WO2004002442A1 - Fragrance cosmetic - Google Patents

Abstract

A fragrance cosmetic containing a fragrant material and a bright pigment, especially a fragrance cosmetic containing a fragrant material and an alcohol wherein a bright pigment can be stably dispersed, which fragrance cosmetic does not deteriorate a feeling of use and is free from skin stickiness. In particular, a fragrance cosmetic comprising a fragrant material and a bright pigment characterized in that a polysaccharide comprising glucose, fucose, glucuronic acid and rhamnose as constituent monosaccharides is contained therein. It is preferred that polysaccharide produced by Alcaligenes latus strain B-16 be contained in the fragrance cosmetic in an amount, in terms of dry solid content, of 0.01 to 0.5 wt.% (based on total weight).

Description

 Frederance Cosmetics Technical Field

 The present invention relates to a fragrance cosmetic containing a fragrance and a glitter pigment.

 Background art

 For cosmetics, it is necessary to use various raw materials such as water, oil, powder, etc., disperse substances that do not dissolve each other, and maintain the dispersion state stably over a wide temperature range for a long time.

For this reason, a cosmetic is prepared by blending a bacterial culture of Alcaligenes latus B- 16 strain, which is one of the polysaccharides containing fucose, glucose, glucuronic acid and rhamnose as constituent monosaccharides, with a hydrophilic polymer substance. There is a method of dispersing water, oil, powder, and the like, which are blended in the oil, and maintaining the dispersion state stably over a wide temperature range for a long time (Japanese Patent Application Laid-Open No. 2001-226250).

In cosmetics and external preparations for the skin, bacterial culture of Alcaligenes latus B-16 strain, one of the brans containing fucose, glucose, glucuronic acid and rhamnose as a constituent monosaccharide, is used as a thickener. , Moisturizers, astringents, whitening agents, anti-inflammatory (anti-inflammatory) agents, UV inhibitors, cell activating agents, etc., active ingredients such as ascorbic acids as whitening components, and animal and plant components such as coconut oil A method for preventing the separation of these components and stabilizing the skin external preparation by adding the same to a skin external preparation containing such components (Japanese Patent Application Laid-Open Nos. 2002-60314 and 2002-29929) There is also. Furthermore, Frederance cosmetics such as perfume, eau de parfum, eau de toilette, eau de cologne and condensed perfume have been used as products for enjoying fragrances. Frederance cosmetics usually include a fragrance composed of various fragrance components with different polarities, alcohols such as ethanol to dissolve the fragrance component, water, and a surfactant for solubilizing the fragrance component in water. It is a cosmetic in the form of a transparent liquid as a component (Japanese Unexamined Patent Application Publication No. 2000-1-1913, Japanese Unexamined Patent Application Publication No. 2001-213187, Japanese Unexamined Patent Application Publication No. — No. 29 4 890 public announcement). Such fragrance cosmetics are usually applied by spraying or by taking a small amount from a container and applying it to make it feel smooth.

 In recent years, new fragrance cosmetics, which are blended with glittering pigments composed of fine metal powder, fiber powder, and fine inorganic substances with luster such as lame and pearl luster, are being marketed. became. Frederance cosmetics containing these glittering pigments generally have a large specific gravity difference between the glittering pigment and the cosmetic base, so that the glittering pigments easily float or settle in fragrance cosmetics. Fragrance at the time of use It is necessary to shake and use cosmetics, which is not desirable as a product.

Therefore, in order to maintain the transparency of fragrance cosmetics and stably disperse and maintain glittering cosmetics in fragrance cosmetics, the use of conventional polysaccharide thickeners and synthetic thickeners was attempted. Was done. However, these thickeners increase the viscosity of Frederance cosmetics to stably disperse and maintain brilliant cosmetics and fragrances dissolved in alcohol, etc. Cause trouble. Furthermore, since the viscosity of the Frederance cosmetics rises, the fragrance cosmetics loses the crisp feel when used after taking a small amount from a container and applying it. The use feeling of the product is spoiled, and the product image is greatly damaged. For this reason, a fragrance cosmetic which contains a fragrance and an organic solvent (especially alcohols), stabilizes the dispersion of the solubilized glittering face, and has a satisfactory sensation in use and satisfactory, has not yet been obtained. Disclosure of the invention

 An object of the present invention has been made in view of the above circumstances, and in a fragrance cosmetic containing a fragrance, an alcohol, and a glitter pigment, the glitter pigment is stably dispersed while maintaining the transparent liquidity of the fragrance cosmetic. The object of the present invention is to provide a fragrance cosmetic which does not impair the feeling of use of the fragrance cosmetic and has no sticky feeling on the skin. The present inventors have conducted intensive studies on fragrance cosmetics containing brilliant pigments and found that the combined use of a specific polysaccharide and a surfactant is effective for solubilizing fragrances and dispersing brilliant pigments. Heading, the present invention has been completed. That is, the invention of claim 1 is directed to a Frederance cosmetic containing a fragrance and a brilliant pigment, wherein the cosmetic contains a polysaccharide containing glucose, fucose, glucuronic acid, and rhamnose as constituent monosaccharides. A fragrance cosmetic.

By incorporating a polysaccharide containing glucose, fucose, glucuronic acid, and rhamnose as constituent monosaccharides, it is possible to obtain a fragrance cosmetic having excellent dispersion stability of a fragrance and a brilliant face. The invention according to claim 2 is the Frederance cosmetic according to claim 1, characterized by containing a surfactant. By containing a surfactant, the perfume is solubilized and the glitter pigment is dispersed. The invention according to claim 3 is the fragrance cosmetic according to claim 1 or 2, wherein the bran is a product of a bacterium of Alcaligenes rhetas B-16 strain.

 The use of Alcaligenes strain B-16 strain bacteria makes it possible to obtain the product polysaccharide more efficiently. The invention according to claim 4 is the fragrance cosmetic according to any one of claims 1 to 3, wherein the glittering pigment is a pearlescent pigment, a metallic luster pigment, a glass flake pigment, a metal-coated inorganic pigment, or a resin. It is characterized by being at least one kind selected from pigments.

 Fragrance with improved glitter and dispersion stability with the use of at least one pigment selected from pearlescent pigments, metallic luster pigments, glass flake pigments, metal-coated inorganic pigments, and resin pigments A cosmetic is obtained. The invention according to claim 5 is the fragrance cosmetic according to any one of claims 1 to 4, wherein the polysaccharide comprises 0.01 to 0.5% by weight (to the total amount) as a dry solid content. It is characterized by

By containing polysaccharides in an amount of 0.1 to 0.5% by weight (as dry solids) with respect to Frederance cosmetics, it improves the solubilization of fragrances, improves the dispersibility of glittering pigments, and provides excellent usability. A cosmetic composition can be obtained. The invention according to claim 6 is the fragrance cosmetic according to any one of claims 2 to 5, wherein the surfactant is polyoxyalkylene-hardened castor oil, polyoxyalkylene sorbitan fatty acid ester, sorbitan fatty acid ester, and sucrose. It is a fragrance cosmetic which is at least one selected from fatty acid esters, glycerin fatty acid esters, polyglycerin fatty acid esters, lecithin and derivatives thereof. The invention according to claim 7 is the fragrance cosmetic according to any one of claims 1 to 6, wherein the fragrance is 0.1 to 40% by weight and the glitter pigment is 0.1 to 30% by weight. the surfactant 0 0 5 -. 2 0 weight _^0/0, the polysaccharide is a 0 0 1-0 5% by weight comprising at fragrances of粧料... ADVANTAGE OF THE INVENTION The fragrance cosmetics of this invention can provide the stable fragrance cosmetics which maintain the uniform dispersion state of a fragrance | flavor and a brilliant pigment, and have no sticky feeling at the time of its use, It greatly contributes to improvement. BEST MODE FOR CARRYING OUT THE INVENTION

 The present invention relates to a translucent cosmetic composition containing a perfume and a glittering pigment (hereinafter referred to as "the frédance cosmetic composition of the present invention") by using a specific polysaccharide and a surfactant in combination. The present invention relates to a Frederance cosmetic in which a pigment is stably dispersed and a smooth feel is obtained.

The Frederance cosmetics of the present invention include perfume (perfume, parfum), ead parfum (perfume colon), genuine detoile (perfume detoile, non-refund). B) Cosmetics containing liquid glittering pigments such as cologne (colon, fresh colon). These Frederance cosmetics generally contain a fragrance, a solvent (organic solvent) for the fragrance, water, a solubilizing surfactant, and a glitter pigment. , Oils, moisturizers, astringents, whitening agents, UV inhibitors, anti-inflammatory (anti-inflammatory) agents, skin (cell) activators, bactericides, fresheners, chelating agents, antioxidants, anti-fading agents, Buffering agents, preservatives, etc. are blended. Flavors (components) used in the Frederance cosmetics of the present invention include natural flavors and synthetic flavors. Natural incense includes rose oil, jasmine oil, neroli oil, lavender oil, tuberose oil, ylang ylang oil, clary sage oil, clove oil, peppermint oil, geranium oil, patch lily oil, sandalwood oil, cinnamon oil, Coriander oil, nutmeg oil, pine oil, vanilla oil, peruvian balsam oil, banana oil, apple oil, fennel oil, ton-bean beans oil, pepper oil, lemon oil, orange oil, benoregamot oil, opoponax oil, vetiver There are vegetable flavors such as oil, oris oil, oak moss oil, varnish oil, and boad rose oil, and animal flavors such as musk oil, civet oil, castorium oil, ambergris oil.

Synthetic fragrances include limonene, hydrocarbons such as] 3-force phyllophylline, cis-1-3-hexenore, lina ichinore, fanolene sonole, β-fueninolechinorea norekonore, gera nonore, citronellonole, Alcohols such as tarpineo monole, menthol nole, santa ronole, pac d'anol and bramanol, rilanol, lireal, aldehydes such as 2,6-nonagenal, citral, α-hexylcinnamic aldehyde, ^ -ionone, -Power Norebon, Six mouth pentadecanone, Damascon, Methino Leionon, Ketones such as ylon, isoi supermarket, acetinoledren, and muscone, benzinole acetate, methyl dihydrodiasmonate, methyl jasmonate, esters such as linalyl acetate, benzyl benzoate, γ_ndedecalactone, jasmin lactone, Ratatones such as cyclopentadecanolide and ethylene brassate; oxides such as galact solid, ambroxane and rose oxide; phenols such as eugenol; nitrogen-containing compounds such as indole; phenylacetoaldehyde dimethyl acetal And Schiff bases such as olanthiol. Fragrances are generally rarely used as a single type, but are used as a combination of multiple types.

The amount of perfume in the fragrance cosmetics, Les yo if it is appropriately determined depending on the purpose, but, usually, 0 for Furedaransu total amount of the cosmetic. 1-4 0 weight _^0/0 (hereinafter, "Weight "%" Is referred to as "%."), Preferably 1 to 35% (total amount of Frederance cosmetics), and more preferably 5 to 30% (total amount of Frederance cosmetics). These fragrances are usually dissolved in an organic solvent at a concentration of 5 to 70% and incorporated into fragrance cosmetics.

The organic solvent used for dissolving the fragrance acts not only as a solvent for the fragrance but also as a solubilizing aid IJ, and includes alcohols, fatty acid esters, ketones, and the like. Specifically, 1,3-butylene glycolone, ethylene glycolone, ethylene glycolone, triethyleneglyconele, polyethylene glycol, propylene glycol, 'recol, dipropylene glycol, glycerin, polyglycerin, There are ptanol, propanol, fatty acid esters such as ethyl acetate and butyl acetate, ketones such as acetone and methyl ethyl ketone, and one or more of them are used. Especially of fragrance Alcohols such as ethanol, 1,3-butylene glycol, ethylene glycol, glycerin, and polyglycerin are preferred from the viewpoints of solubility and lowering the viscosity of fragrance cosmetics. The brilliant pigment used in the present invention usually has a special optical effect such as luster, iris color, metallic feeling, coating, prevention of ultraviolet rays, or adsorbs secreted sebum on a material to be colored to prevent makeup loss. This is a cosmetic powder used for the purpose of giving a soft feeling of use, and is usually used for makeup cosmetics such as lipstick, eye color, cheek color, and nail color, and cosmetics for hair. Pigment.

