CN1558747A - 包含阳离子聚合物和颗粒的洗发剂 - Google Patents
包含阳离子聚合物和颗粒的洗发剂 Download PDFInfo
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- CN1558747A CN1558747A CNA028187938A CN02818793A CN1558747A CN 1558747 A CN1558747 A CN 1558747A CN A028187938 A CNA028187938 A CN A028187938A CN 02818793 A CN02818793 A CN 02818793A CN 1558747 A CN1558747 A CN 1558747A
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- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
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- 239000000230 xanthan gum Substances 0.000 description 1
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- 229910052727 yttrium Inorganic materials 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- VNTDZUDTQCZFKN-UHFFFAOYSA-L zinc 2,2-dimethyloctanoate Chemical compound [Zn++].CCCCCCC(C)(C)C([O-])=O.CCCCCCC(C)(C)C([O-])=O VNTDZUDTQCZFKN-UHFFFAOYSA-L 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
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Abstract
本发明的组合物涉及改善的洗发剂组合物,其具有约5至约50重量百分比的去污表面活性剂,至少约0.1重量百分比的颗粒,所述颗粒的平均粒径小于约300微米,至少约0.05重量百分比的阳离子聚合物,所述聚合物具有约10,000至约10,000,000的分子量和约0.9meq/gm至约7.0meq/gm的电荷密度,和至少约20.0重量百分比的含水载体。
Description
发明领域
本发明涉及包含颗粒的毛发清洁洗发剂。更具体地讲,本发明涉及包含阳离子聚合物和颗粒的洗发剂。
发明背景
固体颗粒已知作为有益剂用于各种制剂和个人护理组合物。固体颗粒能赋予包括它们的组合物和组合物涂敷的表面以有益效果。固体颗粒可作为例如颜料或着色剂、遮光剂、珠光剂、感觉改性剂、油吸收剂、皮肤保护剂、消光剂、摩擦增强剂、增滑剂、调理剂、剥脱剂、气味吸收剂或清洁增强剂而使用。此外,许多有益于作为各种紊乱或社交场合的难堪情形的处理剂的活性成分是可获得的,并典型地以固体颗粒形式使用,这些形式包括止汗剂、去头屑剂、抗微生物剂、抗生素和防晒剂。
典型地,当期望通过应用颗粒来改变表面的性质时,该颗粒通过免洗型制剂而施用,其被擦、喷或直接施用于欲影响的表面。典型的适用于将固体颗粒递送到毛发或皮肤表面的个人护理制剂包括例如湿润剂、乳液、霜膏、松散的或冲压的粉末、棒状物、滋补剂、凝胶和各种喷雾器,如气溶胶或泵式喷雾器。这些产品典型地被直接涂敷于表面,在该表面上颗粒被组合物自身或组合物在蒸发和干燥后的残余非挥发性要素组分沉积和保留。
也已知配制固体颗粒有益剂进入漂洗或清洁组合物,如毛发漂洗剂、洗发剂、液体或棒肥皂、调理剂或着色剂。固体颗粒有益剂经常被用来影响组合物自身的总体外观、稳定性或美观性。例如,为了改善产品对潜在消费者的可接受性和吸引力,在组合物中加入着色剂颗粒、颜料或珠光剂是众所周知的。为了影响组合物在使用中的性能、外观或美观性质或为了提供给使用者以可触知的信号,加入颗粒有益剂也是众所周知的。例如,剥脱剂颗粒是经常用于清洁组合物中的,以改善摩擦及油和污物从被洗表面的去除并赋予使用者一种可感知到的“擦洗”感觉。典型地,这样的固体颗粒剂不打算或期望被沉积到基质上,并在组合物的稀释和漂洗过程中从它们被应用的表面去除。
尽管通过应用和保留固体颗粒于表面,广泛的有益效果可被递送,然而,具有能沉积有效量的固体颗粒于表面的洗去型组合物是高度期望的,所述表面用包含期望的固体颗粒有益剂的组合物处理。旨在将固体颗粒有益剂沉积到毛发或皮肤表面的组合物是已知的,然而,沉积效率迄今为止一直是不可接受的,其要么需要组合物中有过量的固体颗粒有益剂来影响递送,要么获得的有益效果的水平难以察觉或不可接受。固体颗粒有益剂从欲用于清洁或洗涤表面的组合物中的有效沉积和保留尤其困难,如洗发剂或其它个人护理清洁产品,其包含表面活性剂或其它用于溶解、悬浮和从被处理的表面去除颗粒和油状物质的成分。虽然如此,仍高度期望通过简单洗涤组合物的使用的固体颗粒有益剂的沉积而获得有益效果和方便性。
清洁组合物中包含阳离子聚合物以改善某些调理油如硅氧烷油的沉积是已知的,所述油能赋予在此被处理的表面以调理或滑动性质。然而,这些调理油被限制于它们提供的物理、光学和美学有益效果的范围内。此外,已知粘度、粒径和与调理油相关的其它因素可显著影响它们从清洁组合物中沉积的能力。也已知在包含阳离子聚合物的组合物中包括固体颗粒,然而,这些颗粒经常被加入以改变组合物自身的外观或稳定性,且不与调理油或阳离子聚合物一起沉积到在此被处理的表面上。当固体颗粒有益剂从洗涤组合物中沉积是预想时,迄今为止可获得的组合物具有低效率沉积的缺点,从而需要使用过量的颗粒剂或低效率的有益剂的递送。也已尝试对固体颗粒有益剂做具体的修改以改善它们的从漂洗组合物中沉积或保留的效率;然而,这一方法可消极地影响欲使用的固体颗粒有益剂的内在性质、可用性、效用和成本。
所以,高度期望具有漂洗组合物,优选清洁组合物,其能包含并有效沉积和保留固体颗粒有益剂于在此处理的表面。现已发现,当在本发明的清洁组合物中被使用时,精选的阳离子聚合物可令人惊讶地增强固体颗粒有益剂在被处理的表面的沉积和保留。
