US2799599A - Lustered fur hairs and method for - Google Patents
Lustered fur hairs and method for Download PDFInfo
- Publication number
- US2799599A US2799599A US2799599DA US2799599A US 2799599 A US2799599 A US 2799599A US 2799599D A US2799599D A US 2799599DA US 2799599 A US2799599 A US 2799599A
- Authority
- US
- United States
- Prior art keywords
- morpholine
- soap
- fur
- paste
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 210000004209 Hair Anatomy 0.000 title description 58
- YNAVUWVOSKDBBP-UHFFFAOYSA-N morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 124
- 229940113083 morpholine Drugs 0.000 claims description 124
- 239000000344 soap Substances 0.000 claims description 84
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 64
- 239000000194 fatty acid Substances 0.000 claims description 64
- 150000004665 fatty acids Chemical class 0.000 claims description 64
- 229920001296 polysiloxane Polymers 0.000 claims description 62
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 46
- 230000002378 acidificating Effects 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- 238000000354 decomposition reaction Methods 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 230000000717 retained Effects 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N Stearic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 104
- 239000000203 mixture Substances 0.000 description 62
- 235000021355 Stearic acid Nutrition 0.000 description 52
- 229960004274 Stearic acid Drugs 0.000 description 52
- 239000008117 stearic acid Substances 0.000 description 52
- 239000000463 material Substances 0.000 description 40
- 239000002253 acid Substances 0.000 description 24
- 239000007864 aqueous solution Substances 0.000 description 24
- 235000013871 bee wax Nutrition 0.000 description 24
- 239000012166 beeswax Substances 0.000 description 24
- 238000002844 melting Methods 0.000 description 20
- 239000004615 ingredient Substances 0.000 description 18
- 239000000839 emulsion Substances 0.000 description 16
- 239000001993 wax Substances 0.000 description 16
- 239000011248 coating agent Substances 0.000 description 12
- 238000000576 coating method Methods 0.000 description 12
- 239000000047 product Substances 0.000 description 10
- ABKMROZHNTVGPY-UHFFFAOYSA-N N1(CCOCC1)CCCCCCCCCCCCCCCCCC(=O)O Chemical class N1(CCOCC1)CCCCCCCCCCCCCCCCCC(=O)O ABKMROZHNTVGPY-UHFFFAOYSA-N 0.000 description 8
- 125000004432 carbon atoms Chemical group C* 0.000 description 8
- 239000012530 fluid Substances 0.000 description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 229920001558 organosilicon polymer Polymers 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 6
- 229940067606 Lecithin Drugs 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 239000000787 lecithin Substances 0.000 description 6
- 235000010445 lecithin Nutrition 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 6
- 229910052753 mercury Inorganic materials 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 238000004078 waterproofing Methods 0.000 description 6
- VKOBVWXKNCXXDE-UHFFFAOYSA-N Arachidic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 4
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N Oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N Palmitic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 230000001680 brushing Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000011876 fused mixture Substances 0.000 description 4
- 239000011872 intimate mixture Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 239000008149 soap solution Substances 0.000 description 4
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 2
- 235000021357 Behenic acid Nutrition 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N Behenic acid Natural products CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 241000219430 Betula pendula Species 0.000 description 2
- 229940073532 Candelilla Wax Drugs 0.000 description 2
- XMHIUKTWLZUKEX-UHFFFAOYSA-N Cerotic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 description 2
- IUJAMGNYPWYUPM-UHFFFAOYSA-N Hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 2
- KEMQGTRYUADPNZ-UHFFFAOYSA-N Heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- 229940039717 Lanolin Drugs 0.000 description 2
- 229940023607 Myristic Acid Drugs 0.000 description 2
- 235000021360 Myristic acid Nutrition 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 229940056211 Paraffin Drugs 0.000 description 2
- SZHOJFHSIKHZHA-UHFFFAOYSA-N Tridecylic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000001464 adherent Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229940116226 behenic acid Drugs 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000004204 candelilla wax Substances 0.000 description 2
- 235000013868 candelilla wax Nutrition 0.000 description 2
- 239000007765 cera alba Substances 0.000 description 2
- 239000007766 cera flava Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 230000003750 conditioning Effects 0.000 description 2
- 230000000875 corresponding Effects 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 229950008690 docosanoic acid Drugs 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000012182 japan wax Substances 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- UKVYVYQRDUUCBK-UHFFFAOYSA-N morpholin-4-ium;octadecanoate Chemical compound C1COCCN1.CCCCCCCCCCCCCCCCCC(O)=O UKVYVYQRDUUCBK-UHFFFAOYSA-N 0.000 description 2
- 230000001264 neutralization Effects 0.000 description 2
- 239000003027 oil sand Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 150000007530 organic bases Chemical class 0.000 description 2
- 150000003961 organosilicon compounds Chemical class 0.000 description 2
- 125000005375 organosiloxane group Chemical group 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000006069 physical mixture Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 2
- 230000003068 static Effects 0.000 description 2
- 125000005480 straight-chain fatty acid group Chemical group 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/23907—Pile or nap type surface or component
- Y10T428/23986—With coating, impregnation, or bond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Definitions
- This invention relates particularly: to a new and improved method of treating furs and a new and improved composition for such purpose, and a new and improved coated fur or other material.