For example, inorganic pigments such as lake pigments, organic pigments, coloring pigments, white pigments, extender pigments, pearlescent pigments, metallic luster pigments, glass flake pigments, metal-coated inorganic pigments, resin pigments, polymer powders, and functional pigments And one or more of these are used.

 There are two types of lake pigments, one of which is soluble in water, and the other is a face department in which the dye is insolubilized in water as a salt such as calcium.For example, red No. 202, 204, 206, There are 207, 208, and 220. The other is a pigment which is made water-insoluble with aluminum sulfate, zirconium sulfate or the like and adsorbed on alumina, such as Yellow No. 5 and Red No. 230. Organic pigments are colored powders that have no hydrophilic groups in the molecular structure and do not dissolve in water, oil or solvents, and have excellent coloring power and light resistance. Azo pigments, Red No. 228, Indigo pigments, Red No. 226, phthalocyanine pigments, Blue No. 404, and the like.

Inorganic pigments include iron oxides of different colors, such as red iron oxide, black iron oxide, black iron oxide, ultramarine, navy blue, chromium oxide, chromium hydroxide, magnesium oxide, cobalt oxide, cobalt titanate, and manganese violet. , Cobalt violet and the like. The white pigment is used for coloring, coating and the like, and includes titanium dioxide and zinc oxide.

 The extender pigments are used for maintaining the shape of the product, adjusting the extensibility, adhesion, gloss, etc., and adjusting the color tone (diluent) rather than coloring. For example, mica (my strength), muscovite, synthetic mica, phlogopite, Mica pigments such as mica, biotite, and lithia mica, viscous minerals such as sericite, tanolek, kaolin, montmorillonite, and zeolite, magnesium carbonate, calcium carbonate, citric acid, silicic anhydride, aluminum silicate, and magnesium silicate And synthetic inorganic powders such as aluminum magnesium silicate, sulfur-containing aluminum silicate, calcium silicate, barium silicate, strontium silicate, aluminum oxide and barium sulfate. Pearlescent pigments are pigments used to impart pearlescent, iris, or metallic qualities, and include titanium dioxide-coated mica, fish scale foil, and oxychloride bihemous. In addition, pigments coated with iron oxide instead of titanium oxide, and pigments coated with a transparent pigment of a different color on a coating layer of titanium oxide are also used.

 Examples of the metallic luster pigment include aluminum powder, brass powder, copper powder, tin powder, gold powder, platinum powder, silver powder, and the like, and further, a colored metal powder pigment obtained by coloring these metal powders.

 The glass flake pigment is obtained by coating flake glass with metal or the like.

 Metal-coated inorganic pigments are inorganic pigments coated with a metal and / or a metal oxide by metal deposition or the like, and examples thereof include iron oxide-coated aluminum, iron oxide-coated mica, and aluminum manganese-coated mica-like iron oxide. can give.

Resin pigments include resin film colored and cut flakes.For example, polyester film end, polyethylene terephthalate / anoreminimum / epoxy laminated finolem end, polyethylene terephthalate 'polyolefin laminated film end, polymeta Examples include methyl acrylate, polyethylene terephthalate, polymethyl methacrylate laminated powder, and nylon powder.

 Examples of the functional pigment include boron nitride, synthetic fluorophlogopite, photochromic pigment, and composite fine particle powder.

 The form of the brilliant pigment of the present invention is not particularly limited, and may be appropriately selected depending on the purpose and the pigment to be used, such as granules, plates, rods, and colloids. The size of the pigment is not particularly limited and may be appropriately selected depending on the purpose and the pigment to be used.In the case of a granular pigment, the average particle diameter is usually 0.01 μm to A powder having a major axis of 0.1 to 500 μηη is usually used as a foil or rod-like powder.

 The blending amount of the glitter pigment of the present invention cannot be determined uniformly depending on the pigment used, and is appropriately selected. However, it is usually 0.01 to 30%. Preferably it is 0.05 to 10% (to the total amount). If the amount of the brilliant pigment is less than 0.01% by weight, the effect of the fragrance cosmetics containing the brilliant pigment may not be obtained. If the amount is more than 80% by weight, use of spray coating or the like may be hindered. May be harmful. The surfactant used in the Frederance cosmetic of the present invention solubilizes the fragrance and disperses the glittering pigment. The type of the surfactant is not particularly limited, but the hydrophilicity / lipophilicity ratio (HLB Nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants having a value of 12 to 18 are included.

 The surfactant used in the present invention includes a nonionic surfactant, such as polio.

'' Ethenoles, Polyoxynolequinylene Polyoxyalkylene fatty acid esters, polyoxyalkylene sorbitan fatty acid esters, sorbitan fatty acid esters, polyoxyalkylene glycerin fatty acid esters, glycerin fatty acid esters, polyglycerin fatty acid esters, polyoxyalkylene Examples include hardened castor oils, sucrose fatty acid esters, polyoxyalkylene alkylamines, ethylene oxide / propylene oxide block copolymers, and the like.

The polyoxyalkylene in the nonionic surfactant is polyoxyethylene (hereinafter referred to as “POE”), polyoxypropylene (hereinafter referred to as “P〇P”), polyoxybutylene (hereinafter referred to as “POB”). The number of polymerized monomers of P モ ノ E, POP, and POB is appropriately determined depending on the emulsifying properties of the target surfactant, but usually is 3 or more. ~ 200. In addition, the polymerization molar ratio of P〇E, POP, and P 適宜 B is appropriately determined depending on the emulsifying properties of the target surfactant. Preferably, the polyoxyalkylene is a POE: consists POP, POE are those which accounts for 25 mol _^0/0 above.

Polyoxyalkylene alkyl ethers having 2 to 4 carbon atoms are straight-chain or branched, saturated or unsaturated alcohols having 8 to 30 carbon atoms to which polyalkylene oxide is added. Specifically, POE (3 moles) octyl ether, POE (5 moles) dodecyl ether, POE (10 moles) oleyl ether, POE (15 moles) stearinoleethenore, POE (20 moles) Nyl ether, POE (10 mol) P OP (10 mol) Decyl ether, POE (15 mol) POP (2 mol) Isosteryl ether, POE (10 monoles) Cholestanol ether, POE (15 mol) P〇 P (5 mol ) Hydrogenated lanolins. · Polyoxyalkylene alkyl phenol ethers are linear or branched alkynolephenols or phenols having 1 to 22 carbon atoms, to which polyalkylene oxides are added. Oxyethylene (3 moles) methylphenyl ether, POE (5 monoles) octylphenyl ether, POE (10 moles) noenylphenyl ether, P 、 E (15 moles) dodecylphenyl ether, and the like.

 Polyoxyalkylene fatty acid esters are obtained by adding a polyalkylene oxide to a linear or branched saturated or unsaturated fatty acid having 8 to 22 carbon atoms, and specifically include POE (3 mol) octanoate, POE (5 mol) Decanoate, POE (10 mol) Dodecanoate, P〇E (15 mol) Stearic ester, POE (20 mol) Behenylate, POE (15 mol) Isostearate , POE (15 mol) POP (5 monoles) Oleic acid ester and the like.

Polyoxetylene sorbitan fatty acid esters are obtained by adding sorbitol and a straight- or branched-chain saturated or unsaturated fatty acid having 8 to 22 carbon atoms and a polyalkylene oxide, and specifically, POE ( 5 mol) Sorbitan monolaurate, POE (20 mol) Sorbitan trilaurate, POE (20 mol) Sorbitan monostearate, POE (20 mol) Sorbitan sesquistearate, POE (20 mol) Sorbitan tristearate, POE (20 mol) Sorbitan monooleate, PEO (20 mol) monopamitate, ΡΟΕ (20 mol) isostearate, etc. Sorbitan fatty acid esters are esters of sorbitol with linear or branched saturated or unsaturated fatty acids having 8 to 22 carbon atoms, and specifically, sorbitan monoperate, sorbitan monopalmitate, and sonorebitan monostearate. , Sorbitan monoisostearate, sorbitan monooleate, sonorebitan sesquioleate, There are sorbitan trioleate, penter 2-ertihexinole, and diglycerol sorbitan tetra-2-ethylhexylate.

 Polyoxyethylene glycerin fatty acid esters are addition esters of glycerin and linear or branched saturated or unsaturated fatty acids having 8 to 22 carbon atoms and polyalkylene oxides. Specifically, POE (5 mol) glycerin monolaurate, POE (10 monole) glycerin monostearate, POE (15 monole) glycerin distearate, POE (20 mol) POP (5 mol) glycerindiole Eats are available.

 The glycerin fatty acid ester is an ester of glycerin and a linear or branched saturated or unsaturated fatty acid having 8 to 22 carbon atoms, specifically, glycerin monophosphate, glycerin sesquiperate, glycerin trilaurate, monostearin Glycerin acid, glycerin sesquistearate, glycerin tristearate, glycerin monooleate, glycerin sesquioleate, glycerin triacetate, glycerin mono-cottonseed oil fatty acid, glycerin monoerucate, glycerin α'-oleate glycerin, There are esters of glycerin with a saturated fatty acid mixture of 8 to 12 carbon atoms, stearic acid, malic acid, and estenole of glycerin.

Polyglycerin fatty acid esters include condensed hydroxiestearate polyglycerin ester and condensed ricinoleic acid polyglycerin ester. Polyoxyalkylene-cured castor oils include ρ〇Ε (40 mol) castor oil, ΡΟΕ (60 Hardened castor oil, ΡΟΕ (15 moles) Hardened castor oil monoisostearate, ΡΟΕ (20 moles) Hardened castor oil triisostearate, ΡΟΕ (20 monoles) Hardened castor oil monopyroglutamic acid monoisostearate diester , ΡΟΕ (20 monoles) Macar oil and maleic acid.

 Sucrose fatty acid esters are esters of sucrose with a linear or branched saturated or unsaturated fatty acid having 8 to 22 carbon atoms, specifically, sucrose behenate and sucrose stearin. Acid ester, sucrose palmitate, sucrose myristate, sucrose laurate, sucrose oleate, sucrose oleate, and the like.

 The polyoxyalkylene alkylamines are obtained by adding a primary or secondary amine having 3 to 22 carbon atoms and a polyalkylene oxide, and specifically, POE (5 mol) didodecylamine, diPOE ( 10) POP (3) Dodecylamine, POE (10 moles) distearylamine, diPOE (10 moles) stearinoleamine, diPOE (15 moles) oleylamine, diPOE (17 moles) behenylamine, etc. There is.

 Ethylene oxide 'propylene oxide copolymers are copolymers obtained by polymerizing ethylenoxide and propylene oxide in a molar ratio of 1: 9 to 9: 1 with a molecular weight of about 500 to 50,000. is there.

