US20050031560A9 - Water-in-oil emulsion foundation - Google Patents

Water-in-oil emulsion foundation Download PDF

Info

Publication number
US20050031560A9
US20050031560A9 US10/426,630 US42663003A US2005031560A9 US 20050031560 A9 US20050031560 A9 US 20050031560A9 US 42663003 A US42663003 A US 42663003A US 2005031560 A9 US2005031560 A9 US 2005031560A9
Authority
US
United States
Prior art keywords
composition according
chosen
oil
weight
foundation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
US10/426,630
Other versions
US20040009131A1 (en
US7858104B2 (en
Inventor
Jean-Thierry Simonnet
Aurore Verloo
Emmanuelle Ozee
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR0205512A external-priority patent/FR2839259B1/en
Application filed by LOreal SA filed Critical LOreal SA
Priority to US10/426,630 priority Critical patent/US7858104B2/en
Assigned to L'OREAL S.A. reassignment L'OREAL S.A. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: OZEE, EMMANUELLE, VERLOO, AURORE, SIMONNET, JEAN-THIERRY
Publication of US20040009131A1 publication Critical patent/US20040009131A1/en
Publication of US20050031560A9 publication Critical patent/US20050031560A9/en
Application granted granted Critical
Publication of US7858104B2 publication Critical patent/US7858104B2/en
Active legal-status Critical Current
Adjusted expiration legal-status Critical

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • A61K8/064Water-in-oil emulsions, e.g. Water-in-silicone emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11Encapsulated compositions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29Titanium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39Derivatives containing from 2 to 10 oxyalkylene groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • A61K8/604Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41Particular ingredients further characterized by their size
    • A61K2800/412Microsized, i.e. having sizes between 0.1 and 100 microns

