Belgium.
  • Other suitable, natural polymers are Chinese balsam resin and cellulose derivatives, for example hydroxypropyl cellulose with a molecular weight of 30,000 to 50,000 g / mol, which is sold, for example, under the trade name ⁇ ISSO SL TM by Lehmann & Voss / Germany.
  • the agent according to the invention is in an aqueous, alcoholic or in a. ready-made aqueous-alcoholic milieu.
  • solvents or a mixture of solvents with a boiling point below 400 ° C. can be used in an amount of 0.1 to 90% by weight, preferably 1 to 50% by weight.
  • the lower alcohols with 1 to 4 carbon atoms usually used for cosmetic purposes, such as ethanol and isopropanol can be included as alcohols.
  • particularly preferred water-soluble solvents are glycerol and propylene glycol in an amount of up to 30% by weight.
  • the agent according to the invention can also contain the usual additional ingredients for hair treatment agents, for example, wetting agents or emulsifiers from the classes of anionic, amphoteric or nonionic surface-active surfactants, such as fatty alcohol sulfates, alkylbenzenesulfonates, alkyltrimethylammonium salts, alkylbetaines,
  • wetting agents or emulsifiers from the classes of anionic, amphoteric or nonionic surface-active surfactants, such as fatty alcohol sulfates, alkylbenzenesulfonates, alkyltrimethylammonium salts, alkylbetaines,
  • BEST ⁇ TIGU ⁇ GSKOPIE ethoxylated fatty alcohols, ethoxylated nonylphenols, fatty acid alkanolamides, ethoxylated fatty acid esters, in an amount of 0.1 to 30% by weight; Humectants; Perfume oils in an amount of 0.1 to 0.5% by weight; Opacifiers such as ethylene glycol distearate in an amount of about 0.2 to 5.0% by weight; Pearlescent agents, such as a mixture of fatty acid monoalkylolamide and ethylene glycol distearate, in an amount of about 1.0 to 10% by weight; bactericidal and fungicidal active ingredients such as, for example, 2,4,4-trichloro-2-hydroxydiphenyl ether or methyl chloroisothiazole ion, in an amount of 0.01 to 1.0% by weight; Thickeners, such as, for example, coconut fatty acid diethanolamide, in an amount of about 0.2 to 3.0% by weight, buffer substances, such
  • the care substances advantageous according to the invention are cationic surfactants such as monomeric quaternary ammonium compounds or silicone polymers.
  • the cationic substances cetyltrimethylammonium chloride and cetyltrimethylammonium phosphate are very particularly advantageous.
  • Suitable silicone polymers are e.g. Polydimethylsiloxane, ⁇ -hydrp- ⁇ -hydroxypolyoxydimethylsilylene, cyclic dimethylpolysiioxane, dimethylsiloxane-glycol copolymer or
  • the agent according to the invention can be used in various forms of application, for example in aerosol preparations as a foam or as a spray, furthermore as a non-aerosol which is applied by means of a pump or as a "pump and spray" Commitment comes.
  • Use in conventional O / W and W / O emulsions is just as possible as in application forms as a gel, wax or microemulsion.
  • the agent according to the invention is in the form of an aerosol hairspray or aerosol hair lacquer, it additionally contains 3 to 85% by weight of a propellant and is filled into a pressure vessel.
  • a propellant for example, lower alkanes, such as n-butane, i-butane and propane or their mixtures, or also dimethyl ether and fluorocarbons such as F 152 (1,1-difluoroethane) or F 134 (tetrafluoroethane) and, furthermore, in the in Pressurizing gaseous propellants, such as N2, N2O and. CO2 or compressed air and mixtures of the above-mentioned propellants are suitable.
  • the agent according to the invention can also be in the form of a non-aerosol hairspray sprayable with the aid of a suitable mechanically operated spraying device or a non-aerosol hair lacquer.
  • Mechanical spray devices are to be understood as devices which enable the spraying of a liquid without using a propellant.
  • a suitable mechanical spraying device can be, for example, a spray pump or an elastic container provided with a spray valve, in which the cosmetic agent according to the invention is filled under pressure, the elastic container expanding and from which the agent due to the contraction of the elastic container when the spray valve is opened continuously released, can be used.
  • the preparation can further advantageously contain cosmetic substances, although not necessarily, fillers which, for. B. further improve the sensory and cosmetic properties of the formulations.
  • thickeners are used in the preparations according to the invention.
  • these can advantageously be selected from the group of gums.
  • Gums include plant or tree sap that harden in the air and form resins or extracts from aquatic plants. Gum arabic, locust bean gum, tragacanth, karaya, guar gum, pectin, gellan gum, carrageenan, agar, algins, alginates, chondrus and xanthan gum can advantageously be selected from this group for the purposes of the present invention.
  • derivatized gums such as hydroxypropyl guar (Jaguar® HP 8) is also advantageous.
  • polysaccharides and derivatives are e.g. Hyaluronic acid, chitin and chitosan, chondroitin sulfates, starch and starch derivatives as advantageous thickeners according to the invention.
  • cellulose derivatives are e.g. Methyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose as advantageous thickeners according to the invention.
  • Layered silicates contain naturally occurring and synthetic clays such as Montmorillonite, bentonite, hectorite, laponite, aluminum silicates, magnesium aluminum silicates such as Veegum®. These can be used as such or in a modified form as thickeners, e.g. Stearylalkonium hektorite.
  • silica gels can also advantageously be used.
  • homopolymers of acrylic acid are e.g. Carbopol types from Goodrich (Carbopol 940, 980, 981,, 5984, 2984, ETD 2001, ETD 2050 or Ultrez 10). ,
  • Copolymers of acrylic acid or methacrylic acid such as e.g. Carbopol types from Goodrich (Carbopol 1342, 1382, ETD 2020, Ultrez 21, Permulen TR-1 or Pemulen TR-2.
  • the polymers include, for example, polyacrylamides (Seppigel 305), polyvinyl alcohols, PVP, PVP / VA copolymers, polyglycols and ammonium acryloyldimethyltaurates / VP copolymers.
  • polyacrylamides Silicone 305
  • PVP polyvinyl alcohols
  • PVP / VA copolymers polyglycols
  • ammonium acryloyldimethyltaurates / VP copolymers The following examples demonstrate the synergy effect of the preparations according to the invention in comparison to the individual components.

Abstract

The invention relates to hair conditioning agents containing at least one polymer with acid or amphoteric groups and at least one polyhydroxy alkylamine in an alcoholic, aqueous-alcoholic, or aqueous medium. The inventive hair conditioning agent has good sensory qualities and improved olfactory properties. Hair that is conditioned by means of the inventive preparation is provided with natural, long-lasting vitality.