Examples of the anionic surfactant include fatty acid salts, alkyl sulfates and alkenyl sulfates, alkyl phenyl sulfates and alkenyl phenyl sulfates, alkyl phenylpolyoxyalkylene ether sulfates, and alkyl phenylpolyoxyalkylene ether sulfates. Salts, (di) alkylsulfosuccinates, N-acylaminoates (acyls-N-methyltaurines), alkylbenzene sulfonates, alkylnaphthalene sulfonates, and formalin polycondensates of naphthalene sulfonates. Can be The metal salt is preferably a sodium salt, a potassium salt, or an ammonium salt. Fatty acid salts are straight or branched with 8 to 30 carbon atoms, and are saturated or unsaturated Metal salts of fatty acids W 200, specifically sodium octylate, sodium decanoate, sodium dodecanoate, sodium tetradecanoate, sodium stearate, sodium isostearate, sodium oleate, sodium linolenate, sodium edetate Etc.

 Alkyl sulfates and alkenyl sulfates are straight-chain or branched-chain alkyl sulfates and alkenyl sulfates having 8 to 30 carbon atoms, and more specifically, sodium otatyl sulfate and decyl sulfate. There are sodium, sodium dodecyl sulfate, sodium coconut alkyl sulfate, sodium stearyl sulfate, isostearyl sulfate, ammonium oleyl sulfate, and ammonium behenyl sulfate.

 Alkyl phenylpolyoxyalkylene ether sulfates and alkyl phenylpolyoxyalkylene ether sulfates have 1 to 22 carbon atoms and a phenyl group having a linear or branched alkyl or alkenyl group and a 2 to 2 carbon atoms. 4. Sulfates with polyoxyalkylene glycol adducts of 4. Specifically, Tosinole POE (3 moles) sodium sulfate, octylphenyl P〇E (5 moles) sodium sulfate, nourphenyl P〇E (10 moles) potassium sulfate, decylphenyl POE (10 moles) sodium sulfate, octadecyl sulfate Nil P〇E (15 monole) Potassium sulfate, octadecenylphenyl P〇E (15 mol) potassium sulfate, isooctadecylphenyl POE (15 mol) POP (5 mol) Potassium sulfate, etc.

(Di) Alkyl sulfosuccinates include sodium octyl sulfosuccinate, sodium di-2-ethylhexyl sulfosuccinosuccinate, sodium monolau monoethanolamine polyoxyethylene sulfosuccinate, lauryl polypropylene glycol sulfosuccinate There is a nursery. N-Acyl amino acid salts are acyl-N-methyltaurines, specifically, radioyl sarcosine sodium, N-myristoyl-N-methyltaline sodium, coconut oil fatty acid methyl sodium, lauri. There are higher fatty acid amide sulfonates such as sodium noremethaduldate, monosodium N-lauroylglutamate, disodium N-stearoylglutamate, and N-acylglutamate such as N-myristoyl-L-monoglutamate. Examples of the alkylbenzene sulfonates include sodium dodecylbenzenesulfonate, potassium dodecylbenzenesulfonate, and ammonium dodecylbenzenesulfonate. These may be used alone or in combination of two or more.

 Examples of the ionic surfactant include amino acids, alkylamine salts, quaternary ammonium salts, and pyridinium salts.

 Examples of the amino acids include lecithin derived from egg yolk or soybean, and hydrogenated lecithin and lecithin derivatives such as lecithin hydroxide.

 Examples of the alkylamine salts include salts of primary or secondary amines having 3 to 22 carbon atoms and carboxylic acids having 1 to 22 carbon atoms, and salts of inorganic mineral acids.Specifically, dodecylamine acetate, dodecylamine hydrochloride Salts, dodecylamine stearate, dimethylamine stearate and the like.

The quaternary ammonium salts are salts of quaternary amines having 3 to 22 carbon atoms and carboxylic acids having 1 to 22 carbon atoms or salts of inorganic mineral acids.Specifically, stearinole trimethyl ammonium chloride, lauryl trimethyl chloride Examples include ammonium, distearyl dimethylammonium chloride, benzalkonium chloride, benzethonium chloride, cocoalkyl bromide (having a carbon number of 10 to 14), isoquinolium salt, and salt of dodecylimidazolym. Examples of the pyridinium salts include poly (N, N-dimethyl-3,5-methylenepyridine), cetylpyridinium chloride, and the like.

 Other surfactants such as amithoxides such as dodecyl dimethylamine oxide; acrylic acid; cationic polymers such as S--N--N dimethyl-N-ethylammonioethyl vinylinolepyrrolidone copolymer; Can also be used.

 Examples of amphoteric surfactants include betaines, phosphobetaines and sulfobetaines, glycine betaines, imidazolyme betaines, and amine oxides. Specifically, betaines include betaine dodecyldimethylaminoacetate, betaine stearyl dimethylacetate, and betaine dodecanoate pyrdimethylaminoacetate betaine.Phosphobetaines include 2- ( Dimethyldodecylammonio) propiophosphate, 2- (dimethyldodecylammonio) -12-hydroxypropiophosphate, etc., and sulfobetaines such as dodecyldimethylethylammonium sulfate, glycine Dodecyldi (aminoethyl) glycine as a betaine, 2-Indazolyl betaine, Ν, Ν- (hydroxyxylcarboxymethyl) -12-imidazoline sodium, 2-cocoyl-12-imidazolyl betaine Imitazolidium hydroxide 1-carboxyethylo 2-sodium salt, 2-heptadecyl-carboxymethyl-hydroxy-beta-imidazolinium betaine and the like.

Among these, polyoxyalkylene hydrogenated castor oil, polyoxyalkylene sorbitan fatty acid ester, sonolebitan fatty acid ester, sucrose fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, lecithin and lecithin derivative are more preferable. Is sucrose stearic acid ester, sucrose palmitic acid Esters, sucrose myristate, sucrose laurate, sucrose oleate, sucrose oleate, glyceryl monostearate, glycerol oleate, polyglycerin condensed hydroxiestearate, condensed ricinolein Acid polyglycerin ester, lecithin, hydrogenated lecithin, and hydroxylated lecithin, and one or more of these can be used in combination.

 The amount of the surfactant may be appropriately determined depending on the type of the surfactant to be used or the flavors and oils and fats, but is usually from 0.05 to 20%, preferably from 0.1 to 15%. %, More preferably 0.5 to 10%. If the amount of the surfactant is less than 0.05%, satisfactory solubilization cannot be obtained. In addition, even if the amount exceeds 20%, the amount of the surfactant to be added is not improved, and the dispersibility of the brilliant pigment is not improved. Tactile feeling may impair the feeling of use of fragrance cosmetics. The polysaccharide used in the fragrance cosmetic of the present invention can achieve good solubilization of the fragrance by being used in combination with a small amount of a surfactant, and further, makes the glittering pigment in the fraderance cosmetic a uniform dispersion state. It works to maintain. .

 The solubilization of the fragrance by the polysaccharide and the surfactant used in the present invention can be unexpectedly sufficiently obtained with a smaller amount of the surfactant than before, and furthermore, the salariness when using a fragrance cosmetic is improved. The tactile sensation was enhanced.

The polysaccharide used in the present invention is a polysaccharide containing at least fucose, glucose, glucuronic acid, and rhamnose as constituent monosaccharides, and is preferably a repetition of gnorecose, glucuronic acid, and rhamnose represented by the following formula (1). Consisting of the main chain of the structure, It is a polysaccharide composed of a structure in which one fucose is branched into one glucose in the main chain.

 [Formula 1]

The polysaccharide of the above formula (1) can be obtained, for example, as a product of a strain of Alcaligenes stratus B-16 (FERM BP-2015). Bacteria of the strain A. lichenes L. strain B-16 are cultivated by a conventional microbial culture method. After culturing, if an organic solvent such as acetone, ethanol or isopropyl alcohol is added to the culture, the produced polysaccharide is insoluble. Precipitates as The precipitate can be separated to obtain the polysaccharide. Microorganisms generally produce two or more types of polysaccharides, but may contain other types of polysaccharides as long as they do not interfere with the effects of the present invention. For example, it has been confirmed that at least two types of polysaccharides are contained in the saccharides produced by Alcaligenes strain B-16 bacteria, and the constituent monosaccharide ratio of the polysaccharides separated from the culture solution is fucose in molar ratio. : Gnorecose: gnorecuronic acid: rhamnose = 1: (0.5 to 4): (0.5 to 2): (0.5 to 2), one of which is represented by the general formula (1) Polysaccharides that have a structure in which one fucose is branched into one glucose in the main chain of a repeating structure consisting of glucose, darctic acid, and rhamnose, and other polysaccharides that have fucose and mannose as repeating units. It is. The former is a polysaccharide of the present invention, and is fucose: darco Over scan: glucuronic acid: monosaccharides composition ratio of rhamnose is 1: 2: 1: 1, molecular weight 1 0 ⁹ about a polymeric component [1 998 year Japanese Agricultural Chemistry Society Abstracts, 371 Pejisan See). The latter, fucose and mannose is 1:. 1 is a multi-bran such repeating structural, molecular weight of the low molecular component of 10 ³ to 1 0 ⁷ [Y. No hata, J Az uma, R. K urane , Carbo hydrate Research 293, (1996) 213-222]. Although this low-molecular component is out of the range of the polysaccharide of the present invention, it does not impair the stabilizing effect of the present invention and may be used in the present invention as a result. This polysaccharide is commercially available as Alkasilane [trade name, INC Name: A1 caligenes Polysaccharides, Hakuto (fe)].

 Alkaline genostras B_16 strain Polysaccharides produced by bacteria (hereinafter referred to as “B-16 polysaccharides”) stably disperse suspensions in small amounts and maintain their dispersion state for a long period of time. There is an excellent property that can be. The present invention makes use of this excellent property, and it is possible to disperse a luminous pigment which is a fine solid and a fragrance which is a fine droplet in an aqueous medium even in a system containing an organic solvent.