Definitions

  • a fluid foundation cosmetic composition in the form of a water-in-oil emulsion comprising at least one silicone surfactant and coated pigments. Also disclosed herein is a method for applying make-up to skin comprising applying the foundation to the skin.
  • the foundation composition disclosed herein is a make-up composition for the skin of human beings.
  • the compositions disclosed herein may, for example, be provided in at least one of the following forms: foundations to be applied to the face or the neck; a concealer; a tinted cream; and a make-up composition for the body.
  • Foundation compositions are commonly used to give an aesthetic colour to the skin, for example, to the face, but also can be used to conceal skin imperfections, such as redness and spots.
  • fluid emulsions of water-in-oil foundations comprise, as a surfactant, ABIL® WE 09 sold by the company Goldschmidt, which is a mixture of cetyl dimethicone copolyol, polyglyceryl-4 isostearate and hexyl laurate in a 40/30/30 weight ratio.
  • ABIL® WE 09 sold by the company Goldschmidt
  • the fluid emulsions prepared with this mixture may not be stable over time: the emulsion, after storing for 4 months at room temperature (25° C.), can release oil at the surface of the composition and, therefore, may no longer be homogeneous.
  • the application of such a composition to the skin may leave a sensation of greasiness which can damage at least one of the qualities sought for the foundation, for example, ease of application to the skin, pleasant feel and drying speed.
  • the resistance of the mattness of the make-up can be impaired, and as a result, the make-up can rapidly appear glossy. Therefore, the make-up thus obtained may not be aesthetic.
  • the embodiments disclosed herein may, for example, provide a foundation composition which can have good stability after storing at room temperature (25° C.) for at least 4 months and which may make it possible to obtain a homogeneous make-up on the skin, which may have at least one satisfactory aesthetic quality.
  • Such a foundation composition could be obtained using hydrophobic coated pigments and at least one silicone surfactant chosen from alkyl dimethicone copolyols and polyglyceryl-4 isostearates in particular quantities or even after removing the polyglyceryl-4 isostearates from the composition.
  • a foundation composition in the form of a water-in-oil emulsion comprising a fatty phase; an aqueous phase; at least one silcone surfactant chosen from C 8 -C 22 alkyl dimethicone copolyols; and at least 5% by weight, relative to the total weight of the composition, of hydrophobic coated pigments; provided that the composition is free of polyglyceryl-4 isostearate or comprises polyglyceryl-4 isostearate in a quantity such that the weight ratio of the C 8 -C 22 alkyl dimethicone copolyol to the polyglyceryl-4 isostearate is greater than or equal to 2:1.
  • a cosmetic method for non-therapeutic application of make-up to the skin which comprises applying to the skin the composition defined above.
  • the at least one silicone surfactant chosen from C 8 -C 22 alkyl dimethicone copolyols in a foundation composition in the form of a water-in-oil emulsion comprising at least 5% by weight, relative to the total weight of the composition, of hydrophobic coated pigments; provided that the composition is free of polyglyceryl-4 isostearate or comprises polyglyceryl-4 isostearate in a quantity such that the weight ratio of the C 8 -C 22 alkyl dimethicone copolyol to the polyglyceryl-4 isostearate is greater than or equal to 2:1; in order to obtain a foundation composition which can have at least one of the following qualities: stability, homogeneity, and easy application to the skin, and a homogeneous application of make-up to the skin.
  • the foundation compositions disclosed herein may have very good stability at room temperature (25° C.), for example, after storage for 4 months, further, for example, after 6 months, and even further, for example, after 8 months.
  • the foundation compositions disclosed herein can also have at least one quality of being easily applied to the skin, with a sensation of unctuousness, softness and non-greasiness, rapid drying, and spreading homogeneously on the skin.
  • the make-up obtained may also exhibit good stability of the mattness over time.
  • the C 8 -C 22 alkyl dimethicone copolyols present in the foundation compositions disclosed herein may, for example, be chosen from at least one of oxypropylenated and oxyethylenated polymethyl (C 8 -C 22 ) alkyl dimethyl methyl siloxanes.
  • the C 8 -C 22 alkyl dimethicone copolyols may, for example, be chosen from compounds of the following formula (I): wherein:
  • the C 8 -C 22 alkyl dimethicone copolyols may be chosen from cetyl dimethicone copolyols such as the product marketed under the name Abil® EM 90 by the company Goldschmidt.
  • the C 8 -C 22 alkyl dimethicone copolyols may be present, for example, in the compositions disclosed herein in an amount ranging from 2% to 10% by weight, relative to the total weight of the composition, and further, for example, ranging from 2.5% to 5% by weight, relative to the total weight of the composition.
  • the polyglyceryl-4 isostearate may comprise 4 ethylene oxide units. It may be absent from the compositions disclosed herein or may be present in an amount such that the weight ratio of the C 8 -C 22 alkyl dimethicone copolyol to the polyglyceryl-4 isostearate is, for example, greater than or equal to 2:1 and, further, for example, greater than or equal to 3:1.
  • the hydrophobic coated pigments present in the compositions disclosed herein are pigments which can be surface-treated with at least one hydrophobic agent in order to make them compatible with the fatty phase of the emulsion, for example, for them to have good wettability with the oils of the fatty phase.
  • these treated pigments may be well dispersed in the fatty phase.
  • the pigments intended to be coated may be chosen from at least one of inorganic and organic pigments.
  • the pigments may, for example, be chosen from at least one of metal oxides such as iron oxides, for example, those which are yellow, red, brown and black in colour, titanium dioxides, cerium oxide, zirconium oxide, chromium oxide; manganese violet, ultramarine blue, Prussian blue, ferric blue, bismuth oxychloride, pearl, mica coated with at least one of titanium dioxide and bismuth oxychloride, coloured pearlescent pigments such as mica-titanium with iron oxides, mica-titanium with, for example, ferric blue and chromium oxide, mica-titanium with an organic pigment of the abovementioned type and pearlescent pigments based on bismuth oxychlorides.
  • metal oxides such as iron oxides, for example, those which are yellow, red, brown and black in colour, titanium dioxides, cerium oxide, zirconium oxide, chromium
  • pigments chosen from iron oxides and titanium dioxide may be used in the compositions disclosed herein.
  • the at least one hydrophobic treatment agent may be chosen, for example, from silicones such as methicones, dimethicones, and perfluoroalkylsilanes; fatty acids such as stearic acid; metal soaps such as aluminium dimyristate and aluminium salt of hydrogenated tallow glutamate; perfluoroalkyl phosphates; perfluoroalkylsilanes; perfluoroalkylsilazanes; polyhexafluoropropylene oxides; polyorganosiloxanes comprising at least one perfluoroalkyl perfluoropolyether group; amino acids; N-acylated amino acids and the salts thereof; lecithin; and isopropyl triisostearyl titanate.
  • silicones such as methicones, dimethicones, and perfluoroalkylsilanes
  • fatty acids such as stearic acid
  • metal soaps such as aluminium dimyristate and aluminium
  • the N-acylated amino acids may comprise, for example, at least one acyl group comprising from 8 to 22 carbon atoms, such as 2-ethylhexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl and cocoyl groups.
  • the salts of these compounds may be chosen from aluminium, magnesium, calcium, zirconium, zinc, sodium and potassium salts.
  • the amino acid may be, for example, chosen from lysine, glutamic acid and alanine.
  • alkyl as used herein means an alkyl group comprising from 1 to 30 carbon atoms, for example, comprising from 5 to 16 carbon atoms.
  • Hydrophobic treated pigments are, for example, described in Patent Application No. EP-A-1086683.
  • the hydrophobic coated pigments may be present in an amount ranging, for example, from 5% to 20% by weight, relative to the total weight of the composition, further, for example, in an amount at least equal to 8% by weight, and even further, for example, in an amount ranging from 8% to 15% by weight, relative to the total weight of the composition.
  • the fatty phase of the compositions disclosed herein may, for example, further comprise at least one oil.
  • compositions disclosed herein may, for example, comprise from 20% to 45% by weight of oil, relative to the total weight of the composition, and further, for example, from 20% to 42% by weight of oil, and even further, for example, from 30% to 38% by weight of oil, relative to the total weight of the composition.
  • compositions disclosed herein may comprise at least one oil chosen from silicone oils, for example, volatile silicone oils.
  • the at least one oil may be chosen, for example, from carbonaceous and hydrocarbonaceous oils and silicone oils of mineral, animal, vegetable and synthetic origins.
  • the hydrocarbonaceous oils may be chosen from paraffin oils, liquid paraffin oils, vison oil, turtle oil, soya bean oil, perhydrosqualene, sweet almond oil, calophyllum oil, palm oil, grapeseed oil, sesame oil, maize oil, arara oil, rapeseed oil, sunflower oil, cottonseed oil, apricot oil, castor oil, avocado oil, jojoba oil, olive oil and cereal germ oil; esters of lanolic acid, oleic acid, lauric acid and stearic acid; fatty esters, such as isopropyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, diisopropyl adipate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-hexyldecyl laurate, 2-octyldecyl palmitate, 2-octyidode
  • the silicone oils may, for example, be chosen from at least one of polysiloxanes modified with at least one entity chosen from fatty acids, fatty alcohols and polyoxyalkylenes; polydimethylsiloxane (PDMS), which may be optionally phenylated, such as phenyltrimethicones, and which may be optionally substituted with at least one group chosen from aliphatic groups, aromatic groups, and functional groups such as hydroxyl, thiol and amine groups.
  • PDMS polydimethylsiloxane
  • volatile oils means oils which are capable of evaporating from the skin, at room temperature in less than one hour.
  • volatile oils can have a viscosity ranging from 0.5 to 25 centistokes at 25° C. Such a viscosity can readily be determined by one of ordinary skill in the art using the known techniques.
  • the volatile oils may be chosen, for example, from hydrocarbonaceous oils and silicone oils optionally comprising at least one group chosen from alkyl and alkoxy groups at the end of a silicone and/or pendant chain.
  • the volatile oils may, for example, be chosen from volatile silicone oils.
  • the volatile silicone oils which can be used in the compositions disclosed herein, may, for example, be chosen from linear and cyclic silicones comprising from 2 to 7 silicon atoms, these silicones optionally comprising at least one group chosen from alkyl and alkoxy groups comprising from 1 to 10 carbon atoms.
  • the volatile silicone oils may be chosen from at least one of octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, hexadecamethyl-cyclohexasiloxane, heptamethylhexyltrisiloxane, and heptamethyloctyltrisiloxane.
  • the volatile hydrocarbonaceous oils may be chosen, for example, from at least one of C 8 -C 16 isoparaffins such as isooctane, isododecane, isodecane, isohexadecane, and heptane.
  • volatile oils may be present in the compositions disclosed herein in an amount ranging, for example, from 20% to 45% by weight, and further, for example, from 25% to 40% by weight, and even further, for example, from 30 to 40% by weight, relative to the total weight of the composition.
  • the fatty phase may also comprise at least one fatty substance chosen, for example, from waxes, gums, and pasty fatty substances, which may be chosen from pasty fatty substances of vegetable origin, animal origin, mineral origin, synthetic origin, and silicone-based fatty substances.
  • these waxes may be chosen, for example, from hydrocarbon waxes such as beeswax, Carnauba wax, Candelilla wax, Ouricoury wax, Japan wax, cork fibre waxes, sugarcane waxes, paraffin waxes, lignite waxes, microcrystalline waxes, lanolin wax, Montan wax, ozokerites, polyethylene waxes, waxes obtained by Fischer-Tropsch synthesis, hydrogenated oils, fatty esters and glycerides which are concrete at 25° C.
  • hydrocarbon waxes such as beeswax, Carnauba wax, Candelilla wax, Ouricoury wax, Japan wax, cork fibre waxes, sugarcane waxes, paraffin waxes, lignite waxes, microcrystalline waxes, lanolin wax, Montan wax, ozokerites, polyethylene waxes, waxes obtained by Fischer-Tropsch synthesis, hydrogenated oils, fatty esters and glycerides which
  • waxes chosen, for example, from silicone waxes, such as alkyl, alkoxy and esters of polymethylsiloxane.
  • the waxes may be provided in the form of stable dispersions of colloidal particles of wax as may be prepared according to known methods, such as those of “Microemulsions Theory and Practice”, L. M. Prince Ed., Academic Press (1977), pages 21-32.
  • a wax which is liquid at room temperature such as jojoba oil, may also be used in the compositions disclosed herein.
  • the waxes may be present in an amount ranging, for example, from 0.1% to 10% by weight, relative to the total weight of the composition.
  • the pasty fatty compounds may be defined by at least one of the following physicochemical properties:
  • compositions disclosed herein may also comprise at least one component chosen from alkyl, alkoxy and phenyl dimethicone such as the product sold under the name “Abil wax 2440” by the company GOLDSCHMIDT.
  • compositions disclosed herein may also comprise at least one silicone resin comprising a combination of (R) 3 SiO 1/2 , (R) 2 SiO 2/2 , RSiO 3/2 and SiO 4/2 units wherein R is chosen from alkyl radicals comprising from 1 to 6 carbon atoms.
  • compositions disclosed herein may further comprise at least one fatty phase thickening agent.
  • the at least one fatty phase thickening agent may be chosen from:
  • the at least one hydrophobic group may, for example, be chosen from:
  • the pyrogenic silicas may have, for example, an average particle size, which may be nanometric or micrometric, for example, ranging from 5 to 200 nm. Such an average particle size can readily be determined by one of ordinary skill in the art using the known techniques.
  • the at least one fatty phase thickening agent may be present in an amount ranging, for example, from 0.1% to 5% by weight, relative to the total weight of the composition, and further, for example, from 0.4% to 3% by weight, relative to the total weight of the composition.
  • the fatty phase comprising at least one silicone surfactant chosen from C 8 -C 22 alkyl dimethicone copolyols and optionally polyglyceryl-4 isostearates if present, may be present in an amount ranging, for example, from 22% to 50% by weight, relative to the total weight of the composition, further, for example, from 25% to 45% by weight, and even further, for example, from 30% to 40% by weight, relative to the total weight of the composition.
  • the aqueous phase comprises water.
  • the water may be chosen from at least one of floral water such as cornflower water; mineral water such as VITTEL water, LUCAS water and LA ROCHE POSAY water; and thermal water.
  • the aqueous phase may also comprise at least one solvent other than water.
  • the at least one solvent may be chosen from primary alcohols such as ethanol and isopropanol; glycols such as propylene glycol, butylene glycol, dipropylene glycol, and diethylene glycol; and glycol ethers such as (C 1 -C 4 )alkyl ethers of mono-, di- and tripropylene glycols, and mono-, di- and triethylene glycols.
  • the aqueous phase may further comprise at least one stabilizing agent.
  • the at least one stabalizing agent may be chosen, for example, from sodium chloride, magnesium dichloride and magnesium sulphate.
  • the aqueous phase may also comprise at least one entity chosen from water-soluble and water-dispersible entities compatible with an aqueous phase, such as gelling agents, film-forming polymers, thickeners, and surfactants.
  • the aqueous phase may be present in the compositions disclosed herein in an amount ranging from 30% to 75% by weight, further, for example, from 35% to 50% by weight, relative to the total weight of the composition.
  • compositions disclosed herein may further comprise at least one filler.
  • filler means colourless or white, inorganic or synthetic, lamellar or nonlamellar particles.
  • the at least one filler may be present in the compositions disclosed herein in an amount ranging, for example, from 0.1% to 15% by weight, relative to the total weight of the composition, further, for example, from 0.1% to 10% by weight, relative to the total weight of the composition.
  • the at least one filler may be chosen, for example, from talc, mica, silica, kaolin, starch, boron nitride, calcium carbonate, magnesium carbonate, magnesium hydrocarbonate, microcrystalline cellulose, powders of synthetic polymers such as polyethylene, polyesters, polyamides such as those sold under the tradename “Nylon”, and polytetrafluoroethylene (“Teflon”) and silicone powders.
  • the compositions disclosed herein may be fluid (flows under its own weight at room temperature) and may have a viscosity, measured at 25° C., at a shear rate of 200 min ⁇ 1 (200 revolutions per minute, that is a frequency of 50 Hz), ranging, for example, from 0.5 to 3.2 Pa.s (5 to 32 poises), and further, for example, ranging from 0.6 to 1.5 Pa.s (6 to 15 poises).
  • a viscosity may allow easy application of the composition, and may make it possible to obtain a make-up which is homogeneous, uniform and without traces.
  • the viscosity is measured at 25° C. with a TV type CONTRAVES viscometer equipped with a No.
  • compositions disclosed herein may comprise, for example, at least one adjuvant chosen from customary adjuvants used in the cosmetic and dermatological fields, such as hydrophilic and lipophilic gelling and thickening agents; moisturizing agents; emollients; hydrophilic and lipophilic active agents; anti-free radical agents; sequestrants; antioxidants; preservatives; basifying and acidifying agents; perfumes; film-forming agents; and soluble colorants.
  • the quantity of the at least one adjuvant is that conventionally used in the fields considered.
  • Active agents which can be used in the compositions disclosed herein, may be chosen, for example, from at least one of moisturizing agents such as protein hydrolysates and polyols such as glycerine, glycols such as polyethylene glycols, and sugar derivatives; natural extracts; anti-inflammatory agents; procyannidolic oligomers; vitamins such as vitamin A (retinol), vitamin E (tocopherol), vitamin C (ascorbic acid), vitamin B5 (panthenol), vitamin B3 (niacinamide), and derivatives thereof, for example, esters; urea, caffeine, salicylic acid and its derivatives; alpha-hydroxy acids such as lactic acid and glycolic acid and derivatives thereof; retinoids such as carotenoids and derivatives of vitamin A; sunscreens; hydrocortisone; melatonin; extracts of algae, fungi, plants, yeasts and bacteria; enzymes; steroids; anti-bacterial active agents such as 2,4,4′-trichloro-2′-hydroxydip
  • the sunscreens may be chosen from at least one of organic (or chemical) screening agents and physical screening agents.
  • organic (or chemical) sunscreens which may be used in the compositions disclosed herein may be chosen, for example, from any UVA- and UVB-screening agents which may be used in the cosmetic field.
  • the UVB-screening agents may, for example, be chosen from at least one of:
  • the UVA-screening agents may be chosen, for example, from at least one of:
  • the physical screening agents may, for example, be chosen from at least one of titanium oxide (amorphous and crystalline titanium dioxide in rutile and anatase forms), zinc oxide, iron oxide, zirconium oxide, and cerium oxide.
  • These metal oxides may, for example, be in the form of particles having a micrometric or nanometric size (nanopigments). In the form of nanopigments, the average sizes of the particles can range, for example, from 5 to 100 nm. Such an average particle size can readily be determined by one of ordinary skill in the art using the known techniques.
  • These pigments may, for example, be treated so as to make their surface hydrophobic.
  • the treatment may be carried out according to methods known to persons skilled in the art.
  • the pigments may, for example, be coated with silicone compounds such as PDMS and/or with polymers.
  • a foundation was prepared in the form of a water-in-oil emulsion having the following composition: Fatty phase: isostearyl palmitate 6 g cyclopentasiloxane 30 g cetyl dimethicone copolyol 2.7 g (Abil ® EM 90 from the company GOLDSCHMIDT) polyglyceryl-4 isostearate 0.9 g iron oxides coated with disodium salt of 2 g stearoyl glutamate titanium oxide coated with disodium salt of 9 g stearoyl glutamate nylon powder 5 g hectorite 0.5 g hydrophobic pyrogenic silica (Aerosil R 972) 0.35 g hollow microspheres (Expancel) 0.35 g
  • Aqueous phase butylene glycol 5 g magnesium sulphate 1 g PEG 20 1.7 g preservatives qs water qs 100 g
  • the emulsion was prepared at room temperature, on the one hand, by mixing the pigments in part of the cyclopentasiloxane, on the other hand, by mixing the other oils with the surfactants and dispersing the hectorite therein, and then the mixture of pigments and fillers was added to the other mixed constituents of the fatty phase.
  • the mixture of the constituents of the aqueous phase was then prepared and poured into the mixture of the fatty phase, with stirring, according to known means in order to finally obtain the emulsion.
  • This foundation was stable after storing at room temperature (25° C.) for 4 months, or even up to 8 months. It was easy to apply to the skin with a good sensation to the touch, dried rapidly after application, and the make-up obtained exhibited good colour homogeneity.
  • a foundation was prepared in the form of a water-in-oil emulsion having the following composition: Fatty phase: cyclohexasiloxane 33 g cetyl dimethicone copolyol 4 g (Abil ® EM 90 from the company GOLDSCHMIDT) iron oxides coated with disodium salt of 2 g stearoyl glutamate titanium oxide coated with disodium salt of 7 g stearoyl glutamate hectorite 0.7 g silica (Aerosil R 972) 0.6 g
  • Aqueous phase glycerol 3 g sodium chloride 0.5 g preservatives qs water qs 100 g
  • the emulsion was prepared according to the same procedure described in Example 1.
  • This foundation was stable after storing at room temperature (25° C.) for 4 months, or even up to 8 months. It was easy to apply to the skin with a good sensation to the touch, dried rapidly during application, and the make-up obtained exhibited good colour homogeneity without leaving traces.