Description

Beiersdorf AG Hamburg Beiersdorf AG Hamburg
Haarbehandlungsmittel mit verbesserten Film- und GeruchseigenschaftenHair treatment agent with improved film and smell properties
Die Erfindung umfasst Haarbehandlungsmittel enthaltend mindestens ein Polymer mit sauren oder amphoteren Gruppen und. mindestens einem Polyhydroxyalkylamin.The invention comprises hair treatment compositions containing at least one polymer with acidic or amphoteric groups and. at least one polyhydroxyalkylamine.
Das erfindungsgemäße Haarbehandlungsmittel zeigt eine gute Sensorik und verbesserte Geruchseigenschaften. Die mit der erfindungsgemäßen Zubereitung behandelten Haare besitzen eine natürliche, dauerhafte Sprungkraft.The hair treatment composition according to the invention shows good sensors and improved odor properties. The hair treated with the preparation according to the invention has a natural, permanent bounce.
Ein ansprechendes äußeres Erscheinungsbild wurde schon immer als sehr wichtig angesehen. Eine besondere Rolle spielt dabei die Frisur. Basis für ein ansprechendes Äußeres ist gut frisiertes und gepflegtes Haar. Für die Reinigung und Pflege des Haares gibt es eine ganze Reihe von Haarbehandlungsmitteln wie Shampoos, Kuren, Spülungen, Spitzenfluids, die in den unterschiedlichsten Anwendungsarten, zum Beispiel als leave on- oder als rinse off-Produkte, appliziert werden. Neben diesen Pflegeprodukten kommen drei weitere Produktkategorien bei der Haarpflege und Behandlung zum Einsatz; nämlich permanente oder temporäre Haarfärbemittel, permanente Haarverformungsmittel sowie Mittel, die nur eine temporäre Verformung und Stabilisierung der Frisur ermöglichen und allgemein als Stylingmittel bekannt sind. Hierzu zählen Produkte wie Haarsprays, Haarlacke, Festigerlotionen, Festigerschäume, Haargele, glanzgebende Produkte, Frisurcremes etc. Allen diesen Mitteln ist gemeinsam, dass sie in der Regel aus einer Vielzahl an Einzelsubstanzen oder Komponenten bestehen, die die unterschiedlichsten Aufgaben innerhalb der Rezeptur erfüllen.An attractive external appearance has always been considered very important. The hairstyle plays a special role. Well-styled and well-groomed hair is the basis for an attractive appearance. There is a whole range of hair treatment products such as shampoos, cures, conditioners, and top fluids for cleaning and maintaining the hair, which are used in a wide variety of applications, for example as leave on or rinse off products. In addition to these care products, three other product categories are used in hair care and treatment; namely permanent or temporary hair colorants, permanent hair shaping agents as well as agents that only allow temporary shaping and stabilization of the hairstyle and are generally known as styling agents. These include products such as hair sprays, hair lacquers, setting lotions, setting foams, hair gels, glossy products, hairstyle creams, etc. All these agents have in common that they usually consist of a large number of individual substances or components that perform a wide variety of tasks within the formulation.
Die Rezepturen sind vielfältig, wobei die Bestandteile der Haarbehandlungsmittel in ethanolischem, wässrig-ethanolischem oder wässrigem Medium verträglich sein müssen. Stylingmittel mit anionischen oder amphoteren Polymeren, zumeist mit Carboxy- Funktionalitäten ausgestattet, benötigen zur Erreichung ihrer optimalen Performance ein Neutralisationsmittel. Die Neutralisation verbessert die Löslichkeit des Filmes, die Viskoselastizität, die Filmbildungseigenschaft und die KW-Treibgas-Verträglichkeit. Übliche Neutralisationsmittel haben den Nachteil, dass sie entweder leichtflüchtig sind und einen unerwünschten Eigengeruch aufweisen wie beispielsweise Ammoniak, Etha.nolamin oder Aminomethylpropanol oder die Qualität des Filmes unvorteilhaft beeinflussen (Natronhydroxid oder Ammoniak). Die Filme zeigen mangelnde Flexibilität, die Haare besitzen einen unnatürlichen Griff, es können Rückstände in Form von feinen oder groben Schuppen gebildet werden.The formulations are varied, and the components of the hair treatment agent must be compatible in an ethanolic, aqueous-ethanolic or aqueous medium. Styling agents with anionic or amphoteric polymers, mostly equipped with carboxy functionalities, require a neutralizing agent to achieve their optimal performance. The neutralization improves the solubility of the film, the viscous elasticity, the film formation property and the KW propellant compatibility. Common neutralizing agents have the disadvantage that they are either volatile and have an undesirable odor such as ammonia, etha . nolamine or aminomethylpropanol or adversely affect the quality of the film (sodium hydroxide or ammonia). The films show a lack of flexibility, the hair has an unnatural feel, residues in the form of fine or coarse scales can be formed.
DE 19808824 beschreibt ein Haarbehandlungsmittel mit einem Gehalt an mindestens einem Polymeren mit sauren Gruppen und mindestens einem N-unsubstituierten oder N- substituierten Polyhydroxyamin in einer geeigneten kosmetischen Grundlage. Das Polyhydroxyamin weist mindestens 4, besonders bevorzugt 4 bis 6 Hydroxylgruppen auf.DE 19808824 describes a hair treatment composition containing at least one polymer with acidic groups and at least one N-unsubstituted or N-substituted polyhydroxyamine in a suitable cosmetic base. The polyhydroxyamine has at least 4, particularly preferably 4 to 6, hydroxyl groups.
Aufgabe der vorliegenden Erfindung ist es ein Haarbehandlungsmittel bereit zu stellen, das die Nachteile des Standes der Technik beseitigt, insbesondere ein Mittel mit guten Filmbildungseigenschaften und verbesserten Geruchseigenschaften bereit zu stellen. Des weiteren ist eine Aufgabe der vorliegenden Erfindung eine alternatives Häarbehandlungsmittel zum Stand der Technik bereit zu stellen.The object of the present invention is to provide a hair treatment composition which overcomes the disadvantages of the prior art, in particular to provide an composition with good film-forming properties and improved odor properties. Furthermore, it is an object of the present invention to provide an alternative hair treatment agent to the prior art.
Gelöst werden die Aufgaben durch ein Haarbehandlungsmittel entsprechend Anspruch 1. Gegenstand der Unteransprüche sind vorteilhafte Ausführungsformen der erfindungsgemäßen Mittel. Des weiteren umfasst die Erfindung die Verwendung derartiger Mittel.The tasks are solved by a hair treatment agent according to claim 1. The subclaims relate to advantageous embodiments of the agents according to the invention. The invention further comprises the use of such agents.
Es war überraschend und für den Fachmann nicht vorauszusehen, dass ein Haarbehandlungsmittel umfassend mindestens ein Polymer mit sauren und/oder amphoteren Gruppen in alkoholischem, wässrig-alkoholischem oder wässrigem Medium und mindestens ein Polyhydroxyalkylamin der FormelIt was surprising and unforeseeable for the person skilled in the art that a hair treatment composition comprising at least one polymer with acidic and / or amphoteric groups in alcoholic, aqueous-alcoholic or aqueous medium and at least one polyhydroxyalkylamine of the formula
NRTRSRS, wobei R, = Mono-, Di- oder Trihydroxyalkylrest mit einer Kohlenstoffkette C2 - C6,NR T R S R S , where R, = mono-, di- or trihydroxyalkyl radical with a carbon chain C 2 - C 6 ,
R2, R3 = H, Alkylrest mit einer Kohlenstoffkette C-i - C18 oder Mono-, Di- oderR 2 , R 3 = H, alkyl radical with a carbon chain Ci - C 18 or mono-, di- or
Trihydroxyalkylrest mit einer Kohlenstoffkette C2 - C6, oder deren Salze sind, die gestellten Aufgaben löst. Erfindungsgemäß vorteilhaft enthält das erfindungsgemäße Mittel 0,01 bis 5 Gew.% Polyhydroxyalkylamin, bevorzugt 0,01 bis 2 Gew.%, jeweils bezogen auf das Gesamtgewicht der Zubereitung.Trihydroxyalkylrest with a carbon chain C 2 - C 6 , or their salts, which solves the problems. Advantageously according to the invention, the agent according to the invention contains 0.01 to 5% by weight of polyhydroxyalkylamine, preferably 0.01 to 2% by weight, in each case based on the total weight of the preparation.
Als bevorzugtes Polyhydroxyalkylamin ist 1-Amino-2,3-propandiol und/oder 2-Amino-1,3- propandiol (Serinol) anzusehen. Ebenso können die Salze der Polyhydroxyalkylamine, insbesondere die Lactate, als besonders bevorzugt angesehen werden. Auch andere Hydroxyalkylamine, die unter die erfindungsgemäße Verbindungsklasse zählen, haben gute Filmbildungseigenschaften und verbesserte Geruchseigenschaften im kosmetischen Mittel ermöglicht.The preferred polyhydroxyalkylamine is 1-amino-2,3-propanediol and / or 2-amino-1,3-propanediol (serinol). The salts of the polyhydroxyalkylamines, in particular the lactates, can likewise be regarded as particularly preferred. Other hydroxyalkylamines, which belong to the class of compounds according to the invention, have also made possible good film-forming properties and improved odor properties in the cosmetic composition.