发明概述
本发明主要为洗发剂组合物,其中包含:
a)约5至约50重量百分比的去污表面活性剂,
b)至少约0.1重量百分比的颗粒,所述颗粒的平均粒径小于约300微米,
c)至少约0.05重量百分比的阳离子聚合物,所述阳离子聚合物具有约10,000至约10,000,000的分子量和约0.9meq/gm至约7.0meq/gm的电荷密度,和
d)至少约20.0重量百分比的含水载体;
其中所述颗粒选自中空颗粒、固体颗粒以及它们的组合。
本发明还主要涉及使用所述洗发剂组合物的方法。
对于本领域的技术人员来说,通过阅读本说明书的公开内容,本发明的这些和其它特征、方面和优点将变得显而易见。
发明详述
虽然本说明书通过特别指出并清楚地要求保护本发明的权利要求作出结论,但应该相信由下列说明可更好地理解本发明。
本发明洗发剂组合物包括去污表面活性剂、颗粒、阳离子聚合物和含水载体。这些基本组分的每一种,以及优选的或任选的组分,在本发明后面详细地描述。
除非另外指明,所有的百分比、份数和比率均以本发明的组合物的总重量计。所有重量如附属于所列成分是基于活性物质的含量,因此,除非另外指明,不包括可能包括在可商购获得的材料中的溶剂或副产物。
除非另外指明,所有如本发明使用的分子量都是重均分子量,以克/摩尔表示。
本发明使用的术语“电荷密度(charge density)”是指构成聚合物的单体单元上的正电荷数与所述单体单元的分子量的比率。电荷密度乘以聚合物分子量决定给定聚合物链的正电荷位点的数目。
本文中,“包括”是指可加入不影响最终结果的其它步骤和其它成分。该术语包括“由...组成”和“基本上由...组成”。本发明的组合物和方法可包括、由或基本上由基本成分和本发明所述的限制条件以及任何附加的或任选的成分、组分、步骤或所描述的限制条件组成。
本发明使用的术语“流体(fluid)”是指液体或气体,其易于以其容器的形状存在,容器即所述柔韧的中空颗粒的壁。
本发明使用的术语“柔韧的(flexible)”是指本发明的中空颗粒易于压缩,当压力下降时所述中空颗粒将重新获得它们的原始体积。
本发明使用的术语“包封的流体(fluid-encapsulated)”是指本发明的中空颗粒在结构上是中空的。虽然如此,依照本发明,术语“结构上的中空”也允许中空颗粒中包含至少一种附加材料。
本发明使用的术语“中空的(hollow)”是指具有包封的区域的颗粒,所述区域基本上不含固体物质,包封的区域占颗粒总体积的10%至99.8%。
本发明使用的术语“可渗透的(permeable)”是指在给定条件下允许液体或气体通过的物质。
本发明使用的术语“聚合物(polymer)”应当包括或者通过一种类型的单体或者通过两种类型的单体(即共聚物)或更多种类型的单体的聚合而制得的物质。
本发明使用的术语“固体颗粒(solid particle)”的含义是非液体或气体的颗粒。
本发明使用的术语“球体(sphere)”是指球状主体,其是在度量空间的点集,这些点到固定点的距离是近似恒定的。在此,“近似”是指所述固定点在±15%的距离以内。
本发明使用的术语“适于应用于人类毛发(suitable for application tohuman hair)”是指所述组合物或如此描述的其组分适于用于与人类毛发和头皮和皮肤接触而没有不适当的毒性、不相容性、不稳定性、变应性反应等。
本发明使用的术语“水溶性的(water soluble)”是指所述聚合物在本发明的组合物中的水中是溶解的。一般而言,所述聚合物在25℃下,具有按水溶剂重量计0.1%的浓度、优选1%的浓度、更优选5%的浓度、最优选15%的浓度溶解。
所有引用的参考文献均全文引入本文以供参考。任何文献的引用并不是对其作为要求保护的本发明的现有技术的可获得性的认可。
A.去污表面活性剂
本发明洗发剂组合物包括去污表面活性剂。去污表面活性剂被包括以为所述组合物提供清洁性能。所述去污表面活性剂包括阴离子去污表面活性剂、两性离子或两性去污表面活性剂或它们的组合。这样的表面活性剂应当在物理或化学上与本发明所描述的基本组分相容,或不应该不适当地损害产品的稳定性、美观性或性能。
用于本发明的洗发剂组合物的合适的阴离子去污表面活性剂组分包括已知用于毛发护理或其它个人护理的清洁组合物中的那些。所述洗发剂组合物中阴离子表面活性剂组分的浓度应该足以提供期望的清洁和起泡效果,通常为按组合物的重量计约5%至约50%、优选约8%至约30%、更优选约10%至约25%、甚至更优选约12%至约22%。
适用于本发明洗发剂组合物的优选的阴离子表面活性剂是烷基和烷基醚硫酸盐。这些物质具有各自的式ROSO3M和RO(C2H4O)xSO3M,其中R是具有约8至约18个碳原子的烷基或链烯基,x是具有1至10的值的整数,且M是阳离子,如铵、链烷醇胺,如三乙胺,一价的金属,如钠和钾,和多价金属阳离子,如镁和钙。表面活性剂的溶解度将取决于特定的阴离子去污表面活性剂和选定的阳离子。
在烷基和烷基醚硫酸盐中,优选R具有约8至约18个碳原子、更优选约10至约16个碳原子、甚至更优选约12至约14个碳原子。该烷基醚硫酸盐典型地可以作为环氧乙烷和具有约8至约24个碳原子的一元醇的缩合产物制备。醇可以是合成的,也可得自油脂,如椰子油、棕榈仁油、牛油。月桂醇和得自椰子油或棕榈仁油的直链醇是优选的。这样的醇与约0至约10、优选约2至约5、更优选约3摩尔比的环氧乙烷反应,并且所得分子种类的混合物具有例如平均每摩尔醇约3摩尔环氧乙烷被硫酸化并中和。
可用于本发明洗发剂组合物的烷基醚硫酸盐的具体的非限制性实施例包括椰油烷基三甘醇醚硫酸盐、牛油烷基三甘醇醚硫酸盐和牛油烷基六氧化乙烯硫酸盐的钠盐和铵盐。高度优选的烷基醚硫酸盐是包括单独化合物的混合物的那些,其中在所述混合物中的化合物具有约10至约16个碳原子的平均烷基链长和约1至约4摩尔环氧乙烷的平均乙氧基化度。
其它合适的阴离子去污表面活性剂是符合式[R1-SO3-M]的有机硫酸反应产物的水溶性盐,其中R1是具有约8至约24个碳原子,优选约10至约18个碳原子的直链的或支链的、饱和的、脂族烃基;且M是本发明前面所述的阳离子。这种去污表面活性剂的非限制性实施例是甲烷系列的烃,包括具有约8至约24个碳原子,优选约12至约18个碳原子的异-、新-和正-石蜡烃与磺化剂如SO3、H2SO4的有机硫酸反应产物的盐,所述产物是依照已知的磺化方法,包括漂白和水解获得的。优选的是碱金属和铵磺化的C10-C18正-石蜡烃。