Abstract

A foundation composition in the form of a water-in-oil emulsion comprising a fatty phase; an aqueous phase; at least one silicone surfacant chosen from C8-C22 alkyl dimethicone copolyols; and at least 5% by weight, relative to the total weight of the composition, of hydrophobic coated pigments; provided that the composition is free of polyglyceryl-4 isostearate or comprises polyglyceryl-4 isostearate in a quantity such that the weight ratio of the C8-C22 alkyl dimethicone copolyol to the polyglyceryl-4 isostearate is greater than or equal to 2:1, wherein the foundation composition can exhibit good stability at room temperature and can be easy to apply to the skin.

Description

  • This application claims benefit of U.S. Provisional Application No. 60/393,115, filed Jul. 3, 2002.
  • Disclosed herein is a fluid foundation cosmetic composition in the form of a water-in-oil emulsion comprising at least one silicone surfactant and coated pigments. Also disclosed herein is a method for applying make-up to skin comprising applying the foundation to the skin.
  • The foundation composition disclosed herein is a make-up composition for the skin of human beings. The compositions disclosed herein may, for example, be provided in at least one of the following forms: foundations to be applied to the face or the neck; a concealer; a tinted cream; and a make-up composition for the body.
  • Foundation compositions are commonly used to give an aesthetic colour to the skin, for example, to the face, but also can be used to conceal skin imperfections, such as redness and spots.
  • It is known from the document FR-A-2686510 that fluid emulsions of water-in-oil foundations comprise, as a surfactant, ABIL® WE 09 sold by the company Goldschmidt, which is a mixture of cetyl dimethicone copolyol, polyglyceryl-4 isostearate and hexyl laurate in a 40/30/30 weight ratio. However, it has been observed that the fluid emulsions prepared with this mixture may not be stable over time: the emulsion, after storing for 4 months at room temperature (25° C.), can release oil at the surface of the composition and, therefore, may no longer be homogeneous. Without prior stirring, the application of such a composition to the skin may leave a sensation of greasiness which can damage at least one of the qualities sought for the foundation, for example, ease of application to the skin, pleasant feel and drying speed. The resistance of the mattness of the make-up can be impaired, and as a result, the make-up can rapidly appear glossy. Therefore, the make-up thus obtained may not be aesthetic.
  • The embodiments disclosed herein may, for example, provide a foundation composition which can have good stability after storing at room temperature (25° C.) for at least 4 months and which may make it possible to obtain a homogeneous make-up on the skin, which may have at least one satisfactory aesthetic quality.
  • The inventors have discovered that such a foundation composition could be obtained using hydrophobic coated pigments and at least one silicone surfactant chosen from alkyl dimethicone copolyols and polyglyceryl-4 isostearates in particular quantities or even after removing the polyglyceryl-4 isostearates from the composition.
  • For example, disclosed herein is a foundation composition in the form of a water-in-oil emulsion comprising a fatty phase; an aqueous phase; at least one silcone surfactant chosen from C8-C22 alkyl dimethicone copolyols; and at least 5% by weight, relative to the total weight of the composition, of hydrophobic coated pigments; provided that the composition is free of polyglyceryl-4 isostearate or comprises polyglyceryl-4 isostearate in a quantity such that the weight ratio of the C8-C22 alkyl dimethicone copolyol to the polyglyceryl-4 isostearate is greater than or equal to 2:1.
  • Further disclosed herein is a cosmetic method for non-therapeutic application of make-up to the skin, which comprises applying to the skin the composition defined above.
  • Also disclosed herein is the use of the at least one silicone surfactant chosen from C8-C22 alkyl dimethicone copolyols in a foundation composition in the form of a water-in-oil emulsion comprising at least 5% by weight, relative to the total weight of the composition, of hydrophobic coated pigments; provided that the composition is free of polyglyceryl-4 isostearate or comprises polyglyceryl-4 isostearate in a quantity such that the weight ratio of the C8-C22 alkyl dimethicone copolyol to the polyglyceryl-4 isostearate is greater than or equal to 2:1; in order to obtain a foundation composition which can have at least one of the following qualities: stability, homogeneity, and easy application to the skin, and a homogeneous application of make-up to the skin.
  • The foundation compositions disclosed herein may have very good stability at room temperature (25° C.), for example, after storage for 4 months, further, for example, after 6 months, and even further, for example, after 8 months. The foundation compositions disclosed herein can also have at least one quality of being easily applied to the skin, with a sensation of unctuousness, softness and non-greasiness, rapid drying, and spreading homogeneously on the skin. The make-up obtained may also exhibit good stability of the mattness over time.
  • The C8-C22 alkyl dimethicone copolyols present in the foundation compositions disclosed herein may, for example, be chosen from at least one of oxypropylenated and oxyethylenated polymethyl (C8-C22) alkyl dimethyl methyl siloxanes.
  • The C8-C22 alkyl dimethicone copolyols may, for example, be chosen from compounds of the following formula (I):
    Figure US20050031560A9-20050210-C00001