The compounding amount of the polysaccharide in the Frederance cosmetics is usually preferably 0.01 to 0.5% by weight (based on the total amount) as dry solids, and more preferably 0.02 to 0.2% by weight. . If the amount is less than 0.01% by weight, a sufficient effect may not be obtained. Also, if the amount exceeds 0.5% by weight, the effect is not further increased and the viscosity becomes unnecessarily high. There are times when it is not advantageous. Oils to be blended in the Frederance cosmetic of the present invention include hydrocarbons, waxes, and fats. Examples include fatty acids, higher alcohols, fatty acid esters, organic acid esters, glycerides, and fluorocarbons. Specifically, charcoal (including hydrogen squalane, squalene, ceresin, paraffin, paraffin wax, liquid paraffin, pristane, polyisobutylene, microcrystalline wax, cellulose, etc., and waxes such as milow, carnauparo, and canine There are Delila wax, whale wax, etc., and animal oils include bovine gizzard, beef tallow, beef bone fat, hardened tallow, hardened oil, turtle oil, lard, horse fat, mink oil, liver oil, egg yolk oil, etc. Examples of lanolin derivatives include lanolin, liquid lanolin, reduced lanolin, lanolin alcohol, hard lanolin, lanolin acetate, lanolin fatty acid isopropyl, polyoxyethylene-added lanolin alcohol ether, polyoxyethylene-added lanolin alcohol acetate, and lanolin fatty acid polyethylene. Glycols, polyoxyethylene-added hydrogenated lanolin alcohol ethers, etc., and fatty acids such as ralinic acid, myristic acid, palmitic acid, stearic acid, behenic acid, pendecylene acid, oleic acid, arachidonic acid, and docosahexaenoic acid ( DHA), isostearic acid, and 12-hydroxystearic acid, and higher alcohols such as radiuryl alcohol, myristyl alcohol, palmityl alcohol, stearino alcohol, behenyl alcohol alcohol, and hexadecyl alcohol alcohol. , Oleino Real Archone, Isostealino Leano Reno, Hexildo decanol, Otachildodecanol, Setostearino Real Arcone, 2-decyltetradecinol, cholesterol, phytosterol, sitos Roll, lanosterol, polyoxyethylene-added cholesterol monoreether, monostearyl glycerin ether (bacyl alcohol), etc. Fatty acid esters such as diisobutyl adipate, adipic acid-2-hexyldecyl, and didipic acid monodi-2-hepta Acid mono-N-alkyl glycol, isostearin Isocetyl acid, trimethylolpropane triisostearate, di-2-ethylhexyl ethylene glycol, etinole 2-ethylenohexane, trimethylolpropane 2-ethylenohexane, tetra-2-ethylhexanoate Pentaerythritol tonole, cetyl octanoate, octyl dodecyl gum ester, oleyl oleate, octyl dodecyl oleate, decyl oleate, neopentyl glycol dicaprate, triethyl citrate, 1-2-ethylhexyl succinate, amyl acetate, acetic acid Ethyl, butyl acetate, isosecetyl stearate, butyl butyl stearate, diisopropyl sebacate, di-2-ethylhexyl sebacate, cetyl lactate, myristyl lactate, no. Isopropyl propyl noremitate, 2-ethylhexyl palmitate, 2-hexyldecyl panolemitate, 2-heptylpendyl decanoate / remitate, cholesteryl 2-hydroxystearylate, diester erythritol fatty acid ester, isopropyl myristate, There are octyldodecyl myristate, 1-2 myristate, hexyldecyl, myristyl myristate, hexyldecyl dimethyloctanoate, ethyl laurate, hexyl laurate, etc. The amino acid ^diesterol is ^ラウ -lauroylu L-glutamic acid 12-octyldo. Decyl esters, etc .; organic acid esters, such as diisostearyl malate; glycerides, acetoglyceride, triisooctanoic acid glyceride, triisostearin Acid glyceride, triisopalmitic acid glyceride, tri-2-ethylhexanoic acid glyceride, monostearic acid daliseride, G2-heptyl decanoic acid glyceride, trimyristate glyceride, and the like. Perfluoropolyether, perfluorodephosphorus, perfluorooctane, and the like. As siloxane compounds, dimethylpolysiloxane, ethynolemethylpolysiloxane, ethynolepolysiloxane, methinolehydrogen Polyether-modifying organopolyolefins such as polysiloxane, methylphenylpolysiloxane, dimethylsiloxane-methyl (polyoxyethylene) siloxane copolymer, and dimethylsiloxane-methyl (polyoxyethylene-polyoxypropylene) siloxane copolymer Siloxane, dimethyl siloxane monoalkoxy (4 to 12 carbon atoms) methyl siloxane copolymer, cyclic dimethyl polysiloxane such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, Fluoromethylsiloxanes Fluorine-modified organopolysiloxanes such as dimethylsiloxane copolymers, fluoromethylsiloxane / polyoxyethylene methylsiloxane copolymers and fluoromethylmethylsiloxane Fluoroalkyl such as xane polyoxyethylene polyoxypropylene methylsiloxane copolymer; polyoxyalkylene-modified organopolysiloxane; dimethylpolysiloxane-modified product with hydroxyl group at the end; and hydroxy with partial hydroxyl group at the side chain Methylsiloxane .Dimethylpolysiloxane copolymer and other terminals with terminal chain-modified organopoly>

Dimethylamino having dialkylaminoalkyl group in side chain

Modified aminoorganopolysiloxanes such as dimethylsiloxane polymer are exemplified. In order to use these silicone oils in a cosmetic composition, a silicone oil having a viscosity of 100,000 or less (mPa · s: 25 ° C) is usually selected. The compounding amount is 0.1 to 80% (based on the total amount), preferably 0.5 to 50%. There are various types of Frederance cosmetics depending on the purpose of use. Therefore, if necessary, furthermore, purified water, hot spring water, deep water, thickener, which is a component to be added to drugs, quasi-drugs, cosmetics, etc. , Pigments, humectants, astringents, whitening agents, UV inhibitors, anti-inflammatory Flame agents, skin (cell) activators, antibacterial agents, transdermal absorption enhancers, cooling agents, antioxidants, preservatives, chelating agents, anti-fading agents, buffers, etc. are optionally added. The present invention does not restrict the incorporation of these various additives within a range that does not hinder the intended effect. Examples of the thickening agent to be incorporated in the fragrance cosmetic of the present invention include gum arabic, tragacanth, galactan, carob gum, guar gum, karaya gum, carrageenan, pectin, agar, anoregue colloid, fucoidan, trant gum, locust bean gum, galata Plant-based macromolecules such as tomannan; Microbiological macromolecules such as xanthan gum, curdlan, dielan gum, fucogel, dextran, succinoglucan, pullulan, and sclerodium gum; animals such as chi1, sun, casein, albumin, and gelatin Starch-based polymers such as starch, carboxymethyl starch, and methylhydroxypropyl starch; methylcellulose, ethylcellulose, methylhydroxypropinolese / relose, canoleboximetinolose Relose, hydrid xymethinoreseno-relose, hydroxypropyl cellulose, nitrocellulose, cellulose sulfate, carboxymethyl cellulose cellulose sodium, crystalline cellulose, cellulose-based cellulosic polymer; sodium alginate, propylene alginate Alginic acid-based polymers such as recohol esters; vinyl-based polymers such as polybutyl methyl ether, carboxyvinyl polymers, and alkyl-modified carboxyl polymers; polyoxyethylene-based polymers; and polystyrene-polyoxypropylene copolymers Polymers: acryl-based polymers such as poly (sodium acrylate), poly (ethyl acrylate), poly (acrylamide), hydroxy (ethyl acrylate) acrylonitrile dimethyl tallin sodium copolymer Child: Polyethylene Minerals, cationic polymers, bentonite, laponite, inorganic water-soluble polymers such as hectolite, etc., organically modified dimethylbenzyl dodecyl ammonium montmorillonite clay, dimethyl dioctadecyl ammonium montmorillonite clay, etc. There are clay minerals. Among them, there are film forming agents such as polyvinyl alcohol and polyvinyl pyrrolidone, and one or more of these can be used. The dyes used in the present invention include, as organic synthetic dyes, azo dyes such as Yellow No. 5 and Red No. 105, xanthene dyes such as Red No. 21 and Red No. 230, Yellow No. 2 No. 4, quinoline dyes such as No. 4, Blue No. 1, etc., triphenylmethene dyes, Green No. 201, etc., anthraquinone dyes, Indigo dyes, etc., Red No. 202, Red No. 20 Lake pigments such as No. 8, Red No. 228, Red No. 226, Blue No. 404, etc. are carotene, calsamine and cochineal as natural pigments.

Examples of the humectant (component) to be blended in the present invention include mucopolysaccharides such as alkaline simple hot spring water, deep water, hyaluronic acid, chondroitin sulfate, dermatan sulfate, heparan sulfate, heparin and keratan sulfate. Proteins and their derivatives, such as salts, collagen, elastin, keratin, and their salts, phospholipids from soybeans and eggs, glycolipids, ceramides, mucins, honey, erythritol, maltose, maltitol, xylitole tonole, Xylose, pentaerythritol, fenolectose, dextrin and its derivatives, mannitol, sorbitole, inositol, trehalose, glucose and other sugars, urea, asparagine, aspartic acid, alanine, arginine, isoguchi isine, orchid Emissions, glutamine, glycine, glutamic acid and salts of derivatives thereof Narabiniso L et al., Cysteine, cystine, Shitonorerin, threonine, serine, tyrosine, DOO Amino acids such as liptophan, theanine, amino, phosphorus, histidine, hydroxylysine, hydroxyproline, pyrrolidone carboxylic acid and salts thereof, proline, phenylalanine, methionine, lysine, etc. and their derivatives or salts thereof, D-panthenol The plant extracts are raised. Plant extracts further include avocado extract, almond oil, carob extract, rice extract, rice extract, strawberry extract, fennel extract, usveniaoi extract, olive extract, olive oil, odricoso extract, cocoa butter , Oat extract, kizuta extract, kumazasa extract, gardenia extract, grapefruit extract, gennoshoko extract, gentian extract, burdock extract, kobotdul extract, sesame extract, cactus extract, sabonso extract Ginger extract, Zio extract, Shiba, Shimoke extract, Senkiyu extract, Zeniaoi extract, Tachijiakokoso extract, Camellia extract, Maize extract, Eucommia extract, Tormentilla extract, Dokudamimond extract Extract, Howe Citrus extract, Pigeon squirrel extract, Heart-strength extract, Midori-hatsu force extract, Saiha-hatsu force extract, Parsley extract, Barra extract, Castorium extract, Hinoki extract, Hetima extract, Brune extract , Butch Yards Bloom Extract, Borage Oil, Button Extract, Jojoba Oil, Bodaige Extract, Hops Extract, Pine Extract, Malonier Extract, Macadamia Nut Oil, Malmo Mouth Extract, Murasaki Extract, Meadow Home Oil, Melissa extract, Jaguramaso extract, lily extract, citron extract, lime extract, lavender extract, gentian extract, Lemoko extract, apple extract and the like. Alcohols such as yeast metabolites, yeast extract, rice fermented extract, rice bran fermented extract, euglena extract, lactic acid fermented product of raw milk 'skim milk powder, trehalose or derivatives thereof' Polyhydric alcohols such as ethanol and isopropyl alcohol Lono Nonole, Lauri Nole Norecole, Setano Nole, Stearyl Alcohol, Oleilua Natural alcohols such as norecol, lanolin alcohol, cholesterol monophosphate, and phytosterol; and synthetic alcohols such as 2-hexyldecanol, isostearinole alcohol, and 2-octynoledodecanol. Ethylene oxide, ethylene glycol, diethylene glycol, triethylene glycol, ethylene glycol, monoethylene monoethylene, ethylene glycol, monoethylene monoethylene, diethylene glycol monomethinooleate, ethylene glycol, monoethylene glycol Examples include tyl ether, polyethylene glycol, propylene oxide, propylene glycol, polypropylene glycol, 1,3-butylene glycol, glycerin, pentaerythritol, sorbitol, and mannitol. One or more of these moisturizing components are appropriately selected and blended. The amount of the moisturizing component varies depending on the type of the moisturizing component and cannot be determined uniformly, but is usually 0.5 to 20%. It is. Astringents (components) formulated in the present invention include zinc sulfocarbonate, sodium sulfocarbonate, and plant extracts. Plant extracts include Alniki, Hawthorn, Kina, Sanolevia, Podaiju, Panax ginseng, Toshiyou, Mannenrou, Otogiriso, Ichiyou, Melissa, Ononis, Malonier, Assembly, Garlic, Potato Mitsuru, Same, Hatsuzuki, Nettle, Capsicum, ginger, hops, horse chestnuts, lavender, carrots, mustard, kay, pine, senkyu, nittoco, yamazenri, shirodokokoko, button, yamamomo, dokudami, kohonone, shibugaki, tokkinsen, gibijinso grape Mabofu, Daidai, Yuzu, Shobu, Natsu Mikan, Nozuma Melis, Merry Rot, Fennel, Sansho, Shakuyaku, Yuryi, Namogi, Enmeiso, Rice, Clara, Shaw Iodide, Chiyouji, leaves Kunoremi, Ougon, sage, hop, rosemary, Otogirisou, hearts force, a force Mitsure, what neck Plant extracts include birds, orchid, huangbai, huangling, heavy medicine, cinnamon, ginseng, peony, tousin, propolis, taxa, tannin, hamamelis, button, birch tree tar, royal jellyfish, kobobex. As the astringent, one or more of these can be used. The amount used is usually 0.001 to 5 weight of the total amount of cosmetics. /. And preferably 0.01 to 3 weight. / ₀ . The whitening agents (components) to be formulated in the present invention include tyrosinase inhibitors, endothelin antagonists, MSH inhibitors, grabradine, grabrene, liquiritin, isoliquiritin, ellagic acid and its salts and derivatives, kojic acid and its salts Further, its derivatives, arbutin and its salts and derivatives thereof, cysteine and its salts and derivatives thereof, ascorbic acid, sodium ascorbate, ascorbine stearate, ascorbyl nonoremitate, ascorbyl dipalmitate, and ascorbate phosphate Vitamin Cs such as magnesium and their salts and derivatives, daltathione and its salts and their derivatives, resorcin and its salts and their derivatives, lusinol, neoagarobiose, agarose oligosa Kalai de, it includes the plant extracts such. Plant extracts include asparagus extract, Althea extract, Ibukitrano extract, Inchinko extract, Endo bean extract, Age extract, Odgon extract, Ononis extract, Seaweed extract, Fire spike extract , Kanzo extract, Rubus extract, Kujin extract, Brown sugar extract, Cake extract, Gokahi extract, Wheat germ extract, Saishin extract, Hawthorn extract, Sampens extract, Peony extract, Shirahuri extract Material, Sempukuka extract, Soybean extract, Soybean extract, placenta extract, Taranoki extract, Tea extract, Touki extract, Molasses extract, Neubara extract, Bialcane extract, Bu Dough seed extract, beech tree extract, Frodemah-Ita extract, hop extract, Myrica squid extract, mocca extract, Saxifraga extract, Yekoinin extract, Lohan fruit extract, etc. One or two or more are appropriately selected and blended. The compounding amount of the whitening agent component is usually 0.01 to 10%. When the plant extract or the like is used as it is, the amount is in terms of dry solid content. As the ultraviolet ray inhibitor (component) blended in the present invention, there are an organic compound type ultraviolet ray absorber and an inorganic compound type ultraviolet ray scattering agent, and the ultraviolet ray absorber includes a para-aminobenzoic acid type ultraviolet ray absorber, K-skin Acid-based UV absorbers, salicylic acid-based UV absorbers, benzophenone-based UV absorbers, etc., and one or more of these are blended. Para-aminobenzoic acid-based UV absorbers such as para-aminobenzoic acid, glyceryl para-aminobenzoate, ethylaminopropyl benzoate, amyl para-dimethyl para-aminobenzoate, octyl para-methyl para-aminobenzoate, and para-amino benzoate There are acid ethyl, isoaminopropyl paraaminobenzoate, and the like. As the cinnamic acid ultraviolet absorber, isopropyl paramethoxy citrate, diisopropyl cinnamate, methoxy citrate octyl, dipara methoxy citrate mono, 2-ethyl, etc. There are glyceryl xanate and the like. Examples of salicylic acid-based UV absorbers include homomenthyl salicylate, octyl salicylate, phenyl salicylate, ethanolamine salicylate, amyl salicylate, benzyl salicylate, There are p-tert-butyl salicylate, ethylene glycol salicylate, salicylic acid, etc. Examples of benzophenone UV absorbers include dihydroxybenzophenone, tetrahydroxybenzophenone, oxybenzone, oxybenzonesulfonic acid, and hydroxymethoxy. Benzophenone sodium snolefonate, di Hydroxydimethoxybenzophenone, 2-hydroxycyclomouth benzophenone, dioxybenzone, dihydroxydimethoxybenzobenzophenone sodium disonolephonate, 2-hydroxy-4-methoxy-4 'methinobenzobenzophenone, octavenzone, etc. In addition, there are other acids such as perocanic acid, ethyl perocanate, 4-tert-4'-methoxydibenzoylmethane, 2- (2'-hydroxy-5,1-methylphenyl) benzotriazole, and anthranilic acid. Inorganic compounds used as ultraviolet scattering agents include titanium oxide, zinc oxide, cerium oxide, zirconium oxide, iron oxide and the like. Anti-inflammatory agents (components) include zinc oxide, zeolite and its derivatives, glycyrrhizic acid and its derivatives such as glycyrrhizic acid, dikalym glycyrrhizinate, and monoammonium glycyrrhizinate, and their derivatives, and salts thereof. —Glycyrrhetinic acid, stearyl glycyrrhetic acid, 3 Glycyrrhetinic acid and its derivatives such as disodium succinyloxyglycyrrhetinate and their salts, tranexamic acid, chondroitin sulfate, mefenamic acid, fenirbutazone, indomethacin, ibuprofen, ketoprofen, allantoin, guaiazulene and their derivatives and their derivatives And extracts of various microorganisms and animals and plants.

