WO1995022311A1 - Personal washing compositions - Google Patents
Personal washing compositions Download PDFInfo
- Publication number
- WO1995022311A1 WO1995022311A1 PCT/EP1995/000582 EP9500582W WO9522311A1 WO 1995022311 A1 WO1995022311 A1 WO 1995022311A1 EP 9500582 W EP9500582 W EP 9500582W WO 9522311 A1 WO9522311 A1 WO 9522311A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition according
- silicone
- alkyl
- cationic
- copolymer
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 72
- 238000005406 washing Methods 0.000 title claims abstract description 12
- 229920000642 polymer Polymers 0.000 claims abstract description 55
- 230000008021 deposition Effects 0.000 claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- 125000002091 cationic group Chemical group 0.000 claims abstract description 15
- 239000002453 shampoo Substances 0.000 claims description 32
- 229920001577 copolymer Polymers 0.000 claims description 18
- 239000003921 oil Substances 0.000 claims description 17
- 239000003945 anionic surfactant Substances 0.000 claims description 12
- 229920002545 silicone oil Polymers 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 11
- 229920002125 Sokalan® Polymers 0.000 claims description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- 239000011734 sodium Substances 0.000 claims description 9
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- 230000000475 sunscreen effect Effects 0.000 claims description 9
- 239000000516 sunscreening agent Substances 0.000 claims description 9
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 8
- 125000002252 acyl group Chemical group 0.000 claims description 8
- 230000003750 conditioning effect Effects 0.000 claims description 8
- QTDIEDOANJISNP-UHFFFAOYSA-N 2-dodecoxyethyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOCCOS(O)(=O)=O QTDIEDOANJISNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 239000000344 soap Substances 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 229920003118 cationic copolymer Polymers 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 3
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 claims description 3
- 229920006037 cross link polymer Polymers 0.000 claims description 3
- 239000003925 fat Substances 0.000 claims description 3
- 239000000375 suspending agent Substances 0.000 claims description 3
- 229930003231 vitamin Natural products 0.000 claims description 3
- 239000011782 vitamin Substances 0.000 claims description 3
- 235000013343 vitamin Nutrition 0.000 claims description 3
- 229940088594 vitamin Drugs 0.000 claims description 3
- BIHQJMSIEXRWPS-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;dodecyl dihydrogen phosphate Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOP(O)(O)=O BIHQJMSIEXRWPS-UHFFFAOYSA-N 0.000 claims description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 239000003093 cationic surfactant Substances 0.000 claims description 2
- JZKFHQMONDVVNF-UHFFFAOYSA-N dodecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(O)(=O)=O JZKFHQMONDVVNF-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- 230000002209 hydrophobic effect Effects 0.000 claims description 2
- 150000002632 lipids Chemical class 0.000 claims description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 2
- 239000000341 volatile oil Substances 0.000 claims description 2
- 239000001993 wax Substances 0.000 claims description 2
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 6
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims 1
- 150000002170 ethers Chemical class 0.000 claims 1
- 229940049964 oleate Drugs 0.000 claims 1
- 229920000151 polyglycol Polymers 0.000 claims 1
- 239000010695 polyglycol Substances 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 description 34
- -1 polydimethylsiloxanes Polymers 0.000 description 28
- 125000000217 alkyl group Chemical group 0.000 description 21
- 210000003491 skin Anatomy 0.000 description 15
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 12
- 238000009472 formulation Methods 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 11
- 229920002401 polyacrylamide Polymers 0.000 description 10
- 241000282372 Panthera onca Species 0.000 description 9
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 9
- 239000000839 emulsion Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 102220549062 Low molecular weight phosphotyrosine protein phosphatase_C13S_mutation Human genes 0.000 description 8
- 230000014759 maintenance of location Effects 0.000 description 8
- 229920006317 cationic polymer Polymers 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- FLEHQRTTWKDNGI-XTJILODYSA-N (1s,3r)-5-[(2e)-2-[(7ar)-1-[(2s)-5-(cyclopropylamino)pentan-2-yl]-7a-methyl-2,3,3a,5,6,7-hexahydro-1h-inden-4-ylidene]ethylidene]-2-methylidenecyclohexane-1,3-diol Chemical compound C([C@H](C)C1[C@]2(CCCC(/C2CC1)=C\C=C1C[C@@H](O)C(=C)[C@@H](O)C1)C)CCNC1CC1 FLEHQRTTWKDNGI-XTJILODYSA-N 0.000 description 5
- 102100030613 Carboxypeptidase A1 Human genes 0.000 description 5
- 101100112225 Emericella nidulans (strain FGSC A4 / ATCC 38163 / CBS 112.46 / NRRL 194 / M139) cpa-1 gene Proteins 0.000 description 5
- 101000772551 Homo sapiens Carboxypeptidase A1 Proteins 0.000 description 5
- 150000001768 cations Chemical class 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 102100030621 Carboxypeptidase A4 Human genes 0.000 description 4
- 244000303965 Cyamopsis psoralioides Species 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 4
- 239000000084 colloidal system Substances 0.000 description 4
- 210000000245 forearm Anatomy 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 229920001282 polysaccharide Polymers 0.000 description 3
- 239000005017 polysaccharide Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 238000004876 x-ray fluorescence Methods 0.000 description 3
- DUMAFWZFOOOEPH-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;dodecyl benzenesulfonate Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 DUMAFWZFOOOEPH-UHFFFAOYSA-N 0.000 description 2
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 102100030614 Carboxypeptidase A2 Human genes 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004150 EU approved colour Substances 0.000 description 2
- 101000772572 Homo sapiens Carboxypeptidase A4 Proteins 0.000 description 2
- 108091006675 Monovalent cation:proton antiporter-2 Proteins 0.000 description 2
- 108091006676 Monovalent cation:proton antiporter-3 Proteins 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 239000006172 buffering agent Substances 0.000 description 2
- 229940106189 ceramide Drugs 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 229960004106 citric acid Drugs 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000004064 cosurfactant Substances 0.000 description 2
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229940094506 lauryl betaine Drugs 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229940006093 opthalmologic coloring agent diagnostic Drugs 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229940079776 sodium cocoyl isethionate Drugs 0.000 description 2
- 210000000434 stratum corneum Anatomy 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical class C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 description 1
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- JVTIXNMXDLQEJE-UHFFFAOYSA-N 2-decanoyloxypropyl decanoate 2-octanoyloxypropyl octanoate Chemical compound C(CCCCCCC)(=O)OCC(C)OC(CCCCCCC)=O.C(=O)(CCCCCCCCC)OCC(C)OC(=O)CCCCCCCCC JVTIXNMXDLQEJE-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical class CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- KNUPSOXBESCJLY-UHFFFAOYSA-N 2-methoxy-1-phenylhexan-1-one Chemical compound CCCCC(OC)C(=O)C1=CC=CC=C1 KNUPSOXBESCJLY-UHFFFAOYSA-N 0.000 description 1
- WLAMNBDJUVNPJU-UHFFFAOYSA-N 2-methylbutyric acid Chemical compound CCC(C)C(O)=O WLAMNBDJUVNPJU-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- ULPWBLHOWJRDBH-UHFFFAOYSA-N 5-amino-2-methylidenepentanamide Chemical compound NCCCC(=C)C(N)=O ULPWBLHOWJRDBH-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 102100026794 Carboxypeptidase A5 Human genes 0.000 description 1
- RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical class OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 101000910789 Homo sapiens Carboxypeptidase A5 Proteins 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- IZWSFJTYBVKZNK-UHFFFAOYSA-O N-dodecyl-N,N-dimethyl-3-ammonio-1-propanesulfonic acid Chemical compound CCCCCCCCCCCC[N+](C)(C)CCCS(O)(=O)=O IZWSFJTYBVKZNK-UHFFFAOYSA-O 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 244000044822 Simmondsia californica Species 0.000 description 1
- 235000004433 Simmondsia californica Nutrition 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- FPIPGXGPPPQFEQ-BOOMUCAASA-N Vitamin A Natural products OC/C=C(/C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-BOOMUCAASA-N 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical group 0.000 description 1
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- ZWXYEWJNBYQXLK-UHFFFAOYSA-N azanium;4-dodecoxy-4-oxo-3-sulfobutanoate Chemical compound [NH4+].CCCCCCCCCCCCOC(=O)C(S(O)(=O)=O)CC([O-])=O ZWXYEWJNBYQXLK-UHFFFAOYSA-N 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 238000000237 capillary viscometry Methods 0.000 description 1
- 125000004181 carboxyalkyl group Chemical group 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001783 ceramides Chemical class 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 229940114081 cinnamate Drugs 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 229940018562 coco monoisopropanolamide Drugs 0.000 description 1
- 229940079840 cocoyl isethionate Drugs 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- NZZIMKJIVMHWJC-UHFFFAOYSA-N dibenzoylmethane Chemical class C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 NZZIMKJIVMHWJC-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 239000004815 dispersion polymer Substances 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 235000008524 evening primrose extract Nutrition 0.000 description 1
- 229940089020 evening primrose oil Drugs 0.000 description 1
- 239000010475 evening primrose oil Substances 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 231100000640 hair analysis Toxicity 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229960001679 octinoxate Drugs 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- NPSSWQJHYLDCNV-UHFFFAOYSA-N prop-2-enoic acid;hydrochloride Chemical compound Cl.OC(=O)C=C NPSSWQJHYLDCNV-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 229940083542 sodium Drugs 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229960000999 sodium citrate dihydrate Drugs 0.000 description 1
- ADWNFGORSPBALY-UHFFFAOYSA-M sodium;2-[dodecyl(methyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCN(C)CC([O-])=O ADWNFGORSPBALY-UHFFFAOYSA-M 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 150000003445 sucroses Chemical class 0.000 description 1
- AGGIJOLULBJGTQ-UHFFFAOYSA-N sulfoacetic acid Chemical class OC(=O)CS(O)(=O)=O AGGIJOLULBJGTQ-UHFFFAOYSA-N 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- PUVAFTRIIUSGLK-UHFFFAOYSA-M trimethyl(oxiran-2-ylmethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1CO1 PUVAFTRIIUSGLK-UHFFFAOYSA-M 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 238000004846 x-ray emission Methods 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/594—Mixtures of polymers
Definitions
- This invention relates to personal washing compositions which contain a cationic deposition polymer to increase deposition of a benefit agent onto the skin or hair.
- Deposition polymers with a cationic charge have been proposed to enhance the amount of benefit agent deposited from the shampoo.
- cationic guar gum has been described for the enhancement of the deposition of antidandruff particles in US 5 037 818 and for the enhanced deposition of insoluble non-volatile silicone in US 5 085 857.
- the use of cationic polymers in shower gels to enhance deposition of silicone oil is also known from EP-A-457 688 (L'Oreal) .
- Deposition polymers have also been proposed to enhance the deposition of sunscreen materials from a shampoo composition.
- EP 386 898 a cationic polygalactomannan gum derivative is used.
- Polyacrylamides have been proposed for use in shampoos in EP 0 231 997. These polymers are not charged and do not assist in the deposition of benefit agents.
- a personal washing composition comprising: a surface active agent selected from anionic, nonionic, zwitterionic and cationic surfactants, soap and mixtures thereof, water, a non-volatile insoluble benefit agent dispersed in the composition and from 0.001 to 1% by weight of a deposition polymer which is a cationic copolymer wherein the charge density of the copolymer is in the range 0.0001 to 0.005 eq/g, preferably 0.0008 to 0.0025 eq/g; and the average molecular weight of the copolymer is more than 2xl0 6 daltons.
- the amount of deposition polymer lies in the range 0.05 to 0.2% by weight.
- the cationic copolymer is a copolymer of acrylamide and a cationic monomer having the formula:
- T is -O- or -C-
- R is H or CH
- R" is -NH- (CH 2 ) n -N + (CH 3 ) 3 X " or -O- (CH 2 ) n -N + (CH 3 ) 3 X " in which n is an integer from 1 to 4 and X is selected from CI, Br, I and CH 3 S0 3 .
- composition is suitable for cleansing and conditioning of the skin or hair.
- condition is intended to cover “moisturising” and “protection” .
- average molecular weight means a molecular weight calculated as follows.
- the intrinsic viscosity of a polymer may be determined by standard capillary viscometry.
- the viscosity of a series of low polymer concentrations in a given solvent is determined relative to the pure solvent.
- the relative viscosity N r is defined as:
- the specific viscosity N ⁇ D is:
- N sp /c where c is the polymer concentration
- c the polymer concentration
- the intrinsic viscosity can also be related to the molecular weight of the polymer if the Mark-Houwink parameters are known.