    wherein:
      • PE is chosen from groups of (—C2H4O)x—(C3H6O)y—R, wherein
        • R is chosen from a hydrogen atom and alkyl radicals comprising from 1 to 4 carbon atoms,
        • x ranges from 0 to 100, and
        • y ranges from 0 to 80, provided that the x and the y are not simultaneously 0;
      • m ranges from 1 to 40;
      • n ranges from 10 to 200;
      • o ranges from 1 to 100;
      • p ranges from 7 to 21; and
      • q ranges from 0 to 4;
        and, for example:
    • R=H;
    • m=1 to 10;
    • n=10 to 100;
    • o=1 to 30;
    • p=15; and
    • q=3.
  • For example, the C8-C22 alkyl dimethicone copolyols may be chosen from cetyl dimethicone copolyols such as the product marketed under the name Abil® EM 90 by the company Goldschmidt.
  • The C8-C22 alkyl dimethicone copolyols may be present, for example, in the compositions disclosed herein in an amount ranging from 2% to 10% by weight, relative to the total weight of the composition, and further, for example, ranging from 2.5% to 5% by weight, relative to the total weight of the composition.
  • The polyglyceryl-4 isostearate may comprise 4 ethylene oxide units. It may be absent from the compositions disclosed herein or may be present in an amount such that the weight ratio of the C8-C22 alkyl dimethicone copolyol to the polyglyceryl-4 isostearate is, for example, greater than or equal to 2:1 and, further, for example, greater than or equal to 3:1.
  • The hydrophobic coated pigments present in the compositions disclosed herein are pigments which can be surface-treated with at least one hydrophobic agent in order to make them compatible with the fatty phase of the emulsion, for example, for them to have good wettability with the oils of the fatty phase. Thus, these treated pigments may be well dispersed in the fatty phase.
  • The pigments intended to be coated may be chosen from at least one of inorganic and organic pigments. The pigments may, for example, be chosen from at least one of metal oxides such as iron oxides, for example, those which are yellow, red, brown and black in colour, titanium dioxides, cerium oxide, zirconium oxide, chromium oxide; manganese violet, ultramarine blue, Prussian blue, ferric blue, bismuth oxychloride, pearl, mica coated with at least one of titanium dioxide and bismuth oxychloride, coloured pearlescent pigments such as mica-titanium with iron oxides, mica-titanium with, for example, ferric blue and chromium oxide, mica-titanium with an organic pigment of the abovementioned type and pearlescent pigments based on bismuth oxychlorides.
  • For example, pigments chosen from iron oxides and titanium dioxide may be used in the compositions disclosed herein.
  • The at least one hydrophobic treatment agent may be chosen, for example, from silicones such as methicones, dimethicones, and perfluoroalkylsilanes; fatty acids such as stearic acid; metal soaps such as aluminium dimyristate and aluminium salt of hydrogenated tallow glutamate; perfluoroalkyl phosphates; perfluoroalkylsilanes; perfluoroalkylsilazanes; polyhexafluoropropylene oxides; polyorganosiloxanes comprising at least one perfluoroalkyl perfluoropolyether group; amino acids; N-acylated amino acids and the salts thereof; lecithin; and isopropyl triisostearyl titanate.
  • The N-acylated amino acids may comprise, for example, at least one acyl group comprising from 8 to 22 carbon atoms, such as 2-ethylhexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl and cocoyl groups. The salts of these compounds may be chosen from aluminium, magnesium, calcium, zirconium, zinc, sodium and potassium salts. The amino acid may be, for example, chosen from lysine, glutamic acid and alanine.
  • The term “alkyl” as used herein means an alkyl group comprising from 1 to 30 carbon atoms, for example, comprising from 5 to 16 carbon atoms.
  • Hydrophobic treated pigments are, for example, described in Patent Application No. EP-A-1086683.
  • The hydrophobic coated pigments may be present in an amount ranging, for example, from 5% to 20% by weight, relative to the total weight of the composition, further, for example, in an amount at least equal to 8% by weight, and even further, for example, in an amount ranging from 8% to 15% by weight, relative to the total weight of the composition.
  • The fatty phase of the compositions disclosed herein may, for example, further comprise at least one oil.
  • The compositions disclosed herein may, for example, comprise from 20% to 45% by weight of oil, relative to the total weight of the composition, and further, for example, from 20% to 42% by weight of oil, and even further, for example, from 30% to 38% by weight of oil, relative to the total weight of the composition.
  • The compositions disclosed herein, may comprise at least one oil chosen from silicone oils, for example, volatile silicone oils.
  • The at least one oil may be chosen, for example, from carbonaceous and hydrocarbonaceous oils and silicone oils of mineral, animal, vegetable and synthetic origins.
  • For example, the hydrocarbonaceous oils may be chosen from paraffin oils, liquid paraffin oils, vison oil, turtle oil, soya bean oil, perhydrosqualene, sweet almond oil, calophyllum oil, palm oil, grapeseed oil, sesame oil, maize oil, arara oil, rapeseed oil, sunflower oil, cottonseed oil, apricot oil, castor oil, avocado oil, jojoba oil, olive oil and cereal germ oil; esters of lanolic acid, oleic acid, lauric acid and stearic acid; fatty esters, such as isopropyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, diisopropyl adipate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-hexyldecyl laurate, 2-octyldecyl palmitate, 2-octyidodecyl myristate, 2-octyldodecyl lactate, 2-diethylhexyl succinate, diisostearyl malate, glycerine triisostearate, diglycerine triisostearate; higher fatty acids such as myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, and isostearic acid; higher fatty alcohols such as cetanol, stearyl alcohol, oleyl alcohol, linoleyl alcohol, linolenyl alcohol, isostearyl alcohol, and octyldodecanol.
  • The silicone oils may, for example, be chosen from at least one of polysiloxanes modified with at least one entity chosen from fatty acids, fatty alcohols and polyoxyalkylenes; polydimethylsiloxane (PDMS), which may be optionally phenylated, such as phenyltrimethicones, and which may be optionally substituted with at least one group chosen from aliphatic groups, aromatic groups, and functional groups such as hydroxyl, thiol and amine groups.
  • For example, it is possible to use at least one oil which is volatile at room temperature. The expression “volatile oils” means oils which are capable of evaporating from the skin, at room temperature in less than one hour. For example, volatile oils can have a viscosity ranging from 0.5 to 25 centistokes at 25° C. Such a viscosity can readily be determined by one of ordinary skill in the art using the known techniques.
  • The volatile oils may be chosen, for example, from hydrocarbonaceous oils and silicone oils optionally comprising at least one group chosen from alkyl and alkoxy groups at the end of a silicone and/or pendant chain. The volatile oils may, for example, be chosen from volatile silicone oils.
  • The volatile silicone oils, which can be used in the compositions disclosed herein, may, for example, be chosen from linear and cyclic silicones comprising from 2 to 7 silicon atoms, these silicones optionally comprising at least one group chosen from alkyl and alkoxy groups comprising from 1 to 10 carbon atoms. For example, the volatile silicone oils may be chosen from at least one of octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, hexadecamethyl-cyclohexasiloxane, heptamethylhexyltrisiloxane, and heptamethyloctyltrisiloxane.
  • The volatile hydrocarbonaceous oils may be chosen, for example, from at least one of C8-C16 isoparaffins such as isooctane, isododecane, isodecane, isohexadecane, and heptane.
  • These volatile oils may be present in the compositions disclosed herein in an amount ranging, for example, from 20% to 45% by weight, and further, for example, from 25% to 40% by weight, and even further, for example, from 30 to 40% by weight, relative to the total weight of the composition.
  • The fatty phase may also comprise at least one fatty substance chosen, for example, from waxes, gums, and pasty fatty substances, which may be chosen from pasty fatty substances of vegetable origin, animal origin, mineral origin, synthetic origin, and silicone-based fatty substances.
  • Among the waxes solid at room temperature, which may be present in the compositions disclosed herein, these waxes may be chosen, for example, from hydrocarbon waxes such as beeswax, Carnauba wax, Candelilla wax, Ouricoury wax, Japan wax, cork fibre waxes, sugarcane waxes, paraffin waxes, lignite waxes, microcrystalline waxes, lanolin wax, Montan wax, ozokerites, polyethylene waxes, waxes obtained by Fischer-Tropsch synthesis, hydrogenated oils, fatty esters and glycerides which are concrete at 25° C. It may also be possible to use waxes chosen, for example, from silicone waxes, such as alkyl, alkoxy and esters of polymethylsiloxane. The waxes may be provided in the form of stable dispersions of colloidal particles of wax as may be prepared according to known methods, such as those of “Microemulsions Theory and Practice”, L. M. Prince Ed., Academic Press (1977), pages 21-32.
  • A wax which is liquid at room temperature, such as jojoba oil, may also be used in the compositions disclosed herein.
  • The waxes may be present in an amount ranging, for example, from 0.1% to 10% by weight, relative to the total weight of the composition.
  • The pasty fatty compounds may be defined by at least one of the following physicochemical properties:
      • a viscosity ranging from 0.1 to 40 Pa.s (1 to 400 poises), for example, ranging from 0.5 to 25 Pa.s, measured at 40° C. with a CONTRAVES TV rotary viscometer equipped with an MS-r3 or MS-r4 rotor at a frequency of 60 Hz, and
      • a melting point ranging from 25 to 70° C., for example, ranging from 25 to 55° C.
  • The compositions disclosed herein may also comprise at least one component chosen from alkyl, alkoxy and phenyl dimethicone such as the product sold under the name “Abil wax 2440” by the company GOLDSCHMIDT.
  • The compositions disclosed herein may also comprise at least one silicone resin comprising a combination of (R)3SiO1/2, (R)2SiO2/2, RSiO3/2 and SiO4/2 units wherein R is chosen from alkyl radicals comprising from 1 to 6 carbon atoms.
  • The compositions disclosed herein may further comprise at least one fatty phase thickening agent. The at least one fatty phase thickening agent may be chosen from:
      • organomodified clays which are clays treated with compounds chosen, for example, from quaternary amines and tertiary amines. The organomodified clays may, for example, be chosen from organomodified bentonites such as those sold under the name “Bentone 34” by the company RHEOX, and organomodified hectorites such as those sold under the name “Bentone 27”, “Bentone 38” by the company RHEOX; and
      • hydrophobic pyrogenic silicas, which are pyrogenic silicas that are chemically surface-modified by a chemical reaction generating a reduction in the number of silanol groups. The silanol groups may be replaced, for example, by at least one hydrophobic group.
  • The at least one hydrophobic group may, for example, be chosen from:
      • trimethylsiloxyl groups, which are obtained, for example, by treating pyrogenic silicas in the presence of hexamethyldisilazane. Silicas thus treated are called “Silica silylate” according to CTFA (6th edition, 1995). They are, for example, marketed under the references “AEROSIL R812®” by the company Degussa, and “CAB-O-SIL TS-530®” by the company Cabot.
      • dimethylsilyloxyl and polydimethylsiloxane groups, which are, for example, obtained by treating pyrogenic silicas in the presence of polydimethylsiloxane or dimethyldichlorosilane. Silicas thus treated are called “Silica dimethyl silylate” according to CTFA (6th edition, 1995). They are, for example, marketed under the references “AEROSIL R972®”, and “AEROSIL R974®” by the company Degussa, and “CAB-O-SIL TS-610®”, and “CAB-O-SIL TS-720®” by the company Cabot.
  • The pyrogenic silicas may have, for example, an average particle size, which may be nanometric or micrometric, for example, ranging from 5 to 200 nm. Such an average particle size can readily be determined by one of ordinary skill in the art using the known techniques.
  • The at least one fatty phase thickening agent may be present in an amount ranging, for example, from 0.1% to 5% by weight, relative to the total weight of the composition, and further, for example, from 0.4% to 3% by weight, relative to the total weight of the composition.