Skin (cell) activators (components) that can be used include deoxyribonucleic acid and its salts, adenylic acid derivatives such as adenosine triphosphate and adenosine-phosphate and their salts, ribonucleic acid and its salts, cyclic AMP, and cyclic AMP. Click GMP, flavin adenine nucleotides, guanine, adenine, cytosine, thymine, xanthine and their derivatives, caffeine, theopherin and its salts, retinol and retino palmitate , Retinol derivatives such as retinol acetate, retinal derivatives such as retenal and dehydroretinal, carotenoids such as carotene and vitamin A, thiamine and thiamine salts such as thiamine hydrochloride and thiamine sulfate, riboflavin and Riboflavin salts such as riboflavin acetate, pyridoxine salts such as pyridoxine and pyridoxine hydrochloride, pyridoxine syndiooctanoate, flavin adenine nucleotides, cyanocobalamin, folic acids, nicotinic acid and nicotinic acid amide, nicotinic acid Nicotinic acid derivatives such as benzil, vitamins B such as cholines, V-linolenic acid and its derivatives, eicosapentaenoic acid and its derivatives, estradiol and its derivatives and their salts, glycolic acid, succinic acid, and milk Organic acids such as acid and salicylic acid, derivatives thereof, and salts thereof. Antibacterial agents (components) include benzoic acid, sodium benzoate, phenolic acid, sorbic acid, potassium sorbate, paraoxybenzoic acid ester, parachloromethcresol, hexaclofenphen, benzalkonidium chloride, salidrochlorhexidine, trichloro Canole vanilide, photosensitizer, bis (2-pyridylthio-1-oxide) zinc, phenoxyethanol and thiantol, isopropylmethylphenol and the like. Antioxidants (components) include vitamin A such as retinol, dehydroretinol, retinol acetate, retinol palmitate, retinal, retinoic acid, vitamin A oil and their derivatives and salts thereof, carotene, β-carotene, β —Rikokuten, γ-Rikokuten, carotenoids such as cryptoxanthin, astaxanthin, fucoxanthin, and derivatives thereof, pyridoxine, pyridoxal, pyridoxal-5-phosphate Vitamin Bs such as steru and pyridoxamine, their derivatives and their salts, vitamin Cs such as ascorbic acid, sodium ascorbate, ascorbyl stearate, asconolevir palmitate, asconolevir dipanolemitinate, and magnesium phosphate ascorbate; Vitamin Ds such as derivatives and salts thereof, ergocalciferol, cholecalciferol, 1,2,5-dihydroxy-cholecalciferol, derivatives and salts thereof, α-tocopherol, Tocophere, γ-tocophere, δ-tocophere, Hi-cole trienole, / 3-tocotrienole, γ-tocotrienol, δ-tocotrienole, tocopherol acetate, Vita such as nicotinic acid Minerals, their derivatives and their salts, trolox, their derivatives and their salts, dihydroxytoluene, butylhydroxytoluene, butynoledroxyloxyanisole, dibutylhydroxyloxytoluene, α-lipoic acid, dehydrolipoic acid, glutathione , Its derivatives and their salts, erythorbic acid such as uric acid, erythorbic acid, and sodium erysorbate; their derivatives and their salts; gallic acid such as gallic acid and propyl gallate; their derivatives and their salts; rutin; Rutin such as syruletin, its derivatives and their salts, tryptophan, its derivatives and their salts, histidine, its derivatives and their salts, acetylacetylcysteine, acetylinolehomocystein, and octanoinoinole System Cysteine derivatives such as methine, acetylacetonyl tin methyl ester and their salts, cystine derivatives such as Ν, N'-diacetyl Ν, N'-dioctanoyl homocystine dimethyl ester and their salts, carnosine and their salts Derivatives and their salts, homocarnosine and its derivatives and their salts, anserine and its derivatives and their salts, calcinin and its derivatives Derivatives and salts thereof, histidine and Z or tryptophan and / or histamine, diptide or tripeptide derivatives and salts thereof, flavanone, flavone, anthocyanin, anthocyanidin, flavonol, quercetin, quercitrin, myricetin, ficetin, Flavonoids such as hamamelitannin, catechin, epicatechin, gallocatechin, epigallocatechin, eppicatechin gallate, epigallocatechin gallate, tannic acid, caffeic acid, ferulic acid, protocatechuic acid, chalcone, olizanore, and horenorenore Sesamornole, sesamin, sesamorin, zingerone, kunorecumin, tetrahydrodrotanorecmin, clobamide, deoxycyclobamide, ginger, capsaicin Vanillyl amide, ellagic acid, bromphenol, flavonoglasin, melanoidin, riboflavin, riboflavin butyrate, flavin mononucleotide, flavin adenine nucleotide, ubiquinone, ubiquinol, mannitol, bilinolebin, cholesterol, selenomethine, selenomele Plasmin, transferrin, ratataferin, labmin, superoxide dismutase, tytalase, gnoletathione peroxidase, meta-mouth thionein, diphosphonopyridoxylidene rhodamine, and US Pat. No. 5,594,0 12. N- (2-Hydroxyxybenzyl) amino acids, derivatives and salts thereof, and N- (4-pyridoxylmethylene) amino acids, and derivatives and derivatives thereof according to 12. Etc. may be mentioned salts, the content of antioxidants is depends on the type of antioxidants, but not uniformly determined, it is usually 0.0 1-1 0%. When a plant extract or the like is used as it is as an extract, it is the amount of dry solid content conversion. The method for preparing the Frederance cosmetics of the present invention is not particularly limited. Can be prepared by known methods. For example, in the case of a liquid Frederance cosmetic or lotion, the polysaccharide of the present invention is dissolved in water (purified water), and then the fragrance and the surfactant are dissolved with stirring to obtain a glitter pigment. It is obtained by adding a solvent (such as ethanol) in which is dispersed.

 When the fragrance cosmetic of the present invention is solubilized by incorporating a lipophilic component into a hydrophilic component, water (purified water) is added to the polysaccharide, the brilliant pigment, other aqueous components, etc. of the present invention to obtain 70%. Heat to 70 ° C to form an aqueous liquid, while adding surfactants, fragrances, and other oily components, and heat to 70 ° C to make an oily liquid. The oily liquid is added and stirred while stirring, and after cooling, a solubilized liquid is obtained.

 Further, the fragrance cosmetic of the present invention contains a hydrophilic component in a lipophilic component and solubilizes the same, and further disperses the hydrophilic component in the hydrophilic component, or includes a lipophilic component in a hydrophilic component and becomes solubilized. Fredrance cosmetics dispersed in an oil component, microcapsule type cosmetics, nanoemulsion nanosuspension type cosmetics in which the size of oil droplets or glitter pigments is less than 1 μm may be used.

When the hydrophilic component is included in the lipophilic component to be solubilized and further dispersed in the hydrophilic component, a gel is formed from a gel-forming substance such as polyhydric alcohols and a lipophilic surfactant, and the gel is hydrophilic. After the hydrophilic component is encapsulated with the lipophilic component from the aqueous phase containing the hydrophilic core substance and the oil component and solubilized, the solubilized component is dispersed in the external aqueous phase containing the hydrophilic film-forming substance. A type of Frederansi dermocosmetic in which a hydrophilic component is contained in a lipophilic component, solubilized, and further dispersed with a hydrophilic component in which a glittering pigment is dispersed is obtained. Further, an oil phase (inner oil phase) and an aqueous phase in which a hydrophilic polymer gelling agent is dissolved in advance by heating are mixed at a temperature not lower than the solidification temperature of the gelling agent, and the minute lipophilic component is converted into a hydrophilic component. In the oil phase (external oil The microcapsule-type fragrance cosmetic is obtained by dispersing it in the phase) together with the glitter pigment. Alternatively, an oil phase and an aqueous phase (inner aqueous phase) in which a hydrophilic polymer gelling agent is dissolved in advance by heating are mixed at a temperature equal to or higher than the solidification temperature of the gelling agent, and the minute hydrophilic component is converted into a lipophilic component. By enclosing, dispersing, and dispersing this in an aqueous phase (outer aqueous phase) together with a brilliant pigment, a microcapsule type fragrance cosmetic can be obtained.