其它合适的阴离子去污表面活性剂还可以是用羟乙磺酸酯化和用氢氧化钠中和的脂肪酸的反应产物,其中,例如,该脂肪酸得自椰子油或棕榈仁油;甲基氨基乙磺酸盐的脂肪酸酰胺的钠或钾盐,其中,例如,该脂肪酸得自椰子油或棕榈仁油。其它类似的阴离子表面活性剂描述于美国专利2,486,921、2,486,922和2,396,278中,其描述引入本发明以供参考。
适用于本发明洗发剂组合物的其它阴离子去污表面活性剂是琥珀酸盐,其实施例包括N-十八烷基磺基琥珀酸二钠、月桂基磺基琥珀酸二钠、月桂基磺基琥珀酸二铵、N-(1,2-二羧基乙基)-N-十八烷基磺基琥珀酸四钠、磺基琥珀酸钠的二戊基酯、磺基琥珀酸钠的二己基酯;和磺基琥珀酸钠的二辛基酯。
其它合适的阴离子去污表面活性剂包括具有约10至约24个碳原子的磺酸烯烃酯。在本发明的上下文中,术语“磺酸烯烃盐”是指可这样获得的化合物:用未配合的三氧化硫将α-烯烃磺化,随后在如此条件下中和酸性反应混合物,以使任何在反应中形成的砜被水解以得到相应的羟基-链烷磺酸盐。该三氧化硫可以是液体,也可以是气体,并且通常但不是必须地用惰性稀释剂稀释,例如在以液体形式使用时,用液体SO2、氯代烃等稀释,或者在以气体形式使用时,用空气、氮气、气体SO2等稀释。由其得到烯烃磺酸盐的α-烯烃是具有约10至约24个碳原子、优选约12至约16个碳原子的一-烯烃。优选地,它们是直链的烯烃。除了真实的链烯烃磺酸盐和一部分羟基-链烷磺酸盐,烯烃磺酸酯还可包含微量的其它物质,如链烯烃二磺酸盐,这取决于反应条件、反应物的比例、烯烃原料的性质和烯烃原料中的杂质以及磺化过程中的副反应。这样的α-烯烃磺酸盐混合物的非限制性实施例描述于美国专利3,332,880中,其引入本发明以供参考。
适用于洗发剂组合物中的另一类阴离子去污表面活性剂是β-烷氧基链烷磺酸盐。这些表面活性剂符合下式
其中R1是具有约6至约20个碳原子的直链烷基,R2是具有约1至约3个碳原子,优选1个碳原子的低级烷基,和M是如本发明前面所述的水溶性阳离子。
用于本发明洗发剂组合物的优选的阴离子去污表面活性剂包括十二烷基硫酸铵、月桂基聚氧乙烯醚硫酸铵、三乙基胺月桂基硫酸盐、三乙基胺月桂基聚氧乙烯醚硫酸盐、三乙醇胺十二烷基硫酸盐、三乙醇胺月桂基聚氧乙烯醚硫酸盐、单乙醇胺月桂基硫酸盐、单乙醇胺月桂基聚氧乙烯醚硫酸盐、二乙醇胺月桂基硫酸盐、二乙醇胺月桂基聚氧乙烯醚硫酸盐、月桂基甘油单酯硫酸钠、月桂基硫酸钠、月桂基聚氧乙烯醚硫酸钠、月桂基硫酸钾、月桂基聚氧乙烯醚硫酸钾、月桂基肌氨酸钠、月桂酰肌氨酸钠、月桂基肌氨酸、椰油基肌氨酸、椰油基硫酸铵、月桂酰基硫酸铵、椰油基硫酸钠、月桂酰基硫酸钠、椰油基硫酸钾、月桂基硫酸钾、三乙醇胺月桂基硫酸盐、三乙醇胺月桂基硫酸盐、一乙醇胺椰油基硫酸盐、一乙醇胺月桂基硫酸盐、十三烷基苯磺酸钠、十二烷基苯磺酸钠以及它们的组合。
适用于本发明洗发剂组合物的两性或两性离子去污表面活性剂包括已知的用于毛发护理或其它个人护理清洁的那些。这样的两性去污表面活性剂的浓度按组合物的重量计优选为约0.5%至约20%、优选为约1%至约10%。合适的两性离子或两性表面活性剂的非限制性实施例描述于美国专利5,104,646(Bolich Jr.等人)和5,106,609(Bolich Jr.等人)中,其描述引入本发明以供参考。
适用于洗发剂组合物中的两性去污表面活性剂在本领域内是为人所熟知的,并包括广泛地被描述为脂族仲和叔胺的衍生物的那些表面活性剂,其中脂族基团可以是直链或支链的,且其中一个脂族取代基包含约8至约18个碳原子,且一个脂族取代基包含阴离子水溶性基团,如羧基、磺酸根、硫酸根、磷酸根和膦酸根。用于本发明的优选的两性去污表面活性剂包括N-椰油酰胺基乙基-N-羟乙基乙酸盐(cocoamphoacetate)、N-椰油酰胺基乙基-N-羟乙基二乙酸盐(cocoamphodiacetate)、N-月桂酰胺基乙基-N-羟乙基乙酸盐、N-月桂酰胺基乙基-N-羟乙基二乙酸盐(lauroamphodiacetate)以及它们的混合物。
适用于本发明洗发剂组合物的两性离子去污表面活性剂在本领域是为人所熟知的,并包括广泛地被描述为脂族仲和叔胺的衍生物的那些表面活性剂,其中脂族基团可以是直链或支链的,和其中一个脂族取代基包含约8至约18个碳原子,且其中一个脂族取代基包含阴离子基团,如羧基、磺酸根、硫酸根、磷酸根和膦酸根。两性离子化合物如甜菜碱是优选的。
本发明洗发剂组合物可进一步包括附加的表面活性剂,以与本发明如上所述的阴离子去污表面活性剂组分组合。合适的任选表面活性剂包括非离子表面活性剂。任何本领域已知的用于毛发护理或个人护理产品的这样的表面活性剂可以被使用,条件是该任选的附加表面活性剂也是在化学或物理上与洗发剂组合物的基本组分相容,或不会不适当地损害产品的性能、美观性或稳定性。本发明洗发剂组合物中的任选的附加表面活性剂的浓度可依照期望的清洁或起泡性能、选定的任选表面活性剂、期望的产品浓度、组合物中其它组分的存在和本领域内熟知的其它因素而改变。
其它阴离子、两性离子、两性或任选的适用于该洗发剂组合物的附加表面活性剂的非限制性实施例描述于McCutcheon的“Emulsifiers andDetergents”,1989年鉴,M.C.Publishing Co.出版,和美国专利3,929,678、2,658,072、2,438,091、2,528,378中,其描述引入本发明以供参考。
B.颗粒
本发明的组合物包括颗粒。本发明的颗粒优选地具有低于300μm的粒径。更优选地,本发明的颗粒具有低于100μm的粒径。还更优选地,本发明的颗粒具有低于80μm的粒径。甚至更优选地,本发明的颗粒具有低于60μm的颗粒。
本发明的颗粒优选地具有大于0.01μm的粒径。更优选地,本发明的颗粒具有大于1μm的粒径。还更优选地,本发明的颗粒具有大于2μm的粒径。甚至更优选地,本发明的颗粒具有大于约3μm的粒径。还更优选地,本发明的颗粒具有大于约4μm的粒径。
优选地,颗粒具有的粒径为直径约0.01μm至约80μm、还更优选地约0.1μm至约70μm、甚至更优选地约1μm至约60μm。还更优选地,本发明的颗粒将具有约3μm至约80μm的粒径。