- K and a are the Mark-Houwink parameters These have been determined for polyacrylamide, and also for a number of copolymers of acrylamide and N,N,N trimethylaminoethyl chloride acrylate. These polymers are in accordance with those found useful in the present invention. The parameters can be found in Mabire et al, Polymer 1984 (25) 1984.
- CPA1 and CPA5 to 10 we used the MH parameters for 30% cationic polymer.
- CPA 3 and CPA 4 we used MH parameters for acrylamide homopolymer. Whichever is used, the Mw figure is approximately the same. Thus, if the MH parameters for acrylamide are used for CPA 1, the Mw figure becomes 5,000,000 rather than 8,000,000.
- CPA polymers are copolymers of acrylamide and N,N,N- trimethyl aminopropylacrylamide.
- CPA 1, 2, 5, 7, 9 and 10 have cationic charge densities of 0.00145 eq/g.
- CPA 3 and CPA 4 have cationic charge densities of 0.0004 eq/g.
- CPA 6 and CPA 8 have respective cationic charge densities 0.00194 and 0.0009 eq/g. All CPA copolymers were ex Allied colloids.
- the Intrinsic viscosities for CPA 1, 2 and 5 to 10 is data from Allied Colloids.
- the data for CPA3 and CPA4 was produced by the above method and corresponds closely with the data supplied by Allied Colloids for these materials.
- Preferred "CPA" polymers have an intrinsic viscosity of at least 7.
- ⁇ a protective and/or softening substance that maintains softness by retarding the decrease in water content from the skin (stratum corneum) or hair.
- the benefit agent is an oil.
- preferred benefit agents include
- silicone oils, gums and modifications thereof such as linear and cyclic polydimethylsiloxanes; amino, alkyl alkylaryl and aryl silicone oils; b) fats and oils including natural fats and oils such as jojoba and beef tallow; c) waxes such as beeswax and lanolin; d) hydrocarbons such as petrolatum and mineral oil; e) higher fatty acids and higher fatty alcohols, both saturated and unsaturated, having a carbon chain length in the range C_-_ to C 22 ; f) esters such as isopropyl myristate and isopropyl palmitate; g) essential oils such as evening primrose oil; h) lipids such as cholesterol, ceramides, sucrose esters and pseudo-ceramides as described in
- the oil may take the form of a sunscreen, a styling or bodying agent or a conditioning oil.
- sunscreens and other benefit agents there may be mentioned: the group of branched hydrocarbon materials of high molecular weight referred to elsewhere as peralk(en)yl hydrocarbons. These may be either in an organic solvent or directly emulsified in the shampoo composition to give styling or bodying effects.
- Polyisobutene is a preferred branched hydrocarbon material.
- oil soluble sunscreens partitioned into emulsified oil droplets.
- oils suitable for this purpose are phenyl silicones and among the suitable sunscreens are, benzophenone compounds, dibenzoyl methane derivatives and camphor derivatives.
- a preferred sunscreen material is a UV absorber such as 2-ethyl hexyl methoxy cinnamate sold under the trade name Parsol MCX by Givaudan.
- Silicone oil is a preferred conditioning oil for skin or hair.
- the silicone may be in the form of a low viscosity oil which may contain a high viscosity oil or gum in solution.
- the high viscosity material may be in the form of an emulsion in water.
- the emulsion may be of high viscosity oil or of a solution of gum in a lower viscosity oil.
- the particle size of the oil phase may be anywhere in the range from 30 nanometres to up to 20 microns average size.
- the oil when the oil is a silicone it may be a polydimethylsiloxane with an average particle size of less than 20 microns and preferably less than 2 microns. Small particle size enables a more uniform distribution of silicone conditioning agent for the same concentration of silicone in the composition.
- a silicone with a viscosity in the range 1-20 million cst is used.
- the silicone can be cross-linked.
- the personal washing composition may further comprise from 0.1 to 5 % of a suspending agent selected from polyacrylic acids, cross linked polymers of acrylic acid, copolymers of acrylic acid with a hydrophobic monomer, copolymers of carboxylic acid- containing monomers and acrylic esters, cross-linked copolymers of acrylic acid and acrylate esters, heteropolysaccharide gums and crystalline long chain acyl derivatives.
- the long chain acyl derivative is desirably selected from ethylene glycol stearates, alkanolamides of fatty acids having from 16 to 22 carbon atoms and mixtures thereof. Ethylene glycol distearate and Polyethylene glycol 3 distearate are preferred long chain acyl derivatives.
- Polyacrylic acid is available commercially as Carbopol 420, Carbopol 488 or Carbopol 493.
- Polymers of acrylic acid cross-linked with a polyfunctional agent may also be used, they are available commercially as Carbopol 910, Carbopol 934, Carbopol 940, Carbopol 941 and Carbopol 980.
- An example of a suitable copolymer of a carboxylic acid containing a monomer and acrylic acid esters is Carbopol 1342. All Carbopol materials are available from Goodrich and Carbopol is a trade mark.
- the suspending agent is particularly preferred when silicone is present.
- Suitable cross linked polymers of acrylic acid and acrylate esters are Pemulen TR1 or Pemulen TR2.
- a suitable heteropolysaccharide gum is xanthan gum, for example that available as Kelzan mu.
- the surface active agent can be selected from any known surfactant suitable for topical application to the human body. Mild surfactants, ie. surfactants which do not damage the stratum corneum, the outer layer of skin, are particularly preferred.
- One ' preferred anionic surfactant is fatty acyl isethionate of formula: RC0 2 CH 2 CH 2 S0 3 M where R is an alkyl or alkenyl group of 7 to 21 carbon atoms and M is a solubilising cation such as sodium, potassium, ammonium or substituted ammonium.
- RCO groups Preferably at least three quarters of the RCO groups have 12 to 18 carbon atoms and may be derived from coconut, palm or a coconut/palm blend.
- alkyl ether sulphate of formula:
- R is an alkyl group of 8 to 22 carbon atoms
- n ranges from 0.5 to 10 especially 1.5 to 8
- M is a solubilising cation as before.
- anionic surfactants include alkyl glyceryl ether sulphate, sulphosuccinates, taurates, sarcosinates, sulphoacetates, alkyl phosphate, alkyl phosphate esters and acyl lactylate, alkyl glutamates and mixtures thereof.
- Sulphosuccinates may be monoalkyl sulphosuccinates having the formula: R 5 0 2 CCH 2 CH(S0 3 M) C0 2 M; and a ido-MEA sulphosuccinates of the formula: RCONCH 2 CH 2 0 2 CCH,CH(S0 3 M)C0 2 M; wherein R 5 ranges from C B -C 20 alkyl, preferably C 12 -C 15 alkyl and M is a solubilising cation.
- Sarcosinates are generally indicated by the formula : R 5 CON (CH 3 ) CH 2 C0 2 M, wherein R ranges f rom C e -C 20 alkyl , preferably C 12 -C 15 alkyl and M is a solubilising cation .
- Taurates are generally identif ied by the formula :
- R 5 CONR 6 CH 2 CH 2 S0 3 M, wherein R E ranges f rom C B -C 20 alkyl , pref erably C 12 -C 15 alkyl , R- ranges f rom Cj-C 4 alkyl , and M is a solubilising cation . Harsh surfactants such as primary alkane sulphonate or alkyl benzene sulphonate will generally be avoided.
- Suitable nonionic surface active agents include alkyl polysaccharides, lactobionamides, ethyleneglycol esters, glycerol monoethers, polyhydroxyamides (glucamide) , primary and secondary alcohol ethoxylates, especially the C 8 _ 20 aliphatic alcohols ethoxylated with an average of from 1 to 20 moles of ethylene oxide per mole of alcohol.
- the soap is preferably derived from materials with a C 8 to C 22 substantially saturated carbon chain and, preferably, is a potassium soap with a C 12 to C 18 carbon chain.
- the composition includes at least one cosurfactant agent with skin-mildness benefits.
- Suitable materials are zwitterionic detergents which have an alkyl or alkenyl group of 7 to 18 carbon atoms and comply with an overall structural formula
- R 1 is alkyl or alkenyl of 7 to 18 carbon atoms
- R 2 and R 3 are each independently alkyl, hydroxyalkyl or carboxyalkyl of 1 to 3 carbon atoms
- n 0 or 1
- X is alkylene of 1 to 3 carbon atoms optionally substituted with hydroxyl
- Y is -COJ or - SOJ
- Zwitterionic detergents within the above general formula include simple betaines of formula:
- R 1 , R 2 and R 3 are as defined previously.
- R 1 may, in particular, be a mixture of C 12 and C 14 alkyl groups derived from coconut so that at least half, preferably at least three quarters of the groups R 1 have 10 to 14 carbon atoms.
- R 2 and R 3 are preferably methyl.
- a further possibility is a sulphobetaine of formula:
- R 1 , R 2 and R 3 in these formulae are as defined previously.
- the surface active agent is preferably present in amount of from 2 to 40% by weight, and preferably from 5 to 30% by weight.
- the cosurfactant, is present, is preferably present at a level of 0.5 to 15% by weight.
- the skin washing composition according to the invention may also include minor amounts of other ingredients such as antibacterial agents, foam boosters, pearlescers, perfumes, dyes, colouring agents, preservatives, thickeners, proteins, other polymers, phosphate esters and buffering agents.
- other ingredients such as antibacterial agents, foam boosters, pearlescers, perfumes, dyes, colouring agents, preservatives, thickeners, proteins, other polymers, phosphate esters and buffering agents.
- Shampoo compositions of the invention contain anionic surfactant together with optional nonionic and amphoteric surfactant .
- Suitable anionic surfactants are the alkyl sulphates, alkyl ether sulphates, alkaryl sulphonates, alkyl succinates, alkyl sulphosuccinates, N-alkoyl sarcosinates, alkyl phosphates, alkyl ether phosphates, alkyl ether carboxylates, and alpha- olefin sulphonates, especially their sodium, magnesium, ammonium and mono-, di- and triethanolamine salts.
- the alkyl groups generally contains from 8 to 18 carbon atoms and may be unsaturated.
- alkyl ether sulphates, alkyl ether phosphates and alkyl ether carboxylates may contain from one to 10 ethylene oxide or propylene oxide unites per molecule, and preferably contain an average of 2 to 3 ethylene oxide units per molecule.
- anionic surfactants include sodium oleyl succinate, ammonium lauryl sulphosuccinate, ammonium lauryl sulphate, sodium dodecylbenzene sulphonate, triethanolamine dodecylbenzene sulphonate, triethanolamine dodecylbenzene sulphonate and sodium N-lauryl sarcosinate.
- the most preferred anionic surfactants are sodium lauryl sulphate, triethanolamine lauryl sulphate, triethanolamine monolauryl phosphate, sodium lauryl ether sulphate 1EO, 2E0 and 3EO, ammonium lauryl sulphate and ammonium lauryl ether sulphate 1EO, 2EO and 3EO.
- nonionic surfactants suitable for use in the shampoo compositions of the invention include condensation products of aliphatic (C 8 -C 18 ) primary or secondary linear or branched chain alcohols or phenols with alkylene oxides, usually ethylene oxide and generally 6-30 EO.
- nonionics include mono or di alkyl alkanolamides or alkyl polyglucosides .
- Examples include coco mono or diethanolamide, coco mono isopropanolamide, and coco di glucoside.
- amphoteric surfactants suitable for use in the composition of the invention may include alkyl amine oxides, alkyl betaines, alkyl amidopropyl betaines, alkyl sulphobetaines, alkyl glycinates, alkyl carboxyglycinates, alkyl amphopropionates, alkyl amidopropyl hydroxysultaines, acyl taurates and acyl glutameates wherein the alkyl and acyl groups have from 8 to 18 carbon atoms.
- Examples include lauryl amine oxide, cocodimethyl sulphopropyl betaine and preferably lauryl betaine, cocamidopropyl betaine and sodium cocamphopropionate.
- the surfactants are present in the shampoo compositions of the invention in an amount of from 2 to 40% by weight, and preferably from 5 to 30% by weight.
- the shampoo may also include minor amounts of other ingredients such as antibacterial agents, foam boosters, pearlescers, perfumes, dyes, colouring agents, preservatives, thickeners, proteins, other polymers, phosphate esters and buffering agents.
- other ingredients such as antibacterial agents, foam boosters, pearlescers, perfumes, dyes, colouring agents, preservatives, thickeners, proteins, other polymers, phosphate esters and buffering agents.
- Coco amidopropyl betaine was Tergobetaine F ex Goldschmidt or
- Guar hydroxypropyl trimonium chloride was Jaguar C-13-S ex Meyhall.
- Silicone oil emulsion was BC 89/138 ex Basildon.
- Sodium cocoyl isethionate was either Jordapon CI ex PPG/Mazer or Hostapan SCI ex Hoechst.