 As a device used for solubilizing or dispersing a fragrance or an oily component of the Frederance cosmetic of the present invention, a mount gouring homogenizer, a micro-fluidizer, a high-pressure homogenizer, a nanomizer, and the like are used. Hereinafter, the present invention will be described in detail with reference to Examples, but the present invention is not limited thereto.

 [Polysaccharide used for test]

• A—1: Alligne lignes retoras B—Polysaccharide produced by 16 strain bacteria (crude product) Glucose (reagent, manufactured by Wako Pure Chemical Industries, Ltd.) 40.0 g, dipotassium hydrogen phosphate [Wako Pure Chemical Industries Reagent] 4.0 g, potassium dihydrogen phosphate [Wako Pure Chemical Industries, Ltd., reagent] 2.0 g, sodium salt [Reagent], Wako Pure Chemical Industries, Ltd. 1 g, magnesium sulfate [reagent, manufactured by Wako Pure Chemical Industries, Ltd.] 0.2 g, potassium nitrate [reagent, manufactured by Wako Pure Chemical Industries, Ltd.] 1.0 g, yeast extract [OX OID 1.5 g was dissolved in ion-exchanged water, adjusted to pH 6.5 with sodium hydroxide or sulfuric acid, and the total amount was adjusted to 1 liter. 15 OmL of this aqueous solution was placed in a 500 mL Erlenmeyer flask, sterilized by heating in an autoclave (121 ° C, 15 minutes), returned to room temperature, and Alkali Genestras B-16 (FERM BP-20 No. 15) was inoculated with one loopful, and cultured with shaking (180 rpm) at 30 ° C. for 6 days. After cultivation, add about 3 times the volume of isopropyl alcohol to the culture, stir and mix, filter, collect and precipitate the precipitated aggregates and dry them under reduced pressure. Polysaccharide (A-1) was obtained. This polybranche is mainly composed of a polysaccharide composed of fucose, glucose, dalcuronic acid, and rhamnose in a molar ratio of 1: 2: 1: 1, and is composed of fucose and mannose in a molar ratio of 1: 1. And its abundance ratio is 7: 1 (weight ratio). The constituent monosaccharides were analyzed by high performance liquid chromatography (HP LC) after hydrolyzing the polysaccharides with sulfuric acid.

 • A—2: A refined product of A-1 above

 Polysaccharides: 0.5 weight of A_1. /. An aqueous solution was prepared, and the pH was adjusted to 12 with an aqueous sodium hydroxide solution. This aqueous solution is treated with a column of an ion exchange resin “Diaion HP A-75 (OH—) (trade name)” (manufactured by Nippon Shusui Co., Ltd.) at 8 Ri or less, and further filtered. Radiolite RL 700 ”and a 5 μπι membrane filter were used to remove proteins, nucleic acids, and microorganisms. The filtrate was concentrated under reduced pressure after diluting hydrochloric acid to ρΗ7, and acetone was added to precipitate a polysaccharide. The precipitate was further washed with 10 times the amount of acetone, and fucose: glucose: glucuronic acid: rhamnose = ι; : 1: 1 polysaccharide (Α-2) with a molecular weight of 50 million was obtained.

 Α— 3 Alkasylan (Raw material: Alcaligenes-producing polysaccharide, INC Iname: AlcallegenesPolysaccharides, manufactured by Hakutosha) (polymer)

• B-1: (Used in Comparative Examples) Xanthan gum [Kerzan-cho (trade name) manufactured by Sansei Corporation] • B-2: (Used in Comparative Examples) Polyacrylic acid [Carbopol 980 (trade name) manufactured by Nikko Chemicals Co., Ltd.]

 • B-3: Sucre mouth titanium gum [Tinocare GL (product name), manufactured by Ciba Charity Service Co., Ltd.]

 (Fragrance)

 • C-1: Orange oil (Yashara Chemical Co., Ltd.)

 • C-2: Mint blended fragrance [Nagaoka Jitsugyo Co., Ltd.]

 • C—3: Perfume oil [Alisa Ashleimsk J (trade name), manufactured by Ida Laboratories Co., Ltd.]

 (Brilliant pigment)

 • D-1: Anoremi Flake Pigment [Hori Kinfoil Powder Co., Ltd.]

 • D-2: Polyester film powder [Hayashi Textile Co., Ltd., “Polyester Grit Ichi” (brand name)]

 • D—.3: Glass flake pigment [Nippon Sheet Glass Co., Ltd., “Metashine” (brand name)]

 D-4: Iron oxide (red) (Aoi Kasei Co., Ltd.)

 D-5: Iron oxide (yellow) (Aoi Kasei Co., Ltd.)

 D-6: Iron oxide (black) (Aoi Kasei Co., Ltd.)

 D—7 ··· Shi-Dai Zinc (Kanto Chemical Co., Ltd.) '· D-8: Kaolin (Kanto Chemical Co., Ltd.)

 D-9: Talc (Nikko Chemicals Co., Ltd.)

D-10: Titanium dioxide (Kanto Chemical Co., Ltd.) D-11: Caic anhydride (Kanto Chemical Co., Ltd.)

 D-12: Nylon powder (manufactured by Toray Industries, Inc.)

 D-13: Red No. 201 (Nikko Chemicals Co., Ltd.)

 D-14: Red No. 202 (Nikko Chemicals Co., Ltd.)

 D-15: Red No. 223 (Nikko Chemicals Co., Ltd.)

 D-16: Pearl pigment (Nikko Chemicals Co., Ltd.)

 D-17: Ultramarine (Nikko Chemicals Co., Ltd.)

 D-18: Mica (Nikko Chemicals Co., Ltd.)

 (Surfactant)

 E-1: Sucrose fatty acid ester “L-160” (trade name) (Daiichi Kogyo Pharmaceutical Co., Ltd.)

• E—2: Polyglycerin fatty acid ester “〇 一 15D” (trade name) (manufactured by Mitsubishi Chemical Corporation)

 • E-3: Polyoxyethylene (addition of 100 moles) Hardened castor oil "E-HC-100" (trade name) (Nippon Emarzion Co., Ltd.)

 • E-4: Polyoxyethylene (23 mole addition) lauryl ether [Kanto Chemical Co., Ltd., reagent]

 • E-5: Jojoba wax polyethylene glycol (addition of 120 moles) Esthenore "FR〇RAS〇LVS" (trade name) [FRORATECH Co. Ltd.]

 (Solvent)

• F-1: Ethanol [Kanto Chemical Co., Ltd., reagent] • F—2: Glycerin (Kanto Chemical Co., Ltd., reagent)

 • F—3: Dipropylene glycol [Kanto Chemical Co., Ltd., reagent]

 • F-4: 1,3-butylene glycol [Kanto Chemical Co., Ltd., reagent]

 (Preservative)

 · G-1: Methyl paraoxybenzoate [Kanto Chemical Co., Ltd., reagent]

 • G-2: phenoxyethanol (Lion Co., Ltd.), phenoxyethanol S (trade name)]

 [Preparation of Audeco mouth 1: small amount of glitter pigment added type]

 To 54.74 g of purified water, 0.05 g of B-16 polysaccharide (A-1) was added, and the mixture was stirred and dissolved with a small homomixer to obtain a mixture 11. Separately, 30 g of ethanol (F-1), 5 g of glycerin (F-2), 0.1 g of preservative methyl paraoxybenzoate (G-1), and sucrose fatty acid ester of surfactant (E-1 5) and 5 g of perfume (C-1) were added sequentially, and the mixture was stirred and dissolved until there was no insoluble matter, to obtain a mixture 12. While stirring the mixture 1-1, the mixture-2 was added and stirred until the mixture became solubilized. While stirring, 0.1 g of the brilliant pigment (D-1) was calorie to obtain a uniformly dispersed auto-deco mouth 1. Then, the viscosity was measured with a rotational viscometer (20 ° C, 60 rpm, measured 1 minute after the start of measurement). In the same manner, Examples 2 to 7 and Comparative Examples 1 to 9 of fragrance cosmetics having the blending components (%) shown in Table 1 were obtained. [Preparation of fragrance lotion 1: a large amount of bright pigment added]

Nos. 4 to 6 and 11 were uniformly dispersed in compounding components Nos. In addition, Nos. 7 to 10 were added to No. 12 and mixed and dissolved to obtain a mixture 4. Mix mixture 4 拌下, mixture 3 was added, and homogenized to obtain a fragrance lotion one 1 _c

(No.) (Blend ingredients)

 1. Ethano 1 500

 2. Glycerin 200

 3. 1, 3-butylene glycolone 200

 4. Iron oxide (D-4) 0 1 5

 5. Zinc oxide (D-7) 0 50

 6 Power Olin (D-8) 200

 7 B—16 polysaccharide (A-3) 0 05

 8 0 20

 9 Pheno 1 0 02

 10 Paraaminobenzoic acid ester 0 10

1 1 Mint-based blended fragrance (C-1 2) 0 1

 12. Purified water 77 88

[Preparation of Fragrance Lotion 2: High Brightness Pigment Addition Type]

 Nos. 4 to 6 and 13 were uniformly dispersed in the components No. 1 to 3 to obtain a mixture 5. In addition, Nos. 7 to 12 were mixed and dissolved in No. 14 to obtain a mixture 6. While the mixture 6 was stirred, the mixture 5 was added to make the mixture uniform to obtain a fragrance lotion-12.

(No.) (Ingredients) (% by weight)

1. Ethanol 4.00

2. Glycerin 4.00

3. 1,3-butylene glycol cornole 2.00 4. Iron oxide (D-4) 0.15 5. Zinc oxide (D-7) 0.50

6. Power Olin (D-8) 2.00

7. B-16 polysaccharide (A-3) 0.05 8. Camphor 0.15

 9. Phosphorus ascolenolate Rooster Magnesium 3.00

 0. Cuenoic acid 1.00

 1 1. Sodium hydroxide

 1 2. Para-aminobenzoic acid ester 0.10

 1 3. Mint-based fragrance (C-1 2) 0.1

 4. Deep Ocean Water 00

[Preparation of fragrance lotion-3 <Glitter type pigment added>]

 No. 7 of fragrance lotion 1 1: B-16 polysaccharide (A-3) 0.05% was replaced with polyacrylic acid (B-2) 0.05%,

Prepared in the same way as Lotion 1 to obtain Fragrance Lotion 1-3

[Preparation of Frederance Lotion 4 Oil-rich type>]

 Nos. 10 and 11 were added to the compounding component No. 16, and the mixture was stirred and dissolved with a small homomixer to obtain a mixture 7. In addition, Nos. 1 to 5, 7 to 9, and 12 to 14 were sequentially added to the blending component No. 6, and the mixture was stirred and dissolved until there was no insoluble material, thereby obtaining a mixture 8. While stirring the mixture 7, the mixture 8 was added, and the mixture was homogenized and dissolved until it was in a solubilized state, and then No. 15 was added thereto to be uniformly dispersed to obtain a fragrance lotion 14.