对于组合物的特殊目的,典型的颗粒含量被选定。例如,当期望获得递送颜色有益效果时,可掺入赋予期望色泽的颜料颗粒。当期望获得毛发体积或定型有益效果时,可使用能赋予摩擦的颗粒,以减少毛发定型的瓦解和塌陷。当期望调理和滑动时,可掺入合适的小板或球状颗粒。颗粒类型和含量的确定在本领域技术人员的技能之内。通常认为安全的,列于C.T.F.A.“化妆品成分手册”(Cosmetic Ingredient Handbook),第六版,C.T.F.A.,WashingtonD.C.(1995)中的颗粒可被使用,引入本发明以供参考。
在本发明的组合物中,优选地掺入按重量计至少0.025%的颗粒、更优选至少0.1%、还更优选至少0.2%、甚至更优选按重量计至少0.5%的颗粒。在本发明的组合物中,优选地掺入按重量计不多于约20%的颗粒、更优选不多于约10%、还更优选不多于5%、甚至更优选按重量计不多于2%的颗粒。
颗粒可以是有色的或无色的(例如白色)。合适的粉末包括氯氧化铋、钛酸化云母、热解法二氧化硅、球状二氧化硅、聚异丁烯酸甲酯、微粉化特氟伦、氮化硼、丙烯酸酯聚合物、硅酸铝、淀粉辛烯基琥珀酸铝、膨润土、硅酸钙、纤维素、白垩、玉米淀粉、硅藻土、漂白土、甘油基淀粉、锂蒙脱石、二氧化硅水合物、陶土、硅铝酸镁、碳酸镁、氢氧化镁、氧化镁、硅酸镁、三硅酸镁、麦芽糖糊精、蒙脱石、微晶纤维素、大米淀粉、二氧化硅、滑石、云母、二氧化钛、月桂酸锌、肉豆蔻酸锌、新癸酸锌、松香酸锌、硬脂酸锌、聚乙烯、矾土、绿坡缕石、碳酸钙、硅酸钙、右旋糖苷、陶土、尼龙、硅烷化二氧化硅、蚕丝粉末、绢云母、大豆粉、二氧化锡、氢氧化钛、磷酸三镁、胡桃壳粉末以及它们的混合物。如上所述的粉末可用卵磷脂、氨基酸、矿物油、硅氧烷油或各种其它试剂或单独或组合地表面处理,其涂层于粉末表面并使颗粒具有疏水性质。
粉末组分也可包括各种有机和无机颜料。有机颜料通常是各种芳族类型,包括偶氮、靛蓝类、三苯甲烷、蒽醌和黄嘌呤染料,其被指定为D & C和FD&C蓝、棕、绿、橙、红、黄等。有机颜料通常由被鉴定的颜色添加剂的不溶性金属盐组成,称为色淀。无机颜料包括氧化铁、群青颜料和铬或氢氧化铬颜料以及它们的混合物。
各种形状和密度的水不溶性固体颗粒是有用的。在优选的实施方案中,颗粒倾向于具有球状、椭圆、不规则的或任何其它形状,其中最大尺寸与最小尺寸的比率(定义为纵横比)低于10。更优选地,颗粒的纵横比低于8。还更优选地,颗粒的纵横比低于5。
在本发明中有用的颗粒在组合物中可以是无机的、合成的或半合成的。混合颗粒也是有用的。合成颗粒可由交联的或非交联的高分子制得。本发明的颗粒可具有表面电荷或它们的表面可用有机或无机材料如例如表面活性剂、聚合物和无机材料改性。颗粒复合物也是有用的。
有用的无机颗粒的实施例包括各种二氧化硅颗粒,其中包括胶态二氧化硅、热解法二氧化硅、沉淀二氧化硅和硅胶。胶态二氧化硅的非限制性实施例包括Snowtex C、Snowtex O、Snowtex 50、Snowtex OL、Snowtex ZL,得自Nissan Chemical America Corporation,和以商品名Ludox出售的得自W.R.Grace & Co的胶态二氧化硅。热解法二氧化硅的非限制性实施例包括亲水和疏水形式,以商品名Aerosil 130、Aerosil 200、Aerosil 300、Aerosil R972和Aerosil R812得自Degussa Corp.和以商品名Cab-O-Sil,包括Cab-O-Silm-5、HS-5、TS-530、TS-610和TS-720得自Cabot Corp.的那些。沉淀二氧化硅的非限制性实施例包括那些以亲水的和疏水的形式,以商品名Sipernat,包括Sipernat 350、360、22LS、22S、320、50S、D10、D11、D17和C630得自Degussa Corp.的那些;由W.R.Grace & Co.以商品名Syloid出售的那些,由J.M.Huber Corp.以商品名Zeothix和Zeodent出售的那些,和以商品名Tixosil得自Rhodia的那些。也有用于本发明的是各种粒径和多孔性的球状二氧化硅。球状二氧化硅颗粒的非限制性实施例包括MSS-500/H、MSS-500/3H、MSS-500、MSS-500/3、MSS-500/N和MSS-500/3N,得自KOBOProducts Inc.;以商品名Spheron,包括Spheron P-1500和L-1500得自Presperse Inc.的那些,和以商品名Sunsil,包括Sunsil 20、20L、20H、50L、50、50H、130L、130和130H得自Sunjin Chemical Co.的那些。有用于本发明的无机颗粒的其它非限制性实施例包括各种硅酸盐,如以商品名CM-111Cosmeticmicrospheres得自3M的那些,玻璃颗粒,如以商品名GlamurGloGlass Chips和PrizmaLite Glass Spheres得自Nippon Paint Corp.的那些;滑石、云母、绢云母和各种天然和合成粘土,包括膨润土、锂蒙脱石和蒙脱石。
合成颗粒的实施例包括尼龙、硅氧烷树脂、聚(甲基)丙烯酸酯、聚乙烯、聚酯、聚丙烯、聚苯乙烯、聚四氟乙烯、聚氨酯、聚酰胺、环氧树脂、尿素树脂和丙烯酸粉末。有用颗粒的非限制性实施例是Microease 110S、114S、116(微粉化合成蜡),Micropoly 210、250S(微粉化聚乙烯),Microslip(微粉化聚四氟乙烯),和Microsilk(聚乙烯和聚四氟乙烯的组合),所有这些都得自Micro Powder,Inc.。其它实施例包括MP-2200、BPA-500(聚异丁烯酸甲酯)、EA-209(乙烯/丙烯酸酯共聚物)、SP-501(尼龙-12)、SP-10(尼龙-12)、ES-830(聚异丁烯酸甲酯)、BPD-800、BPD-500、BPA-500(聚氨酯)和CL2080(聚乙烯)颗粒,得自Kobo Products,Inc.,聚乙烯粉末如那些得自QuantumChemical的,商品名Microthene,包括MN701、MN710、MN-714、MN-722和FN5100和得自Shamrock Technologies,Inc.的,商品名CeraPURE的那些,尼龙颗粒如那些得自ElfAtochem的,商品名Orgasol,丙烯酸酯共聚物得自Advanced Polymer Systems,商品名Microsponge和Polytrap,聚四氟乙烯粉末如那些得自Shamrock Technologies,Inc.的,商品名FluoroPURE和HydroPURE,和GE Silicones以商品名Tospearl出售的硅氧烷树脂颗粒,包括Tospearl 105、120、130、145、3120和240。Ganzpearl GS-0605交联聚苯乙烯(得自Presperse)也是有用的。