- compositions according to the invention and comparative compositions were tested by the following method.
- a strip of adhesive tape is pressed onto the areas on the forearms keeping it in place for 30 seconds using a spring loaded device bearing on a rubber bung to press the tape onto the skin with a repeatable pressure of 85g.c ⁇ f 2 .
- the adhesive tape employed was J-Lar Superclear (TM) tape having a width of 25mm. Two strips of tape are applied to each forearm in this way to adjacent areas of the skin.
- the amounts of silicon and skin adhering to the tape are determined by means of X-ray fluorescence spectroscopy.
- the tape strips are placed in an X-ray fluorescence spectrometer with the adhesive side facing the beam of this machine.
- a mask is applied over the tape to define a standardised area in the middle of the tape which is exposed to the X-ray beam.
- the sample chamber of the machine is placed under vacuum before making measurements and the spectrometer is then used to measure the quantities of silicon and sulphur.
- the sulphur is representative of the amount of skin which has transferred to the tape. Results are presented in terms of the ratio of Si:S. Example 1
- the base formulation was:-
- Polymers were added to the base formulation at a level of 0.1 %w .
- compositions were prepared by forming a 1% dispersion of the polymer by adding it to water at ⁇ 50°C. SLES and CAPB were added to the excess water of the formulation with gentle stirring. Thereafter the silicone oil emulsion was added with stirring to the surfactant mixture. This was followed by the polymer dispersion and finally the minors. Deposition of silicone was determined according to the procedure described above. The Si : S ratio for the comparison was normalised to 1 and the values for the compositions according to the invention expressed relative to the comparison.
- the base formulation was: -
- a figure of zero for silicone retention indicates that the amount detected was negligible and could not accurately be measured.
- C13S is JAGUAR (trade mark) C13S
- C15 is JAGUAR C15, also a cationic guar derivative ex Meyhall
- JR400 is POLYMER JR400, a polysaccharide derivative ex Union Carbide JR30M is POLYMER JR30M, a polysaccharide derivative ex Union Carbide
- FC370 is Luviquat FC 370 (trade mark) , ex BASF Quat-pva is a copolymer prepared by reacting glycidyltrimethylammonium chloride with a commercial PVA; Mowiol 40-88, ex Hoeschst .
- the molecular weight (Mw) is
- example K is polyacrylamide based.
- the value given for polymer Mw in the table is suppliers data for all examples except Example K.
- Merquat 550 has a weight average molecular weight of 2.8 million, however, when measured using our Intrinsic viscosity method a value for Mw of 700 000 is obtained.
- Silicone retention efficiency from formulations containing these low Mw polymers does not exceed 25%.
- Example N Shampoo A with Jaguar C13S 983 ppm 20% efficiency
- Example O Shampoo A with Jaguar C171 413 ppm 29% efficiency
- polyacrylamides with high molecular weight (Examples 1,2,4 and 6) clearly outperform Jaguar C17.
- the silicone level in these shampoos was 2% by weight.
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002180942A CA2180942C (en) | 1994-02-18 | 1995-02-16 | Personal washing compositions |
JP7521593A JP2746758B2 (en) | 1994-02-18 | 1995-02-16 | Body wash composition |
EP95909734A EP0744935B2 (en) | 1994-02-18 | 1995-02-16 | Personal washing compositions |
AU18097/95A AU1809795A (en) | 1994-02-18 | 1995-02-16 | Personal washing compositions |
BR9506797A BR9506797A (en) | 1994-02-18 | 1995-02-16 | Personal wash composition |
DE69519372T DE69519372T3 (en) | 1994-02-18 | 1995-02-16 | SKIN CLEANERS |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9403156A GB9403156D0 (en) | 1994-02-18 | 1994-02-18 | Hair shampoo |
GB9414332A GB9414332D0 (en) | 1994-07-15 | 1994-07-15 | Detergent composition |
GB9403156.4 | 1994-07-15 | ||
GB9414332.8 | 1994-07-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1995022311A1 true WO1995022311A1 (en) | 1995-08-24 |
Family
ID=26304353
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1995/000582 WO1995022311A1 (en) | 1994-02-18 | 1995-02-16 | Personal washing compositions |
Country Status (9)
Country | Link |
---|---|
US (1) | US5543074A (en) |
EP (1) | EP0744935B2 (en) |
JP (1) | JP2746758B2 (en) |
AU (1) | AU1809795A (en) |
BR (1) | BR9506797A (en) |
CA (1) | CA2180942C (en) |
DE (1) | DE69519372T3 (en) |
ES (1) | ES2153026T5 (en) |
WO (1) | WO1995022311A1 (en) |
Cited By (166)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997003637A1 (en) * | 1995-07-14 | 1997-02-06 | Unilever Plc | Antimicrobial hair treatment composition |
US5612307A (en) * | 1994-07-19 | 1997-03-18 | Lever Brothers Company, Division Of Conopco, Inc. | Detergent compositions containing separate stripes of surface active agents and benefit agent |
WO1997016168A1 (en) * | 1995-11-03 | 1997-05-09 | Colgate-Palmolive Company | Personal cleansing composition |
WO1997028785A1 (en) * | 1996-02-09 | 1997-08-14 | The Procter & Gamble Company | Photoprotective compositions |
WO1997029736A1 (en) * | 1996-02-15 | 1997-08-21 | Unilever Plc | Liquid cleansing compositions comprising select cationic polymers |
WO1997035543A1 (en) * | 1996-03-27 | 1997-10-02 | The Procter & Gamble Company | Conditioning shampoo compositions containing select cationic conditioning polymers |
FR2750046A1 (en) * | 1996-06-19 | 1997-12-26 | Oreal | Cosmetic or dermatological topical composition in form of aqueous gel |
WO1998018443A1 (en) * | 1996-10-25 | 1998-05-07 | The Procter & Gamble Company | Conditioning shampoo composition |
WO1998018435A2 (en) * | 1996-10-25 | 1998-05-07 | The Procter & Gamble Company | Conditioning shampoo composition |
US5804538A (en) * | 1996-06-20 | 1998-09-08 | The Procter & Gamble Company | Perfume delivery systems in liquid personal cleansing compositions |
US5843875A (en) * | 1996-06-20 | 1998-12-01 | The Procter & Gamble Company | Perfume delivery systems in liquid personal cleansing |
US5900394A (en) * | 1996-04-10 | 1999-05-04 | Lever Brothers Company | Detergent compositions for enhanced delivery of functional ingredients |
WO1999062462A2 (en) * | 1998-06-01 | 1999-12-09 | Unilever Plc | Hair treatment compositions |
US6010689A (en) * | 1997-04-21 | 2000-01-04 | Helene Curtis, Inc. | Hair treatment compositions containing amidopolyether functional silicone |
US6048519A (en) * | 1997-03-27 | 2000-04-11 | Helene Curtis, Inc. | Hair treatment compositions |
EP1000612A1 (en) * | 1998-11-12 | 2000-05-17 | Beiersdorf Aktiengesellschaft | Preparations of W/O type emulsions with high water content and further containing one or more alkylmethicone copolyols and/or alkyl-dimethicone copolyols as well as cationic polymers |
WO2000033807A1 (en) * | 1998-12-10 | 2000-06-15 | Unilever Plc | Washing compositions |
WO2000035416A1 (en) * | 1998-12-15 | 2000-06-22 | Unilever Plc | Detergent composition |
US6224852B1 (en) | 1999-04-23 | 2001-05-01 | Unilever Home & Personal Care Usa | Liquid sunscreen compositions which both deposit and lather well |
US6248317B1 (en) | 1996-10-25 | 2001-06-19 | The Procter & Gamble Company | Styling shampoo compositions with improved styling polymer deposition |
US6277361B1 (en) | 1998-03-05 | 2001-08-21 | Helene Curtis, Inc. | Shampoo compositions comprising a surfactant, an amino functionalized silicone, and a non-amino functionalized silicone |
US6355234B1 (en) | 1996-08-05 | 2002-03-12 | Helene Curtis, Inc. | Shampoo compositions and method |
US6362146B1 (en) | 1998-06-05 | 2002-03-26 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Personal washing compositions |
US6491902B2 (en) | 2001-01-29 | 2002-12-10 | Salvona Llc | Controlled delivery system for hair care products |
US6509011B1 (en) | 1999-07-23 | 2003-01-21 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Method of hair treatment using organic amino compounds |
US6551361B1 (en) | 1999-07-23 | 2003-04-22 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Method of hair treatment using organic amino compounds |
US6627585B1 (en) | 1999-06-15 | 2003-09-30 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Mousse-forming shampoo compositions |
US6706258B1 (en) | 1998-04-20 | 2004-03-16 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Shampoo compositions comprising and emulsified silicone an a microemulsified silicone |
US6719967B1 (en) | 1998-04-03 | 2004-04-13 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Hair treatment compositions |
US6864314B1 (en) | 1999-05-26 | 2005-03-08 | Dominic Wai-Kwing Yeung | Block polymers, compositions and methods of use for foams, laundry detergents, shower rinses and coagulants |
US6979440B2 (en) | 2001-01-29 | 2005-12-27 | Salvona, Llc | Compositions and method for targeted controlled delivery of active ingredients and sensory markers onto hair, skin, and fabric |
US7183243B2 (en) | 2002-11-12 | 2007-02-27 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Compositions for washing and conditioning hair |
US7241729B2 (en) | 1999-05-26 | 2007-07-10 | Rhodia Inc. | Compositions and methods for using polymeric suds enhancers |
US7300912B2 (en) | 2005-08-10 | 2007-11-27 | Fiore Robert A | Foaming cleansing preparation and system comprising coated acid and base particles |
US7416735B2 (en) | 2002-03-28 | 2008-08-26 | The Procter & Gamble Company | Emulsion compositions |
EP2082726A2 (en) | 2005-03-12 | 2009-07-29 | Unilever PLC | Hair and/or scalp care compositions incorporating flavonoid compounds |
EP2236126A1 (en) | 2005-03-12 | 2010-10-06 | Unilever PLC | Hair and/or Scalp Care Compositions Incorporating Isophaseollin |
EP2246034A2 (en) | 2008-10-10 | 2010-11-03 | Unilever PLC | Use of personal care composition |
WO2011003695A1 (en) | 2009-07-10 | 2011-01-13 | Unilever Plc | Hair treatment compositions |
WO2011019539A2 (en) | 2009-08-13 | 2011-02-17 | Dow Corning Corporation | Granulated dry cleanser for the care of keratinous substrates |
WO2011028765A1 (en) | 2009-09-03 | 2011-03-10 | Dow Corning Corporation | Personal care compositions with pituitous silicone fluids |
WO2011062805A1 (en) | 2009-11-23 | 2011-05-26 | Lubrizol Advanced Materials, Inc. | Surfactant-polymer blends |
WO2011066359A1 (en) | 2009-11-25 | 2011-06-03 | Dow Corning Corporation | Personal care compositions containing certain cyclic siloxanes |
WO2011092083A2 (en) | 2010-02-01 | 2011-08-04 | Unilever Plc | Composition |
WO2011117023A1 (en) | 2010-03-26 | 2011-09-29 | Unilever Plc | Shampoo containing a dendritic macromolecule and a gel network |
WO2011120736A1 (en) | 2010-03-29 | 2011-10-06 | Unilever Plc | Hair care composition comprising alkyl -modified siloxane |
WO2011124560A2 (en) | 2010-04-09 | 2011-10-13 | Dsm Ip Assets B.V. | Hair care compositions |