Der sich durch das Mittel bildende Film wird hochelastisch, die Haare besitzen eine natürliche, dauerhafte Sprungkraft ohne Beeinträchtigung der guten Festigung der Haare bei hoher Luftfeuchtigkeit und ohne Klebrigkeit des Filmes. Der Film zeigt eine guteThe film formed by the agent becomes highly elastic, the hair has a natural, permanent bounce without impairing the good firmness of the hair in high humidity and without stickiness of the film. The film shows a good one
Sensorik und im Vergleich zu herkömmlichen Neutralisationsmitteln werden die geruchlichen Eigenschaften der Formulierung verbessert.Sensor technology and compared to conventional neutralizing agents, the olfactory properties of the formulation are improved.
Die Polymere mit saurer oder amphoteren Gruppen können in dem erfindungsgemäßen Haarbehandlungsmittel teilweise oder vollständig mit dem Polyhydroxyalkylamin neutralisiert werden. Bevorzugt sind solche Mittel, in welchen im Polymer die sauren Gruppen zu 20 bis 100%, besonders bevorzugt zu 50 bis 100% mit dem Amin des Neutralisationsmittels neutralisiert werden.The polymers with acidic or amphoteric groups can be partially or completely neutralized with the polyhydroxyalkylamine in the hair treatment composition according to the invention. Preference is given to agents in which 20 to 100%, particularly preferably 50 to 100%, of the acid groups in the polymer are neutralized with the amine of the neutralizing agent.
Das Polymer mit Säuregruppen kann ein natürliches oder ein synthetisches Homo- oder Copolymer mit Säuregruppen enthaltenden Monomereinheiten sein, welches gegebenenfalls mit Comonomeren, die keine Säuregruppen enthalten, copolymerisiert ist. Als Säuregruppen kommen Sulfonsäure-, Phosphorsäure- und Carbonsäuregruppen in Betracht, von denen die Carbόnsäuregruppen bevorzugt sind. Geeignete Säuregruppen enthaltende Monomere sind beispielsweise Acrylsäüre, Methacrylsäure, Crotonsäure, Maleinsäure bzw. Maleinsäureanhydrid, Aldehydocarbonsäuren oder Ketocarbonsäuren.The polymer with acid groups can be a natural or a synthetic homo- or copolymer with monomer units containing acid groups, which is optionally copolymerized with comonomers which do not contain acid groups. Suitable acid groups are sulfonic acid, phosphoric acid and carboxylic acid groups, of which the carboxylic acid groups are preferred. Suitable monomers containing acid groups are, for example, acrylic acid, methacrylic acid, crotonic acid, maleic acid or maleic anhydride, aldehydocarboxylic acids or ketocarboxylic acids.
Nicht mit Säuregruppen substituierte Comonomere sind beispielsweise Acrylamid, Methacrylamid, Alkyl- und Dialkylacrylamid, Alkyl- und Dialkylmethacrylamid, Alkylacrylat, Alkylmethacrylat, Vinylcaprolacton, Vinylpyrrolidon, Vinylester, Vinylalkohol, Propylenglykol oder Ethylenglykol, aminsubstituierte Vinylmonomere wie zum Beispiel Dialkylaminoalkylacrylat, Dialkylaminoalkylmethacrylat, Monoalkylaminoalkylacrylat undNot substituted with acid groups comonomers are for example acrylamide, methacrylamide, alkyl- and dialkylacrylamide, alkyl- and dialkylmethacrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone, vinyl pyrrolidone, Vinylester, vinyl alcohol, propylene glycol or ethylene glycol, amine substituted vinyl monomers such as dialkylaminoalkyl acrylate, dialkylaminoalkyl methacrylate, monoalkylaminoalkyl acrylate and
Monoalkylaminoalkylmethacrylat, wobei die Alkylgruppen dieser Monomere vorzugsweise C1- bis C7- Alkyigruppen, besonders bevorzugt C1- bis C3-Alkylgruppen sind.Monoalkylaminoalkyl methacrylate, with the alkyl groups of these monomers preferably C1 to C7 alkyl groups, particularly preferably C1 to C3 alkyl groups.
Geeignete Polymere mit Säuregruppen sind insbesondere unvemetzte oder mit polyfunktionellen Agentien vernetzte Homopolymere der Acrylsäure oder der Methacrylsaure, Copolymere der Acrylsäure oder Methacrylsaure mit Monomeren ausgewählt aus Acrylsäure- oder Methacrylsäureestern, Acrylamiden, Methacrylamiden und Vinylpyrrolidon, Homopolymere der Crotonsäure sowie Copolymere der Crotonsäure mit Monomeren ausgewählt aus Vinylestern, Acrylsäure- oder Methacrylsäureestern, Acrylamiden und Methacrylamiden. Ein geeignetes natürliches Polymer ist beispielsweise Schellack.Suitable polymers with acid groups are in particular uncrosslinked or crosslinked with polyfunctional agents, homopolymers of acrylic acid or methacrylic acid, copolymers of acrylic acid or methacrylic acid with monomers selected from acrylic acid or methacrylic acid esters, acrylamides, methacrylamides and vinylpyrrolidone, homopolymers of crotonic acid and copolymers of crotonic acid with monomers selected from Vinyl esters, acrylic or methacrylic acid esters, acrylamides and methacrylamides. A suitable natural polymer is shellac, for example.
Andere Polymere sind: vernetzte oder unvemetzte Vinylacetat/ Crotonsäure Copolymere (INCI VA/Crotonates Copolymer) z.B. Resyn 28-1310 von National Starch oder Luviset CA66 von BASF; Terpolymere aus Vinylacetat, Crotonat und Vinylalkanoat, insbesondere Vinylacetat Crotonat Vinylnoedecanoat Copolymere (INCI: VA/Crotonates/Other polymers are: cross-linked or uncross-linked vinyl acetate / crotonic acid copolymers (INCI VA / crotonates copolymer) e.g. Resyn 28-1310 from National Starch or Luviset CA66 from BASF; Terpolymers of vinyl acetate, crotonate and vinyl alkanoate, in particular vinyl acetate crotonate vinyl noedecanoate copolymers (INCI: VA / Crotonates /
Vinylneodecanoate Copolymer) z.B. Resyn 28-2930 von National Starch; partialveresterte Copolymere zwischen Vinylmethylether und Malein-säureanhydrid (INCI: Ethyl-, Isopropyl-, Butylester of PVM/MA Copolymer) z.B. Gantrez ES 225 oder Gantrez ES 425 von ISP; Copolymere aus Acrylsäure oder Methacrylsaure mit Alkylacrylaten und/oder N- Alkylacrylamiden, insbesondere Co-polymere aus Methacrylsaure und Alkyacrylaten sowie Terpolymeren aus Acrylsäure, Alkylacrylaten und N-Alkylacrylamiden wie Acrylsäure/Ethylacrylat/N-tert.-Butylacrylamid Terpolymer (INCI: Acrylate/Acrylamide Copolymer) z.B. Ultrahold 8 von BASF oder tert.-Butylacrylat/Ethylacrylat/ Methacrylsaure Terpolymer (INCI: Acrylates Copolymer), z.B. Luvimer von BASF; Polystyrolsulfonate (INCI: Sodium Polystyrene Sulfonate) z.B. Flexan 130 von National Starch.Vinyl neodecanoate copolymer) e.g. National Starch Resyn 28-2930; partially esterified copolymers between vinyl methyl ether and maleic anhydride (INCI: ethyl, isopropyl, butyl ester of PVM / MA copolymer) e.g. Gantrez ES 225 or Gantrez ES 425 from ISP; Copolymers of acrylic acid or methacrylic acid with alkyl acrylates and / or N-alkyl acrylamides, in particular copolymers of methacrylic acid and alkyl acrylates, and terpolymers of acrylic acid, alkyl acrylates and N-alkyl acrylamides such as acrylic acid / ethyl acrylate / N-tert.-butylacrylamide terpolymer (INCI: acrylates / acrylates Copolymer) e.g. Ultrahold 8 from BASF or tert-butyl acrylate / ethyl acrylate / methacrylic acid terpolymer (INCI: Acrylates Copolymer), e.g. Luvimer from BASF; Polystyrene sulfonates (INCI: Sodium Polystyrene Sulfonate) e.g. Flexan 130 from National Starch.
Geeignete anionische Polymere sind auch in Wasser lösliche oder dispergierbare anionische Polyurethane, z.B. Luviset PUR von BASF oder Polyester.Suitable anionic polymers are also water-soluble or dispersible anionic polyurethanes, e.g. Luviset PUR from BASF or polyester.
Geeignete amphotere Polymere sind Octylacrylamide/Acrylates/Butylaminoethyl Methacrylate Copolymer (Amphomer 28-4910; National Starch) oder Methacryloyl Ethylbetaine/Methacrylates Copolymer (Diaformer; Mitsubishi). Weiterhin sind geeignet Copolymerisate aus Carboxylgruppen oder Sulfongruppen enthaltenden Monomeren, z.B. (Meth)Acrylsäure und Itaconsäure mit basischen insbesondere Aminogruppen enthaltenden Monomeren wie z.B. Mono- bzw. Dialkylamino-alkyl(meth)acrylaten und/oder Mono- bzw. Dialkylaminoalkyl(meth)acrylamiden, Copolymere aus N- Octylacrylamid, Methylmethacrylat, Hydroxypropylmethacrylat, N-tert.-Suitable amphoteric polymers are octylacrylamides / acrylates / butylaminoethyl methacrylate copolymers (Amphomer 28-4910; National Starch) or methacryloyl ethyl betaines / methacrylates copolymers (Diaformer; Mitsubishi). Also suitable are copolymers of monomers containing carboxyl groups or sulfone groups, for example (meth) acrylic acid and itaconic acid with basic monomers containing in particular amino groups, such as, for example, mono- or dialkylaminoalkyl (meth) acrylates and / or mono- or dialkylaminoalkyl (meth) acrylamides, Copolymers of N- Octylacrylamide, methyl methacrylate, hydroxypropyl methacrylate, N-tert.-
Butylaminoethylmethacrylat und Acrylsäure.Butylaminoethyl methacrylate and acrylic acid.
Zu den erfindungsgemäßen Polymeren zählen daher insbesondere Polymere mit Carboxy-, Sulfonsäure-, Phosphorsäure-, Säureamid-, Anhydrid- und/oder anionische Polyurethan-Funktionalität.The polymers according to the invention therefore include, in particular, polymers with carboxy, sulfonic acid, phosphoric acid, acid amide, anhydride and / or anionic polyurethane functionality.