- the invention relates particul'ar'ly to. the lustering of furcoats.
- the invention is no'tlimited to the treatment of furs, as. it applies to the treatmentof otherfiber materials and even non-fiber materials.
- Infcleaningand renovating a fur coat it is common practice to cleanthe coat, and then toapply various oil andwaxcompositions, to the hair, side, of the coat, and then to treat the fur coat by heating it, preferablyunder pressure, and also while simultaneously combing the fur hairs.
- an organo-silicon polymer which is preferably a silicone.
- This silicone is preferably a liquid at normal room temperature of 20 C.25 C.
- the silicones are well-known poly-organo-siloxanes which contain the unitR2SiO-, in which R represents an alkyl or aryl group. These silicones and other organo-silicon polymers are described in many standard text-books, such as A Text-Book of Organic Chemistry by Schmidt & Rule, published in 1947 by D. Van Nostrand Company Inc. These organo-silicon polymers or polyorgano'siloxanes may contain the group R(H2Si-O)$ and the invention includes polyorganosiloxanes other than the silicones, which have the desired property.
- organo-silicon compounds may be made by combining silicon dioxide with methyl or ethyl groups derived from alcohols, or with ethylene chloride or phenol. Both straight-chain or ring-type organic molecules may be combined with the silicon dioxide. These materials are stable, inert, and strongly water-repellent.
- Ingredient C may be ordinary commercial stearic acid.
- the general formula of stearic acid is C1sHseO2.
- stearic acid exemplifies, a class of fatty acids which preferably have at least thirteen carbon atoms and which are solids at 20 C.-25 C.
- this preferred class includes, as additional examples of such'preferred class which can be used for the purposes of my invention, the following:
- Tridecylic acid CH:i(CH z-)11COOH, whose melting point is.51, C.
- I can alsouse hydrogenated fatty acids.
- Ordinary commercial stearic acid usually contains another fatty, acid.
- the stearic, acidof, commerce which I can use contains 45% of stearic acidand 55% of palmitic acid and Imay use a gradeofcommereialstearic acid which has a melting point of,5'3 C. 5 5 C.
- Ingredient B which is optional, exemplifies a class qfcwax es which are preferably solids at 20 C.25 C., suchas Japanwax, menta wax, candelilla wax, and many, others. These other waxes may be substituted for thebeeswax I can use waxeswhichare notsaponified in the composition, orwhich are wholly or partially, sapqnifie er in.
- Morpho line O:(CaI-I ):NH, isanamine, which like other amines pr oduces salts or, soaps with long: straight chain fatty acids.
- One mole of morpholine reacts with one mole ofthe fatty acid to produce the respective salt or sqap withthe formation of one mole of water as a byproduct.
- Morpholine is stronglyv basic. It is freely miscible with water, boils at 128 C. and it isa good emulsifying agent.
- the ,stea ric acid may be fused at 60 C. and maintained fused at this temperature.
- the invention is not limited to the use of a morpholine soap in the composition which is applied to the fur or other material, the use of a m'orph-o-line soap is preferred for practical purposes, because it is particularly selective and effective for the desired purpose.
- the morpholine which is liberated from the decomposed soap is readily volatile at moderate temperature.
- beeswax contains :a substantial percentage of compounds which react with the morpholine to produce additional soaps.
- -I can use either the yellow beeswax of commerce or the white beeswax which is described at page 1282 of the 1947 edition of The Dispensatory of the United States of America.
- Beeswax contains a substantial percentage of cerotic acid. It may have an acid value of 17 to 24. These beeswax soaps are in the composition which is applied to the fur.
- morpholine or other watersoluble volatile organic base which is readily volatile at the lustering temperature
- the invention is not limited to the use of morpholine.
- the morpholine may be replaced by an equivalent amount of ammonia, alkyl and other amines, whose soaps or additional compounds are also similarly decomposed by heat.
- the purpose of adding a water-repellant wax or waxes is to improve the :body of the composition and the lustering effect and the water-proofing effect.
- conditioning ingredients may be added, such as vegetable and mineral oils, paraffin, lecithin, lanolin, glycols, antistatic agents, etc.
- the anhydrous silicone and the anhydrous wax '(if the wax is used) are mixed with the fused anhydrous stearic acid at about 65 C., if said grade of commercial stearic acid is used, until a homogeneous fluid and initial fused mixture is formed which is anhydrous or substantially anhydrous.
- the three parts of morpholine are separately dissolved in the 50 parts of water.
- This aqueous morpholine solution is slowly added to said initial fluid mixture with constant stirring, while maintaining a temperature of 65-70 C. This may be done in air at normal pressure of 760 millimeters of mercury. This produces a stable composition.
- the aqueous solution of the morpholine or other base, when added, is preferably at the same temperature as the initial I fluid mixture.