  • The fatty phase, comprising at least one silicone surfactant chosen from C8-C22 alkyl dimethicone copolyols and optionally polyglyceryl-4 isostearates if present, may be present in an amount ranging, for example, from 22% to 50% by weight, relative to the total weight of the composition, further, for example, from 25% to 45% by weight, and even further, for example, from 30% to 40% by weight, relative to the total weight of the composition.
  • The aqueous phase comprises water. The water may be chosen from at least one of floral water such as cornflower water; mineral water such as VITTEL water, LUCAS water and LA ROCHE POSAY water; and thermal water.
  • The aqueous phase may also comprise at least one solvent other than water. For example, the at least one solvent may be chosen from primary alcohols such as ethanol and isopropanol; glycols such as propylene glycol, butylene glycol, dipropylene glycol, and diethylene glycol; and glycol ethers such as (C1-C4)alkyl ethers of mono-, di- and tripropylene glycols, and mono-, di- and triethylene glycols.
  • The aqueous phase may further comprise at least one stabilizing agent. The at least one stabalizing agent may be chosen, for example, from sodium chloride, magnesium dichloride and magnesium sulphate.
  • The aqueous phase may also comprise at least one entity chosen from water-soluble and water-dispersible entities compatible with an aqueous phase, such as gelling agents, film-forming polymers, thickeners, and surfactants.
  • For example, the aqueous phase may be present in the compositions disclosed herein in an amount ranging from 30% to 75% by weight, further, for example, from 35% to 50% by weight, relative to the total weight of the composition.
  • The compositions disclosed herein may further comprise at least one filler. The expression “filler” means colourless or white, inorganic or synthetic, lamellar or nonlamellar particles.
  • The at least one filler may be present in the compositions disclosed herein in an amount ranging, for example, from 0.1% to 15% by weight, relative to the total weight of the composition, further, for example, from 0.1% to 10% by weight, relative to the total weight of the composition. The at least one filler may be chosen, for example, from talc, mica, silica, kaolin, starch, boron nitride, calcium carbonate, magnesium carbonate, magnesium hydrocarbonate, microcrystalline cellulose, powders of synthetic polymers such as polyethylene, polyesters, polyamides such as those sold under the tradename “Nylon”, and polytetrafluoroethylene (“Teflon”) and silicone powders.
  • For example, the compositions disclosed herein may be fluid (flows under its own weight at room temperature) and may have a viscosity, measured at 25° C., at a shear rate of 200 min−1 (200 revolutions per minute, that is a frequency of 50 Hz), ranging, for example, from 0.5 to 3.2 Pa.s (5 to 32 poises), and further, for example, ranging from 0.6 to 1.5 Pa.s (6 to 15 poises). Such a viscosity may allow easy application of the composition, and may make it possible to obtain a make-up which is homogeneous, uniform and without traces. The viscosity is measured at 25° C. with a TV type CONTRAVES viscometer equipped with a No. 3 rotor, the measurement being carried out after 10 minutes of rotation of the rotor (time after which stabilization of the viscosity and of the speed of rotation of the rotor is observed), at a shear rate of 200 min−1 (200 revolutions per minute).
  • The compositions disclosed herein may comprise, for example, at least one adjuvant chosen from customary adjuvants used in the cosmetic and dermatological fields, such as hydrophilic and lipophilic gelling and thickening agents; moisturizing agents; emollients; hydrophilic and lipophilic active agents; anti-free radical agents; sequestrants; antioxidants; preservatives; basifying and acidifying agents; perfumes; film-forming agents; and soluble colorants. The quantity of the at least one adjuvant is that conventionally used in the fields considered.
  • Active agents, which can be used in the compositions disclosed herein, may be chosen, for example, from at least one of moisturizing agents such as protein hydrolysates and polyols such as glycerine, glycols such as polyethylene glycols, and sugar derivatives; natural extracts; anti-inflammatory agents; procyannidolic oligomers; vitamins such as vitamin A (retinol), vitamin E (tocopherol), vitamin C (ascorbic acid), vitamin B5 (panthenol), vitamin B3 (niacinamide), and derivatives thereof, for example, esters; urea, caffeine, salicylic acid and its derivatives; alpha-hydroxy acids such as lactic acid and glycolic acid and derivatives thereof; retinoids such as carotenoids and derivatives of vitamin A; sunscreens; hydrocortisone; melatonin; extracts of algae, fungi, plants, yeasts and bacteria; enzymes; steroids; anti-bacterial active agents such as 2,4,4′-trichloro-2′-hydroxydiphenyl ether (or triclosan), 3,4,4′-trichlorocarbanilide (or triclocarban) and the acids indicated above, for example, salicylic acid and its derivatives; and tightening agents.
  • The sunscreens (or UV-screening agents) may be chosen from at least one of organic (or chemical) screening agents and physical screening agents.
  • The organic (or chemical) sunscreens, which may be used in the compositions disclosed herein may be chosen, for example, from any UVA- and UVB-screening agents which may be used in the cosmetic field.
  • The UVB-screening agents may, for example, be chosen from at least one of:
    • (1) salicylic acid derivatives, for example, homomenthyl salicylate and octyl salicylate;
    • (2) cinnamic acid derivatives, for example, 2-ethylhexyl p-methoxycinnamate, marketed by the company Givaudan under the name Parsol MCX;
    • (3) liquid β,β′-diphenylacrylate derivatives, for example, 2-ethylhexyl α-cyano-α,β′-diphenylacrylate and octocrylene, marketed by the company BASF under the name UVINUL N539;
    • (4) p-aminobenzoic acid derivatives;
    • (5) 4-methylbenzylidenecamphor marketed by the company Merck under the name EUSOLEX 6300;
    • (6) 2-phenylbenzimidazole-5-sulphonic acid marketed under the name EUSOLEX 232 by the company Merck; and
    • (7)1,3,5-triazine derivatives, for example:
      • 2,4,6-tris[p-(2′-ethylhexyl-1′-oxycarbonyl)anilino]-1,3,5-triazine marketed by the company BASF under the name UVINUL T150, and
      • dioctylbutamidotriazone marketed by the company Sigma 3V under the name UVASORB HEB.
  • The UVA-screening agents may be chosen, for example, from at least one of:
    • (1) dibenzoylmethane derivatives, for example, 4-(tert-butyl)-4′-methoxydibenzoylmethane marketed by the company Givaudan under the name PARSOL 1789;
    • (2) 1,4-benzene[di(3-methylidene-10-camphorsulphonic)] acid optionally in partially and completely neutralized form, marketed under the name MEXORYL SX by the company Chimex;
    • (3) benzophenone derivatives, for example:
    • 2,4-dihydroxybenzophenone (benzophenone-1);
    • 2,2′,4,4′-tetrahydroxybenzophenone (benzophenone-2);
    • 2-hydroxy-4-methoxybenzophenone (benzophenone-3), marketed under the name UVINUL M40 by the company BASF;
    • 2-hydroxy-4-methoxybenzophenone-5-sulphonic acid (benzophenone-4) and its sulphonate form (benzophenone-5), marketed by the company BASF under the name UVINUL MS40;
    • 2,2′-dihydroxy-4,4′-dimethoxybenzophenone (benzophenone-6);
    • 5-chloro-2-hydroxybenzophenone (benzophenone-7);
    • 2,2′-dihydroxy-4-methoxybenzophenone (benzophenone-8);
    • the disodium salt of 2,2′-dihydroxy-4,4′-dimethoxybenzophenone-5,5′-disulphonic diacid (benzophenone-9);
    • 2-hydroxy-4-methoxy-4′-methylbenzophenone (benzophenone-10);
    • benzophenone-11;
    • 2-hydroxy-4-(octyloxy)benzophenone (benzophenone-12);
    • (4) silane derivatives and polyorganosiloxanes comprising at least one benzophenone group;
    • (5) anthranilates, for example, menthyl anthranilate marketed by the company Haarman & Reimer under the name NEO HELIOPAN MA;
    • (6) compounds comprising, per molecule, at least two benzoazolyl groups or at least one benzodiazolyl group, for example, 1,4-bis-benzimidazolyl-phenylene-3,3′,5,5′-tetrasulphonic acid, and its salts, marketed by the company Haarman & Reimer;
    • (7) silicon-containing derivatives of N-substituted benzimidazolyl-benzazoles and of benzofuranyl-benzazoles, for example:
    • 2-[1-[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]disiloxanyl]propyl]-1H-benzimidazol-2-yl]benzoxazole;
    • 2-[1-[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]disiloxanyl]propyl]-1H-benzimidazol-2-yl]benzothiazole;
    • 2-[1-(3-trimethylsilanylpropyl)-1H-benzimidazol-2-yl]benzoxazole;
    • 6-methoxy-1,1′-bis(3-trimethylsilanylpropyl)-1H,1′H-[2,2′]dibenzimidazolylbenzoxazole;
    • 2-[1-(3-trimethylsilanylpropyl)-1H-benzimidazol-2-yl]benzothiazole;
      which are described in Patent Application No. EP-A-1 028 120; and
    • (8) triazine derivatives, for example, 2,4-bis{[4-(2-ethylhexyloxy)-2-hydroxy]phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine marketed by the company Ciba Geigy under the name TINOSORB S, and 2,2′-methylenebis-[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol] marketed by the company Ciba Geigy under the name TINOSORB M.
  • It is also possible to use a mixture of several of these screening agents, e.g., a mixture of UVB-screening agents, and UVA-screening agents, and at least one of the physical screening agents.
  • The physical screening agents may, for example, be chosen from at least one of titanium oxide (amorphous and crystalline titanium dioxide in rutile and anatase forms), zinc oxide, iron oxide, zirconium oxide, and cerium oxide. These metal oxides may, for example, be in the form of particles having a micrometric or nanometric size (nanopigments). In the form of nanopigments, the average sizes of the particles can range, for example, from 5 to 100 nm. Such an average particle size can readily be determined by one of ordinary skill in the art using the known techniques.
  • These pigments may, for example, be treated so as to make their surface hydrophobic. The treatment may be carried out according to methods known to persons skilled in the art. The pigments may, for example, be coated with silicone compounds such as PDMS and/or with polymers.
  • Of course, persons skilled in the art will be careful to choose the possible adjuvant(s) added to the compositions disclosed herein such that the advantageous properties intrinsically attached to the compositions disclosed herein are not, or not substantially, impaired by the addition envisaged.
  • The embodiments disclosed herein are illustrated in greater detail in the following examples.
  • EXAMPLE 1
  • A foundation was prepared in the form of a water-in-oil emulsion having the following composition:
    Fatty phase:
    isostearyl palmitate   6 g
    cyclopentasiloxane   30 g
    cetyl dimethicone copolyol  2.7 g
    (Abil ® EM 90 from the company GOLDSCHMIDT)
    polyglyceryl-4 isostearate  0.9 g
    iron oxides coated with disodium salt of   2 g
    stearoyl glutamate
    titanium oxide coated with disodium salt of   9 g
    stearoyl glutamate
    nylon powder   5 g
    hectorite  0.5 g
    hydrophobic pyrogenic silica (Aerosil R 972) 0.35 g
    hollow microspheres (Expancel) 0.35 g
    Aqueous phase:
    butylene glycol   5 g
    magnesium sulphate   1 g
    PEG 20  1.7 g
    preservatives qs
    water qs  100 g
  • The emulsion was prepared at room temperature, on the one hand, by mixing the pigments in part of the cyclopentasiloxane, on the other hand, by mixing the other oils with the surfactants and dispersing the hectorite therein, and then the mixture of pigments and fillers was added to the other mixed constituents of the fatty phase. The mixture of the constituents of the aqueous phase was then prepared and poured into the mixture of the fatty phase, with stirring, according to known means in order to finally obtain the emulsion.
  • This foundation was stable after storing at room temperature (25° C.) for 4 months, or even up to 8 months. It was easy to apply to the skin with a good sensation to the touch, dried rapidly after application, and the make-up obtained exhibited good colour homogeneity.
  • EXAMPLE 2
  • A foundation was prepared in the form of a water-in-oil emulsion having the following composition:
    Fatty phase:
    cyclohexasiloxane 33 g
    cetyl dimethicone copolyol  4 g
    (Abil ® EM 90 from the company GOLDSCHMIDT)
    iron oxides coated with disodium salt of  2 g
    stearoyl glutamate
    titanium oxide coated with disodium salt of  7 g
    stearoyl glutamate
    hectorite 0.7 g 
    silica (Aerosil R 972) 0.6 g 
    Aqueous phase:
    glycerol  3 g
    sodium chloride 0.5 g 
    preservatives qs
    water qs 100 g 
  • The emulsion was prepared according to the same procedure described in Example 1.
  • This foundation was stable after storing at room temperature (25° C.) for 4 months, or even up to 8 months. It was easy to apply to the skin with a good sensation to the touch, dried rapidly during application, and the make-up obtained exhibited good colour homogeneity without leaving traces.