Erfindungsgemäß zählen die zuvor genannten Polymere zu den Polymeren mit sauren und/oder amphoteren Gruppen, wobei die amphoteren Polymere aus einer anioischen und einer kationischen Funktionalität im selben Molekül aufgebaut sind.According to the invention, the aforementioned polymers are among the polymers with acidic and / or amphoteric groups, the amphoteric polymers being composed of an anioic and a cationic functionality in the same molecule.
Vorzugsweise handelt es sich bei den Polymeren um filmbildende und haarfestigende Polymere. Unter filmbildenden, haarfestigenden Polymeren sollen solche Polymere verstanden werden, welche allein in 0,01 bis 20%iger, bevorzugt in 0,1 bis 10%iger, besonders bevorzugt in 1 ,0 bis 5,0%iger wässriger, alkoholischer oder wässrig- alkoholischer Lösung angewandt, in der Lage sind, auf dem Haar einen Polymerfilm abzuscheiden und auf diese Weise das Haar zu festigen.The polymers are preferably film-forming and hair-fixing polymers. Film-forming, hair-fixing polymers are understood to mean those polymers which are used alone in 0.01 to 20%, preferably in 0.1 to 10%, particularly preferably in 1.0 to 5.0% aqueous, alcoholic or aqueous alcoholic solution used, are able to deposit a polymer film on the hair and in this way to strengthen the hair.
Zusätzlich kann das erfindungsgemäße Mittel als weitere Komponente 0,01 bis 20 Gew.%, bevorzugt 0,1 bis 10 Gew.%, besonders bevorzugt 1 ,0 bis 5,0 Gew.%, mindestens eines synthetischen oder natürlichen, filmbildenden, nichtionischen oder kationischen haarfestigenden Polymers enthalten. Die haarfestigenden Polymere können einzeln oder in einem Gemisch eingesetzt werden. Des weiteren können Polymere mit verdickender Wirkung eingesetzt werden.In addition, the agent according to the invention can, as a further component, 0.01 to 20% by weight, preferably 0.1 to 10% by weight, particularly preferably 1.0 to 5.0% by weight, of at least one synthetic or natural, film-forming, nonionic or contain cationic hair-fixing polymer. The hair-fixing polymers can be used individually or in a mixture. Furthermore, polymers with a thickening effect can be used.
Geeignete synthetische, nichtionische, filmbildende, haarfestigende Polymere sind zum Beispiel Homopolymere des Vinylpyrrolidons, die beispielsweise unter den Handelsbezeichnungen LUVISKOL TM K von der Firma BASF, Deutschland oder PVP-K von der Firma ISP, USA vertrieben werden, sowie Homopolymere des N-Vinylformamids, die beispielsweise unter der Handelsbezeichnung PVF von der Firma National Starch/USA vertrieben werden. Weitere geeignete synthetische filmbildende, nichtionische haarfestigende Polymere sind zum Beispiel Copolymerisate aus Vinylpyrrolidon und Vinylacetat, die beispielsweise unter den Handelsbezeichnungen LUVISKOL TM VA von der Firma BASF/Deutschland vertrieben werden; Terpolymere ausSuitable synthetic, nonionic, film-forming, hair-fixing polymers are, for example, homopolymers of vinylpyrrolidone, which are sold, for example, under the trade names LUVISKOL TM K by BASF, Germany or PVP-K by ISP, USA, and homopolymers of N-vinylformamide, which are sold, for example, under the trade name PVF by the company National Starch / USA. Other suitable synthetic film-forming, nonionic hair-fixing polymers are, for example, copolymers of vinylpyrrolidone and vinyl acetate, which are sold, for example, under the trade names LUVISKOL ™ VA by the company BASF / Germany; Terpolymers
Vinylpyrrolidon, Vinylacetat und Vinylpropionat, die beispielsweise unter der Handelsbezeichnung LUVISKOL TM VAP der Firma BASF/Deutschland vertrieben werden; Polyvinylcaprolactam, Polyvinylamide und deren Salze sowie Copolymere aus Vinylpyrrolidon und Dimethylaminoethylmethacrylat, Terpolymere aus Vinylcaprolactam, Vinylpyrrolidon und Dimethylaminomethacrylat; Polyacrylamide, die beispielsweise unterVinyl pyrrolidone, vinyl acetate and vinyl propionate, for example, under the Trade name LUVISKOL TM VAP from BASF / Germany; Polyvinylcaprolactam, polyvinylamides and their salts and copolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate, terpolymers of vinylcaprolactam, vinylpyrrolidone and dimethylaminomethacrylate; Polyacrylamides, for example under
5 den Handelsbezeichnungen AKYPOMINE TM P 191 von der Firma CHEM-Y/Deutschland oder SEPI TM 305 von der Firma SEPPIC/USA vertrieben werden; Polyvinylalkohole, die beispielsweise unter den Handelsbezeichnungen ELVANOL TM der Firma Du Pont oder VINOL TM 523/540 der Firma Air Products/USA vertrieben werden, sowie hochmolekulares Polyethylenglykol oder hochmolekulare Copolymere von Ethylenglykol5 the commercial names AKYPOMINE TM P 191 by CHEM-Y / Germany or SEPI TM 305 by SEPPIC / USA; Polyvinyl alcohols, which are sold, for example, under the trade names ELVANOL ™ from Du Pont or VINOL ™ 523/540 from Air Products / USA, as well as high molecular weight polyethylene glycol or high molecular weight copolymers of ethylene glycol
10. mit Propylenglykol mit festigenden Eigenschaften, die beispielsweise unter den Handelsbezeichnungen LIPOXOL TM 1000 von der Firma HÜLS AG/Deutschland,. PLURACOL E 4000 von der Firma BASF/Deutschland oder UPIWAX TM 20.000 von der Firma UPI vertrieben werden; Polysiloxane und dergleichen mehr.10. with propylene glycol with strengthening properties, for example under the trade names LIPOXOL TM 1000 from HÜLS AG / Germany. PLURACOL E 4000 from BASF / Germany or UPIWAX TM 20,000 from UPI; Polysiloxanes and the like.
15 Geeignete kationische Polymere sind z.B. Copolymere von aminsubstituierten Vinylmonomeren und nicht aminsubstituierten, nicht kationischen Monomeren. Aminsubstituierte Vinylmonomere sind z.B.Dialkylaminoalkylacrylat,Suitable cationic polymers are e.g. Copolymers of amine-substituted vinyl monomers and non-amine-substituted, non-cationic monomers. Amine-substituted vinyl monomers include dialkylaminoalkyl acrylate,
Dialkylaminoalkylmethacrylat, Monoalkylaminoalkylacrylat, Monoalkylaminoalkyl- methacrylat, wobei die Alkylgruppen dieser Monomere vorzugsweise niedereDialkylaminoalkyl methacrylate, monoalkylaminoalkyl acrylate, monoalkylaminoalkyl methacrylate, the alkyl groups of these monomers preferably being lower
20 Alkylgruppen wie z.B. C1-C7- Alkylgruppen, besonders bevorzugt C1- C3-Alkylgruppen sind.20 alkyl groups such as C1-C7 alkyl groups, particularly preferably C1-C3 alkyl groups.
Geeignete ammoniumsubstituierte Vinylmonomere sind z.B. Trialkylmethacryloxy- alkylammonium, Trialkylacryloxyalkylammonium, Dialkyldiallylammonium und quarternäre Vinylammoniummonomere mit cyclischen, kationische Stickstoffe enthaltenden GruppenSuitable ammonium substituted vinyl monomers are e.g. Trialkylmethacryloxy- alkylammonium, trialkylacryloxyalkylammonium, dialkyldiallylammonium and quaternary vinylammonium monomers with cyclic, cationic nitrogen-containing groups
25 wie Pyridinium oder Imidazolium, z.B. Alkylvinylpyridinium oder Alkylvinylimidazolium Salze. Die Alkylgruppen dieser Monomere sind vor-zugsweise niedere Alkylgruppen wie z.B. C1-C7- Alkylgruppen, besonders bevorzugt C1- C3-Alkylgruppen. Geeignete Polymere sind unter den Bezeichnungen Poly-quatemium beschriebenen Polymere wie quaternisierte Copolymere von Vinylimidazol, Vinylpyrrolidon und/oder Vinylcaprolactam25 such as pyridinium or imidazolium, e.g. Alkyl vinyl pyridinium or alkyl vinyl imidazolium salts. The alkyl groups of these monomers are preferably lower alkyl groups such as e.g. C1-C7 alkyl groups, particularly preferably C1-C3 alkyl groups. Suitable polymers are polymers described under the names polyquaternium, such as quaternized copolymers of vinylimidazole, vinylpyrrolidone and / or vinylcaprolactam
30 (Polyquaternium-16, -44 oder -46), quaternisiertes Vinylpyrrolidon/- Dimethylaminoethylmethacrylat Copolymer (Polyquatemium-11), Homo- und Copolymere von Dimethyldiallyl-ammoniumchlorid (Polyquatemium-6, -7 oder-22), quaternisierte Hydroxy-ethylcellulose (Polyquaternium-10) oder quaternisierte Guarderivate. Nicht aminsubstituierte, nichtkationische Comonomere sind z.B. Acrylamid,30 (polyquaternium-16, -44 or -46), quaternized vinyl pyrrolidone / - dimethylaminoethyl methacrylate copolymer (polyquaternium-11), homo- and copolymers of dimethyldiallyl ammonium chloride (polyquaternium-6, -7 or-22), quaternized hydroxyethyl cellulose ( Polyquaternium-10) or quaternized guar derivatives. Non-amine-substituted, non-cationic comonomers are e.g. acrylamide,
35 Methäcrylamid, Alkyl- und Dialkylacrylamid, Alkyl- und Dialkylmethacrylamid, Acrylacrylat,35 methacrylamide, alkyl and dialkyl acrylamide, alkyl and dialkyl methacrylamide, acrylic acrylate,