- 1 can use a molar proportion of morpholine to combine with all the fatty acid or all of the mixture of fatty acids, or I can use a greater or less proportion than the molar proportion.
- a substantial part of the morpholine reacts with the beeswax to produce a soap or soaps so that a substantial proportion of the stearic acid, or of the mixture of fatty acids in the commercial stearic acid, remains in uncombined form in the composition or is in the form of an acid soap.
- This is a stable emulsion or dispersion in which the uncombined acid or acids and other uncombined materials are finely dispersed.
- This composition is a soft paste at 20 C.- C.
- This composition may be diluted with the additional 25 parts of water, by stirring at 20 C.25 C.
- the silicone is mixed with the fatty acid material at 60 C., to form an initial fluid mixture, the aqueous solution of morpholine is added thereto at 60 C. to make an initial emulsion, and this initial emulsion is mixed with a separately made aqueous emulsion of the beeswax, oils, lecithin, etc. This separately made emulresponds to said acid radical.
- 4 sion may be made with a part of the stearic acid material and a part of the morpholine.
- the molecular proportion of the morpholine may 'be from to of the total fatty acid material which is reacted with the morpholine. This proportion may "be calculated upon the entire weight of the material which reacts with the morpholine, including the reactive material of the beeswax. This applies if the morpholine is replaced by an equivalent material. In either case, the non-soap ingredients, including some of the stearic acid, are dispersed in the emulsion.
- aqueous silicone emulsions are on the market, and such pre-formed aqueous emulsions can be used, if compatible.
- a composition which is thus made, is applied to the cleaned fur, as by brushing at 20 C.-25 C.
- the composition is applied to the base of the fur and its hairs or to the hairs alone.
- the fur is then heated, optionally pressed under heat or combed under heat and pressure, using well-known hand appliances or machinery for this purpose. This is done in an atmosphere of air under normal pressure of 760 millimeters of mercury. Any conventional lustering procedure may be used.
- the temperature of the fur and of the applied aqueous composition is gradually raised. Before the water of the composition is wholly evaporated, the soap is decomposed, and the fatty acid or fatty acids are regenerated and the morpholine is liberated and it is wholly evaporated.
- a thin coating of the composition may be applied to the fur hairs, which may be simultaneously combed and heated to decompose the morpholine soap and to drive an the morpholine, and to regenerate the stearic acid or other fatty acid.
- the silicone and the deposited water-insoluble fatty acid or acids and other water-insoluble deposited material provide a very intimate and stable coating on the base and hairs of the fur.
- the particles of silicone are coated with the other material or materials, which act as a binder. The result is much superior than if the silicone or an ordinary aqueous emulsion thereof is applied by brushing.
- the regenerated stearic acid or other fatty acid material when thus formed and deposited in situ, acts as a vehicle and binder which is intimately physically combined with the silicone, and this intimate physical mixture is very adherent and stable and it minimizes the rubbing off of the silicone.
- oleic acid can be used as the fatty acid material or as a part thereof, it is highly preferable to use fatty acid material which has a melting point above 25 C., and which preferably has a melting point of at least 50 C., so that it remains unfused and does not soften under ordinary conditions of wear.
- the composition When the composition is used to luster a fur, the fur hairs retain their original color.
- a silicone as a lustering water-proofing agent
- the invention applies to other waterproofing materials which may be oils, waxes, etc.
- the coating composition has anti-static properties, so that the fur hairs do not clump because of static electricity.
- the finished composition is a soft paste which is slightly pourable at 20 C.25 C.
- the finished composition is an aqueous dispersion of a water-insoluble organo-silicon polymer, in which the dispersing agent is a water-soluble morpholine soap which is decomposed when said composition is heated in order to liberate and drive off the morpholine and to combine the acid radical of said soap with water of said dispersion, in order to regenerate the original acid which cor- This polymer is substantially non-volatile at the temperature which is required to decompose said soap.
- a combination method of lustering fur hair which consists in making a mixture of an oily silicone and a fused, free fatty acid, said free fatty acid having at least 13 carbon atoms in its chain, mixing said mixture while said free fatty acid is in fused form with an aqueous solution of morpholine to react only a part of said fused fatty acid with the dissolved morpholine in said aqueous solution to form the morpholine soap of said fatty acid in a coating product which is a soft aqueous paste, enough of said free fatty acid being left unreacted and enough water being provided in said aqueous solution to provide said soft aqueous paste, applying said soft aqueous paste to the fur hair, and heating and combing said aqueous paste on said fur hair to evaporate its water and to decompose said morpholine soap and to regenerate the free fatty acid thereof and to drive ofi the morpholine which results from the decomposition of the morpholine soap before all the water of said aque
- a combination method of lustering fur hair which consists in making a substantially anhydrous mixture of an oily silicone and fused beeswax and fused free stearic acid, said mixture consisting of substantially 10 parts of said silicone and substantially parts of beeswax and substantially parts of free stearic acid, mixing said mixture with an aqueous solution of substantially 3 parts of morpholine in substantially 50 parts of water at substantially 65 C.70 C.