Claims (55)

1. A foundation composition in the form of a water-in-oil emulsion comprising
a fatty phase;
an aqueous phase;
at least one silicone surfactant chosen from C8-C22 alkyl dimethicone copolyols;
at least 5% by weight, relative to the total weight of the composition, of hydrophobic coated pigments;
provided that the composition is free of polyglyceryl-4 isostearate or comprises polyglyceryl-4 isostearate in a quantity such that the weight ratio of the C8-C22 alkyl dimethicone copolyol to the polyglyceryl-4 isostearate is greater than or equal to 2:1.
2. The foundation composition according to claim 1, wherein the C8-C22 alkyl dimethicone copolyols are chosen from compounds of the following formula (I):
Figure US20050031560A9-20050210-C00002
wherein:
PE is chosen from groups of (—C2H4O)x—(C3H6O)y—R, wherein
R is chosen from a hydrogen atom and alkyl radicals comprising from 1 to 4 carbon atoms,
x ranges from 0 to 100, and
y ranges from 0 to 80, provided that the x and the y are not simultaneously 0;
m ranges from 1 to 40;
n ranges from 10 to 200;
o ranges from 1 to 100;
p ranges from 7 to 21; and
q ranges from 0 to 4.
3. The foundation composition according to claim 2, wherein
R=H;
m=1 to 10;
n=10 to 100;
o=1 to 30;
p=15; and
q=3.
4. The foundation composition according to claim 1, wherein the C8-C22 alkyl dimethicone copolyols are chosen from cetyl dimethicone copolyols.
5. The foundation composition according to claim 1, wherein the at least one silicone surfactant chosen from C8-C22 alkyl dimethicone copolyols is present in an amount ranging from 2% to 10% by weight, relative to the total weight of the composition.
6. The foundation composition according to claim 1, wherein the at least one silicone surfactant chosen from C8-C22 alkyl dimethicone copolyols is present in an amount ranging from 2.5% to 5% by weight, relative to the total weight of the composition.
7. The foundation composition according to claim 1, wherein the polyglyceryl-4 isostearate is present in an amount such that the weight ratio of the C8-C22 alkyl dimethicone copolyol to the polyglyceryl-4 isostearate is greater than or equal to 3:1.
8. The foundation composition according to claim 1, wherein the hydrophobic coated pigments are chosen from pigments treated with at least one hydrophobic agent.
9. The foundation composition according to claim 8, wherein the pigments are chosen from at least one of metal oxides, manganese violet, ultramarine blue, Prussian blue, ferric blue, bismuth oxychloride, pearl, mica coated with titanium dioxide, mica coated with bismuth oxychloride, and coloured pearlescent pigments.
10. The foundation composition according to claim 9, wherein the pigments are chosen from at least one of iron oxides and titanium dioxides.
11. The foundation composition according to claim 8, wherein the at least one hydrophobic agent is chosen from silicones, fatty acids, metal soaps, perfluoroalkyl phosphates, perfluoroalkylsilanes, perfluoroalkylsilazanes, polyhexafluoropropylene oxides, polyorganosiloxanes comprising at least one perfluoroalkyl perfluoropolyether group, amino acids, N-acylated amino acids and salts thereof, lecithin, and isopropyl triisostearyl titanate.
12. The foundation composition according to claim 11, wherein the N-acylated amino acids comprise at least one acyl group comprising from 8 to 22 carbon atoms.
13. The foundation composition according to claim 1, wherein the hydrophobic coated pigments are present in an amount ranging from 5% to 20% by weight, relative to the total weight of the composition.
14. The foundation composition according to claim 13, wherein the hydrophobic coated pigments are present in an amount at least equal to 8% by weight, relative to the total weight of the composition.
15. The foundation composition according to claim 14, wherein the hydrophobic coated pigments are present in an amount ranging from 8% to 15% by weight, relative to the total weight of the composition.
16. The foundation composition according to claim 1, further comprising at least one oil.
17. The foundation composition according to claim 16, wherein the at least one oil is chosen from carbonaceous oils, hydrocarbonaceous oils, and silicone oils.
18. The foundation composition according to claim 16, wherein the at least one oil is chosen from volatile oils.
19. The foundation composition according to claim 17, wherein the at least one oil is chosen from silicone oils.
20. The foundation composition according to claim 19, wherein the silicone oils are chosen from at least one of polydimethylsiloxanes, phenylated silicone oils, and polysiloxanes modified with at least one entity chosen from fatty acids, fatty alcohols, and polyoxyalkylenes.
21. The foundation composition according to claim 19, wherein the silicone oils are chosen from volatile silicone oils.
22. The foundation composition according to claim 21, wherein the volatile silicone oils are chosen from at least one of octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, hexadecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, and heptamethyloctyltrisiloxane.
23. The foundation composition according to claim 17, wherein the at least one oil is chosen from hydrocarbonaceous oils.
24. The foundation composition according to claim 23, wherein the hydrocarbonaceous oils are chosen from at least one of paraffin oils, liquid paraffin oils, vison oil, turtle oil, soya bean oil, perhydrosqualene, sweet almond oil, calophyllum oil, palm oil, grapeseed oil, sesame oil, maize oil, arara oil, rapeseed oil, sunflower oil, cottonseed oil, apricot oil, castor oil, avocado oil, jojoba oil, olive oil, cereal germ oil; esters of lanolic acid, oleic acid, lauric acid, stearic acid; isopropyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, diisopropyl adipate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-hexyldecyl laurate, 2-octyldecyl palmitate, 2-octyidodecyl myristate, 2-octyldodecyl lactate, 2-diethylhexyl succinate, diisostearyl malate, glycerine triisostearate, diglycerine triisostearate; myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid; cetanol, stearyl alcohol, oleyl alcohol, linoleyl alcohol, linolenyl alcohol, isostearyl alcohol, and octyldodecanol.
25. The foundation composition according to claim 23, wherein the hydrocarbonaceous oils are chosen from volatile hydrocarbonaceous oils.
26. The foundation composition according to claim 25, wherein the volatile hydrocarbonaceous oils are chosen from at least one of C8-C16 isoparaffins and heptane.
27. The foundation composition according to claim 26, wherein the C8-C16 isoparaffins are chosen from isooctane, isododecane, isodecane, and isohexadecane.
28. The foundation composition according to claim 16, wherein the at least one oil is present in an amount ranging from 20% to 45% by weight, relative to the total weight of the composition.
29. The foundation composition according to claim 28, wherein the at least one oil is present in an amount ranging from 30% to 38% by weight, relative to the total weight of the composition.
30. The foundation composition according to claim 18, wherein the at least one oil chosen from volatile oils is present in an amount ranging from 20% to 45% by weight, relative to the total weight of the composition.
31. The foundation composition according to claim 30, wherein the at least one oil chosen from volatile oils is present in an amount ranging from 25% to 40% by weight, relative to the total weight of the composition.
32. The foundation composition according to claim 31, where in the at least one oil chosen from volatile oils is present in an amount ranging from 30% to 40% by weight, relative to the total weight of the composition.
33. The foundation composition according to claim 1, wherein the fatty phase further comprises at least one fatty substance chosen from waxes, gums, and pasty fatty substances.
34. The foundation composition according to claim 1, further comprising at least one fatty phase thickening agent.
35. The foundation composition according to claim 34, wherein the at least one fatty phase thickening agent is chosen from organomodified clays and hydrophobic pyrogenic silicas.
36. The foundation composition according to claim 34, wherein the at least one fatty phase thickening agent is present in an amount ranging from 0.1% to 5% by weight, relative to the total weight of the composition.
37. The foundation composition according to claim 36, wherein the at least one fatty phase thickening agent is present in an amount ranging from 0.4% to 3% by weight, relative to the total weight of the compostion.
38. The foundation composition according to claim 1, wherein the fatty phase is present in an amount ranging from 22% to 50% by weight, relative to the total weight of the composition.
39. The foundation composition according to claim 38, wherein the fatty phase is present in an amount ranging from 25% to 45% by weight, relative to the total weight of the composition.
40. The foundation composition according to claim 39, wherein the fatty phase is present in an amount ranging from 30% to 40% by weight, relative to the total weight of the composition.
41. The foundation composition according to claim 1, wherein the aqueous phase is present in an amount ranging from 30% to 75% by weight, relative to the total weight of the composition.
42. The foundation composition according to claim 41, wherein the aqueous phase is present in an amount ranging from 35% to 50% to by weight, relative to the total weight of the composition.
43. The foundation composition according to claim 1, wherein the aqueous phase comprises at least one solvent chosen from primary alcohols, glycols, and glycol ethers.
44. The foundation composition according to claim 1, wherein the aqueous phase comprises at least one stabilizing agent.
45. The foundation composition according to claim 1, further comprising at least one filler.
46. The foundation composition according to claim 45, wherein the at least one filler is chosen from talc, mica, silica, kaolin, starch, boron nitride, calcium carbonate, magnesium carbonate, magnesium hydrocarbonate, microcrystalline cellulose, polyethylene powders, polyesters, polyamides, polytetrafluoroethylene, and silicone powders.
47. The foundation composition according to claim 45, wherein the at least one filler is present in an amount ranging from 0.1% to 15% by weight, relative to the total weight of the composition.
48. The foundation composition according to claim 47, wherein the at least one filler is present in an amount ranging from 0.1% to 10% by weight, relative to the total weight of the composition.
49. The foundation composition according to claim 1, further comprising at least one additive chosen from gelling agents; hydrophilic and lipophilic thickening agents; moisturizing agents; emollients; hydrophilic and lipophilic active agents; anti-free radical agents; sequestrants; antioxidants; preservatives; basifying and acidifying agents; perfumes; film-forming agents; and soluble colorants.
50. The foundation composition according to claim 1, wherein the composition has a viscosity, measured at 25° C., at a shear rate of 200 revolutions per minute, ranging from 0.5 to 3.2 Pa.s.
51. The foundation composition according to claim 50, wherein the composition has a viscosity, measured at 25° C., at a shear rate of 200 revolutions per minute, ranging from 0.6 to 1.5 Pa.s.
52. A process for non-therapeutic application of make-up to skin comprising applying to the skin a foundation composition in the form of a water-in-oil emulsion comprising:
a fatty phase;
an aqueous phase;
at least one silicone surfactant chosen from C8-C22 alkyl dimethicone copolyols;
at least 5% by weight, relative to the total weight of the composition, of hydrophobic coated pigments,
provided that the composition is free of polyglyceryl-4 isostearate or comprises polyglyceryl-4 isostearate in a quantity such that the weight ratio of the C8-C22 alkyl dimethicone copolyol to the polyglyceryl-4 isostearate is greater than or equal to 2:1.
53. A process for making a foundation composition, comprising including at least one silicone surfactant chosen from C8-C22 alkyl dimethicone copolyols in the composition in the form of a water-in-oil emulsion comprising at least 5% by weight, relative to the total weight of the composition, of hydrophobic coated pigments,
provided that the composition is free of polyglyceryl-4 isostearate or comprises polyglyceryl-4 isostearate in a quantity such that the weight ratio of the C8-C22 alkyl dimethicone copolyol to the polyglyceryl-4 isostearate is greater than or equal to 2:1; wherein the composition has at least one of properties of being stable, homogeneous, and easily applied to the skin.
54. A process for obtaining a homogeneous application of make-up to skin, comprising including at least one silicone surfactant chosen from C8-C22 alkyl dimethicone copolyols in the composition in the form of a water-in-oil emulsion comprising at least 5% by weight, relative to the total weight of the composition, of hydrophobic coated pigments,
provided that the composition is free of polyglyceryl-4 isostearate or comprises polyglyceryl-4 isostearate in a quantity such that the weight ratio of the C8-C22 alkyl dimethicone copolyol to the polyglyceryl-4 isostearate is greater than or equal to 2:1; wherein the composition is homogeneous.
55. A foundation composition in the form of an oil-in-water emulsion, comprising:
at least one silicone surfactant chosen from C8-C22 alkyl dimethicone copolyols;
at least 5% by weight, relative to the total weight of the composition, of hydrophobic coated pigments, provided that the composition is free of polyglyceryl-4 isostearate or comprises polyglyceryl-4 isostearate in a quantity such that the weight ratio of the C8-C22 alkyl dimethicone copolyol to the polyglyceryl-4 isostearate is greater than or equal to 2:1;
wherein the composition has at least one of properties of being stable, homogeneous, and easily applied to the skin.
US10/426,630 2002-05-02 2003-05-01 Water-in-oil emulsion foundation Active 2025-02-28 US7858104B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US10/426,630 US7858104B2 (en) 2002-05-02 2003-05-01 Water-in-oil emulsion foundation