混合颗粒的非限制性实施例包括Ganzpearl GSC-30SR(绢云母和交联聚苯乙烯混合颗粒)、SM-1000、SM-200(云母和二氧化硅混合颗粒,得自Presperse)和FluroTOUCH 135C和235C(聚乙烯和聚四氟乙烯,得自Shamrock Technologies,Inc)。
在本发明的一个实施方案中,用于洗发剂组合物的颗粒是中空颗粒。在优选的实施方案中,中空颗粒是包封了流体的柔韧微球体。该微球体是结构上中空的,然而,它们可包括各种流体,其包括液体和气体以及它们的异构体。气体包括但不限于丁烷、戊烷、空气、氮气、氧气、二氧化碳和二甲基醚。如果被使用,液体可仅是部分地填充微球体。液体包括水和任何相容的溶剂。液体也可包含维生素、氨基酸、蛋白质和蛋白质衍生物、草本植物提取物、颜料、染料、抗微生物剂、螯合剂、紫外线吸收剂、荧光增白剂、硅氧烷化合物、香料、通常是水溶性的湿润剂、通常是水不溶性的附加的调理剂以及它们的混合物。在一个实施方案中,被包封的物质优选是水溶性组分。在另一个方案中,被包封的物质优选是选自维生素、氨基酸、蛋白、蛋白衍生物、草本植物提取物及它们的混合物的组分。在另一个实施方案中,被包封的物质优选选自维生素E、泛基乙基醚、泛醇、何首乌提取物及它们的混合物。
本发明的颗粒可具有表面电荷或它们的表面可用有机或无机材料如例如表面活性剂、聚合物和无机材料改性。颗粒复合物也是有用的。气体包封的微球体的复合物的非限制性实施例是DSPCS-I2TM(二氧化硅改性的乙烯/异丁烯酸酯共聚物微球体)和SPCAT-I2TM(滑石改性的乙烯/异丁烯酸酯共聚物微球体),全部得自Kobo Products,Inc.。
颗粒的表面可以通过静电发展而荷电,或者以各种直接地或通过短的、长的或支链烷基基团连接的离子基团的连接而荷电。表面电荷性质上可以是阴离子的、阳离子的、两性离子的或两性的。
本发明的颗粒的壁可由热塑性材料形成。该热塑性材料可以是选自如下的至少一种单体的聚合物或共聚物:丙烯酸酯、异丁烯酸酯、苯乙烯、取代苯乙烯、不饱和二卤化物、丙烯腈、异丁烯腈。该热塑性材料可包含酰胺、酯、尿烷、脲、醚、碳酸酯、缩醛、硫化物、磷酸酯、磷酸酯和硅氧烷连接基。中空颗粒可包括1%至60%的衍生自1,1-二氯乙烯的重复结构单元,20%至90%的衍生自丙烯腈的重复结构单元和1%至50%的衍生自(甲基)丙烯酸单体的重复结构单元,其百分比的和(按重量计)等于100。(甲基)丙烯酸单体是,例如,丙烯酸甲酯或异丁烯酸甲酯,尤其是异丁烯酸甲酯。优选地,颗粒由至少一种选自扩展的或非扩展的1,1-二氯乙烯、丙烯酸、苯乙烯和(甲基)丙烯腈的单体的聚合物或共聚物组成。更优选地,该颗粒由丙烯腈和异丁烯腈的共聚物组成。
也可以使用由得自酯例如乙酸乙烯酯或乳酸乙烯酯,或酸例如衣康酸、柠康酸、马来酸或富马酸的聚合物和共聚物组成的颗粒。在这方面,参见日本专利申请JP-A-2-112304,其完整公开内容引入本发明以供参考。
可商购获得的合适的颗粒的非限制性实施例是551 DE(粒径范围为约30至50μm和密度为约42kg/m3)、551 DE 20(粒径范围为约15至25μm和密度为约60kg/m3)、461 DE(粒径范围为约20至40μm和密度为60kg/m3)、551 DE 80(粒径为约50至80μm和密度为约42kg/m3)、091 DE(粒径范围为约35至55μm和密度为约30kg/m3),所有这些都以商标EXPANCELTM由Akzo Nobel出售。其它适合用于本发明的颗粒的实施例是以商标DUALITE和MICROPEARLTM系列微球体出售的,得自Pierce & Stevens Corporation。尤其优选的中空颗粒是091 DE和551DE 50。本发明中空颗粒以干燥的或者是水合物状态存在。前述颗粒是无毒的且对皮肤无刺激。
有用益于本发明的中空颗粒可通过,例如,描述于欧洲专利EP-56,219、EP-348,372、EP-486,080、EP-320,473、EP-112,807和美国专利3,615,972中的方法制备,每个的完整公开内容引入本发明以供参考。
可供选择地,有用于本发明的中空颗粒的壁可由无机材料形成。该无机材料可以是二氧化硅、碱石灰硼硅酸盐玻璃、二氧化硅-矾土陶瓷或碱性硅铝酸盐陶瓷。可商购获得的合适的低密度、无机颗粒的非限制性实施例是H50/10,000 EPX(粒径范围为约20至60μm)、S38(粒径范围为约15至65μm)、W-210(粒径范围为约1至12μm)、W-410(粒径范围为约1至24μm)、W-610(粒径范围为约1至40μm)、G-200(粒径范围为约1至12μm)、G-400(粒径范围为约1至24μm)、G-600(粒径范围为约1至40μm),所有这些都以商标3MTM ScotchliteTM Glass Bubbles、3MTM ZeeospheresTM陶瓷微球体和3MTMZ-Light SpheresTM陶瓷微球体出售。也有用的是二氧化硅外壳(平均粒径3μm),得自KOBO Products,和LUXSILTM(3-13μm平均直径),得自PQCorporation。
优选地,有用于本发明的中空颗粒的壁是柔韧的。本发明所使用的“柔韧的”是指中空颗粒易于压缩。当压力降低时,中空颗粒将重新获得其原始体积。柔韧的中空颗粒能在应用的压力下或由于温度改变导致的热膨胀和收缩而改变它们的形状。因此,颗粒能可能在热作用下膨胀。
本发明的颗粒可以是可渗透的或不可渗透的。本发明使用的“可渗透的”是指它们允许液体或气体在给定条件下通过。优选地,本发明的大部分颗粒将在洗发剂组合物的正常使用过程中保持它们的结构完整性。更优选地,基本上所有颗粒在洗发剂组合物的正常使用中保持它们的结构完整性。