Alkylmethacrylat, Vinylcaprolacton, Vinylpyrrolidon, Vinylester, Vinylalkohol, Maleinsäreanhydrid, Propylenglycol oder Ethylenglycol, wobei die Alkylgruppen dieser Monomere vorzugsweise niedere Alkylgruppen wie z.B. C1-C7- Alkylgruppen, besonders bevorzugt C1- C3-Alkylgruppen sind. Weitere kationische Polymere sind: quaternisiertes Vinylpyrrolidon/- Dialkylaminoalkylmethacrylat Copolymere, insbesondere quaternisiertes Vinyl- pyrrolidon/Dimethylaminoethylmethylacrylat Copolymer (INCI: Polyquatemium-11), z.B. Gafquat 755 von ISP oder Luviquat PQ11 von BASF; Methylvinylimidazolium- chloriαWinylpyrrolidon. Copolymer (INCI: Polyquaternium-16), z.B. die Luviquat Typen FC 370, FC 550, FC 905 oder HM552 von BASF; Methylvinylimidazolium Methylsulfat/Ninylpyrrolidon Copolymer (IΝCI: Polyquaternium-44), z.B. Luviquat Care oder Luviquat MS 370 von BASF; oder das Copolymer aus Vinylcaprolactam, Vinylpyrrolidon und quatemisiertem Vinylimidazol (IΝCI Polyquatemium-46), z.B. Luviquat Hold von BASF.Alkyl methacrylate, vinyl caprolactone, vinyl pyrrolidone, vinyl ester, vinyl alcohol, Maleic anhydride, propylene glycol or ethylene glycol, the alkyl groups of these monomers preferably being lower alkyl groups such as, for example, C1-C7-alkyl groups, particularly preferably C1-C3-alkyl groups. Other cationic polymers are: quaternized vinyl pyrrolidone / dialkylaminoalkyl methacrylate copolymers, in particular quaternized vinyl pyrrolidone / dimethylaminoethyl methyl acrylate copolymer (INCI: Polyquatemium-11), for example Gafquat 755 from ISP or Luviquat PQ11 from BASF; Methyl vinylimidazolium chloriα vinyl pyrrolidone. Copolymer (INCI: Polyquaternium-16), for example the Luviquat types FC 370, FC 550, FC 905 or HM552 from BASF; Methyl vinyl imidazolium methyl sulfate / vinyl pyrrolidone copolymer (IΝCI: Polyquaternium-44), for example Luviquat Care or Luviquat MS 370 from BASF; or the copolymer of vinyl caprolactam, vinyl pyrrolidone and quaternized vinyl imidazole (IΝCI Polyquatemium-46), for example Luviquat Hold from BASF.
Geeignete natürliche filmbildende Polymere mit haarfestigender Wirkung sind zum Beispiel verschiedene Saccharidtypen wie zum Beispiel Polysaccharide oder Gemische aus Oligo-, Mono- und Disacchariden, welche beispielsweise unter dem Handelsnamen C-PUR TM von der Firma Cerestar, Belgien vertrieben werden. Weitere geeignete, natürliche Polymere sind chinesisches Balsamharz und Cellulosederivate, zum Beispiel Hydroxypropylcellulose mit einem Molekulargewicht von 30.000 bis 50.000 g/mol, welche beispielsweise unter der Handelsbezeichnung ΝISSO SL TM von der Firma Lehmann & Voss/Deutschland vertrieben wird.Suitable natural film-forming polymers with hair-setting action are, for example, various types of saccharides such as, for example, polysaccharides or mixtures of oligo-, mono- and disaccharides, which are sold, for example, under the trade name C-PUR ™ by the company Cerestar, Belgium. Other suitable, natural polymers are Chinese balsam resin and cellulose derivatives, for example hydroxypropyl cellulose with a molecular weight of 30,000 to 50,000 g / mol, which is sold, for example, under the trade name ΝISSO SL TM by Lehmann & Voss / Germany.
Das erfindungsgemäße Mittel wird in einem wässrigen, alkoholischen oder in einem . wässrig-alkoholischen Milieu konfektioniert. Des weiteren können Lösungsmittel oder ein Gemisch aus Lösungsmitteln mit einem Siedepunkt unter 400 DEG C in einer Menge von 0,1 bis 90 Gew.% bevorzugt von 1 bis 50 Gew.% eingesetzt werden. Als Alkohole können insbesondere die für kosmetische Zwecke üblicherweise verwendeten niederen Alkohole mit 1 bis 4 Kohlenstoffatomen wie zum Beispiel Ethanol und Isopropanol enthalten sein. Weitere, besonders bevorzugte wasserlösliche Lösungsmittel sind Glycerin und Propylenglykol in einer Menge bis 30 Gew.%.The agent according to the invention is in an aqueous, alcoholic or in a. ready-made aqueous-alcoholic milieu. Furthermore, solvents or a mixture of solvents with a boiling point below 400 ° C. can be used in an amount of 0.1 to 90% by weight, preferably 1 to 50% by weight. In particular, the lower alcohols with 1 to 4 carbon atoms usually used for cosmetic purposes, such as ethanol and isopropanol, can be included as alcohols. Further, particularly preferred water-soluble solvents are glycerol and propylene glycol in an amount of up to 30% by weight.
Das erfindungsgemäße Mittel kann darüber hinaus die für Haarbehandlungsmittel üblichen Zusatzbestandteile enthalten, zum Beispiel Νetzmittel oder Emulgatoren aus den Klassen der anionischen, amphoteren oder nichtionogenen oberflächenaktiven Tenside, wie Fettalkoholsulfate, Alkylbenzolsulfonate, Alkyltrimethylammoniumsalze, Alkylbetaine,The agent according to the invention can also contain the usual additional ingredients for hair treatment agents, for example, wetting agents or emulsifiers from the classes of anionic, amphoteric or nonionic surface-active surfactants, such as fatty alcohol sulfates, alkylbenzenesulfonates, alkyltrimethylammonium salts, alkylbetaines,
BESTÄTIGUΝGSKOPIE oxethylierte Fettalkohole, oxethylierte Nonylphenole, Fettsäurealkanolamide, oxethylierte Fettsäureester, in einer Menge von 0,1 bis 30 Gew.%; Feuchthaltemittel; Parfümöle in einer Menge von 0,1 bis 0,5 Gew.%; Trübungsmittel, wie zum Beispiel Ethylenglykoldistearat, in einer Menge von etwa 0,2 bis 5,0 Gew.%; Perlglanzmittel, wie zum Beispiel ein Gemisch aus Fettsäuremonoalkylolamid und Ethylenglykoldistearat, in einer Menge von etwa 1 ,0 bis 10 Gew.%; bakterizide und fungizide Wirkstoffe wie zum Beispiel 2,4,4-Trichlor-2-hydroxydiphenylether oder Methylchlorisothiazolion, in einer Menge von 0,01 bis 1 ,0 Gew.%; Verdickungsmittel, wie beispielsweise Kokosfettsäurediethanolamid, in einer Menge von etwa 0,2 bis 3,0 Gew.%, Puffersubstanzen, wie beispielsweise Natriumeitrat oder Natriumphosphat, in einer Menge von 0,1 bis 1 ,0 Gew.%; Lösungsvermittler, wie zum Beispiel ethoxyliertes Rizinusöl, in einer Menge von etwa 0,1 bis 1 ,0 Gew.%; Anfärbestoffe, wie zum Beispiel Fluorescein Natriumsalz, in einer Menge von etwa 0,1 bis 1 ,0 Gew.%; Pflegestoffe, wie Beispiel Pflanzen- und Kräuterextrakte, Protein- und Seidenhydrolysate, kationische Harze, Lanolinderivate, in einer Menge von 0,1 bis 5 Gew.%; physiologisch verträgliche Silikonderivate, wie zum Beispiel Silikonöl, Silikonpolymere und Siloxane; Lichtschutzmittel, Antioxidantien, Radikalfänger, Antischuppenwirkstoffe, in einer Menge von etwa 0,01 bis 2 Gew.%; direktziehende Haarfarbstoffe, Haarfarbstoffe, die oxidativ entwickelt werden, Oxidationsmittel, Reduktionsmittel, Fettalkohole, Glanzgeber, Vitamine, Weichmacher, Kämmbarkeitsverbesserer, rückfettende Agentien, Schaumstabilisatoren und Entschäumer..BESTÄTIGUΝGSKOPIE ethoxylated fatty alcohols, ethoxylated nonylphenols, fatty acid alkanolamides, ethoxylated fatty acid esters, in an amount of 0.1 to 30% by weight; Humectants; Perfume oils in an amount of 0.1 to 0.5% by weight; Opacifiers such as ethylene glycol distearate in an amount of about 0.2 to 5.0% by weight; Pearlescent agents, such as a mixture of fatty acid monoalkylolamide and ethylene glycol distearate, in an amount of about 1.0 to 10% by weight; bactericidal and fungicidal active ingredients such as, for example, 2,4,4-trichloro-2-hydroxydiphenyl ether or methyl chloroisothiazole ion, in an amount of 0.01 to 1.0% by weight; Thickeners, such as, for example, coconut fatty acid diethanolamide, in an amount of about 0.2 to 3.0% by weight, buffer substances, such as, for example, sodium citrate or sodium phosphate, in an amount of 0.1 to 1.0% by weight; Solubilizers, such as, for example, ethoxylated castor oil, in an amount of about 0.1 to 1.0% by weight; Stains, such as fluorescein sodium salt, in an amount of about 0.1 to 1.0% by weight; Care substances, such as plant and herbal extracts, protein and silk hydrolyzates, cationic resins, lanolin derivatives, in an amount of 0.1 to 5% by weight; physiologically compatible silicone derivatives, such as silicone oil, silicone polymers and siloxanes; Light stabilizers, antioxidants, radical scavengers, antidandruff agents, in an amount of about 0.01 to 2% by weight; direct hair dyes, hair dyes that are developed oxidatively, oxidizing agents, reducing agents, fatty alcohols, gloss agents, vitamins, plasticizers, combability improvers, moisturizing agents, foam stabilizers and defoamers ..
Als Kosmetisches Mittel ist bevorzugt, dass Pflegestoffe enthalten sind.It is preferred as a cosmetic agent that care substances are contained.
Die erfindungsgemäß vorteilhaften Pflegesubstanzen sind kationische Tenside wie monomere quaternäre Ammoniumverbindungen oder Silikonpolymere. Ganz besonders vorteilhaft sind dabei die kationischen Substanzen Cetyltrimethylammoniumchlorid und Cetyltrimethylammoniumphosphat. Geeignete Siiikonpolymere sind z.B. Polydimethylsiloxan, α-Hydrp-ω-hydroxypolyoxydimethylsilylen, cyclisches Dimethylpolysiioxan, Dimethylsiloxan-Glycol-Copolymer oderThe care substances advantageous according to the invention are cationic surfactants such as monomeric quaternary ammonium compounds or silicone polymers. The cationic substances cetyltrimethylammonium chloride and cetyltrimethylammonium phosphate are very particularly advantageous. Suitable silicone polymers are e.g. Polydimethylsiloxane, α-hydrp-ω-hydroxypolyoxydimethylsilylene, cyclic dimethylpolysiioxane, dimethylsiloxane-glycol copolymer or