WO2011130460A1 (en) | 2010-04-14 | 2011-10-20 | Lubrizol Advanced Materials, Inc. | Thickened amino acid surfactant compositions and methods therefor |
WO2011154315A2 (en) | 2010-06-10 | 2011-12-15 | Unilever Plc | Hair care composition |
WO2012004126A2 (en) | 2010-07-08 | 2012-01-12 | Unilever Plc | Hair care composition |
WO2012022552A1 (en) | 2010-08-18 | 2012-02-23 | Unilever Plc | Anti-dandruff shampoo |
WO2012022553A1 (en) | 2010-08-18 | 2012-02-23 | Unilever Plc | Anti-dandruff shampoo |
WO2012072424A2 (en) | 2010-12-02 | 2012-06-07 | Unilever Plc | Anti-dandruff shampoo |
WO2012119810A2 (en) | 2011-03-10 | 2012-09-13 | Unilever Plc | Composition |
WO2012119825A2 (en) | 2011-03-10 | 2012-09-13 | Unilever Nv | Composition |
WO2012119824A2 (en) | 2011-03-10 | 2012-09-13 | Unilever Nv | Composition |
WO2012139943A2 (en) | 2011-04-13 | 2012-10-18 | Unilever Plc | Hair care composition |
WO2012139947A2 (en) | 2011-04-13 | 2012-10-18 | Unilever Plc | Hair care composition |
WO2012139948A2 (en) | 2011-04-13 | 2012-10-18 | Unilever Plc | Hair care composition |
WO2012139944A2 (en) | 2011-04-13 | 2012-10-18 | Unilever Plc | Hair care composition |
WO2012139951A1 (en) | 2011-04-13 | 2012-10-18 | Unilever Plc | Hair care composition |
US8298553B2 (en) | 2007-12-06 | 2012-10-30 | Conopco, Inc. | Personal care composition |
WO2012150259A1 (en) | 2011-05-04 | 2012-11-08 | Unilever Plc | Composition |
WO2012150260A1 (en) | 2011-05-04 | 2012-11-08 | Unilever Plc | Hair care composition comprising hydrophobically-modified anionic polymer and a methylcellulose |
WO2012156177A1 (en) | 2011-05-13 | 2012-11-22 | Unilever Plc | Hair treatment compositions |
WO2012159920A1 (en) | 2011-05-25 | 2012-11-29 | Unilever Plc | Hair care composition |
WO2012159919A1 (en) | 2011-05-25 | 2012-11-29 | Unilever Plc | Hair colouring product comprising metal ions and a component from the fruit of the redcurrant or blackcurrant |
WO2012159918A1 (en) | 2011-05-25 | 2012-11-29 | Unilever Plc | Hair colouring product comprising metal ions and a component from vaccinium berries |
WO2013007606A2 (en) | 2011-07-08 | 2013-01-17 | Unilever Plc | Hair care composition |
WO2013007607A2 (en) | 2011-07-08 | 2013-01-17 | Unilever Plc | Hair care composition |
WO2013026656A1 (en) | 2011-08-24 | 2013-02-28 | Unilever Plc | Benefit agent delivery particles comprising dextran |
WO2013026657A1 (en) | 2011-08-24 | 2013-02-28 | Unilever Plc | Benefit agent delivery particles comprising non-ionic polysaccharides |
WO2013082096A1 (en) | 2011-11-29 | 2013-06-06 | Dow Corning Corporation | Aminofunctional silicone emulsions for fiber treatments |
WO2013082224A1 (en) | 2011-11-29 | 2013-06-06 | Dow Corning Corporation | Aminofunctional organosiloxanes |
WO2013083510A2 (en) | 2011-12-06 | 2013-06-13 | Unilever Plc | Hair colour composition |
WO2013087644A2 (en) | 2011-12-12 | 2013-06-20 | Unilever Plc | Method of strengthening hair fibres |
WO2013093475A1 (en) | 2011-12-22 | 2013-06-27 | Innospec Limited | Composition and method |
WO2013107778A1 (en) | 2012-01-18 | 2013-07-25 | Unilever Plc | Hair treatment composition |
WO2013107771A1 (en) | 2012-01-18 | 2013-07-25 | Unilever Plc | Hair care composition |
US8501743B2 (en) | 2007-12-06 | 2013-08-06 | Conopco, Inc. | Personal care composition |
EP2636402A1 (en) | 2012-03-07 | 2013-09-11 | Unilever PLC | Hair colouring composition |
WO2013131756A2 (en) | 2012-03-07 | 2013-09-12 | Unilever Plc | Hair care composition |
WO2013131752A2 (en) | 2012-03-07 | 2013-09-12 | Unilever Plc | Hair care composition |
WO2013131758A2 (en) | 2012-03-07 | 2013-09-12 | Unilever Plc | Hair care composition |
US8592361B2 (en) | 2002-11-25 | 2013-11-26 | Colgate-Palmolive Company | Functional fragrance precursor |
WO2014023448A1 (en) | 2012-08-06 | 2014-02-13 | Unilever Plc | Hair composition |
WO2014023440A1 (en) | 2012-08-06 | 2014-02-13 | Unilever N.V. | Shampoo composition |
US8664328B2 (en) | 2008-04-14 | 2014-03-04 | Dow Corning Corporation | Emulsions of boron crosslinked organopolysiloxanes |
EP2705772A1 (en) | 2012-09-07 | 2014-03-12 | Unilever PLC | Hair care composition |
EP2705771A1 (en) | 2012-09-07 | 2014-03-12 | Unilever PLC | Hair care composition |
WO2014040811A1 (en) | 2012-09-17 | 2014-03-20 | Dsm Ip Assets B.V. | Hair care polymer |
WO2014058887A1 (en) | 2012-10-11 | 2014-04-17 | Dow Corning Corporation | Aqueous silicone polyether microemulsions |
WO2014064121A2 (en) | 2012-10-25 | 2014-05-01 | Unilever Plc | Improvements relating to surface treatment compositions |
US8734767B2 (en) | 2008-10-22 | 2014-05-27 | Dow Corning Corporation | Aminofunctional endblocked silicone polyether copolymers in personal care compositions |
WO2014082846A1 (en) | 2012-11-29 | 2014-06-05 | Unilever Plc | Hair care composition |
WO2014095289A2 (en) | 2012-12-20 | 2014-06-26 | Unilever Plc | Method of treating hair ageing |
WO2014106603A1 (en) | 2013-01-03 | 2014-07-10 | Unilever Plc | Hair care composition |
WO2014122132A1 (en) | 2013-02-06 | 2014-08-14 | Unilever Plc | Topical colouring composition |
WO2014143757A1 (en) | 2013-03-15 | 2014-09-18 | Dow Corning Corporation | Cosmetic compositions containing silicone resin emulsions |
EP2799115A1 (en) | 2013-05-03 | 2014-11-05 | Unilever PLC | Hair care composition |
WO2014177315A1 (en) | 2013-04-29 | 2014-11-06 | Unilever Plc | Hair colouring composition |
US8907033B2 (en) | 1999-05-26 | 2014-12-09 | Solvay Usa Inc. | Polymers, compositions and methods of use for foams, laundry detergents, shower rinses and coagulants |
EP2873412A1 (en) | 2013-11-13 | 2015-05-20 | Unilever PLC | A hair colour composition and method of colouring hair |
WO2015078943A1 (en) | 2013-11-28 | 2015-06-04 | Unilever Plc | Improvements relating to encapsulated benefit agents |
WO2015179513A1 (en) | 2014-05-21 | 2015-11-26 | Dow Corning Corporation | Cross-linked aminosiloxane polymer and method of forming |
WO2016014127A1 (en) | 2014-07-23 | 2016-01-28 | Dow Corning Corporation | Pituitous silicone fluid |
WO2016034521A1 (en) | 2014-09-03 | 2016-03-10 | Unilever Plc | Transparent compositions |
WO2016058837A1 (en) | 2014-10-17 | 2016-04-21 | Unilever Plc | Anti-dandruff hair composition |
WO2016058836A1 (en) | 2014-10-17 | 2016-04-21 | Unilever Plc | Hair care composition |
WO2016071113A1 (en) | 2014-11-04 | 2016-05-12 | Unilever Plc | Anti-ageing composition |
WO2016102177A1 (en) | 2014-12-22 | 2016-06-30 | Unilever Plc | Hair composition |
WO2016188691A1 (en) | 2015-05-22 | 2016-12-01 | Unilever Plc | Hair treatment compositions |
WO2017040876A1 (en) | 2015-09-02 | 2017-03-09 | Dow Corning Corporation | Silicones for heat protection |
WO2017067888A1 (en) | 2015-10-21 | 2017-04-27 | Unilever Plc | Method |
WO2017084826A1 (en) | 2015-11-17 | 2017-05-26 | Unilever Plc | Climbazole microcapsule and hair care composition comprising surfactant and climbazole |
WO2017097817A1 (en) | 2015-12-08 | 2017-06-15 | Clariant International Ltd | A shampoo composition comprising at least one oligoester ammonium salt |
WO2017157993A1 (en) | 2016-03-18 | 2017-09-21 | Unilever Plc | Hair treatment compositions |
WO2017189077A1 (en) | 2016-04-27 | 2017-11-02 | Dow Corning Corporation | Hydrophilic silanes |
WO2018065248A1 (en) | 2016-10-05 | 2018-04-12 | Unilever Plc | Hair treatment composition |
WO2018095813A1 (en) | 2016-11-28 | 2018-05-31 | Clariant International Ltd | Cosmetic composition comprising a cationic copolymer |
WO2019030034A1 (en) | 2017-08-09 | 2019-02-14 | Unilever Plc | Hair compositions for damage treatment |
WO2019086274A1 (en) | 2017-11-03 | 2019-05-09 | Unilever Plc | Antidandruff composition and method of use |
WO2019086276A1 (en) | 2017-11-03 | 2019-05-09 | Unilever Plc | Shampoo composition and method of use |
US10358529B2 (en) | 2014-12-19 | 2019-07-23 | Dow Silicones Corporation | Method of preparing functionalized particles |
WO2020025404A1 (en) | 2018-07-30 | 2020-02-06 | Unilever Plc | Hair cleansing composition |
WO2020126356A1 (en) | 2018-12-21 | 2020-06-25 | Unilever N.V. | Hair care composition comprising pyrithione |
EP3677244A2 (en) | 2020-02-04 | 2020-07-08 | Clariant International Ltd | Compositions comprising multilamellar vesicles |
WO2020144060A1 (en) | 2019-01-09 | 2020-07-16 | Unilever Plc | Shampoo composition and method of use |
EP3695825A1 (en) | 2019-02-15 | 2020-08-19 | Unilever PLC | Hair care composition |
WO2020229203A1 (en) | 2019-05-14 | 2020-11-19 | Unilever N.V. | Hair care composition comprising a 2(1h)-pyridinone and piroctone olamine |
WO2021004770A1 (en) | 2019-07-09 | 2021-01-14 | Unilever N.V. | Hair care composition comprising antidandruff agent |
WO2021037679A1 (en) | 2019-08-23 | 2021-03-04 | Unilever Global Ip Limited | Use of hair treatment composition in foam format |
WO2021037676A1 (en) | 2019-08-23 | 2021-03-04 | Unilever Global Ip Limited | Hair treatment composition in foam format |
WO2021043628A1 (en) | 2019-09-06 | 2021-03-11 | Unilever Global Ip Limited | Microcapsule and hair care composition |
WO2021043627A1 (en) | 2019-09-06 | 2021-03-11 | Unilever Global Ip Limited | Microcapsule and hair care composition |
WO2021069533A1 (en) | 2019-10-08 | 2021-04-15 | Unilever Ip Holdings B.V. | Hair treatment compositions |
WO2021074012A1 (en) | 2019-10-18 | 2021-04-22 | Unilever Ip Holdings B.V. | Hair treatment method |
EP3811923A1 (en) | 2019-10-25 | 2021-04-28 | Unilever PLC | Cleansing compositions |
EP3818972A2 (en) | 2021-01-29 | 2021-05-12 | Clariant International Ltd | Piroctone olamine granules for use in cosmetic compositions |
WO2021089306A1 (en) | 2019-11-06 | 2021-05-14 | Unilever Ip Holdings B.V. | Anti-inflammatory composition |
WO2021099117A1 (en) | 2019-11-21 | 2021-05-27 | Unilever Ip Holdings B.V. | A cosmetic composition |
WO2021129968A1 (en) | 2019-12-25 | 2021-07-01 | Unilever Ip Holdings B.V. | Microcapsules and cosmetic compositions comprising the same |
WO2021144272A1 (en) | 2020-01-17 | 2021-07-22 | Unilever Ip Holdings B.V. | Hair treatment composition |
WO2021156213A1 (en) | 2020-02-04 | 2021-08-12 | Clariant International Ltd | Lipid nanoparticles for delayed delivery of fragrance with enhanced water solubility, their preparation and use |
WO2021175499A1 (en) | 2020-03-06 | 2021-09-10 | Unilever Ip Holdings B.V. | Personal care composition and methods |
WO2021175583A1 (en) | 2020-03-06 | 2021-09-10 | Clariant International Ltd | Lipid nanoparticles comprising a fragrance |
WO2021181099A1 (en) | 2020-03-12 | 2021-09-16 | Innospec Active Chemicals Llc | Solid cleansing composition comprising an acyl alkyl isethionate |
WO2021181098A1 (en) | 2020-03-11 | 2021-09-16 | Innospec Active Chemicals Llc | Solid cleansing composition |
WO2021224118A1 (en) | 2020-05-08 | 2021-11-11 | Unilever Ip Holdings B.V. | Personal care compositions comprising a metal piroctone complex |