优选的颗粒也将具有物理性质,所述性质不被组合物的典型加工显著影响。优选地,熔点大于约70℃的颗粒被使用。还更优选地,熔点大于80℃的颗粒被使用和更优选地,熔点大于约95℃的颗粒被使用。如本发明使用,熔点将是指颗粒转变成液体或流体状态或发生显著变形或物理性质改变时的温度。此外,许多本发明的颗粒是交联的或具有交联的表面膜。这些颗粒不显示清楚的熔点。交联的颗粒也是有用的,只要它们在制造本组合物中使用的加工和储存条件下是稳定的。优选地,颗粒不是药物活性物质。更优选地,颗粒不是去头屑活性物质。
C.阳离子聚合物
本发明的组合物包括足够高阳离子电荷密度的阳离子沉积聚合物以有效增强本发明所述固体颗粒组分的沉积。合适的阳离子聚合物具有的阳离子电荷密度在洗发剂组合物欲使用的pH下,至少约0.9meq/gm、优选至少约1.2meq/gm、更优选至少约1.5meq/gm、甚至更优选至少约1.7meq/gm,和还甚至更优选至少约1.9meq/gm,但也优选小于约7meq/gm、更优选小于约5meq/gm、甚至更优选小于约4.5meq/gm,其中所述洗发剂组合物欲使用的pH通常为约pH 3至约pH 9,优选为约pH 4至约pH 8。这样的阳离子聚合物的平均分子量将通常在约10,000和1千万之间、优选在约50,000和约5百万之间、更优选在约100,000和约3百万之间。本发明使用的术语“阳离子电荷密度”是指组成聚合物的单体单元上正电荷数与所述单体单元的分子量的比率。阳离子电荷密度乘以聚合物分子量决定了在给定聚合物链上的正电荷位置数。
洗发剂组合物中的阳离子聚合物的浓度按洗发剂组合物的重量计为约0.05%至约3%、优选约0.075%至约2.0%、更优选约0.1%至约1.0%。洗发剂组合物中的阳离子聚合物与颗粒(本发明后面述及)重量比率为约2∶1至约1∶30、优选约1∶1至约1∶20、更优选约1∶2至约1∶10。
用于本发明洗发剂组合物的合适的阳离子聚合物包含阳离子含氮部分,如季铵或阳离子质子化氨基部分。阳离子质子化氨基可以是伯、仲或叔胺(优选仲或叔),取决于定型洗发剂组合物的特定种类和所选的pH。任何阴离子反离子可以与阳离子聚合物联合使用,只要该聚合物在水、洗发剂组合物或洗发剂组合物的凝聚层相中保持溶解,和只要该反离子与洗发剂组合物的基本组分在物理和化学上是相容的或不会不适当地损害产品性能、稳定性或美观性。这样的反离子的非限制性实施例包括卤素离子(例如氯离子、氟离子、溴离子、碘离子)、硫酸根和甲基硫酸根。
阳离子聚合物的阳离子含氮部分通常作为取代基存在于所有,或典型地,存在于在一些单体单元上。因此,用于本发明洗发剂组合物的阳离子聚合物包括季铵或阳离子氨基取代的单体单元(任选地与本发明称为间隔单体的非阳离子单体一起)的均聚物、共聚物、三元共聚物等。这样的聚合物的非限制性实施例描述于CTFACosmetic Ingredient Dictionary,第三版,Estrin、Crosley和Haynes编(CTFA,华盛顿D.C.(1982))中,其描述引入本发明以供参考。
合适的阳离子聚合物的非限制性实施例包括具有阳离子质子化胺或季铵官能团的乙烯基单体与水溶性间隔单体如丙烯酰胺、异丁烯酰胺、烷基和二烷基丙烯酰胺、烷基和二烷基异丁烯酰胺、丙烯酸烷基酯、异丁烯酸烷基酯、乙烯基己内酯或乙烯基吡咯烷酮的共聚物。烷基和二烷基取代的单体优选地具有C1-C7烷基、更优选C1-C3烷基。其它合适的间隔单体包括乙烯基酯、乙烯醇(由聚乙酸乙烯酯水解制得)、马来酸酐、丙二醇和乙二醇。
用于包括在本发明洗发剂组合物的阳离子聚合物中的合适的阳离子质子化氨基和季铵单体包括被丙烯酸二烷基氨基烷基酯、异丁烯酸二烷基氨基烷基酯、丙烯酸一烷基氨基烷基酯、异丁烯酸一烷基氨基烷基酯、三烷基异丁烯酰氧基烷基铵盐、三烷基丙烯酰氧基烷基铵盐、二烯丙基季铵盐取代的乙烯基化合物,和具有环状阳离子含氮环如吡啶鎓、咪唑鎓和季铵化吡咯烷酮的乙烯基季铵单体,例如烷基乙烯基咪唑鎓、烷基乙烯基吡啶鎓、烷基乙烯基吡咯烷酮盐。这些单体的烷基部分优选地为低级烷基,如C1、C2或C3烷基。
适用于本发明的胺取代的乙烯基单体包括丙烯酸二烷基氨基烷基酯、异丁烯酸二烷基氨基烷基酯、二烷基氨基烷基丙烯酰胺以及二烷基氨基烷基异丁烯酰胺,其中该烷基基团优选为C1-C7烃基、更优选为C1-C3烷基。
其它用于本发明洗发剂组合物的合适的阳离子聚合物包括1-乙烯基-2-吡咯烷酮和1-乙烯基-3-甲基咪唑鎓盐(例如盐酸盐)的共聚物(参见工业界的化妆品、CTFA)的Polyquaternium-16),如可以商品名LUVIQUAT(例如LUVIQUATFC 370和FC 905)商购获得自BASF Wyandotte Corp(Parsippany,N.J.,USA)的那些;1-乙烯基-2-吡咯烷酮和异丁烯酸二甲基氨基乙酯的共聚物(参见工业界的CTFA中的Polyquaternium-11)如以商品名GAFQUAT(例如GAFQUAT 755N)商购得自Gaf Corporation(Wayne,N.J.,USA)的那些;包括阳离子二烯丙基季铵盐的聚合物,包括,例如二甲基二烯丙基氯化铵均聚物、丙烯酰胺和二甲基二烯丙基氯化铵的共聚物(分别参见工业界的CTFA中的Polyquaternium 6和Polyquaternium 7),如那些以商品名MERQUAT得自Calgon Corp.(Pittsburgh,Pa.,USA)的Merquat 100和Merquat 550;两性的丙烯酸共聚物,包括丙烯酸和二甲基二烯丙基氯化铵共聚物(参见工业界的CTFA中的Polyquaternium 22)如以商品名merquat(例如Merquat 280和295)得自Calgon Corp.。丙烯酸与二甲基二烯丙基氯化铵和丙烯酰胺的三元共聚物(参见工业界的CTFA中的Polyquaternium 39)如以商品名Merquat(例如即Merquat 3300和3331)得自Calgon Corp.。和丙烯酸与异丁烯酰氨基丙基三甲基氯化铵和异丁烯酸酯的三元共聚物(参见工业界的CTFA中的Polyquaternium 47),以商品名Merquat(例如Merquat 2001)得自Calgon Corp。优选的阳离子取代的单体是阳离子取代的二烷基氨基烷基丙烯酰胺、二烷基氨基烷基异丁烯酰胺以及它们的组合。这些优选的单体符合下式