- a method of lustering fur hair which consists in applying a soft aqueous paste to the fur hair, said aqueous paste containing the morpholine soap of a fatty acid which has at least 13 carbon atoms and which is a solid at 25 C.30 C., said paste also containing an oily silicone, said morpholine soap and said oily silicone being uniformly intermixed and dispersed in said aqueous paste, and combing and heating said aqueous paste on said fur hair to decompose said morpholine soap and to regenerate the acidic component of said soap and to drive off the morpholine which results from said decomposition and to evaporate the Water of said paste, said morpholine soap being decomposed and said morpholine being driven off before the water of said paste is wholly evaporated said paste being thus heated at a temperature at which said oily silicone and said regenerated acidic component are retained on said fur hair.
- Fur which has lustered fur hairs said fur hairs having surface coatings which consist substantially of an intimate mixture of 10 parts of an oily silicone, substantially 5 parts of beeswax and substantially 10 parts of stearic acid, said stearic acid being the regenerated stearic acid of an aqueous solution of a morpholine soap of stearic acid decomposed in the presence of water on said fur hairs.
- Fur which has lustered fur hairs, said fur hairs having surface coatings whose major ingredients is an oily silicone, said surface coatings also including the regenerated fatty acid of a morpholine soap, said fatty acid having at least 13 carbon atoms, said oily silicone and said regenerated fatty acid being in the form of an intimate mixture on said for hairs, said regenerated fatty acid being the regenerated acid of an aqueous solution of a morpholine soap of said fatty acid and decomposed in the presence of water on said fur hairs.
Description
Mia W;
United States Patent Cfihce Patented July 16, 19 57 5. Claims. (Cl.i117141) N Drawing.
This invention. relates particularly: to a new and improved method of treating furs and a new and improved composition for such purpose, and a new and improved coated fur or other material. The invention relates particul'ar'ly to. the lustering of furcoats. The invention is no'tlimited to the treatment of furs, as. it applies to the treatmentof otherfiber materials and even non-fiber materials.
Infcleaningand renovating a fur coat, it is common practice to cleanthe coat, and then toapply various oil andwaxcompositions, to the hair, side, of the coat, and then to treat the fur coat by heating it, preferablyunder pressure, and also while simultaneously combing the fur hairs.
The purpose of such treatment istoincrease the gloss and texture of the fur hairs and to water-proof them. This operation is generally known as lustering..
According to one feature of my invention, I replace the vegetable and mineral oilsand the waxes which have been used for this purpose, either in whole or inpart, by an organo-silicon polymer, which is preferably a silicone. This silicone ispreferably a liquid at normal room temperature of 20 C.25 C.
The silicones are well-known poly-organo-siloxanes which contain the unitR2SiO-, in which R represents an alkyl or aryl group. These silicones and other organo-silicon polymers are described in many standard text-books, such as A Text-Book of Organic Chemistry by Schmidt & Rule, published in 1947 by D. Van Nostrand Company Inc. These organo-silicon polymers or polyorgano'siloxanes may contain the group R(H2Si-O)$ and the invention includes polyorganosiloxanes other than the silicones, which have the desired property.
These organo-silicon compounds may be made by combining silicon dioxide with methyl or ethyl groups derived from alcohols, or with ethylene chloride or phenol. Both straight-chain or ring-type organic molecules may be combined with the silicon dioxide. These materials are stable, inert, and strongly water-repellent.
One illustrative example of my invention, to which the invention is not limited, is stated below in which the proportions are by weight.
Example Ingredient: Parts A. Silicone 10 B. Beeswax 5 C. Stearic acid D. Morpholine 3 E. Water 50 F. Added water Ingredient A is a silicone which has a viscosity of one hundred centipoises at ordinary room temperature of 20 C.25 C. It is a well-known commercial product. It is a pourable liquid at 20 C.-25 C.
Ingredient C may be ordinary commercial stearic acid. The general formula of stearic acid is C1sHseO2. The
2 stearic acid exemplifies, a class of fatty acids which preferably have at least thirteen carbon atoms and which are solids at 20 C.-25 C.
Hence this preferred class includes, as additional examples of such'preferred class which can be used for the purposes of my invention, the following:
Tridecylic acid, CH:i(CH z-)11COOH, whose melting point is.51, C.
' Myri stic acid, CHa(CH2)12COOH, whose melting point is 58 C.
Rentadecyh'c acid, CH3.(,CH2)13.COOH, whose melting point is 54 C.
Ealmiticacid,CH3(CH2)14.COOH, whose melting point is 64 C.
Margaric acid, CH3,(CH2)15.COQH, whose melting point is 599 C.
Arachidic acid, CH CH2)20COOH, whose melting point is,77 C.
Behenic acid CH3(CH2)20COOH, whose melting point is 84 C.
I can alsouse hydrogenated fatty acids.
Ordinary commercial stearic acid usually contains another fatty, acid.
The stearic, acidof, commerce which I can use contains 45% of stearic acidand 55% of palmitic acid and Imay use a gradeofcommereialstearic acid which has a melting point of,5'3 C. 5 5 C.