Dimethylsioxanaminoalkylsiloxan-Copolymer mit Hydroxyendgruppen;Dimethylsioxanaminoalkylsiloxane copolymer with hydroxy end groups;
Das erfindungsgemäße Mittel kann in verschiedenen Applikationsformen Anwendung finden, wie beispielsweise in Aerosolzubereitungen als Schaum oder als Spray, des weiteren als Non-Aerosol, welches mittels einer Pumpe oder als "Pump and Spray" zum Einsatz kommt. Der Einsatz in üblichen O/W und W/O Emulsionen ist ebenso möglich wie in Anwendungsformen als Gel, Wachs oder Mikroemulsion.The agent according to the invention can be used in various forms of application, for example in aerosol preparations as a foam or as a spray, furthermore as a non-aerosol which is applied by means of a pump or as a "pump and spray" Commitment comes. Use in conventional O / W and W / O emulsions is just as possible as in application forms as a gel, wax or microemulsion.
Wenn das erfindungsgemäße Mittel in Form eines Aerosol- Haarsprays oder Aerosol- Haarlackes vorliegt, so enthält es zusätzlich 3 bis 85 Gew.% eines Treibmittels und wird in einem Druckbehälter abgefüllt. Als Treibmittel sind beispielsweise niedere Alkane, wie zum Beispiel n- Butan, i-Butan und Propan oder deren Gemische oder auch Dimethylether und Fluorkohlenwasserstoffe wie beispielsweise F 152 (1,1-Difluorethan) oder F 134 (Tetrafluorethan) sowie, ferner bei den in Betracht kommenden Drücken gasförmig vorliegende Treibmittel, wie beispielsweise N2, N2O und. CO2 oder komprimierte Luft sowie Gemische der vorstehend genannten Treibmittel geeignet.If the agent according to the invention is in the form of an aerosol hairspray or aerosol hair lacquer, it additionally contains 3 to 85% by weight of a propellant and is filled into a pressure vessel. As blowing agents are, for example, lower alkanes, such as n-butane, i-butane and propane or their mixtures, or also dimethyl ether and fluorocarbons such as F 152 (1,1-difluoroethane) or F 134 (tetrafluoroethane) and, furthermore, in the in Pressurizing gaseous propellants, such as N2, N2O and. CO2 or compressed air and mixtures of the above-mentioned propellants are suitable.
Das erfindungsgemäße Mittel kann auch in Form eines mit Hilfe einer geeigneten mechanisch betriebenen Sprühvorrichtung versprühbaren Noh-Aerosol-Haarsprays oder eines Non-Aerosol-Haarlacks vorliegen. Unter mechanischen Sprühvorrichtungen sind solche Vorrichtungen zu verstehen, welche das Versprühen einer Flüssigkeit ohne Verwendung eines Treibmittels ermöglichen. Als geeignete mechanische Sprühvorrichtung kann beispielsweise eine Sprühpumpe oder ein mit einem Sprühventil versehener elastischer Behälter, in dem das erfindungsgemäße kosmetische Mittel unter Druck abgefüllt wird, wobei sich der elastische Behälter ausdehnt und aus dem das Mittel infolge der Kontraktion des elastischen Behälters bei Öffnen des. Sprühventils kontinuierlich abgegeben wird, verwendet werden.The agent according to the invention can also be in the form of a non-aerosol hairspray sprayable with the aid of a suitable mechanically operated spraying device or a non-aerosol hair lacquer. Mechanical spray devices are to be understood as devices which enable the spraying of a liquid without using a propellant. A suitable mechanical spraying device can be, for example, a spray pump or an elastic container provided with a spray valve, in which the cosmetic agent according to the invention is filled under pressure, the elastic container expanding and from which the agent due to the contraction of the elastic container when the spray valve is opened continuously released, can be used.
Des weiteren kann die Zubereitung weitere kosmetische Stoffe ferner vorteilhaft, wenngleich nicht zwingend, Füllstoffe enthalten, welche z. B. die sensorischen und kosmetischen Eigenschaften der Formulierungen weiter verbessern.Furthermore, the preparation can further advantageously contain cosmetic substances, although not necessarily, fillers which, for. B. further improve the sensory and cosmetic properties of the formulations.
Ferner ist es erfindungsgemäß von Vorteil, wenn in den erfindungsgemäßen Zubereitungen Verdicker eingesetzt werden. Diese können beispielsweise vorteilhaft aus der Gruppe der Gummen gewählt werden.It is also advantageous according to the invention if thickeners are used in the preparations according to the invention. For example, these can advantageously be selected from the group of gums.
Zu den Gummen zählt man Pflanzen- oder Baumsäfte, die an der Luft erhärten und Harze bilden oder Extrakte aus Wasserpflanzen. Aus dieser Gruppe können vorteilhaft im Sinne der vorliegenden Erfindung gewählt werden beispielsweise Gummi Arabicum, Johannisbrotmehl, Tragacanth, Karaya, Guar Gummi, Pektin, Gellan Gummi, Carrageen, Agar, Algine, Alginate.Chondrus, Xanthan Gummi. Weiterhin vorteilhaft ist die Verwendung von derivatisierten Gummen wie z.B. Hydroxy- propyl Guar (Jaguar® HP 8).Gums include plant or tree sap that harden in the air and form resins or extracts from aquatic plants. Gum arabic, locust bean gum, tragacanth, karaya, guar gum, pectin, gellan gum, carrageenan, agar, algins, alginates, chondrus and xanthan gum can advantageously be selected from this group for the purposes of the present invention. The use of derivatized gums such as hydroxypropyl guar (Jaguar® HP 8) is also advantageous.
Unter den Polysacchariden und -derivaten befinden sich z.B. Hyaluronsäure, Chitin und Chitosan, Chondroitinsulfate, Stärke und Stärkederivate als erfindungsgemäß vorteilhafte Verdicker.Among the polysaccharides and derivatives are e.g. Hyaluronic acid, chitin and chitosan, chondroitin sulfates, starch and starch derivatives as advantageous thickeners according to the invention.
Unter den Cellulosederivaten befinden sich z.B. Methylcellulose, Carboxymethylcellulose, Hydroxyethylcellulose, Hydroxypropylmethylcellulose als erfindungsgemäß vorteilhafte Verdicker.Among the cellulose derivatives are e.g. Methyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl methyl cellulose as advantageous thickeners according to the invention.
Unter den Schichtsilikaten befinden sich natürlich vorkommende und synthetische Tonerden wie z.B. Montmorillonit, Bentonit, Hektorit, Laponit, Aluminiumsilicate, Magnesiumaluminiumsilikate wie Veegum®. Diese können als solche oder in modifizierter Form als Verdicker verwendet werden wie z.B. Stearylalkonium Hektorite.Layered silicates contain naturally occurring and synthetic clays such as Montmorillonite, bentonite, hectorite, laponite, aluminum silicates, magnesium aluminum silicates such as Veegum®. These can be used as such or in a modified form as thickeners, e.g. Stearylalkonium hektorite.
Weiterhin können vorteilhaft auch Kieselsäuregele verwendet werden..In addition, silica gels can also advantageously be used.
Unter den Homopolymeren der Acrylsäure (Molekulargewicht: 2000000 bis 6000000) befinden sich z.B. Carbopol Typen der Firma Goodrich (Carbopol 940, 980, 981 , , 5984, 2984, ETD 2001 , ETD 2050 oder Ultrez 10). .Among the homopolymers of acrylic acid (molecular weight: 2,000,000 to 6,000,000) are e.g. Carbopol types from Goodrich (Carbopol 940, 980, 981,, 5984, 2984, ETD 2001, ETD 2050 or Ultrez 10). ,
Außerdem geeignet sind Copolymere der Acrylsäure oder der Methacrylsaure wie z.B. Carbopol Typen der Firma Goodrich (Carbopol 1342, 1382, ETD 2020, Ultrez 21, Permulen TR-1 oder Pemulen TR-2.Copolymers of acrylic acid or methacrylic acid such as e.g. Carbopol types from Goodrich (Carbopol 1342, 1382, ETD 2020, Ultrez 21, Permulen TR-1 or Pemulen TR-2.
Polymere aus Acrylsäure und Acrylamid (Natriumsalz) mit einem Molekulargewicht von 2000000 bis 6000000 wie z.B. Hostacerin PN 73 oder das unter dem Namen Amigel vertriebene Sclerotium Gum.Polymers from acrylic acid and acrylamide (sodium salt) with a molecular weight of 2,000,000 to 6,000,000, e.g. Hostacerin PN 73 or Sclerotium Gum sold under the name Amigel.
Unter den Polymeren befinden sich z.B. Polyacrylamide (Seppigel 305), Polyvinylalko- hole, PVP, PVP / VA Copolymere, Polyglycole und Ammonium Acryloyldimethyltaurate / VP Copolymer. Folgende Beispiele belegen den Synergieeffekt der erfindungsgemäßen Zubereitungen im Vergleich zu den Einzelbestandteilen.The polymers include, for example, polyacrylamides (Seppigel 305), polyvinyl alcohols, PVP, PVP / VA copolymers, polyglycols and ammonium acryloyldimethyltaurates / VP copolymers. The following examples demonstrate the synergy effect of the preparations according to the invention in comparison to the individual components.
Die Mengenangaben in den Beispielen sind Gew.-%.The amounts in the examples are% by weight.
Beispiele 1 - 6 , • . • Examples 1-6 , •. •
Schaumfestigermousse
Figure imgf000012_0001
Figure imgf000012_0001
0 0
Beispiele 7-8 Haarspray, Beispiele 9-10 GeleExamples 7-8 hairspray, Examples 9-10 gels
Figure imgf000013_0001
Figure imgf000013_0001