 (No.) (Blend ingredients)

 1-Stearic acid 2.00

 2. Cetyl alcohol 1.00

3. Pserin 5.00 4. Dimethylsiloxane 2.00

 5. Liquid paraffin 5.00

 6. Ethanore 20.00

 7. Glyceryl monostearate 1.00

 8. Polyoxyethylene (25 mole addition) Monoolate 1.00

 9. Sucrose fat residual ester 5.00

 10. Polyethylene glycol 1500 5.00

 1 1. B-16 polysaccharide (A-3) 0.10

 1 2. Titanium dioxide (D_10) 5.00

 1 3. Octyl paramethoxycinnamate 3.00

 14. Perfume Oinore (C-1 3) 0.50

 1 5. Phenoxy ethanol

 16. Purified water 44. 30 [Preparation of fragrance lotion 1-5 containing oil

 The blending components Nos. 8 to 15 and 17 were mixed to form a mixture 9. In addition, the ingredients No. 1 to 7 and 16 are mixed by heating, and kept at 70 ° C to obtain a mixture 10.The mixture 10 is solubilized while stirring the mixture 9 with a small homomixer, and then cooled to room temperature. And got Fragrance Lotion 5

 (No.) (Ingredients) (% by weight)

 1,3-butylene glycol cornole 5.00

2. Polyoxyethylene (addition of 60 mol) Sorbito tetraole, 1 5.00

 3. Glycerinolemonosteale 1.00

 4. Stearic acid 0.50

 5. Bené Nore "Noreko ^" Nore 0.50

 6. Squalane 8.00

 7. Isopropyl propyl citrate 0.50

 8. B-16 polysaccharide (A-3) 0 10

 9. Magnesium phosphate asconolevic acid salt 5 00

 10. Cuenoic acid 50

 1 1. Titanium dioxide (D-10) 500

 12. Paraoxybenzoate 0 10

 1 3. Ripoxyvinyl polymer 0 10

 4. Sodium hydroxide 0 05

 15. Glycerin 5.00

16. Orange oil (C-1) 0.05

 1 7.Purified water 57.60

(Fragrance; Preparation of K water one 6)

N 0.8 of fragrance lotion 1-5: 0.1% of B-16 polysaccharide (A-3) and 9.9% of purified water were replaced with 10% of screech gum (B-3). Mixing components Nos. 8 to 15 and 17 were mixed to form a mixture 11. Also, heat the ingredients Nos. 1 to 7 and 16 and mix them at 70 ° C to obtain a mixture 10, and mix the mixture 9 with a small homomixer. W

When the mixture 12 was added with stirring, the whole was emulsified and insoluble, and a fragrance lotion 16 which became an emulsion was obtained.

(Preparation of Frederance Water Foundation 1)

 The components No. to 11 and 19 were mixed and dissolved to form a mixture 13. Also, No. 20

: No. 17 B 6 Polysaccharide (A-3) was dissolved in an aqueous solution of homogenizer with No.

12-: I6 and No. 18 were added, and mixed, dissolved and stirred. Mixture 13 was mixed with this aqueous solution and homogenized to obtain a fragrance water foundation 11.

 (N o.) (Blend component)

 1. Lanolin 00

 2. Liquid paraffin 00

 3. Stearic acid 00

 4. Setano One 00

5. 1-Ethylhexyl paramethoxycinnamate 00

 6. 4—t—butyl-4′-methodidine 00

 7. Glycerin 500

 8 3—butylene glycol 5 00

 9. Polyoxyethylene (addition of 60 mol) Sonorebit

 15.00

10 Lietano noreamine 1.00

 11. Sucrose fat residual ester 5.00

2. Canoleboximetinoresenorelose 0.10 3. My strength (D-18) 15.00

 14. Talc (D-9) 6.00

 15. Iron oxide (D-4) 1.50

 14. Iron oxide (D-5) 4. 20

 16. Iron oxide (D-6) 0.60

 1 7. B-16 polysaccharide (A-3) 0.05

 18. Jokinin extract 0.50

 1 9. Orange oil (C-1) 0.05

 20. Purified water 26. 00

.T.-Preparation of 1)

 No. 17 of the fragrance water foundation 1 No. 17: B- 16 polysaccharide (A-3) 0.05% and purified water 0.45% xanthan gum (B-1) 0.5

Replaced with a 0%, Nra "A Deployment - and was prepared in the same manner, the full Chillon one 2 ^ = was _£

-1 Preparation of bright pigments with a large amount added>)

Nos. 3 to 7 and 10 were uniformly dispersed in compounding components Nos. 1 and 2 to obtain a mixture 14. _c . Nos. 8, 9, and 11 were mixed and dissolved to obtain a mixture 15. While the mixture 15 was stirred, the mixture 14 was added to make the mixture uniform, and a Frederance wilt 11 was obtained.

 (No.) (Ingredients) (% by weight)

1. Glycerin 4.00 2. 1, 3-butylen glycolone 4.00

 3. Iron oxide (red) (D-4) 0.50

 4. Iron oxide (yellow) (D-5) 1.40

 5. Iron oxide (black) (D-6) 0.20

 6. Power Olin (D-8) 5.00

 7. Titanium dioxide (D_ 10) 5.00

 8. Paraoxybenzoic acid mouth pill 0. 10

 9. B-16 polysaccharide (A-3) 0.06

10. Orange oil (C-1) 0.05

1 1. Purified water 79. 69

Preparation of 1 and 2 <Large amount of bright pigment>

 Ingredients Nos. 9 to: Nos. 1 to 8 were uniformly dispersed in parts of 12, 16 and 17 to obtain mixture 16. In addition, Nos. 13 to 15 and 17 were mixed and dissolved to obtain a mixture 17. While the mixture 17 was stirred, the mixture 16 was added to make the mixture uniform, and Frederanth's powdered 1-2 was obtained.

(No.) (Ingredients) (% by weight)

 1. Talc (D-9) 4.00

 2. Power Olin (D-8) 4.00

 3. Titanium dioxide (D_ 10) 4.00

4. Iron oxide (D-4) 1.00 5. Iron oxide (D-5) 3.00

 6. Iron oxide (D-6) 0.20

 7. Nylon powder (D-1 2) 2.00

 8. Caic anhydride (D—11) 00

 9. Ethanol 6 00

 0. Glycerin 2 00

 Dipropylene glycol 200

 2. 1, 3-butylene glycol cornole 200

 3. B-16 polysaccharide (A-3) 0 08

 14. Kojic acid 400

 1 5. Phenoxyethanol 0 20

 16. Orange oil (C-1) 0 05

1 7. Deep-sea water 64 47

 No. 13 of the fragrance ingredient 1 No. 13: Replace B- 16 polysaccharide (A-3) 0.06% and deep seawater 0.34% with xanthan gum (B-1) 0.40% The rest was prepared in the same manner as in Fredlans Insulin-1 4 to obtain the fragrance Insulin-1 3.

-Preparation of a large amount of bright pigments

Ingredients N o. 1, 2, 3 , 8 were uniformly dispersed in No. 4, 5, and a mixture 1 8 _t Nos. 6, 7, and 9 were mixed and dissolved to obtain a mixture 18. While stirring the mixture 19, the mixture 18 was added to make the mixture uniform, and a Frederance Airliner 111 was obtained.

 (No.) (Components) (Weight /.)

 1. Iron oxide (black) (D-6) 4.00

 2. Titanium dioxide (D-10) 5.00

 3. Pearl pigment (D-16) 0.20

 4. Etano 1 4.00

 5. Glycerin 6.00

 6. B—16 Poly bran (A— 3) 0.08

 7. Phenoxyethanol 0.15

 8. Orange oil (C-1) 0.05

 9- Preparation of purified water 80.52

 Nos. 1, 2, 3, and 8 were uniformly dispersed in Nos. 4 and 5 to obtain a mixture 20. Further, Nos. 6, 7, and 9 were mixed and dissolved to obtain a mixture 20. While the mixture 21 was stirred, the mixture 20 was added thereto to make the mixture uniform, thereby obtaining Airiner '^ 12.

 (No.) (Blend ingredients)

 1. Ultramarine (D— 1 7) 0.50

 2. Titanium dioxide (D-10) 5.00

 3. Pearl pigment (D-16) 0.20

4 Etano 1 4.00 5. Glycerin 6.00

6. B-16 polysaccharide (A-3) 0.08

 7. Phenoxyethanol 0.15

 8. Orange oil (C-1) 0.05

 9. Purified water 84.02 3 Preparation of brilliant pigment large quantity type>]

No. 6 of the components of Frederance Eyeliner: B-16 polysaccharide (A-3)

Without the addition of 08% 0., other f - ^ one 1 Similarly was prepared, Fureda lance eye liner 3 The resulting _c Mao Beniichi 1 Preparation rather bright pigment addition of a large amount type>]

 Compound components Nos. 1 to 4 and 9 were uniformly dispersed in some of Nos. 5, 6 and 10 to obtain mixture 21. Nos. 7, 8, and 10 were mixed and dissolved to obtain a mixture 22. While the mixture 22 was being stirred, the mixture 21 was added to make the mixture uniform, and a fragrance Hokuni 1 was obtained.

(No.) (Blend component)

 1. Power Olin (D-8) 0.00

 2. Titanium dioxide (D-10) 2.00

 3. Iron oxide (red) (D-4) 0.20

 4. Red No. 202 (D-14) 0.30

 5. Ethanosole 4.00

6. Glycerin 4.00 7. B 6 Poly bran (A-3) 0.10

8. Phenoxy Ethanore 0.15

 9. Mint-based blended fragrance (C-1 2) 0.05

 10. Purified water 79.20 A large amount of brilliant pigment added to Mao Benichi 2>] Compounding components Nos. 1 to 7 are evenly dispersed in parts of Nos. 8, 9, 12, and 13 23. Nos. 10, 11, and 13 were mixed and dissolved to obtain a mixture 24. While the mixture 24 was stirred, the mixture 23 was added thereto, and the mixture was homogenized to obtain cheek red 12.

 (o.) (Ingredients)

 1. Power Olin (D-8) 0.00

 2. Titanium dioxide (D-10) 2.00

 3. Iron oxide (red) (D-4) 0.20

 4. Red No. 201 (D-13) 0.30

 5. Red No. 202 (D-14) 1.50

 6. Red No. 223 (D—15) 0.02

 7. Pearl pigment (D-16) 0.01

 8. Ethanor 4.00

 9. Glycerin 4.00

10. B— 16 Polysaccharide (A— 1) 0.08

 . Phenoxyethanol 0.1 5

2. Perfume oil (C-1 3) 0.05 3. Remaining amount of purified water to be 100. A lot of brilliant pigments, which are prepared by adding reddish cheek 3 >>Frederance's No. 7 of the components of reddish cheek 1: B-16 polysaccharide (A_3) 0.1 0% Was replaced with 0.1% of polyacrylic acid (B-2), and the other conditions were adjusted in the same manner as Fredlans Cheongsam 1 to obtain Fredlans Chenbin 3.

[Preparation of Frederance Jiel-1 <WZ O ZW type composite dispersion type>]

 A mixture of the components Nos. 10, 11 and 14 (10% by weight) and the components Nos. 1 to 3 were mixed by paddle stirring at room temperature to form a viscous gel. Next, the ingredients Nos. 4 to 7, 12, and 13 are sequentially added to the viscous gel, and the peripheral speed of the blade tip is 5 mZs, 60 ° using a homomixer (Special Kika Co., Ltd.). Stir for 30 minutes until the particle size of the core (W) becomes 0.5 μηι with C to prepare the solubilized substance contained in the WZ〇 type, and then mix the premixed ingredients No. 8, 9 and Add this mixture to No. 14 and stir at the tip of the blade at a peripheral speed of 3 m / s and 60 for 10 minutes using the paddle stirring described above. This WZO / W composite solubilized fragrance gel Got one.