EP3944852A1 (en) | 2020-07-28 | 2022-02-02 | Clariant International Ltd | Use of a booster to enhance the anti-dandruff or preservative activity of piroctone olamine |
WO2022084489A1 (en) | 2020-10-23 | 2022-04-28 | Clariant International Ltd | Opacifier compositions |
WO2022089892A1 (en) | 2020-10-27 | 2022-05-05 | Unilever Ip Holdings B.V. | Hair care composition |
WO2022128551A1 (en) | 2020-12-18 | 2022-06-23 | Unilever Ip Holdings B.V. | Anti-dandruff composition comprising piroctone olamine |
WO2022214437A1 (en) | 2021-04-08 | 2022-10-13 | Unilever Ip Holdings B.V. | Hair treatment composition |
WO2022218767A1 (en) | 2021-04-15 | 2022-10-20 | Unilever Ip Holdings B.V. | Hair treatment method |
WO2022238590A2 (en) | 2021-07-19 | 2022-11-17 | Clariant International Ltd | Piroctone particles for use in cosmetic compositions |
EP4091675A1 (en) | 2021-07-19 | 2022-11-23 | Clariant International Ltd | Cosmetic composition comprising piroctone and a fragrance |
US11530373B2 (en) | 2016-11-28 | 2022-12-20 | Clariant International Ltd | Cleaning agent compositions containing copolymer |
WO2023285195A1 (en) | 2021-07-15 | 2023-01-19 | Unilever Ip Holdings B.V. | Hydratable concentrated surfactant compositions |
WO2023046529A1 (en) | 2021-09-21 | 2023-03-30 | Unilever Ip Holdings B.V. | Conditioning shampoo composition |
US11649310B2 (en) | 2016-11-28 | 2023-05-16 | Clariant International Ltd | Copolymers and the use of same in cleaning agent compositions |
WO2023094599A1 (en) | 2021-11-29 | 2023-06-01 | Unilever Ip Holdings B.V. | Hydratable concentrated surfactant compositions |
WO2023094600A1 (en) | 2021-11-29 | 2023-06-01 | Unilever Ip Holdings B.V. | Hydratable concentrated surfactant compositions |
US11692052B2 (en) | 2016-11-28 | 2023-07-04 | Clariant International Ltd | Copolymers and use thereof in cleaning-agent compositions |
WO2023148138A1 (en) | 2022-02-02 | 2023-08-10 | Clariant International Ltd | Compounds for use as hair repair agents or fabric repair agents |
WO2023227305A1 (en) | 2022-05-27 | 2023-11-30 | Unilever Ip Holdings B.V. | Concentrated cleansing compositions |
Families Citing this family (59)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2718961B1 (en) * | 1994-04-22 | 1996-06-21 | Oreal | Compositions for washing and treating hair and skin based on ceramide and polymers with cationic groups. |
ES2171658T3 (en) * | 1995-04-04 | 2002-09-16 | Ici Plc | SURFACTING COMPOSITIONS. |
US6077816A (en) * | 1995-08-07 | 2000-06-20 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Liquid cleansing composition comprising soluble, lamellar phase inducing structurant |
EP0839023B1 (en) * | 1995-08-07 | 2003-04-09 | Unilever Plc | Liquid cleansing composition comprising soluble, lamellar phase inducing structurant |
ID18376A (en) * | 1996-01-29 | 1998-04-02 | Johnson & Johnson Consumer | DETERGENT COMPOSITIONS |
US6090773A (en) * | 1996-01-29 | 2000-07-18 | Johnson & Johnson Consumer Products, Inc. | Personal cleansing |
US5723426A (en) * | 1996-02-29 | 1998-03-03 | Zhen; Yueqian | Liquid laundry detergent compositions containing surfactants and silicone emulsions |
EP0805197A1 (en) * | 1996-05-03 | 1997-11-05 | The Procter & Gamble Company | Cleaning compositions |
US6551970B2 (en) | 1996-05-06 | 2003-04-22 | L'oréal | Detergent cosmetic compositions for hair-care application and use thereof |
JP3498199B2 (en) * | 1996-09-04 | 2004-02-16 | 株式会社コーセー | Skin cleansing composition |
GB9623935D0 (en) * | 1996-11-18 | 1997-01-08 | Unilever Plc | Aqueous cleansing composition |
GB9704643D0 (en) | 1997-03-06 | 1997-04-23 | Johnson & Johnson | Chemical composition |
US6165454A (en) * | 1997-09-18 | 2000-12-26 | Colgate-Palmolive Company | Stabilized hair care products |
AU737541B2 (en) * | 1997-11-12 | 2001-08-23 | Bausch & Lomb Incorporated | Disinfecting contact lenses with polyquaterniums and polymeric biguanides |
US6040282A (en) * | 1998-02-03 | 2000-03-21 | The Procter & Gamble Company | Styling shampoo compositions which deliver improved hair curl retention and hair feel |
ES2242340T3 (en) * | 1998-10-26 | 2005-11-01 | Dsm Ip Assets B.V. | SHAMPOO COMPOSITION CONTAINING LIGHT PROTECTIVE AGENTS. |
DE19854827A1 (en) * | 1998-11-27 | 2000-06-08 | Merz & Co Gmbh & Co | Water-based vesicle-forming surfactant-containing cleaning preparations, process for their preparation and their use |
US6126954A (en) * | 1999-04-05 | 2000-10-03 | Unilever Home & Personal Care Usa, Division Of Conopco | Liquid compositions comprising stable emulsion of small particle skin benefit agent |
US6150312A (en) * | 1999-04-05 | 2000-11-21 | Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. | Liquid composition with enhanced low temperature stability comprising sodium tricedeth sulfate |
US6974569B2 (en) * | 1999-05-03 | 2005-12-13 | The Procter & Gamble Company | Shampoos providing a superior combination anti-dandruff efficacy and condition |
US6649155B1 (en) | 1999-05-03 | 2003-11-18 | The Procter & Gamble Company | Anti-dandruff and conditioning shampoos containing certain cationic polymers |
US6451300B1 (en) | 1999-05-03 | 2002-09-17 | The Procter & Gamble Company | Anti-dandruff and conditioning shampoos containing polyalkylene glycols and cationic polymers |
US6808701B2 (en) | 2000-03-21 | 2004-10-26 | Johnson & Johnson Consumer Companies, Inc. | Conditioning compositions |
US6514918B1 (en) | 2000-08-18 | 2003-02-04 | Johnson & Johnson Consumer Companies, Inc. | Viscous, mild, and effective cleansing compositions |
FR2813189B1 (en) * | 2000-08-31 | 2003-02-28 | Oreal | COSMETIC FOAMING CREAM FOR THE TREATMENT OF OILY SKIN |
US6998372B2 (en) | 2001-08-16 | 2006-02-14 | J&J Consumer Companies, Inc. | Moisturizing detergent compositions |
FR2829693B1 (en) * | 2001-09-20 | 2004-02-27 | Oreal | FOAMING COSMETIC CREAM |
US6838078B2 (en) | 2002-01-16 | 2005-01-04 | 3M Innovative Properties Company | Film-forming compositions and methods |
US7147873B2 (en) | 2002-01-16 | 2006-12-12 | 3M Innovative Properties Company | Antiseptic compositions and methods |
CA2482038A1 (en) * | 2002-04-22 | 2003-10-30 | The Procter & Gamble Company | Shampoo containing a cationic guar derivative |
AU2003273287A1 (en) * | 2002-06-04 | 2003-12-19 | The Procter & Gamble Company | Conditioning shampoo composition containing select cationic conditioning polymers |
DE60337004D1 (en) * | 2002-06-18 | 2011-06-16 | Procter & Gamble | COMPOSITIONS OF CATIONIC POLYMERS HAVING HIGH LOADING DENSITY AND CONDITIONING AGENT |
US20040091445A1 (en) * | 2002-11-01 | 2004-05-13 | The Procter & Gamble Company | Rinse-off personal care compositions comprising cationic perfume polymeric particles |
GB0226380D0 (en) * | 2002-11-12 | 2002-12-18 | Unilever Plc | Compositions for washing and conditioning hair |
MXPA05008384A (en) * | 2003-02-07 | 2005-10-05 | Ciba Sc Holding Ag | Cosmetic eye-care compositions comprising a low molecular weight cationic copolymer. |
US7378382B2 (en) * | 2004-05-05 | 2008-05-27 | The Clorox Company | Rheologically stabilized silicone dispersions comprising a polydimethylsiloxane mixture |
US7871972B2 (en) * | 2005-01-12 | 2011-01-18 | Amcol International Corporation | Compositions containing benefit agents pre-emulsified using colloidal cationic particles |
CA2594810C (en) * | 2005-01-12 | 2013-05-21 | Amcol International Corporation | Detersive compositions containing hydrophobic benefit agents pre-emulsified using colloidal cationic particles |
US7977288B2 (en) * | 2005-01-12 | 2011-07-12 | Amcol International Corporation | Compositions containing cationically surface-modified microparticulate carrier for benefit agents |
US7915214B2 (en) * | 2006-01-12 | 2011-03-29 | Amcol International Corporation | Compositions containing benefit agent composites pre-emulsified using colloidal cationic particles |
CA2691036A1 (en) | 2007-05-14 | 2008-11-27 | Amcol International Corporation | Compositions containing benefit agent composites pre-emulsified using colloidal cationic particles |
US20090049623A1 (en) * | 2007-08-20 | 2009-02-26 | Mark Anthony Brown | Method for Preventing Color Loss in Oxidatively Dyed Hair |
US20090087398A1 (en) * | 2007-08-20 | 2009-04-02 | Mark Anthony Brown | Method for Treating Damaged Hair |
US20090053165A1 (en) * | 2007-08-20 | 2009-02-26 | Mark Anthony Brown | Method for Treating Damaged Hair |
US8188022B2 (en) | 2008-04-11 | 2012-05-29 | Amcol International Corporation | Multilayer fragrance encapsulation comprising kappa carrageenan |
DE102008032179A1 (en) | 2008-07-09 | 2010-01-21 | Henkel Ag & Co. Kgaa | Surfactant-containing composition, useful for cleaning the skin, comprises a film former and a beneficial substance comprising UV filter substances or tanning agents |
CA2730309C (en) * | 2008-07-28 | 2014-03-25 | The Procter & Gamble Company | Multiphase personal care composition with enhanced deposition |
WO2010013203A2 (en) * | 2008-07-28 | 2010-02-04 | The Procter & Gamble Company | In-vitro deposition evaluation method for identifying personal care compositions which provide improved deposition of benefit agents |
KR20110047265A (en) * | 2008-08-29 | 2011-05-06 | 다우 코닝 코포레이션 | Silicone-Organic Hybrid Emulsions in Personal Care Applications |
US20100202985A1 (en) * | 2009-02-11 | 2010-08-12 | Amcol International Corporation | Sunscreen compositions including particulate sunscreen actives that exhibit boosting of sun protection factor |
BRPI1013238B1 (en) * | 2009-03-05 | 2017-05-16 | Basf Se | conditioning polymer, personal cleansing composition or personal care, process for conditioning a keratinous substrate, and method for enhancing silicone deposition to skin, hair or nails |
US8697041B2 (en) | 2010-08-10 | 2014-04-15 | Conopco, Inc. | Anti-dandruff compositions with citrus fibers |
WO2012042000A1 (en) * | 2010-10-01 | 2012-04-05 | Rhodia Operations | Cleaning composition for hard surface |
KR102045878B1 (en) * | 2015-09-30 | 2019-11-18 | (주)아모레퍼시픽 | Cleansing composition comprising higt content of fat-soluble ingredients |
CN109071820B (en) | 2016-05-10 | 2021-08-17 | 美国陶氏有机硅公司 | Silicone block copolymers with amino-functional end-capping groups and methods of making and using the same |
JP2018044273A (en) * | 2016-09-16 | 2018-03-22 | 栗田工業株式会社 | Manufacturing method of paper, manufacturing device of additive for making paper and manufacturing device of paper |
WO2019086275A1 (en) | 2017-11-03 | 2019-05-09 | Unilever Plc | Skin cleansing composition and method of use |
EP3714005B1 (en) | 2017-11-20 | 2022-02-23 | Dow Silicones Corporation | Crosslinked aminosilicone polymer and methods for its preparation and use |
BR112023026360A2 (en) | 2021-06-28 | 2024-03-05 | Dow Silicones Corp | AMINOSILOXANE ESTER COPOLYMER, PROCESS FOR PREPARING THE COPOLYMER, EMULSION, METHOD FOR PREPARING AN EMULSION, AND, USE OF THE COPOLYMER |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4299817A (en) * | 1977-08-24 | 1981-11-10 | Union Carbide Corporation | Hair care compositions |