Claims

Patentansprüche claims
1. Haarbehandlungsmittel umfassend mindestens ein Polymer mit sauren und/oder amphoteren Gruppen in ethanolischem, wässrig-ethanolischem oder wässrigem Medium und mindestens ein Polyhydroxyalkylamin der Formel1. Hair treatment composition comprising at least one polymer with acidic and / or amphoteric groups in ethanolic, aqueous-ethanolic or aqueous medium and at least one polyhydroxyalkylamine of the formula
NR1R R3, wobeiNR 1 RR 3 , where
RT = Mono-, Di- oder Trihydroxyalkylrest mit einer Kohlenstoffkette C2 - C6, R2, R3 = H, Alkylrest mit einer Kohlenstoffkette C - C18 oder Mono-, Di- oder Trihydroxyalkylrest mit einer Kohlenstoffkette C2 - C6, oder deren Salze.RT = mono-, di- or trihydroxyalkyl radical with a carbon chain C 2 - C 6 , R 2 , R 3 = H, alkyl radical with a carbon chain C - C 18 or mono-, di- or trihydroxyalkyl radical with a carbon chain C 2 - C 6 , or their salts.
2. Haarbehandlungsmittel nach Anspruch 1 umfassend mindestens ein Polymer mit Carboxy-, Sulfonsäure-, Phosphorsäure-, Säureamid-, Anhydrid- und oder anionische Polyurethan-Funktionalität.2. Hair treatment composition according to claim 1 comprising at least one polymer with carboxy, sulfonic acid, phosphoric acid, acid amide, anhydride and or anionic polyurethane functionality.
3. Haarbehandlungsmittel nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass als Polymer Octylacrylamide/Acrylates/Buthylaminoethyl Methacrylate Copolymer oder PVP/VA Copolymer ausgewählt wird.3. Hair treatment composition according to claim 1 or 2, characterized in that the polymer selected is octylacrylamide / acrylate / butylaminoethyl methacrylate copolymer or PVP / VA copolymer.
4. Haarbehandlungsmittel nach Anspruch 1 , 2 oder 3, dadurch gekennzeichnet, dass im Polymer die sauren Gruppen zu 20 bis 100%, besonders bevorzugt zu 50 bis 100%, mit dem Amin des Neutralisationsmittels neutralisiert sind.4. Hair treatment composition according to claim 1, 2 or 3, characterized in that in the polymer the acidic groups are neutralized to 20 to 100%, particularly preferably 50 to 100%, with the amine of the neutralizing agent.
5. Mittel nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass das Mittel 0,01 bis 20 Gew% des Polymers, bevorzugt 0,1 bis 10 Gew%, besonders bevorzugt 1 ,0 bis 5,0 Gew%, bezogen auf das gesamte Mittel, umfasst.5. Agent according to one of claims 1 to 4, characterized in that the agent 0.01 to 20% by weight of the polymer, preferably 0.1 to 10% by weight, particularly preferably 1.0 to 5.0% by weight, based on the entire mean.
6. Mittel nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass das Mittel 0,01 bis 5 Gew.% Polyhydroxyalkylamin, bevorzugt 0,01 bis 2 Gew.%., bezogen auf das gesamte Mittel, umfasst.6. Agent according to one of claims 1 to 5, characterized in that the agent comprises 0.01 to 5% by weight of polyhydroxyalkylamine, preferably 0.01 to 2% by weight, based on the total agent.
7. Mittel nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, dass als . Polyhydroxyalkylamin 2-Amino- 1 ,3 propandiol und/oder 1 -Amino-2,3 propandiol oder deren Salze enthalten ist. 7. Composition according to one of the preceding claims, characterized in that as. Polyhydroxyalkylamine 2-amino-1, 3 propanediol and / or 1-amino-2,3-propanediol or their salts is contained.
8. Mittel nach einem der vorstehenden Ansprüche umfassend zusätzlich O/W- Emulgatoren.8. Composition according to one of the preceding claims additionally comprising O / W emulsifiers.
9. Mittel nach einem der vorstehenden Ansprüche umfassend zusätzlich W/O- Emulgatoren.9. Composition according to one of the preceding claims additionally comprising W / O emulsifiers.
10. Mittel nach einem der Ansprüche 1 bis 9, dadurch gekennzeichnet, dass zusätzlich mindestens ein Pflegestoff, insbesondere kationische Tenside wie monomere quatemäre Ammoniumverbindungen und/oder kationischen Substanzen, wie Cetyltrimethylammoniumchlorid oder Cetyltrimethylammoniumphosphat und/oder Silikonpolymere, wie Pqjydimethylsiloxan, α-Hydro-ω-hydroxypolyoxydimethylsilylen, cyclisches Dimethylpolysiloxan, Dimethylsiloxan-Glycol-Copolymer oder Dimethylsioxanaminoalkylsiloxan-Copolymer mit Hydroxyendgruppen, enthalten sind.10. Composition according to one of claims 1 to 9, characterized in that in addition at least one care substance, in particular cationic surfactants such as monomeric quaternary ammonium compounds and / or cationic substances such as cetyltrimethylammonium chloride or cetyltrimethylammonium phosphate and / or silicone polymers such as pqjydimethylsiloxane, α-hydro-ω -hydroxypolyoxydimethylsilylene, cyclic dimethylpolysiloxane, dimethylsiloxane-glycol copolymer or dimethylsioxanaminoalkylsiloxane copolymer with hydroxy end groups are contained.
11. Mittel nach einem der Ansprüche 1 bis 10, dadurch gekennzeichnet, dass zusätzlich mindestens ein synthetisches oder natürliches, filmbildendes, nichtionisches und/oder kationisches haarfestigenden Polymer, Verdicker, Aerosole, Lösungsmittel, Netzmittel, Emulgatoren, Tenside, Feuchthaltemittel, Parfüm, Schaumstabilisatoren und/ode Entschäumern enthalten sind.11. Agent according to one of claims 1 to 10, characterized in that in addition at least one synthetic or natural, film-forming, nonionic and / or cationic hair-fixing polymer, thickeners, aerosols, solvents, wetting agents, emulsifiers, surfactants, humectants, perfume, foam stabilizers and / or defoamers are included.
12. Mittel nach Anspruch 11 , dadurch gekennzeichnet, dass das Mittel 0,01 bis 20 Gew.%, bevorzugt 0,1 bis 10 Gew.%, besonders bevorzugt 1 ,0 bis 5,0 Gew.%, des zusätzlichen harrfestigenden Polymers enthält.12. Composition according to claim 11, characterized in that the composition contains 0.01 to 20% by weight, preferably 0.1 to 10% by weight, particularly preferably 1.0 to 5.0% by weight, of the additional hardening polymer ,
13. Verwendung von Zubereitungen nach einem der Ansprüche 1 bis 12 als Stylingmittel, Spray, Aerosol-Spray, . Haarlack, versprühbaren Non-Aerosol-Haarspray, versprühbaren Non-Aerosol-Haarlack, Schaumfestiger, Gel, Wachs, Mikroemulsion, Schaum und/oder Stylingemulsion. 13. Use of preparations according to one of claims 1 to 12 as a styling agent, spray, aerosol spray,. Hair lacquer, sprayable non-aerosol hair spray, sprayable non-aerosol hair lacquer, foaming agent, gel, wax, microemulsion, foam and / or styling emulsion.
PCT/EP2003/012135 2002-11-02 2003-10-31 Hair conditioning agents having improved coating and olfactory properties WO2004041224A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003282063A AU2003282063A1 (en) 2002-11-02 2003-10-31 Hair conditioning agents having improved coating and olfactory properties