Ingredient B, which is optional, exemplifies a class qfcwax es which are preferably solids at 20 C.25 C., suchas Japanwax, menta wax, candelilla wax, and many, others. These other waxes may be substituted for thebeeswax I can use waxeswhichare notsaponified in the composition, orwhich are wholly or partially, sapqnifie er in.
Morpho line, O:(CaI-I ):NH, isanamine, which like other amines pr oduces salts or, soaps with long: straight chain fatty acids. One mole of morpholine reacts with one mole ofthe fatty acid to produce the respective salt or sqap withthe formation of one mole of water as a byproduct.
Morpholine is stronglyv basic. It is freely miscible with water, boils at 128 C. and it isa good emulsifying agent.
The ,stea ric acid may be fused at 60 C. and maintained fused at this temperature.
An aqueoussolution of morpholine, which is also at 60 C., is addedslowly to the fused-.stearic acid, with constant stirring, while the temperature is maintained at 60-70 C. The reaction is exothermic. This will form the morpholine-stearic acid salt or soap which is the water soluble neutral salt. This soap isdissolved in the water of the aqueousv solution.
If the aqueous solution of this morpholine-stearic acid soap is heated up to 130 C., in air under norrnal pressurejof 760 millimeters of mercury, the solution is evaporated and the high temperature decomposes the dissolved soap, the morpholine is. liberated and evaporated, and the stearic acid is substantially regenerated, remaining as a dry and water-insoluble residue.
In one test, grams of said grade of stearic acid were fused, and this fusedstearic acid was reacted under the above mentioned conditions with 33 grams of morpholine, which had beendissolved in, 133 grams of distilled water. The weight of the aqueous morpholine-stearic acid soap solution was 266 grams. 1
This solution was gradually evaporated at said temperature by. heating from C. up to C., under said standard pressure. The weight of the residue was 104 grams.
The colloidal soapy mass of the original morpholine stearic acid soapsolution, was-converted to a clear oily liquid at 130 C., which is above the boiling point of morpholine. In the last stage of the reaction, there is no odor of morpholine. This residue was substantially the original stearic acid.
While the invention is not limited to the use of a morpholine soap in the composition which is applied to the fur or other material, the use of a m'orph-o-line soap is preferred for practical purposes, because it is particularly selective and effective for the desired purpose. The morpholine which is liberated from the decomposed soap is readily volatile at moderate temperature.
If beeswax is used, this contains :a substantial percentage of compounds which react with the morpholine to produce additional soaps. -I can use either the yellow beeswax of commerce or the white beeswax which is described at page 1282 of the 1947 edition of The Dispensatory of the United States of America. Beeswax contains a substantial percentage of cerotic acid. It may have an acid value of 17 to 24. These beeswax soaps are in the composition which is applied to the fur.
While 'I prefer to use morpholine or other watersoluble volatile organic base which is readily volatile at the lustering temperature, the invention is not limited to the use of morpholine. Thus, the morpholine may be replaced by an equivalent amount of ammonia, alkyl and other amines, whose soaps or additional compounds are also similarly decomposed by heat.
The purpose of adding a water-repellant wax or waxes is to improve the :body of the composition and the lustering effect and the water-proofing effect.
Other conditioning ingredients may be added, such as vegetable and mineral oils, paraffin, lecithin, lanolin, glycols, antistatic agents, etc.
According to one embodiment of making the composition, which is highly preferred, the anhydrous silicone and the anhydrous wax '(if the wax is used) are mixed with the fused anhydrous stearic acid at about 65 C., if said grade of commercial stearic acid is used, until a homogeneous fluid and initial fused mixture is formed which is anhydrous or substantially anhydrous.
The three parts of morpholine are separately dissolved in the 50 parts of water.
This aqueous morpholine solution is slowly added to said initial fluid mixture with constant stirring, while maintaining a temperature of 65-70 C. This may be done in air at normal pressure of 760 millimeters of mercury. This produces a stable composition. The aqueous solution of the morpholine or other base, when added, is preferably at the same temperature as the initial I fluid mixture.
1 can use a molar proportion of morpholine to combine with all the fatty acid or all of the mixture of fatty acids, or I can use a greater or less proportion than the molar proportion.
Thus, in the specific example, a substantial part of the morpholine reacts with the beeswax to produce a soap or soaps so that a substantial proportion of the stearic acid, or of the mixture of fatty acids in the commercial stearic acid, remains in uncombined form in the composition or is in the form of an acid soap. This is a stable emulsion or dispersion in which the uncombined acid or acids and other uncombined materials are finely dispersed. This composition is a soft paste at 20 C.- C.
This composition may be diluted with the additional 25 parts of water, by stirring at 20 C.25 C.
If additional agents, such as oils, lecithin, etc. are used, these are added to the initial fused mixture, prior to adding the aqueous solution of morpholine or other amine or ammonia thereto.