EP0093601A2 (en) * | 1982-04-30 | 1983-11-09 | Unilever N.V. | Washing composition |
EP0219830A2 (en) * | 1985-10-24 | 1987-04-29 | Dow Corning Corporation | Hair treating composition containing cationic organic polymer and carboxyfunctional silicone |
WO1992010162A1 (en) * | 1990-12-05 | 1992-06-25 | The Procter & Gamble Company | Shampoo compositions with silicone and cationic organic polymeric conditioning agents |
EP0524434A2 (en) * | 1991-06-24 | 1993-01-27 | Helene Curtis, Inc. | Mild condition shampoo with high foam level |
WO1993007903A1 (en) * | 1991-10-16 | 1993-04-29 | Richardson-Vicks, Inc. | Enhanced skin penetration system for improved topical delivery of drugs |
WO1993008787A2 (en) * | 1991-10-29 | 1993-05-13 | The Procter & Gamble Company | Shampoo compositions with silicone, cationic polymer, and oily liquid conditioning agents |
FR2698004A1 (en) * | 1992-11-13 | 1994-05-20 | Oreal | Aqueous cosmetic or dermatological dispersion for the treatment of hair or skin, based on sugar fatty acid esters or alkylsugar and crosslinked copolymers of acrylamide. |
WO1994021224A1 (en) * | 1993-03-16 | 1994-09-29 | L'oreal | Cosmetic or topical use of an aqueous dispersion based on non-volatile organopolysiloxanes and an acrylamide or homopolymeric copolymer type cross-linked methacryloyloxyethyl trimethylammonium chloride polymer |
WO1995009599A1 (en) * | 1993-10-06 | 1995-04-13 | Unilever Plc | Hair conditioning composition |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2826551A (en) * | 1954-01-04 | 1958-03-11 | Simoniz Co | Nontangling shampoo |
US3580853A (en) * | 1967-09-27 | 1971-05-25 | Procter & Gamble | Detergent compositions containing particle deposition enhancing agents |
US5037818A (en) * | 1982-04-30 | 1991-08-06 | Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. | Washing composition for the hair |
EP0115252A3 (en) † | 1982-12-29 | 1985-12-27 | Ciba-Geigy Ag | Mixtures of quaternary polymer ammonium salts, surfactants and fatty acids, their preparation and use in cosmetic compositions |
GB8600496D0 (en) * | 1986-01-09 | 1986-02-12 | Unilever Plc | Shampoo |
US4983383A (en) * | 1988-11-21 | 1991-01-08 | The Procter & Gamble Company | Hair care compositions |
GB8903777D0 (en) * | 1989-02-20 | 1989-04-05 | Unilever Plc | Shampoo composition |
FR2653331B1 (en) * | 1989-10-20 | 1994-05-20 | Oreal | USE IN COSMETICS, FOR THE TREATMENT OF HAIR OR SKIN AND / OR IN DERMATOLOGY, AN AQUEOUS DISPERSION BASED ON ORGANOPOLYSILOXANES AND A COPOLYMER ACRYLATE AMMONIUM / ACRYLAMIDE CROSSLINKED. |
IN171189B (en) * | 1989-12-04 | 1992-08-15 | Lever Hindustan Ltd | |
US5417965A (en) † | 1991-06-24 | 1995-05-23 | Helene Curtis, Inc. | Stable conditioning shampoo having a high foam level containing a silicone conditioner, a cationic quaternary acrylate copolymer, an anionic surfactant and polyethyleneimine |
GB9117740D0 (en) * | 1991-08-16 | 1991-10-02 | Unilever Plc | Cosmetic composition |
EP0652774B1 (en) † | 1992-07-28 | 1997-05-07 | The Procter & Gamble Company | Pharmaceutical composition for topical use containing a crosslinked cationic polymer and an alkoxylated ether |
-
1995
- 1995-02-16 JP JP7521593A patent/JP2746758B2/en not_active Expired - Lifetime
- 1995-02-16 EP EP95909734A patent/EP0744935B2/en not_active Expired - Lifetime
- 1995-02-16 BR BR9506797A patent/BR9506797A/en not_active IP Right Cessation
- 1995-02-16 WO PCT/EP1995/000582 patent/WO1995022311A1/en active IP Right Grant
- 1995-02-16 US US08/389,384 patent/US5543074A/en not_active Expired - Lifetime
- 1995-02-16 AU AU18097/95A patent/AU1809795A/en not_active Abandoned
- 1995-02-16 CA CA002180942A patent/CA2180942C/en not_active Expired - Lifetime
- 1995-02-16 ES ES95909734T patent/ES2153026T5/en not_active Expired - Lifetime
- 1995-02-16 DE DE69519372T patent/DE69519372T3/en not_active Expired - Lifetime
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4299817A (en) * | 1977-08-24 | 1981-11-10 | Union Carbide Corporation | Hair care compositions |
EP0093601A2 (en) * | 1982-04-30 | 1983-11-09 | Unilever N.V. | Washing composition |
EP0219830A2 (en) * | 1985-10-24 | 1987-04-29 | Dow Corning Corporation | Hair treating composition containing cationic organic polymer and carboxyfunctional silicone |
WO1992010162A1 (en) * | 1990-12-05 | 1992-06-25 | The Procter & Gamble Company | Shampoo compositions with silicone and cationic organic polymeric conditioning agents |
EP0524434A2 (en) * | 1991-06-24 | 1993-01-27 | Helene Curtis, Inc. | Mild condition shampoo with high foam level |
WO1993007903A1 (en) * | 1991-10-16 | 1993-04-29 | Richardson-Vicks, Inc. | Enhanced skin penetration system for improved topical delivery of drugs |
WO1993008787A2 (en) * | 1991-10-29 | 1993-05-13 | The Procter & Gamble Company | Shampoo compositions with silicone, cationic polymer, and oily liquid conditioning agents |
FR2698004A1 (en) * | 1992-11-13 | 1994-05-20 | Oreal | Aqueous cosmetic or dermatological dispersion for the treatment of hair or skin, based on sugar fatty acid esters or alkylsugar and crosslinked copolymers of acrylamide. |
WO1994021224A1 (en) * | 1993-03-16 | 1994-09-29 | L'oreal | Cosmetic or topical use of an aqueous dispersion based on non-volatile organopolysiloxanes and an acrylamide or homopolymeric copolymer type cross-linked methacryloyloxyethyl trimethylammonium chloride polymer |
WO1995009599A1 (en) * | 1993-10-06 | 1995-04-13 | Unilever Plc | Hair conditioning composition |
Cited By (205)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5612307A (en) * | 1994-07-19 | 1997-03-18 | Lever Brothers Company, Division Of Conopco, Inc. | Detergent compositions containing separate stripes of surface active agents and benefit agent |
US5723112A (en) * | 1995-07-14 | 1998-03-03 | Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. | Pyrithione containing hair treatment composition |
WO1997003637A1 (en) * | 1995-07-14 | 1997-02-06 | Unilever Plc | Antimicrobial hair treatment composition |
US6365560B1 (en) | 1995-11-03 | 2002-04-02 | Colgate-Palmolive Company | Composition comprising triclocarban or triclosan |
WO1997016168A1 (en) * | 1995-11-03 | 1997-05-09 | Colgate-Palmolive Company | Personal cleansing composition |
US6008173A (en) * | 1995-11-03 | 1999-12-28 | Colgate-Palmolive Co. | Bar composition comprising petrolatum |
US6156713A (en) * | 1995-11-03 | 2000-12-05 | Colgate-Palmolive Company | Composition |
CN1305456C (en) * | 1995-11-03 | 2007-03-21 | 科尔加特·帕尔莫利弗公司 | Personal cleansing composition |
US5759524A (en) * | 1996-02-09 | 1998-06-02 | The Procter & Gamble Company | Photoprotective compositions |
WO1997028785A1 (en) * | 1996-02-09 | 1997-08-14 | The Procter & Gamble Company | Photoprotective compositions |
US6024942A (en) * | 1996-02-09 | 2000-02-15 | The Procter & Gamble Company | Photoprotective compositions |
WO1997029736A1 (en) * | 1996-02-15 | 1997-08-21 | Unilever Plc | Liquid cleansing compositions comprising select cationic polymers |
WO1997035543A1 (en) * | 1996-03-27 | 1997-10-02 | The Procter & Gamble Company | Conditioning shampoo compositions containing select cationic conditioning polymers |
US5900394A (en) * | 1996-04-10 | 1999-05-04 | Lever Brothers Company | Detergent compositions for enhanced delivery of functional ingredients |
FR2750046A1 (en) * | 1996-06-19 | 1997-12-26 | Oreal | Cosmetic or dermatological topical composition in form of aqueous gel |
US5804538A (en) * | 1996-06-20 | 1998-09-08 | The Procter & Gamble Company | Perfume delivery systems in liquid personal cleansing compositions |
US5843875A (en) * | 1996-06-20 | 1998-12-01 | The Procter & Gamble Company | Perfume delivery systems in liquid personal cleansing |
US6355234B1 (en) | 1996-08-05 | 2002-03-12 | Helene Curtis, Inc. | Shampoo compositions and method |
US6004544A (en) * | 1996-10-25 | 1999-12-21 | The Procter & Gamble Co. | Conditioning shampoo composition |
US6248317B1 (en) | 1996-10-25 | 2001-06-19 | The Procter & Gamble Company | Styling shampoo compositions with improved styling polymer deposition |
WO1998018443A1 (en) * | 1996-10-25 | 1998-05-07 | The Procter & Gamble Company | Conditioning shampoo composition |
WO1998018435A2 (en) * | 1996-10-25 | 1998-05-07 | The Procter & Gamble Company | Conditioning shampoo composition |
AU721696B2 (en) * | 1996-10-25 | 2000-07-13 | Procter & Gamble Company, The | Conditioning shampoo composition |
WO1998018435A3 (en) * | 1996-10-25 | 1998-09-17 | Procter & Gamble | Conditioning shampoo composition |
US6174522B1 (en) | 1996-10-25 | 2001-01-16 | The Procter & Gamble Company | Conditioning shampoo composition |
US6048519A (en) * | 1997-03-27 | 2000-04-11 | Helene Curtis, Inc. | Hair treatment compositions |
US6010689A (en) * | 1997-04-21 | 2000-01-04 | Helene Curtis, Inc. | Hair treatment compositions containing amidopolyether functional silicone |
US6277361B1 (en) | 1998-03-05 | 2001-08-21 | Helene Curtis, Inc. | Shampoo compositions comprising a surfactant, an amino functionalized silicone, and a non-amino functionalized silicone |
US6719967B1 (en) | 1998-04-03 | 2004-04-13 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Hair treatment compositions |
US6706258B1 (en) | 1998-04-20 | 2004-03-16 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Shampoo compositions comprising and emulsified silicone an a microemulsified silicone |
US6432420B2 (en) | 1998-06-01 | 2002-08-13 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Hair treatment compositions |
WO1999062462A2 (en) * | 1998-06-01 | 1999-12-09 | Unilever Plc | Hair treatment compositions |
WO1999062462A3 (en) * | 1998-06-01 | 2000-03-02 | Unilever Plc | Hair treatment compositions |
US6362146B1 (en) | 1998-06-05 | 2002-03-26 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Personal washing compositions |
EP1000612A1 (en) * | 1998-11-12 | 2000-05-17 | Beiersdorf Aktiengesellschaft | Preparations of W/O type emulsions with high water content and further containing one or more alkylmethicone copolyols and/or alkyl-dimethicone copolyols as well as cationic polymers |
WO2000033807A1 (en) * | 1998-12-10 | 2000-06-15 | Unilever Plc | Washing compositions |
US6348188B1 (en) * | 1998-12-10 | 2002-02-19 | Unilever Home & Personal Care Usa | Washing compositions |
AU747078B2 (en) * | 1998-12-15 | 2002-05-09 | Unilever Plc | Detergent composition |
US6255264B1 (en) | 1998-12-15 | 2001-07-03 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Detergent composition containing a benefit agent made up of aggregated particles |
WO2000035416A1 (en) * | 1998-12-15 | 2000-06-22 | Unilever Plc | Detergent composition |
CZ302598B6 (en) * | 1998-12-15 | 2011-07-27 | Unilever N. V. | Aqueous liquid cleansing and moisturizing composition and process for preparing thereof |