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR0205512A FR2839259B1 (en) 2002-05-02 2002-05-02 FOUNDATION EMULSION WATER-IN-OIL
FR0205512 2002-05-02
US39311502P 2002-07-03 2002-07-03
US10/426,630 US7858104B2 (en) 2002-05-02 2003-05-01 Water-in-oil emulsion foundation

Publications (3)

Publication Number Publication Date
US20040009131A1 US20040009131A1 (en) 2004-01-15
US20050031560A9 true US20050031560A9 (en) 2005-02-10
US7858104B2 US7858104B2 (en) 2010-12-28

Family

ID=30118800

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/426,630 Active 2025-02-28 US7858104B2 (en) 2002-05-02 2003-05-01 Water-in-oil emulsion foundation

Country Status (1)

Country Link
US (1) US7858104B2 (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080003195A1 (en) * 2006-05-31 2008-01-03 Pascal Arnaud Cosmetic composition comprising at least one vinyl polymer and at least one olefin copolymer
US20090048212A1 (en) * 2006-01-03 2009-02-19 Frederic Auguste Cosmetic composition comprising an oil
US20090130152A1 (en) * 2006-01-03 2009-05-21 Frederic Auguste Cosmetic composition comprising an oil
US20090264541A1 (en) * 2006-01-03 2009-10-22 Frederic Auguste Cosmetic composition comprising an oil
US20090299025A1 (en) * 2008-05-27 2009-12-03 O'lenick Kevin Anthony Multi alkoxylated silicone surfactants
US20110020258A1 (en) * 2007-12-20 2011-01-27 Raluca Lorant Water-in-oil (w/o) emulsion stabilized with a lipophilic emulsifier and a hydrophobically modified polysaccharide
US8580285B2 (en) 2011-06-09 2013-11-12 Momentive Performance Materials Inc. Clarifying agents for organomodified silicones
KR20170081221A (en) * 2014-12-03 2017-07-11 로레알 Compositions comprising an autoassociative polyurethane, a fatty alcohol or acid, a nonionic surfactant, and a pigment
US20180245020A1 (en) * 2013-08-13 2018-08-30 Dow Silicones Corporation Method of forming an antifoam granule
US20220133609A1 (en) * 2020-10-29 2022-05-05 L'oreal Makeup composition
US11453598B2 (en) 2009-08-31 2022-09-27 Colgate-Palmolive Company Surface modified pigment