Optionally, the silicone is mixed with the fatty acid material at 60 C., to form an initial fluid mixture, the aqueous solution of morpholine is added thereto at 60 C. to make an initial emulsion, and this initial emulsion is mixed with a separately made aqueous emulsion of the beeswax, oils, lecithin, etc. This separately made emulresponds to said acid radical.
4 sion may be made with a part of the stearic acid material and a part of the morpholine.
The molecular proportion of the morpholine may 'be from to of the total fatty acid material which is reacted with the morpholine. This proportion may "be calculated upon the entire weight of the material which reacts with the morpholine, including the reactive material of the beeswax. This applies if the morpholine is replaced by an equivalent material. In either case, the non-soap ingredients, including some of the stearic acid, are dispersed in the emulsion.
Various pre-formed aqueous silicone emulsions are on the market, and such pre-formed aqueous emulsions can be used, if compatible.
A composition which is thus made, is applied to the cleaned fur, as by brushing at 20 C.-25 C. The composition is applied to the base of the fur and its hairs or to the hairs alone.
The fur is then heated, optionally pressed under heat or combed under heat and pressure, using well-known hand appliances or machinery for this purpose. This is done in an atmosphere of air under normal pressure of 760 millimeters of mercury. Any conventional lustering procedure may be used.
The temperature of the fur and of the applied aqueous composition is gradually raised. Before the water of the composition is wholly evaporated, the soap is decomposed, and the fatty acid or fatty acids are regenerated and the morpholine is liberated and it is wholly evaporated.
A thin coating of the composition may be applied to the fur hairs, which may be simultaneously combed and heated to decompose the morpholine soap and to drive an the morpholine, and to regenerate the stearic acid or other fatty acid.
There is little or no loss of the silicone. The silicone and the deposited water-insoluble fatty acid or acids and other water-insoluble deposited material provide a very intimate and stable coating on the base and hairs of the fur. The particles of silicone are coated with the other material or materials, which act as a binder. The result is much superior than if the silicone or an ordinary aqueous emulsion thereof is applied by brushing. The regenerated stearic acid or other fatty acid material, when thus formed and deposited in situ, acts as a vehicle and binder which is intimately physically combined with the silicone, and this intimate physical mixture is very adherent and stable and it minimizes the rubbing off of the silicone.
While oleic acid can be used as the fatty acid material or as a part thereof, it is highly preferable to use fatty acid material which has a melting point above 25 C., and which preferably has a melting point of at least 50 C., so that it remains unfused and does not soften under ordinary conditions of wear.
When the composition is used to luster a fur, the fur hairs retain their original color.
While it is preferred to use a silicone as a lustering water-proofing agent, the invention applies to other waterproofing materials which may be oils, waxes, etc.
I believe that the coating composition has anti-static properties, so that the fur hairs do not clump because of static electricity.
As one example, the finished composition is a soft paste which is slightly pourable at 20 C.25 C. In this example, the finished composition is an aqueous dispersion of a water-insoluble organo-silicon polymer, in which the dispersing agent is a water-soluble morpholine soap which is decomposed when said composition is heated in order to liberate and drive off the morpholine and to combine the acid radical of said soap with water of said dispersion, in order to regenerate the original acid which cor- This polymer is substantially non-volatile at the temperature which is required to decompose said soap.
I claim:
1. A combination method of lustering fur hair which consists in making a mixture of an oily silicone and a fused, free fatty acid, said free fatty acid having at least 13 carbon atoms in its chain, mixing said mixture while said free fatty acid is in fused form with an aqueous solution of morpholine to react only a part of said fused fatty acid with the dissolved morpholine in said aqueous solution to form the morpholine soap of said fatty acid in a coating product which is a soft aqueous paste, enough of said free fatty acid being left unreacted and enough water being provided in said aqueous solution to provide said soft aqueous paste, applying said soft aqueous paste to the fur hair, and heating and combing said aqueous paste on said fur hair to evaporate its water and to decompose said morpholine soap and to regenerate the free fatty acid thereof and to drive ofi the morpholine which results from the decomposition of the morpholine soap before all the water of said aqueous paste is evaporated, said aqueous paste being thus heated at a temperature at which said fur hair retains said oily silicone and the free fatty acid in said paste and said regenerated fatty acid.
2. A combination method of lustering fur hair, which consists in making a substantially anhydrous mixture of an oily silicone and fused beeswax and fused free stearic acid, said mixture consisting of substantially 10 parts of said silicone and substantially parts of beeswax and substantially parts of free stearic acid, mixing said mixture with an aqueous solution of substantially 3 parts of morpholine in substantially 50 parts of water at substantially 65 C.70 C. to form a coating product while reacting a part of said morpholine with only a part of said free and fused stearic acid and while reacting the remainder of said morpholine with a part of said fused beeswax to form the corresponding morpholine soap, enough water being used in said aqueous solution of morpholine to provide a coating product which is a soft aqueous paste at 20 C.25 C., said coating product containing free stearic acid and also containing said morpholine-stearic acid soap and also containing said soap of morpholine formed from the saponifiable material of the beeswax, applying said soft aqueous paste to the fur hair, and heating and combing said aqueous paste in the fur hair to evaporate the water of said paste and to decompose said morpholine soaps and to regenerate the acidic ingredients of said soaps and to drive 01f the morpholine which results from the decomposition of said morpholine soaps before all the water of said aqueous paste is evaporated, said aqueous paste being heated at a temperature at which said fur hair retains said oily silicone and the unsaponified material in said paste and said regenerated acidic ingredients.