US6399045B1 (en) | 1999-04-23 | 2002-06-04 | Unilever Home & Personal Care Usa A Division Of Conopco, Inc. | Liquid sunscreen compositions which both deposit and lather well |
US6224852B1 (en) | 1999-04-23 | 2001-05-01 | Unilever Home & Personal Care Usa | Liquid sunscreen compositions which both deposit and lather well |
US6864314B1 (en) | 1999-05-26 | 2005-03-08 | Dominic Wai-Kwing Yeung | Block polymers, compositions and methods of use for foams, laundry detergents, shower rinses and coagulants |
US8907033B2 (en) | 1999-05-26 | 2014-12-09 | Solvay Usa Inc. | Polymers, compositions and methods of use for foams, laundry detergents, shower rinses and coagulants |
US9044413B2 (en) | 1999-05-26 | 2015-06-02 | Solvay Usa Inc. | Block polymers, compositions and methods for use for foams, laundry detergents, and shower rinses and coagulants |
US7241729B2 (en) | 1999-05-26 | 2007-07-10 | Rhodia Inc. | Compositions and methods for using polymeric suds enhancers |
US6627585B1 (en) | 1999-06-15 | 2003-09-30 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Mousse-forming shampoo compositions |
US6551361B1 (en) | 1999-07-23 | 2003-04-22 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Method of hair treatment using organic amino compounds |
US6509011B1 (en) | 1999-07-23 | 2003-01-21 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Method of hair treatment using organic amino compounds |
US6491902B2 (en) | 2001-01-29 | 2002-12-10 | Salvona Llc | Controlled delivery system for hair care products |
US6979440B2 (en) | 2001-01-29 | 2005-12-27 | Salvona, Llc | Compositions and method for targeted controlled delivery of active ingredients and sensory markers onto hair, skin, and fabric |
US7416735B2 (en) | 2002-03-28 | 2008-08-26 | The Procter & Gamble Company | Emulsion compositions |
US7183243B2 (en) | 2002-11-12 | 2007-02-27 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Compositions for washing and conditioning hair |
US8906843B2 (en) | 2002-11-25 | 2014-12-09 | Colgate-Palmolive Company | Functional fragrance precursor |
US8592361B2 (en) | 2002-11-25 | 2013-11-26 | Colgate-Palmolive Company | Functional fragrance precursor |
US8901068B2 (en) | 2002-11-25 | 2014-12-02 | Colgate-Palmolive Company | Functional fragrance precursor |
US8895495B2 (en) | 2002-11-25 | 2014-11-25 | Colgate-Palmolive Company | Functional fragrance precursor |
US8895496B2 (en) | 2002-11-25 | 2014-11-25 | Colgate-Palmolive Company | Functional fragrance precursor |
EP2236126A1 (en) | 2005-03-12 | 2010-10-06 | Unilever PLC | Hair and/or Scalp Care Compositions Incorporating Isophaseollin |
EP2082726A2 (en) | 2005-03-12 | 2009-07-29 | Unilever PLC | Hair and/or scalp care compositions incorporating flavonoid compounds |
US7300912B2 (en) | 2005-08-10 | 2007-11-27 | Fiore Robert A | Foaming cleansing preparation and system comprising coated acid and base particles |
US8298553B2 (en) | 2007-12-06 | 2012-10-30 | Conopco, Inc. | Personal care composition |
US8501743B2 (en) | 2007-12-06 | 2013-08-06 | Conopco, Inc. | Personal care composition |
US8664328B2 (en) | 2008-04-14 | 2014-03-04 | Dow Corning Corporation | Emulsions of boron crosslinked organopolysiloxanes |
EP2246034A2 (en) | 2008-10-10 | 2010-11-03 | Unilever PLC | Use of personal care composition |
US8734767B2 (en) | 2008-10-22 | 2014-05-27 | Dow Corning Corporation | Aminofunctional endblocked silicone polyether copolymers in personal care compositions |
WO2011003695A1 (en) | 2009-07-10 | 2011-01-13 | Unilever Plc | Hair treatment compositions |
WO2011019539A2 (en) | 2009-08-13 | 2011-02-17 | Dow Corning Corporation | Granulated dry cleanser for the care of keratinous substrates |
WO2011028765A1 (en) | 2009-09-03 | 2011-03-10 | Dow Corning Corporation | Personal care compositions with pituitous silicone fluids |
WO2011062805A1 (en) | 2009-11-23 | 2011-05-26 | Lubrizol Advanced Materials, Inc. | Surfactant-polymer blends |
WO2011066359A1 (en) | 2009-11-25 | 2011-06-03 | Dow Corning Corporation | Personal care compositions containing certain cyclic siloxanes |
WO2011092083A2 (en) | 2010-02-01 | 2011-08-04 | Unilever Plc | Composition |
WO2011117023A1 (en) | 2010-03-26 | 2011-09-29 | Unilever Plc | Shampoo containing a dendritic macromolecule and a gel network |
WO2011120736A1 (en) | 2010-03-29 | 2011-10-06 | Unilever Plc | Hair care composition comprising alkyl -modified siloxane |
WO2011124560A2 (en) | 2010-04-09 | 2011-10-13 | Dsm Ip Assets B.V. | Hair care compositions |
WO2011130460A1 (en) | 2010-04-14 | 2011-10-20 | Lubrizol Advanced Materials, Inc. | Thickened amino acid surfactant compositions and methods therefor |
WO2011154315A2 (en) | 2010-06-10 | 2011-12-15 | Unilever Plc | Hair care composition |
WO2012004126A2 (en) | 2010-07-08 | 2012-01-12 | Unilever Plc | Hair care composition |
US9040031B2 (en) | 2010-07-08 | 2015-05-26 | Conopco, Inc. | Hair care composition |
US9242002B2 (en) | 2010-08-18 | 2016-01-26 | Conopco, Inc. | Anti-dandruff shampoo |
WO2012022552A1 (en) | 2010-08-18 | 2012-02-23 | Unilever Plc | Anti-dandruff shampoo |
WO2012022553A1 (en) | 2010-08-18 | 2012-02-23 | Unilever Plc | Anti-dandruff shampoo |
WO2012072424A2 (en) | 2010-12-02 | 2012-06-07 | Unilever Plc | Anti-dandruff shampoo |
US8771377B2 (en) | 2011-03-10 | 2014-07-08 | Conopco, Inc. | Hair care composition comprising pyrithione and a purple, pink or red colouring component |
WO2012119824A2 (en) | 2011-03-10 | 2012-09-13 | Unilever Nv | Composition |
WO2012119825A2 (en) | 2011-03-10 | 2012-09-13 | Unilever Nv | Composition |
WO2012119810A2 (en) | 2011-03-10 | 2012-09-13 | Unilever Plc | Composition |
US8778318B2 (en) | 2011-03-10 | 2014-07-15 | Conopco, Inc. | Hair care composition comprising pyrithione and a pearliser system based on bismuth oxychloride |
WO2012139947A2 (en) | 2011-04-13 | 2012-10-18 | Unilever Plc | Hair care composition |
WO2012139943A2 (en) | 2011-04-13 | 2012-10-18 | Unilever Plc | Hair care composition |
WO2012139944A2 (en) | 2011-04-13 | 2012-10-18 | Unilever Plc | Hair care composition |
WO2012139948A2 (en) | 2011-04-13 | 2012-10-18 | Unilever Plc | Hair care composition |
WO2012139951A1 (en) | 2011-04-13 | 2012-10-18 | Unilever Plc | Hair care composition |
WO2012150260A1 (en) | 2011-05-04 | 2012-11-08 | Unilever Plc | Hair care composition comprising hydrophobically-modified anionic polymer and a methylcellulose |
WO2012150259A1 (en) | 2011-05-04 | 2012-11-08 | Unilever Plc | Composition |
WO2012156177A1 (en) | 2011-05-13 | 2012-11-22 | Unilever Plc | Hair treatment compositions |
WO2012159918A1 (en) | 2011-05-25 | 2012-11-29 | Unilever Plc | Hair colouring product comprising metal ions and a component from vaccinium berries |
WO2012159919A1 (en) | 2011-05-25 | 2012-11-29 | Unilever Plc | Hair colouring product comprising metal ions and a component from the fruit of the redcurrant or blackcurrant |
WO2012159920A1 (en) | 2011-05-25 | 2012-11-29 | Unilever Plc | Hair care composition |
WO2013007607A2 (en) | 2011-07-08 | 2013-01-17 | Unilever Plc | Hair care composition |
WO2013007606A2 (en) | 2011-07-08 | 2013-01-17 | Unilever Plc | Hair care composition |
WO2013026656A1 (en) | 2011-08-24 | 2013-02-28 | Unilever Plc | Benefit agent delivery particles comprising dextran |
WO2013026657A1 (en) | 2011-08-24 | 2013-02-28 | Unilever Plc | Benefit agent delivery particles comprising non-ionic polysaccharides |
WO2013082224A1 (en) | 2011-11-29 | 2013-06-06 | Dow Corning Corporation | Aminofunctional organosiloxanes |
WO2013082096A1 (en) | 2011-11-29 | 2013-06-06 | Dow Corning Corporation | Aminofunctional silicone emulsions for fiber treatments |
WO2013083510A2 (en) | 2011-12-06 | 2013-06-13 | Unilever Plc | Hair colour composition |
WO2013087644A2 (en) | 2011-12-12 | 2013-06-20 | Unilever Plc | Method of strengthening hair fibres |
US9877905B2 (en) | 2011-12-22 | 2018-01-30 | Innospec Limited | Personal care composition and method of use thereof |
WO2013093475A1 (en) | 2011-12-22 | 2013-06-27 | Innospec Limited | Composition and method |
WO2013107771A1 (en) | 2012-01-18 | 2013-07-25 | Unilever Plc | Hair care composition |
WO2013107778A1 (en) | 2012-01-18 | 2013-07-25 | Unilever Plc | Hair treatment composition |
WO2013131758A2 (en) | 2012-03-07 | 2013-09-12 | Unilever Plc | Hair care composition |
EP2636402A1 (en) | 2012-03-07 | 2013-09-11 | Unilever PLC | Hair colouring composition |
WO2013131756A2 (en) | 2012-03-07 | 2013-09-12 | Unilever Plc | Hair care composition |
WO2013131752A2 (en) | 2012-03-07 | 2013-09-12 | Unilever Plc | Hair care composition |
WO2014023448A1 (en) | 2012-08-06 | 2014-02-13 | Unilever Plc | Hair composition |
WO2014023440A1 (en) | 2012-08-06 | 2014-02-13 | Unilever N.V. | Shampoo composition |
EP2705771A1 (en) | 2012-09-07 | 2014-03-12 | Unilever PLC | Hair care composition |
EP2705772A1 (en) | 2012-09-07 | 2014-03-12 | Unilever PLC | Hair care composition |
WO2014040811A1 (en) | 2012-09-17 | 2014-03-20 | Dsm Ip Assets B.V. | Hair care polymer |
WO2014058887A1 (en) | 2012-10-11 | 2014-04-17 | Dow Corning Corporation | Aqueous silicone polyether microemulsions |
WO2014064121A2 (en) | 2012-10-25 | 2014-05-01 | Unilever Plc | Improvements relating to surface treatment compositions |
WO2014082846A1 (en) | 2012-11-29 | 2014-06-05 | Unilever Plc | Hair care composition |
WO2014095289A2 (en) | 2012-12-20 | 2014-06-26 | Unilever Plc | Method of treating hair ageing |
WO2014106603A1 (en) | 2013-01-03 | 2014-07-10 | Unilever Plc | Hair care composition |
WO2014122132A1 (en) | 2013-02-06 | 2014-08-14 | Unilever Plc | Topical colouring composition |
WO2014143757A1 (en) | 2013-03-15 | 2014-09-18 | Dow Corning Corporation | Cosmetic compositions containing silicone resin emulsions |
WO2014177315A1 (en) | 2013-04-29 | 2014-11-06 | Unilever Plc | Hair colouring composition |
EP2799115A1 (en) | 2013-05-03 | 2014-11-05 | Unilever PLC | Hair care composition |
EP2873412A1 (en) | 2013-11-13 | 2015-05-20 | Unilever PLC | A hair colour composition and method of colouring hair |
WO2015078943A1 (en) | 2013-11-28 | 2015-06-04 | Unilever Plc | Improvements relating to encapsulated benefit agents |
WO2015179513A1 (en) | 2014-05-21 | 2015-11-26 | Dow Corning Corporation | Cross-linked aminosiloxane polymer and method of forming |
WO2015179512A1 (en) | 2014-05-21 | 2015-11-26 | Dow Corning Corporation | Aminosiloxane polymer and method of forming |
US10059806B2 (en) | 2014-05-21 | 2018-08-28 | Dow Silicones Corporation | Aminosiloxane polymer and method of forming |
US9890253B2 (en) | 2014-05-21 | 2018-02-13 | Dow Corning Corporation | Cross-linked aminosiloxane polymer and method of forming |
US10172781B2 (en) | 2014-07-23 | 2019-01-08 | Dow Silicones Corporation | Pituitous silicone fluid |
US10500151B2 (en) | 2014-07-23 | 2019-12-10 | Dow Silicones Corporation | Silicone elastomer composition |