其中R1是氢、甲基或乙基;每个R2、R3和R4独立地为氢或具有约1至约8个碳原子、优选约1至约5个碳原子、更优选约1至约2个碳原子的短链烷基;n是具有约1至约8,优选约1至约4的值的整数;X是反离子。连接到R2、R3和R4上的氮可以是质子化的胺(伯、仲或叔),但优选是季铵,其中每个R2、R3和R4是烷基,其非限制性实施例是聚异丁烯酰氨基丙基三甲基氯化铵,以商品名Polycare 133得自Rhone-Poulenc,Cranberry,N.J.,U.S.A.。
用于本发明洗发剂组合物的其它合适的阳离子聚合物包括多糖聚合物,如阳离子纤维素衍生物和阳离子淀粉衍生物。合适的阳离子多糖聚合物包括符合下式的那些:
其中A是葡糖酐残基,如淀粉或纤维素葡糖酐残基;R是亚烷基氧化烯、聚氧化烯或羟基亚烷基以及它们的组合;R1、R2和R3独立地为烷基、芳基、烷基芳基、芳基烷基、烷氧基烷基或烷氧基芳基,每个基团包含约18个碳原子,每个阳离子部分的碳原子总数(即R1、R2和R3中碳原子数之和)优选地为约20或更少;和X是前述的阴离子反离子。这些多糖聚合物中的阳离子取代度典型地为每葡糖酐单元约0.01-1个阳离子基团。
优选的阳离子纤维素聚合物是羟乙基纤维素与三甲基铵盐取代环氧化物反应得的盐,工业界(CTFA)称为Polyquaternium 10,得自AmercholCorp.(Edison,N.J.,USA)的Polymer JR30M,电荷密度为1.25meq/g,分子量为约900,000,Polymer JR400,电荷密度为1.25meq/g和分子量为约400,000,和PolymerkG30M,电荷密度为1.9和分子量为约1.25百万。其它合适类型的阳离子纤维素包括羟乙基纤维素与月桂基二甲基铵取代的环氧化物反应的聚合物的季铵盐,工业界(CTFA)称为Polyquaternium 24。
其它合适的阳离子聚合物包括瓜耳胶衍生物,如瓜耳胶羟丙基三甲基氯化铵,其具体实施例包括Jaguar C17,电荷密度为0.9,分子量为约2.2百万,可商购自Rhone-Poulenc Incorporated。任何阴离子反离子可与阳离子瓜耳胶结合使用,只要阳离子瓜耳胶保持溶于水、溶于洗发剂组合物、溶于洗发剂组合物的凝聚层相,和只要反离子在物理和化学上与洗发剂组合物的基本组分相容或不会不适当地损害产品的性能、稳定性或美观性。这样的反离子的非限制性实施例包括:卤离子(例如氯离子、氟离子、溴离子、碘离子)、硫酸根、甲基硫酸根以及它们的混合物。
瓜耳胶是阳离子取代的半乳甘露聚糖(瓜耳)树胶衍生物。用于制备这些瓜耳胶衍生物的瓜耳胶是典型地以天然产物得自瓜耳植物的种子。瓜耳胶分子自身是直链甘露聚糖,所述直链在规则间隔以一元半乳糖单元在交替甘露糖单元上支化。甘露糖单元通过β(1-4)糖苷键互相连接。半乳糖支化通过α(1-6)键发生。瓜耳胶的阳离子衍生物通过半乳甘露聚糖的羟基和反应性季铵化合物反应得到。阳离子基团在瓜耳胶结构上的取代度必须足以提供需要的上述阳离子电荷密度。
用于形成阳离子瓜耳胶聚合物的合适的季铵化合物包括符合如下通式(XII)的那些:
其中R1、R2和R3是甲基或乙基;R4是任何如下通式(XIII)的环氧烷基:
或R4是通式(XIV)的卤代醇基团:
其中R5是C1-C3亚烷基;X是氯或溴,和Z是阴离子,如Cl-、Br-、I-或HSO4 -。
由上述试剂形成的阳离子瓜耳胶聚合物(瓜耳胶的阳离子衍生物)通过如下通式(XV)表示:
其中R是瓜耳胶。优选地,阳离子瓜耳胶聚合物是瓜耳胶羟丙基三甲基氯化铵。
其它合适的阳离子聚合物包括季含氮纤维素醚,其一些实施例描述于美国专利3,962,418中,其描述引入本发明以供参考。其它合适的阳离子聚合物包括醚化的纤维素、瓜耳胶和淀粉的共聚物,其一些实施例描述于美国专利3,958,581中,其描述引入本发明以供参考。
本发明的阳离子聚合物或者溶于洗发剂组合物或者溶于洗发剂组合物中的复合凝聚层相,所述凝聚层相通过阳离子聚合物与上述阴离子去污表面活性剂形成。阳离子聚合物的复合凝聚层也能通过洗发剂组合物中的其它荷电物质形成。
凝聚层形成取决于各种标准,如分子量、组分浓度和相互作用的离子组分的比率、离子强度(包括离子强度改性,例如通过加入盐)、阳离子和阴离子组分的电荷密度、pH和温度。凝聚层体系和这些参数的影响已被描述,例如J.Caelles等人,“混合体系中的阴离子和阳离子化合物”(Anionic andCationic Compounds inmixed Systems),Cosmetics & Toiletries,第106卷,1991年4月,第49至54页,C.J.van Oss,“凝聚、配位积并作用和絮凝”(Coacervation,Complex-Coacervation and Flocculation),J.DispersionScience and Technology,第9(5,6)卷,1988-89,第561至573页,和D.J.Burgess,“配合物凝聚层体系的实用分析”(Practical Analysis of ComplexCoacervate Systems),J.ofColloid and Interface Science,卷140,第一期,1990年11月,第227至238页中,其描述引入本发明以供参考。
据信尤其有利的是阳离子聚合物存在于洗发剂组合物中的凝聚层相,或经毛发上涂敷或润洗洗发剂而形成凝聚层相。复合凝聚层据信更容易沉积于毛发。因此,一般而言优选阳离子聚合物以凝聚层相或经稀释形成凝聚层相而存在于洗发剂组合物中。
用于分析复合物凝聚层形成过程的技术是本领域已知的。举例来说,在任何选定的稀释阶段,可以对洗发剂组合物采用显微分析来识别是否形成了凝聚层相。这种凝聚层相将作为组合物中的另外的乳化相而被识别。使用染料能辅助将凝聚层相与其它分散于洗发剂组合物中的不溶相区别开。
在本发明的组合物中,据信高电荷密度阳离子聚合物形成相对大尺寸的约20微米至约500微米的凝聚层的倾向,其能有效结合或絮凝化颗粒并促进递送至毛发,而有助于提高沉积效率。此外,凝聚层具有内聚特征,如大的、有结构的絮凝物所证明,所述絮凝物经稀释保留了大量的颗粒组分,并在暴露于剪切时抵抗脱絮凝作用,促进颗粒在毛发上的沉积和保留。
D.含水载体
本发明的组合物包括含水载体。根据与其它组分的相容性和产品所需的其它特性选择载体的含量和种类。
用于本发明的载体包括水和低级烷基醇的水溶液。适用于本发明的低级烷基醇是具有1至6个碳原子的一元醇、更优选乙醇和异丙醇。