3. A method of lustering fur hair, which consists in applying a soft aqueous paste to the fur hair, said aqueous paste containing the morpholine soap of a fatty acid which has at least 13 carbon atoms and which is a solid at 25 C.30 C., said paste also containing an oily silicone, said morpholine soap and said oily silicone being uniformly intermixed and dispersed in said aqueous paste, and combing and heating said aqueous paste on said fur hair to decompose said morpholine soap and to regenerate the acidic component of said soap and to drive off the morpholine which results from said decomposition and to evaporate the Water of said paste, said morpholine soap being decomposed and said morpholine being driven off before the water of said paste is wholly evaporated said paste being thus heated at a temperature at which said oily silicone and said regenerated acidic component are retained on said fur hair.
4. Fur which has lustered fur hairs, said fur hairs having surface coatings which consist substantially of an intimate mixture of 10 parts of an oily silicone, substantially 5 parts of beeswax and substantially 10 parts of stearic acid, said stearic acid being the regenerated stearic acid of an aqueous solution of a morpholine soap of stearic acid decomposed in the presence of water on said fur hairs.
5. Fur which has lustered fur hairs, said fur hairs having surface coatings whose major ingredients is an oily silicone, said surface coatings also including the regenerated fatty acid of a morpholine soap, said fatty acid having at least 13 carbon atoms, said oily silicone and said regenerated fatty acid being in the form of an intimate mixture on said for hairs, said regenerated fatty acid being the regenerated acid of an aqueous solution of a morpholine soap of said fatty acid and decomposed in the presence of water on said fur hairs.
References Cited in the file of this patent UNITED STATES PATENTS 2,140,759 1\'luller Dec. 20, 1938 2,374,678 Gruenwald May 1, 1945 2,581,296 Rickus et al. Ian. 1, 1952 2,597,871 Iler May 27, 1952 2,614,049 Swanson Oct. 14, 1952 2,626,870 Cooke et al. Jan. 27, 1953 2,635,060 Cheronis et al Apr. 14, 1953
Claims (1)
- 3. A METHOD OF LUSTERING FUR HAIR, WHICH CONSISTS IN APPLYING A SOFT AQUEOUS PASTE TO THE FUR HAIR, SAID AQUEOUS PASTE CONTAINING THE MORPHOLINE SOAP OF A FATTY ACID WHICH HAS AT LEAST 13 CARBON ATOMS AND WHICH IS A SOLID AT 25*C.-30*C., SAID PASTE ALSO CONTAINING AN OILY SILICONE, SAID MORPHOLINE SOAP AND SAID OILY SILICONE BEING UNIFORMLY INTERMIXED AND DISPERSED IN SAID AQUEOUS PASTE, AND COMBING AND HEATING SAID AQUEOUS PASTE ON SAID FUR HAIR TO DECOMPOSE SAID MORPHOLINE SOAP AND TO REGENERATE THE ACIDIC COMPONENT OF SAID SOAP AND TO DRIVE OFF THE MORPHOLINE WHICH RESULTS FROM SAID DECOMPOSITION AND TO EVAPORATE THE WATER OF SAID PASTE, SAID MORPHOLINE SOAP BEING DECOMPOSED AND SAID MORPHOLINE BEING DRIVEN OFF BEFORE THE WATER OF SAID PASTE IS WHOLLY EVAPORATED SAID PASTE BEING THUS HEATED AT A TEMPERATURE AT WHICH SAID OILY SILICONE AND SAID REGENERATED ACIDIC COMPONENT ARE RETAINED ON SAID FUR HAIR.