 (No.) (Blend component)

 Polyoxyethylene (40 calories with mono) Monostearate 2.00

 2. Glycerin monostearate 5.00

 3. Behino alcohol 0.50

 4. Stearic acid 3.00

5. Squalane 5.00 6. Cetyl isooctanoate 5.00 7. Paraoxybenzoate 0.10

 8. 1, 3-butylene glycol 5.00

 9. B-16 polysaccharide (A-3) 0.08

 0.Indomethacin 0.50

 Hyanole humic acid 0.001

 12. Orange oil (C-1) 0.001

 13. Titanium dioxide (D-10) 2.00

 4 Purified water 71.818

[Preparation of fragrance jewel 2 W / OZW type microphone mouth capsule>]

 The internal aqueous phase in which the components Nos. 1 to 4 were mixed was gradually added to the oil phase in which the Nos. 5 to 8 were uniformly dissolved to obtain a solubilized product contained in the WZO type. Next, about 50 of an aqueous agar solution obtained by heating and dissolving compounding component No. 9 in a part of No. 12 at about 90 ° C. Cooled to C. An aqueous agar solution was added to the solubilized substance heated to 50 ° C. with stirring to obtain a solubilized substance (average particle diameter 0.5 m) encapsulated in WZO type. This soluble material was previously mixed uniformly, added to the solubilized material of No. 10 to 12 kept at 50 ° C., and stirred at 500 rpm to prepare a W / OZW type dispersion. This is gradually cooled to room temperature, and the aqueous phase agar is solidified to obtain a microcapsule oil-based dispersion, Frederans Jr. 2 (capsule average particle diameter 100 μm, encapsulated oil droplet average particle diameter 0. 5 μΐ).

 (No.) (Ingredients) (% by weight)

1.1,3-butylene glycolonole 0.00 2. Polyoxyethylene (60 calories with mono) Hard castor oil 1.00

 3. Indomethacin 0.50

 4. Hyanore Mouth Rooster Odds 0.001

 5. Orange oil (C1) 5.00

 6. Dioctyl senocate 15.00

 7. POE methinorepo, ricillo'xane copolymer 1.00

 8. Octamethinolecyclotetrasiloxane 5.00

 9. Agar 0.50

 10. B-16 polysaccharide (A-3) 0.20

 11. Titanium dioxide (D-10) 2.00

 12. Purified water 59.799

[Preparation of fragrance Jeru 3 OZWZO type microphone mouth capsule]

The inner oil phase, which is a mixture of the components No. 1 and No. 2, was gradually added to the mixture of No. 3 and No. 467 to obtain a solubilized product included in the OZW type. Next, the blended component N 0.5 was heated and dissolved at 90 ° C. in a part of No. 8 to prepare an aqueous agar solution, which was cooled to 50 ° C. An aqueous agar solution was added to the solubilizate heated to 50 ° C. with stirring to obtain a solubilizate incorporated in the O / W dispersion (average particle size 0.5 zm). This solubilized product was added to the external oil phase in which the ingredients Nos. 9 and 10 were mixed, and the mixture was stirred at 500 rpm to prepare an O / W / O emulsion. This is gradually cooled to room temperature, and the agar in the aqueous phase is solidified to form a microcapsule oil-based dispersion, Fragrance Gero 3 (capsule average particle diameter 100 / xm, encapsulated oil droplet average particle diameter 0.5 μΐΏ). Got. (No.) (Blend component)

 Orange oil (C-1) 5.00

 2. Dioctyl sebacate 5.00

 3. 1, 3-butylene glycolone 10 00

 4. POE (addition of 60 moles)

 5. Agar 00

 6. B-16 polysaccharide (A-3) 0 08

 7. Titanium dioxide (D-10) 200

 8. Purified water 5 92

 9. POLYOXE: ^ Copolymer 1.00

 10. Otatamethylcyclotetrasiloxane 49.00 Preparation of nano-sized solubilizing solution O / W type nano-sized solubilizing type>] Heat the ingredients No. 9 to 15, and 17 ° C and a mixture of 25 was obtained. In addition, after blending the ingredients No. 1 to 7 and 16 with heat, homogenize, mix at 70 ° C using a turbomixer homogenizer, and then mix with a SoaVi-Niro machine. Using a high-pressure homogenizer, at 1200 bar pressure and while maintaining the product temperature at about 35 ° C or lower, add the aqueous solution of the ingredient No. 8: Polybranze (A-3) to mixture 25, and homogenize it. To obtain a solubilizate of Frederans nano-size, which is a solubilized substance included in the nano-size OZW type.

 (No.) (Blend ingredients)

1. Polyoxyethylene (addition of 10 mol) 1.00

2. Polyoxyethylene (addition of 60 moles)

 0.50

 3. Glyceryl monostearate 1.00

 4. Stearic acid 0.5〇

 5. Behe ^ Norea Noreconore 0.50

 6.8.00

 7. Isopropyl paramethoxyl citrate 0.50

 8. B-16 polysaccharide (A-3) 0.10

 9. Magnesium phosphate ascorbic acid salt 5.00

 10. Cunic acid 1.50

 1 1. Titanium dioxide (D-10) 5.00

 12. Paraoxybenzoate 0.10

 13. Ripoxy bienole polymer 0.10

 4. Sodium hydroxide 0.05

 15. Ethanore 5.00

 16. Orange oil (C_ 1) 0.001

17 · Purified water 71. 149 (Sensory test on stickiness of fragrance cosmetics)

Five male and female panelists were selected and prepared as shown in Table 1. ·〉 One drop was applied to the inside of the arm, and the feeling of stickiness was evaluated as follows. 〇: More than 8 out of 10 people felt non-sticky

△: 5 to 7 out of 10 people felt non-sticky

X: No more than 4 out of 10 people felt non-sticky (fragrance cosmetic stability test)

 Put the Frederance cosmetics prepared in Table 1 into a cylindrical glass container with a lid (height: 50 mm, inner diameter: 20 mm) until it reaches a height of 40 mm above the bottom and keep at 40 ° C. It was left for 3 months in the place where it had been. Three months after standing, the volume of the deficient pigment in the upper part of the fragrance cosmetic due to sedimentation of the glitter in the fragrance cosmetic was measured, and evaluated as follows.

 〇: Defect volume of glittering pigment is less than 20% by volume

X: 20% by volume or more of the defective part volume of the glittering pigment

It is not preferable that the volume of the brilliant pigment is 20% by volume or more. Table 2 shows the results. The perfume, eau de toilette, eau de cologne, lotion, foundation, tongue, eyeliner, blusher, and giel containing the fragrance of the present invention, brilliant pigment and polysaccharide have no sticky feeling on the skin and uniform brilliant pigment. It was recognized that the dispersion was maintained for a long time.

【table 1】

 Ingredients (% by weight)

 化 Fragrance

 E.g. polysaccharides and surfactants, water,

0 Cosmetics Bright pigment Perfume

 Polymer other

 E-1: 5.00, F-1: 30.0, Cologne

 1 D-1: 0.10 G-1: 5.00 A-1: 0.05 F-2: 5.00, G-1: 0.10, 1

 Water: 54.75

 E- 2: 5.00, F-1: 10.0,

2 D-2: 0.30 C-2: 3.00 A- 2: 0.10 F-3: 5.00, G-2: 0.10,

Two

 Water: 76.50

 E-1: 5.00, F-1: 10.0, Cologne

 3 D-3: 0.50 C-3: 3.00 A-3: 0.06 F-3: 5.00, F-4: 5.00, 3

 G-2: 0.10, water: 71.30

E-1: 5.00, F-1: 20.0, actual

 4 Eau de toilette 1 D-3: 0.40 G-1: 10.00 A-3: 0.04 F-2: 5.00, F-3: 5.00,

 G-1: 0.10, water: 54.46 examples

 E— 4: 10.00, F— 1: 20.0,

5 Eau de toilette 2 D-3: 0.50 G-2: 10.00 A-3: 0.04 F-2: 5.00 F-3-.5.00,

 G-1: 0.10, water: 49.36

E-5: 5.00, F-1: 20.0,

6 Perfume 1 1D-1: 0.15 C-3: 15.00 A-3: 0.10 F-2: 5.00, F-4: 5.00,

 G-1: 0.10, water: 39.65

E-1: 5.00, E-5: 5.00, F-1: 20.0, F-2: 5 wind F Perfume 1 2D-1: 0.20 C-3: 25.00 A- 3: 0.06

 F-4: 5.00, G-1: 0.10, Water: 34.64

 Ratio E-1: 5.00, F-1: 30.0, Decolon

 1 D-1: 0.10 C-1: 5.00 F-2: 5.00, G-1: 0.10, 4

 Example water: 54.80

 E-1: 5.00, F-1: 30.0,

2 D- 1: 0.10 G-1: 5.00 B-1: 0.20 F-2: 5.00, G-1: 0.10,

Five

 Water: 54.60

 E-1: 5.00, F-1: 30.0, Cologne

 3 D-1: 0.10 C-1: 5.00 B-1: 1.00 F-2: 5.00, G-1: 0.10, 6

 Water: 53.80

 E-1: 5.00, F-1: 20.0,

4 Eau de toilette-3D-3: 0.50 C-1: 10.00 F-2: 5.00, F-3: 5.00,

 G-1: 0.10, water: 54.40

E-1: 5.00, F-1: 20.0,

5 Eau De Toilette 4 D-3: 0.50 G-1: 10.00 B-2: 0.05 F-2: 5.00, F-3: 5.00,

 G-1: 0.10, water: 54.35

E-1: 5.00, F-1: 20.0,

6 Eau de Toilette 5 D-3: 0.50 C-1: 10.00 B-2: 0.10 F-2: 5.00, F-3: 5.00,

 G-1: 0.10, water: 54.30

E-5: 5.00, F-1: 20.0,

7 One perfume 3 D-1: 0.15 C-3: 15.00 F-2: 5.00, F-4: 5.00,

 G-1: 0.10, water: 49.75

E—5: 5.00, F-1: 20.0,

8 One perfume 4 D-1: 0.15 C-3: 15.00 B-1: 0.50 F-2: 5.00, F-4: 5.00,

G-1: 0.10, water: 49.25

[Table 2]

Claims

The scope of the claims

1. A fragrance cosmetic comprising a fragrance and a brilliant pigment, which comprises a polysaccharide containing glucose, fucose, glucuronic acid, and rhamnose as constituent monosaccharides.

 2. The fragrance cosmetic according to claim 1, wherein the fragrance cosmetic comprises a surfactant.

 3. The fragrance cosmetic according to claim 1 or 2, wherein the polysaccharide is a product of a bacterial strain of Algaricus ligennes L'etas B-16.

4. The fragrance cosmetic according to any one of claims 1 to 3, wherein the glitter pigment is at least one selected from pearlescent pigments, metallic luster pigments, glass flake pigments, metal-coated inorganic pigments, and resin pigments.

5. The fragrance cosmetic according to any one of claims 1 to 4, wherein the polysaccharide contains 0.01 to 0.5% by weight (based on the total amount) as a dry solid content.

6. Surfactant 'I freshener selected from polyoxyalkylene hydrogenated castor oil, polyoxyalkylene sorbitan fatty acid ester, sorbitan fatty acid ester, sucrose fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, lecithin and derivatives thereof The fragrance cosmetic according to any one of claims 2 to 5, which is at least one kind.

7. 0.1 to 40% by weight of fragrance, 0.01 to 30% by weight of glitter pigment, 0.05 to 20% by weight of surfactant, 0.01 to 0% of polysaccharide Claim comprising 5% by weight

7. The fragrance cosmetic according to any one of 1 to 6.