WO2016014128A1 (en) | 2014-07-23 | 2016-01-28 | Dow Corning Corporation | Silicone elastomer composition |
WO2016014127A1 (en) | 2014-07-23 | 2016-01-28 | Dow Corning Corporation | Pituitous silicone fluid |
WO2016034521A1 (en) | 2014-09-03 | 2016-03-10 | Unilever Plc | Transparent compositions |
WO2016058837A1 (en) | 2014-10-17 | 2016-04-21 | Unilever Plc | Anti-dandruff hair composition |
WO2016058836A1 (en) | 2014-10-17 | 2016-04-21 | Unilever Plc | Hair care composition |
WO2016071113A1 (en) | 2014-11-04 | 2016-05-12 | Unilever Plc | Anti-ageing composition |
US10358529B2 (en) | 2014-12-19 | 2019-07-23 | Dow Silicones Corporation | Method of preparing functionalized particles |
WO2016102177A1 (en) | 2014-12-22 | 2016-06-30 | Unilever Plc | Hair composition |
WO2016188691A1 (en) | 2015-05-22 | 2016-12-01 | Unilever Plc | Hair treatment compositions |
WO2017040876A1 (en) | 2015-09-02 | 2017-03-09 | Dow Corning Corporation | Silicones for heat protection |
WO2017067888A1 (en) | 2015-10-21 | 2017-04-27 | Unilever Plc | Method |
WO2017084826A1 (en) | 2015-11-17 | 2017-05-26 | Unilever Plc | Climbazole microcapsule and hair care composition comprising surfactant and climbazole |
WO2017097817A1 (en) | 2015-12-08 | 2017-06-15 | Clariant International Ltd | A shampoo composition comprising at least one oligoester ammonium salt |
US11266587B2 (en) | 2015-12-08 | 2022-03-08 | Clariant International Ltd. | Oligoester ammonium salts and their use in compositions for conditioning hair |
US11369555B2 (en) | 2016-03-18 | 2022-06-28 | Conopco, Inc. | Hair treatment compositions |
WO2017157993A1 (en) | 2016-03-18 | 2017-09-21 | Unilever Plc | Hair treatment compositions |
WO2017189077A1 (en) | 2016-04-27 | 2017-11-02 | Dow Corning Corporation | Hydrophilic silanes |
WO2018065248A1 (en) | 2016-10-05 | 2018-04-12 | Unilever Plc | Hair treatment composition |
US11649310B2 (en) | 2016-11-28 | 2023-05-16 | Clariant International Ltd | Copolymers and the use of same in cleaning agent compositions |
WO2018095813A1 (en) | 2016-11-28 | 2018-05-31 | Clariant International Ltd | Cosmetic composition comprising a cationic copolymer |
US11530373B2 (en) | 2016-11-28 | 2022-12-20 | Clariant International Ltd | Cleaning agent compositions containing copolymer |
US11692052B2 (en) | 2016-11-28 | 2023-07-04 | Clariant International Ltd | Copolymers and use thereof in cleaning-agent compositions |
WO2019030034A1 (en) | 2017-08-09 | 2019-02-14 | Unilever Plc | Hair compositions for damage treatment |
US11547647B2 (en) | 2017-08-09 | 2023-01-10 | Conopco, Inc. | Hair compositions for damage treatment |
WO2019086274A1 (en) | 2017-11-03 | 2019-05-09 | Unilever Plc | Antidandruff composition and method of use |
WO2019086276A1 (en) | 2017-11-03 | 2019-05-09 | Unilever Plc | Shampoo composition and method of use |
US11918678B2 (en) | 2018-07-30 | 2024-03-05 | Conopco, Inc. | Hair cleansing composition |
WO2020025404A1 (en) | 2018-07-30 | 2020-02-06 | Unilever Plc | Hair cleansing composition |
WO2020126356A1 (en) | 2018-12-21 | 2020-06-25 | Unilever N.V. | Hair care composition comprising pyrithione |
WO2020144060A1 (en) | 2019-01-09 | 2020-07-16 | Unilever Plc | Shampoo composition and method of use |
EP3695825A1 (en) | 2019-02-15 | 2020-08-19 | Unilever PLC | Hair care composition |
WO2020229203A1 (en) | 2019-05-14 | 2020-11-19 | Unilever N.V. | Hair care composition comprising a 2(1h)-pyridinone and piroctone olamine |
WO2021004770A1 (en) | 2019-07-09 | 2021-01-14 | Unilever N.V. | Hair care composition comprising antidandruff agent |
WO2021037676A1 (en) | 2019-08-23 | 2021-03-04 | Unilever Global Ip Limited | Hair treatment composition in foam format |
WO2021037679A1 (en) | 2019-08-23 | 2021-03-04 | Unilever Global Ip Limited | Use of hair treatment composition in foam format |
WO2021043628A1 (en) | 2019-09-06 | 2021-03-11 | Unilever Global Ip Limited | Microcapsule and hair care composition |
WO2021043627A1 (en) | 2019-09-06 | 2021-03-11 | Unilever Global Ip Limited | Microcapsule and hair care composition |
WO2021069533A1 (en) | 2019-10-08 | 2021-04-15 | Unilever Ip Holdings B.V. | Hair treatment compositions |
WO2021074012A1 (en) | 2019-10-18 | 2021-04-22 | Unilever Ip Holdings B.V. | Hair treatment method |
EP3811923A1 (en) | 2019-10-25 | 2021-04-28 | Unilever PLC | Cleansing compositions |
WO2021089306A1 (en) | 2019-11-06 | 2021-05-14 | Unilever Ip Holdings B.V. | Anti-inflammatory composition |
WO2021099117A1 (en) | 2019-11-21 | 2021-05-27 | Unilever Ip Holdings B.V. | A cosmetic composition |
WO2021129968A1 (en) | 2019-12-25 | 2021-07-01 | Unilever Ip Holdings B.V. | Microcapsules and cosmetic compositions comprising the same |
WO2021144272A1 (en) | 2020-01-17 | 2021-07-22 | Unilever Ip Holdings B.V. | Hair treatment composition |
EP3677244A2 (en) | 2020-02-04 | 2020-07-08 | Clariant International Ltd | Compositions comprising multilamellar vesicles |
WO2021156213A1 (en) | 2020-02-04 | 2021-08-12 | Clariant International Ltd | Lipid nanoparticles for delayed delivery of fragrance with enhanced water solubility, their preparation and use |
WO2021175583A1 (en) | 2020-03-06 | 2021-09-10 | Clariant International Ltd | Lipid nanoparticles comprising a fragrance |
WO2021175499A1 (en) | 2020-03-06 | 2021-09-10 | Unilever Ip Holdings B.V. | Personal care composition and methods |
WO2021181098A1 (en) | 2020-03-11 | 2021-09-16 | Innospec Active Chemicals Llc | Solid cleansing composition |
WO2021181099A1 (en) | 2020-03-12 | 2021-09-16 | Innospec Active Chemicals Llc | Solid cleansing composition comprising an acyl alkyl isethionate |
WO2021224118A1 (en) | 2020-05-08 | 2021-11-11 | Unilever Ip Holdings B.V. | Personal care compositions comprising a metal piroctone complex |
EP3944852A1 (en) | 2020-07-28 | 2022-02-02 | Clariant International Ltd | Use of a booster to enhance the anti-dandruff or preservative activity of piroctone olamine |
WO2022084489A1 (en) | 2020-10-23 | 2022-04-28 | Clariant International Ltd | Opacifier compositions |
WO2022089892A1 (en) | 2020-10-27 | 2022-05-05 | Unilever Ip Holdings B.V. | Hair care composition |
WO2022128551A1 (en) | 2020-12-18 | 2022-06-23 | Unilever Ip Holdings B.V. | Anti-dandruff composition comprising piroctone olamine |
EP3818972A2 (en) | 2021-01-29 | 2021-05-12 | Clariant International Ltd | Piroctone olamine granules for use in cosmetic compositions |
WO2022214437A1 (en) | 2021-04-08 | 2022-10-13 | Unilever Ip Holdings B.V. | Hair treatment composition |
WO2022218767A1 (en) | 2021-04-15 | 2022-10-20 | Unilever Ip Holdings B.V. | Hair treatment method |
WO2023285195A1 (en) | 2021-07-15 | 2023-01-19 | Unilever Ip Holdings B.V. | Hydratable concentrated surfactant compositions |
EP4091675A1 (en) | 2021-07-19 | 2022-11-23 | Clariant International Ltd | Cosmetic composition comprising piroctone and a fragrance |
WO2022238590A2 (en) | 2021-07-19 | 2022-11-17 | Clariant International Ltd | Piroctone particles for use in cosmetic compositions |
WO2023046529A1 (en) | 2021-09-21 | 2023-03-30 | Unilever Ip Holdings B.V. | Conditioning shampoo composition |
WO2023094599A1 (en) | 2021-11-29 | 2023-06-01 | Unilever Ip Holdings B.V. | Hydratable concentrated surfactant compositions |
WO2023094600A1 (en) | 2021-11-29 | 2023-06-01 | Unilever Ip Holdings B.V. | Hydratable concentrated surfactant compositions |
WO2023094601A1 (en) | 2021-11-29 | 2023-06-01 | Unilever Ip Holdings B.V. | Hydratable concentrated surfactant compositions |
WO2023148138A1 (en) | 2022-02-02 | 2023-08-10 | Clariant International Ltd | Compounds for use as hair repair agents or fabric repair agents |
WO2023227305A1 (en) | 2022-05-27 | 2023-11-30 | Unilever Ip Holdings B.V. | Concentrated cleansing compositions |
Also Published As
Publication number | Publication date |
---|---|
JP2746758B2 (en) | 1998-05-06 |
AU1809795A (en) | 1995-09-04 |
US5543074A (en) | 1996-08-06 |
DE69519372D1 (en) | 2000-12-14 |
CA2180942A1 (en) | 1995-08-24 |
EP0744935B2 (en) | 2003-09-10 |
EP0744935A1 (en) | 1996-12-04 |
CA2180942C (en) | 2001-12-04 |
ES2153026T5 (en) | 2004-05-16 |
BR9506797A (en) | 1997-09-16 |
DE69519372T2 (en) | 2001-04-26 |
EP0744935B1 (en) | 2000-11-08 |
ES2153026T3 (en) | 2001-02-16 |
JPH09501951A (en) | 1997-02-25 |
DE69519372T3 (en) | 2004-06-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0744935B1 (en) | Personal washing compositions | |
JP3895074B2 (en) | Cosmetic composition for cleaning and use thereof | |
AU747078B2 (en) | Detergent composition | |
US6110451A (en) | Synergistic combination of cationic and ampholytic polymers for cleansing and/or conditioning keratin based substrates | |
EP0892631B1 (en) | Conditioning shampoo compositions containing select cationic conditioning polymers | |
AU718900B2 (en) | Conditioning and detergent composition and use | |
EP0889712B1 (en) | Hair care compositions | |
EP0655909B1 (en) | Detergent composition | |
AU602729B2 (en) | Personal skin care products containing dimethyl diallyl ammonium chloride/acrylic acid-type polymers | |
JP3483562B2 (en) | Conditioning shampoo containing polyvalent metal cation | |
KR100658100B1 (en) | Conditioning shampoo compositions | |
EP0573229A2 (en) | Cosmetic composition | |
CZ102594A3 (en) | Hair shampoo preparation with a conditioner | |
EP0671463B1 (en) | Detergent composition | |
WO2002036095A2 (en) | Personal cleansing composition | |
EP0541347A2 (en) | Cosmetic composition | |
US6511671B1 (en) | Detergent cosmetic composition comprising a silicone and an amphoteric polymer with fatty chains and use | |
US20040197355A1 (en) | Cosmetic composition comprising calcuim carbonate particles and a combination of surfactants | |
US7485288B2 (en) | Cosmetic composition comprising calcium carbonate particles and conditioning agents | |
WO2004043413A1 (en) | Compositions for washing and conditioning hair | |
Dalrymple et al. | Multifunctional ingredients in hair care products | |
MXPA99006780A (en) | Cosmetic detergent compositions and their use | |
CA2246621A1 (en) | Hair care compositions | |
MXPA99005967A (en) | Conditioning and detergent compositions and use | |
MXPA00001915A (en) | Cleansing compositions |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AM AT AU BB BG BR BY CA CH CN CZ DE DK EE ES FI GB GE HU JP KE KG KP KR KZ LK LR LT LU LV MD MG MN MW MX NL NO NZ PL PT RO RU SD SE SI SK TJ TT UA UG UZ VN |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): KE MW SD SZ UG AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 1995909734 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2180942 Country of ref document: CA |
|
WWP | Wipo information: published in national office |
Ref document number: 1995909734 Country of ref document: EP |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
WWG | Wipo information: grant in national office |
Ref document number: 1995909734 Country of ref document: EP |