Publications (1)
Publication Number | Publication Date |
---|---|
US2799599A true US2799599A (en) | 1957-07-16 |
Family
ID=3446559
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US2799599D Expired - Lifetime US2799599A (en) | Lustered fur hairs and method for |
Country Status (1)
Country | Link |
---|---|
US (1) | US2799599A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2861949A (en) * | 1956-09-10 | 1958-11-25 | Willis C Ware | Fur glazing composition and method for preparing same |
US3124535A (en) * | 1964-03-10 | Fur cleaning composition | ||
US3124536A (en) * | 1964-03-10 | Composition for cleaning synthetic fur | ||
DE1180880B (en) * | 1961-10-05 | 1964-11-05 | Boehme Chem Fab Kg | Process for glossing fur skins |
US3395028A (en) * | 1966-09-12 | 1968-07-30 | Drackett Co | Wax composition and method for making the same |
US3402071A (en) * | 1963-08-08 | 1968-09-17 | Boehme Chem Fab Kg | Process to render leathers and furs water-resistant |
US3498748A (en) * | 1967-05-18 | 1970-03-03 | Pfizer & Co C | Preparation of magnetic ferric oxide |
USRE34584E (en) * | 1984-11-09 | 1994-04-12 | The Procter & Gamble Company | Shampoo compositions |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2140759A (en) * | 1938-01-28 | 1938-12-20 | Dri Wear Inc | Method for dressing, treating, and finishing furs |
US2374678A (en) * | 1940-03-18 | 1945-05-01 | Louis A Gruenwald | Surface active materials |
US2581296A (en) * | 1947-08-04 | 1952-01-01 | Hat Corp America | Treated fur fibers |
US2597871A (en) * | 1947-09-20 | 1952-05-27 | Du Pont | Wax emulsion polishing composition containing silica |
US2614049A (en) * | 1952-10-14 | Polishing composition | ||
US2626870A (en) * | 1949-12-05 | 1953-01-27 | Standard Oil Dev Co | Wax and silicone oil auto polish |
US2635060A (en) * | 1946-01-25 | 1953-04-14 | Greenebaum Tanning Co J | Water-resistant leather and process for producing same |
-
0
- US US2799599D patent/US2799599A/en not_active Expired - Lifetime
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2614049A (en) * | 1952-10-14 | Polishing composition | ||
US2140759A (en) * | 1938-01-28 | 1938-12-20 | Dri Wear Inc | Method for dressing, treating, and finishing furs |
US2374678A (en) * | 1940-03-18 | 1945-05-01 | Louis A Gruenwald | Surface active materials |
US2635060A (en) * | 1946-01-25 | 1953-04-14 | Greenebaum Tanning Co J | Water-resistant leather and process for producing same |
US2581296A (en) * | 1947-08-04 | 1952-01-01 | Hat Corp America | Treated fur fibers |
US2597871A (en) * | 1947-09-20 | 1952-05-27 | Du Pont | Wax emulsion polishing composition containing silica |
US2626870A (en) * | 1949-12-05 | 1953-01-27 | Standard Oil Dev Co | Wax and silicone oil auto polish |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3124535A (en) * | 1964-03-10 | Fur cleaning composition | ||
US3124536A (en) * | 1964-03-10 | Composition for cleaning synthetic fur | ||
US2861949A (en) * | 1956-09-10 | 1958-11-25 | Willis C Ware | Fur glazing composition and method for preparing same |
DE1180880B (en) * | 1961-10-05 | 1964-11-05 | Boehme Chem Fab Kg | Process for glossing fur skins |
US3402071A (en) * | 1963-08-08 | 1968-09-17 | Boehme Chem Fab Kg | Process to render leathers and furs water-resistant |
US3395028A (en) * | 1966-09-12 | 1968-07-30 | Drackett Co | Wax composition and method for making the same |
US3498748A (en) * | 1967-05-18 | 1970-03-03 | Pfizer & Co C | Preparation of magnetic ferric oxide |
DE1771327B1 (en) * | 1967-05-18 | 1972-02-03 | Pfizer | METHOD FOR MANUFACTURING MAGNETIC EMX GAMMA FE LOW 2 O LOW 3 FROM ALPHA FERRIOXIDE OR HYDRATED ALPHA FERRIOXIDE |
USRE34584E (en) * | 1984-11-09 | 1994-04-12 | The Procter & Gamble Company | Shampoo compositions |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2799599A (en) | Lustered fur hairs and method for | |
JPH0322844B2 (en) | ||
US2598666A (en) | Wax composition | |
US3852075A (en) | Hard surface rinse-coating composition and method | |
EP0548789B2 (en) | Polish for hard surfaces | |
US2393866A (en) | Metal tarnish remover | |
US3702769A (en) | Method of polishing leather with compositions containing reaction product of hydroxy endblocked siloxanes and aminofunctional silanes | |
GB699196A (en) | Improvements in or relating to compositions suitable for use in the manufacture of shoes | |
US2807557A (en) | Method of treating furs | |
JPS61159474A (en) | Lustering agent composition | |
US4597964A (en) | Cationic polydiorganosiloxanes for treating proteinaceous substrates | |
JPS6354477A (en) | Lustering agent composition | |
US2798858A (en) | Treatment of leather with methylpolysiloxanes | |
US4472566A (en) | Cationic polydiorganosiloxanes for treating proteinaceous substrates | |
US2327495A (en) | Process of removing wax from | |
US2698805A (en) | Polishing composition | |
US1821932A (en) | Waterproofing composition and method of preparing same | |
DE19923477A1 (en) | Surface cleaner-conditioner, useful for treating hard or soft, compact or porous surface or as antifoam, cosmetic conditioner or textile finish, contains aminoorganopolysiloxanes with aggregate state varying with temperature | |
US3615739A (en) | Floor polishing composition containing substituted {11 -triazines | |
US3323925A (en) | Wax polish compositions | |
US160741A (en) | Improvement in blackings for boots | |
US1380299A (en) | Wax-finish remover | |
US545505A (en) | Composition for dressing leather | |
US1981608A (en) | Process for producing an aqueous wax emulsion | |
US272606A (en) | Half to louis n |