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2787027B1 (en) * 1998-12-14 2001-01-12 Oreal NANOEMULSION BASED ON SUGAR FATTY ESTERS OR SUGAR FATHER ETHERS AND ITS USE IN THE COSMETIC, DERMATOLOGICAL AND / OR OPHTHALMOLOGICAL FIELDS
FR2855043B1 (en) * 2003-05-22 2006-08-11 Oreal MAKE-UP COMPOSITION FOR THE SKIN, AND MORE PARTICULARLY A FLUID FOUNDATION-TYPE COMPOSITION, WITH OPTIMIZED APPLICATION QUALITIES
US8974590B2 (en) 2003-12-18 2015-03-10 The Armor All/Stp Products Company Treatments and kits for creating renewable surface protective coatings
US8034173B2 (en) * 2003-12-18 2011-10-11 Evonik Degussa Gmbh Processing compositions and method of forming the same
US7828889B2 (en) * 2003-12-18 2010-11-09 The Clorox Company Treatments and kits for creating transparent renewable surface protective coatings
US20080038360A1 (en) * 2006-08-11 2008-02-14 Joseph Michael Zukowski Personal care composition
KR100981353B1 (en) 2008-04-30 2010-09-10 (주)아모레퍼시픽 Makeup cosmetic composition of W/O emulsion with inner dispersing pigments
CN101584647B (en) * 2008-05-20 2012-10-31 赢创德固赛特种化学(上海)有限公司 Polylol-in-oil composition with high vitamin C content and preparation method thereof
CN101904802B (en) * 2009-06-03 2015-03-11 赢创德固赛有限公司 Water-in-oil emulsion system and preparation method thereof
FR2949954B1 (en) * 2009-09-11 2012-10-05 Oreal COSMETIC SET OF MAKE-UP AND / OR CARE OF KERATINIC MATERIAL.
BR112012012335B1 (en) 2009-11-24 2020-01-07 Momentive Performance Materials Gmbh POLYSILOXAN COMPOUNDS, PROCESS FOR THE PRODUCTION OF POLYSILOXAN COMPOUNDS, USE OF POLYSILOXAN POLYMERS, AND A / O EMULSIONS
FR2954104B1 (en) * 2009-12-18 2012-03-09 Oreal W / O EMULSION COMPRISING EMULSIFYING SILICONE ELASTOMER AND VOLATILE LINEAR ALKANE
US10947347B2 (en) 2014-10-10 2021-03-16 Momentive Performance Materials Gmbh Hyrophilic ethylene oxide free emulsifier comprising dendrimeric polyhydroxylated ester moieties
WO2017007143A1 (en) * 2015-07-09 2017-01-12 (주)케이피티 Cosmetic product combining bead-type liquid foundation cosmetic composition and cosmetic container having mesh
US9988404B2 (en) 2016-04-07 2018-06-05 Momentive Performance Materials Inc. Ester-modified organosilicon-based surfactants, methods of making same and applications containing the same
JP6984557B2 (en) * 2018-07-18 2021-12-22 トヨタ自動車株式会社 Seat belt controller
WO2022005894A1 (en) * 2020-06-30 2022-01-06 L'oreal Water in oil emulsion for improving the appearance of the skin
JP2024508898A (en) * 2021-04-30 2024-02-28 ロレアル Solid anhydrous composition for caring for and/or making up keratin materials
CN114656943B (en) * 2022-02-24 2023-04-11 西南石油大学 Leak-proof leak-stopping water-based drilling fluid composition and preparation method and application thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5879668A (en) * 1997-02-03 1999-03-09 L'oreal Transfer-resistant make-up compositions and process of making
US5942213A (en) * 1992-01-27 1999-08-24 L'oreal Water-in-oil emulsion stable in the course of time, with silicone content
US5976510A (en) * 1996-10-17 1999-11-02 Lancaster Group Gmbh Cosmetic tanning and sunscreen agent
US6638519B1 (en) * 1999-11-08 2003-10-28 L'oreal Composition for topical application comprising a sugar and its cosmetic uses
US20030228339A1 (en) * 2002-03-28 2003-12-11 The Procter & Gamble Company Emulsion compositions
US20050008592A1 (en) * 2002-06-26 2005-01-13 Nadia Gardel Water-in-oil emulsion foundation

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2776183B1 (en) 1998-03-17 2004-05-28 Oreal USE OF A SILKONE SURFACTANT OF THE ALKYLDIMETHICONE COPOLYOL TYPE FOR THE PREPARATION OF SOLID WATER-IN-OIL COSMETIC EMULSIONS AND SOLID WATER-IN-OIL EMULSIONS THUS OBTAINED
DE19945283A1 (en) 1999-09-22 2001-03-29 Beiersdorf Ag Water-in-oil type emulsions containing one or more silicone oils and one or more cationic polymers

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5942213A (en) * 1992-01-27 1999-08-24 L'oreal Water-in-oil emulsion stable in the course of time, with silicone content
US5976510A (en) * 1996-10-17 1999-11-02 Lancaster Group Gmbh Cosmetic tanning and sunscreen agent
US5879668A (en) * 1997-02-03 1999-03-09 L'oreal Transfer-resistant make-up compositions and process of making
US6638519B1 (en) * 1999-11-08 2003-10-28 L'oreal Composition for topical application comprising a sugar and its cosmetic uses
US20030228339A1 (en) * 2002-03-28 2003-12-11 The Procter & Gamble Company Emulsion compositions
US20050008592A1 (en) * 2002-06-26 2005-01-13 Nadia Gardel Water-in-oil emulsion foundation

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090048212A1 (en) * 2006-01-03 2009-02-19 Frederic Auguste Cosmetic composition comprising an oil
US20090130152A1 (en) * 2006-01-03 2009-05-21 Frederic Auguste Cosmetic composition comprising an oil
US20090264541A1 (en) * 2006-01-03 2009-10-22 Frederic Auguste Cosmetic composition comprising an oil
US20080003195A1 (en) * 2006-05-31 2008-01-03 Pascal Arnaud Cosmetic composition comprising at least one vinyl polymer and at least one olefin copolymer
US8828372B2 (en) * 2006-05-31 2014-09-09 L'oreal Cosmetic composition comprising at least one vinyl polymer and at least one olefin copolymer
US8758736B2 (en) * 2007-12-20 2014-06-24 L'oreal Water-in-oil (W/O) emulsion stabilized with a lipophilic emulsifier and a hydrophobically modified polysaccharide
US20110020258A1 (en) * 2007-12-20 2011-01-27 Raluca Lorant Water-in-oil (w/o) emulsion stabilized with a lipophilic emulsifier and a hydrophobically modified polysaccharide
US20090299025A1 (en) * 2008-05-27 2009-12-03 O'lenick Kevin Anthony Multi alkoxylated silicone surfactants
US7718750B2 (en) * 2008-05-27 2010-05-18 Siltech Llc Multi alkoxylated silicone surfactants
US11453598B2 (en) 2009-08-31 2022-09-27 Colgate-Palmolive Company Surface modified pigment
US8580285B2 (en) 2011-06-09 2013-11-12 Momentive Performance Materials Inc. Clarifying agents for organomodified silicones
US20180245020A1 (en) * 2013-08-13 2018-08-30 Dow Silicones Corporation Method of forming an antifoam granule
US10689601B2 (en) * 2013-08-13 2020-06-23 Dow Silicones Corporation Method of forming an antifoam granule containing a silicone polyether
KR20170081221A (en) * 2014-12-03 2017-07-11 로레알 Compositions comprising an autoassociative polyurethane, a fatty alcohol or acid, a nonionic surfactant, and a pigment
KR102072517B1 (en) 2014-12-03 2020-02-03 로레알 Compositions comprising an autoassociative polyurethane, a fatty alcohol or acid, a nonionic surfactant, and a pigment
US20220133609A1 (en) * 2020-10-29 2022-05-05 L'oreal Makeup composition
US11766389B2 (en) * 2020-10-29 2023-09-26 L'oreal Makeup composition

Also Published As

Publication number Publication date
US20040009131A1 (en) 2004-01-15
US7858104B2 (en) 2010-12-28

Similar Documents

Publication Publication Date Title
US7858104B2 (en) Water-in-oil emulsion foundation
US7776348B2 (en) Water-in-oil emulsion foundation
JP4373141B2 (en) Water-in-oil emulsion foundation
US8529918B2 (en) Water-in oil emulsion foundation comprising a polyol
US9675532B2 (en) Fluid cosmetic composition comprising a monoalcohol
US7022346B2 (en) Spherical powder components and solid cosmetic compositions comprising thereof
AU2003212430B2 (en) Cosmetic composition comprising double coated pigment
US20190374446A1 (en) Water-in-oil emulsion comprising a particular emulsifying system, a lipophilic clay, and an organopolysiloxane elastomer powder coated with a silicone resin
JP3950078B2 (en) Water-in-oil emulsion foundation
FR2841464A1 (en) Cosmetic foundation e.g. water-in-oil emulsion comprises alkyl dimethicone copolyol, dimethicone copolyol, hydrophobic coated pigments and volatile oils
KR102357676B1 (en) Water-in-oil emulsion containing baicalin, xanthine base, vitamin B3, and polyvalent metal cation salts
FR2846229A1 (en) Fluid cosmetic composition in the form of a water-in-oil emulsion based on a volatile hydrocarbon oil includes a pigment coated with an N-alkanoyl sarcosine or sarcosinate

Legal Events

Date Code Title Description
AS Assignment

Owner name: L'OREAL S.A., FRANCE

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:SIMONNET, JEAN-THIERRY;VERLOO, AURORE;OZEE, EMMANUELLE;REEL/FRAME:014524/0431;SIGNING DATES FROM 20030520 TO 20030523

Owner name: L'OREAL S.A., FRANCE

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:SIMONNET, JEAN-THIERRY;VERLOO, AURORE;OZEE, EMMANUELLE;SIGNING DATES FROM 20030520 TO 20030523;REEL/FRAME:014524/0431

FEPP Fee payment procedure

Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

STCF Information on status: patent grant

Free format text: PATENTED CASE

FPAY Fee payment

Year of fee payment: 4

MAFP Maintenance fee payment

Free format text: PAYMENT OF MAINTENANCE FEE, 8TH YEAR, LARGE ENTITY (ORIGINAL EVENT CODE: M1552)

Year of fee payment: 8

MAFP Maintenance fee payment

Free format text: PAYMENT OF MAINTENANCE FEE, 12TH YEAR, LARGE ENTITY (ORIGINAL EVENT CODE: M1553); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

Year of fee payment: 12