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10251122.5 2002-11-02
DE2002151122 DE10251122A1 (en) 2002-11-02 2002-11-02 Hair treating agents with improved film-forming and odor properties contain a polymer with acid and/or amphoteric groups and a polyhydroxyalkylamine or salt

Publications (1)

Publication Number Publication Date
WO2004041224A1 true WO2004041224A1 (en) 2004-05-21

Family

ID=32115148

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2003/012135 WO2004041224A1 (en) 2002-11-02 2003-10-31 Hair conditioning agents having improved coating and olfactory properties

Country Status (3)

Country Link
AU (1) AU2003282063A1 (en)
DE (1) DE10251122A1 (en)
WO (1) WO2004041224A1 (en)

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3810977A (en) * 1967-03-23 1974-05-14 Nat Starch Chem Corp Hair fixing composition and process containing a solid terpolymer
DE2404070A1 (en) * 1974-01-29 1975-08-14 Henkel & Cie Gmbh SKIN CARE AND SKIN PROTECTION PRODUCTS WITH A CONTENT OF SKIN MOISTURIZERS
GB1595649A (en) * 1978-05-25 1981-08-12 Nat Starch Chem Corp Aerosol hair spray compositions
FR2697160A1 (en) * 1992-10-28 1994-04-29 Oreal Aqueous cosmetic composition for fixing the hair based on a pseudo-latex.
DE4316242A1 (en) * 1993-05-14 1994-11-17 Henkel Kgaa Hair treatment products
US5853706A (en) * 1997-03-19 1998-12-29 Townley Jewelry, Inc. Scented hair gel having particulate matter in the form of glitter
DE19808824C1 (en) * 1998-03-03 1999-10-28 Wella Ag Hair treatment agent useful as styling liquid, mousse, gel or spray
EP1075835A1 (en) * 1999-08-09 2001-02-14 Shiseido Company Limited Use of aminodiol derivatives in skin cosmeics
WO2003053381A1 (en) * 2001-12-11 2003-07-03 Basf Aktiengesellschaft Cosmetic agent containing at least one copolymer having n-vinyllactam units

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2996471A (en) * 1958-06-23 1961-08-15 Nat Starch Chem Corp Reaction product of an aminohydroxy compound with a copolymer of vinyl acetate and crotonic acid, compositions and products thereof
GB1146155A (en) * 1965-03-26 1969-03-19 Mitsubishi Rayon Co Hair lacquers
US3405084A (en) * 1965-06-30 1968-10-08 Barr Company G Neutralized terpolymeric resin of vinyl pyrrolidone, alkyl acrylate or methacrylate,and unsaturated monocarboxylic acid
GB1321836A (en) * 1969-07-07 1973-07-04 Ici Ltd Hair setting compositions
US3726288A (en) * 1971-08-04 1973-04-10 Nat Starch Chem Corp Process for setting hair using a preparation comprising a single fixative-thickener
US4192861A (en) * 1978-05-05 1980-03-11 National Starch And Chemical Corporation Hydrocarbon propelled aerosol hair spray compositions
DE3643897A1 (en) * 1986-12-22 1988-06-30 Henkel Kgaa HAIR FIXING AGENTS
DE10061420A1 (en) * 2000-12-09 2002-06-13 Henkel Kgaa New use of polyhydroxy compounds

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3810977A (en) * 1967-03-23 1974-05-14 Nat Starch Chem Corp Hair fixing composition and process containing a solid terpolymer
DE2404070A1 (en) * 1974-01-29 1975-08-14 Henkel & Cie Gmbh SKIN CARE AND SKIN PROTECTION PRODUCTS WITH A CONTENT OF SKIN MOISTURIZERS
GB1595649A (en) * 1978-05-25 1981-08-12 Nat Starch Chem Corp Aerosol hair spray compositions
FR2697160A1 (en) * 1992-10-28 1994-04-29 Oreal Aqueous cosmetic composition for fixing the hair based on a pseudo-latex.
DE4316242A1 (en) * 1993-05-14 1994-11-17 Henkel Kgaa Hair treatment products
US5853706A (en) * 1997-03-19 1998-12-29 Townley Jewelry, Inc. Scented hair gel having particulate matter in the form of glitter
DE19808824C1 (en) * 1998-03-03 1999-10-28 Wella Ag Hair treatment agent useful as styling liquid, mousse, gel or spray
EP1075835A1 (en) * 1999-08-09 2001-02-14 Shiseido Company Limited Use of aminodiol derivatives in skin cosmeics
WO2003053381A1 (en) * 2001-12-11 2003-07-03 Basf Aktiengesellschaft Cosmetic agent containing at least one copolymer having n-vinyllactam units

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NN: "Neutrol TE as a neutralization agent for carbopol polymer", NOVEON INC., January 2002 (2002-01-01), Ohio/USA, pages 1 - 8, XP002272014, Retrieved from the Internet <URL:http://www.pharma.noveoninc.com/literature/tds/tds90.pdf> [retrieved on 20040301] *

Also Published As

Publication number Publication date
AU2003282063A1 (en) 2004-06-07
DE10251122A1 (en) 2004-05-19

Similar Documents

Publication Publication Date Title
DE69720204T2 (en) COSMETIC AEROSOL COMPOSITION FOR HAIR FASTENERS WITH SHINE AND TREATMENT METHOD
EP2098217A2 (en) Volumising hair fixer with ampholytic copolymer
EP1110536B1 (en) Hair treating composition comprising a polymer combination
DE19805434C2 (en) Hair treatment agent with fluorinated acids and polymers
WO2010112361A2 (en) Agents for fibers containing keratin, containing at least one special cross-linked amphiphilic, anionic polymer and at least one further special non-cross-linked amphiphilic anionic polymer
EP0756859B1 (en) Hair care composition
DE19833516C1 (en) Hair fixatives with amphoteric and acidic polymers
DE19919785A1 (en) Hair treatment agent with polymers of unsaturated saccharides, unsaturated saccharic acids or their derivatives
EP3082734B1 (en) Hair fixatives including cellulose ether based polyglucose polymers
US20080089855A1 (en) Non-fluid hair treatment product comprising hair fixative absorbed on waxy carrier
DE60124130T2 (en) FOAMED HAIR COSMETIC PREPARATION USING AN AMINOOPLAST ETHER THAN THICKENING
DE19808824C1 (en) Hair treatment agent useful as styling liquid, mousse, gel or spray
EP2451530A2 (en) Composition for keratin-containing fibres containing at least one special cellulose and at least one additional film-forming polymer and/or strengthening polymer
WO2014095165A2 (en) Foam aerosol for increasing volume
EP1192931B1 (en) Hair treatment composition comprising a combination of three polymers
DE602004010996T2 (en) Cosmetic composition containing gellan gum or a derivative thereof, a fixing polymer, a monovalent salt and an alcohol, methods based on this composition and applications
EP0955033B1 (en) Hair treatment composition comprising alpha-hydroxy carboxylic acid esters and polymers
DE602004004479T2 (en) Hair cosmetic composition based on tridecyl trimellitate and eicosan
WO2004041224A1 (en) Hair conditioning agents having improved coating and olfactory properties
DE10352470A1 (en) Modulating properties of film formers, especially anionic and/or amphoteric polymers, in hair-styling compositions, using creatine and/or creatinine, providing improved elasticity and handling
DE60316687T2 (en) Method of hair treatment characterized by application of certain 2-hydroxyalkanoic acids
DE602004009760T2 (en) COSMETIC COMPOSITION CONTAINING IONIC HYDROGELIC AMID AND HAIRPREPARING POLYMER
DE602004001018T2 (en) Hair cosmetic composition containing tridecyl trimellitate and a fixing polymer.
DE19718185C1 (en) New poly-N-acyl-alkylene-imine modified organo poly:siloxane compounds
EP2659876B1 (en) New hair fixative with sorbitol

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SC SD SE SG SK SL TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): BW GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
NENP Non-entry into the national phase

Ref country code: JP

WWW Wipo information: withdrawn in national office

Country of ref document: JP