优选地,含水载体基本上是水。优选使用去离子水。包含矿物阳离子的天然来源的水也可被使用,这取决于产品的期望特征。通常,本发明的组合物包括约20%至约99%、优选约40%至约98%、更优选约60%至约98%的含水载体。
本发明的组合物的pH优选为约4至约9、更优选为约4.5至约7.5。为获得所需的pH,可包含缓冲剂和pH调节剂。
E.附加的组分
本发明洗发剂组合物可进一步包括一种或多种已知用于毛发护理或个人护理产品的任选组分,条件是该任选组分与本发明所述基本组分在物理和化学上相容,或不会不适当地损害产品的稳定性、美观性或性能。这样的任选组分的各自的浓度可以是按洗发剂组合物的重量计约0.001%至约10%。
用于洗发剂组合物的任选组分的非限制性实施例包括阳离子聚合物、调理剂(烃油、脂肪族酯、硅氧烷)、去头屑剂、悬浮剂、粘度调节剂、染料、非挥发性的溶剂或稀释剂(水溶性的或不溶性的)、珠光助剂、泡沫促进剂、附加表面活性剂或非离子助表面活性剂、杀虱剂、pH调节剂、香料、防腐剂、螯合剂、蛋白质、皮肤活性剂、防晒剂、紫外线吸收剂和维生素。
调理剂
调理剂包括任何对毛发和/或皮肤给出特殊调理有益效果的物质。在毛发处理组合物中,合适的调理剂是递送一种或多种有益效果的那些,这些有益效果包括光泽、柔软性、相容性、抗静电性、湿处理、抗损伤、整理性、主体和抗油腻。有用于本发明洗发剂组合物的调理剂典型地包括水不溶性、水可分散的非挥发性液体,其形成乳化的液体颗粒或被阴离子去污表面活性剂组分中(如上所述)的表面活性剂胶束溶解。用于洗发剂组合物的合适的调理剂是那些特征通常为硅氧烷(例如硅氧烷油、阳离子硅氧烷、硅氧烷树胶、高折射硅氧烷和硅氧烷树脂)、有机调理油(例如烃油、聚烯烃和脂肪族酯)和其组合物的调理剂,或那些在本发明含水表面活性剂基质中形成液体、分散的颗粒的调理剂。这样的调理剂应该在物理或化学上与组合物的基本组分相容,和不应该不适当地损害产品的稳定性、美观性或性能。
洗发剂组合物中的调理剂的浓度应该足以提供期望的调理有益效果,这对本领域的普通技术人员将是显而易见的。这样的浓度可依照调理剂、期望的调理性能、调理剂颗粒的平均粒径、其它组分的类型和浓度等因素而改变。
1.硅氧烷(silicone)
本发明洗发剂组合物的调理剂优选地是不溶性硅氧烷调理剂。硅氧烷调理剂颗粒可包括挥发性硅氧烷、非挥发性硅氧烷以及它们的组合。优选的是非挥发性硅氧烷调理剂。如果存在挥发性硅氧烷,它将典型地是附带的应用它们作为可商购获得的非挥发性硅氧烷材料成分如硅氧烷树胶和树脂的溶剂或载体。硅氧烷调理剂颗粒可包括聚硅氧烷流体调理剂,并且也可以包括其它成分,如硅氧烷树脂以改善聚硅氧烷流体沉积性能或增强毛发光泽(尤其是当高折射率(例如高于约1.46)硅氧烷被使用时(例如高苯基化硅氧烷)。
硅氧烷调理剂的浓度典型地为按组合物的重量计约0.01%至约10%、优选约0.1%至约8%、更优选约0.1%至约5%、最优选约0.2%至约3%。合适的硅氧烷调理剂和任选的硅氧烷的悬浮剂的非限制性实施例描述于美国重新公布的专利34,584、美国专利5,104,646和美国专利5,106,609中,其描述引入本发明以供参考。用于本发明洗发剂组合物的硅氧烷调理剂在25℃下测得的粘度优选地为约20至约2,000,000厘沲、更优选约1,000至约1,800,000厘沲、甚至更优选约50,000至约1,500,000厘沲、最优选约100,000至约1,500,000厘沲。
分散的硅氧烷调理剂颗粒典型地具有约0.01μm至约50μm的数均颗粒直径。对于涂敷于毛发的小颗粒,数均颗粒直径典型地为约0.01μm至约4μm、优选约0.01μm至约2μm、更优选约0.01μm至约0.5μm。对于涂敷于毛发的较大颗粒,数均颗粒直径为约4μm至约50μm、优选约6μm至约30μm、更优选约9μm至约20μm、最优选约12μm至约18μm。具有平均粒径小于约5μm的调理剂可更有效地沉积于毛发。据信小尺寸颗粒的调理剂被包含在凝聚层,该层是经洗发剂稀释,在阴离子表面活性剂组分(如上所述)和阳离子聚合物组分(如下所述)之间形成的。
关于硅氧烷的背景资料,包括讨论聚硅氧烷流体、树胶和树脂以及硅氧烷制造的部分,可参见“Encyclopedia of Polymer Science and Engineering”,第15卷,第二版,第204-308页,John Wiley & Sons,Inc.(1989)中,引入本发明以供参考。
a.硅氧烷油
硅氧烷流体包括硅氧烷油,其为可流动的硅氧烷物质,在25℃下测得的粘度低于1,000,000厘沲、优选约5厘沲至约1,000,000厘沲、更优选约10厘沲至约100,000厘沲。用于本发明洗发剂组合物的合适的硅氧烷油包括聚烷基硅氧烷、聚芳基硅氧烷、聚烷基芳基硅氧烷、聚醚硅氧烷共聚物以及它们的混合物。其它具有毛发调理性质的不溶性非挥发性聚硅氧烷流体也可被使用。
硅氧烷包括聚烷基或聚芳基硅氧烷,其符合下式(III):
其中R是脂族基团,优选烷基或链烯基,或芳基,R可以是取代的或未取代的,且x是1至约8,000的整数。用于本发明洗发剂组合物的合适的未取代R基团包括但不限于烷氧基、芳氧基、烷芳基、芳烷基、芳烯基、烷氨基和醚取代的、羟基取代的和卤素取代的脂族基团和芳基。合适的R基团还包括阳离子胺和季铵基团。
在硅氧烷链上取代的脂族基团或芳基可具有任何结构,只要所得硅氧烷在室温下保持流体,是疏水性的,当涂敷于毛发时,其既无刺激性、无毒性,无害,与洗发剂组合物中其它组分相容,在正常使用和储存条件下在化学上是稳定的,在本发明洗发剂组合物中是不溶的,并且能沉积于毛发上并调理毛发。每个单体硅氧烷单元的硅原子上的两个R基团可代表相同或不同的基团。优选地,两个R基团代表相同的基团。
优选的烷基和链烯基取代基是C1-C5烷基和链烯基、更优选C1-C4、最优选C1-C2。其它包含烷基、链烯基或炔基的基团(如烷氧基、烷芳基和烷氨基)的脂族部分可以是直链或支链,并优选C1-C5、更优选C1-C4、甚至更优选C1-C3、最优选C1-C2。如上所讨论,R取代基也可包含官能团(例如烷氨基),其可以是伯、仲或叔胺或季铵。这些基团包括一、二和三烷基氨基和烷氧基氨基,其中脂族部分链长优选如上所述。R取代基也可被其它基团例如卤素(例如氯、氟和溴)、卤代脂族基团或芳基、羟基(例如羟基取代的脂族基团)以及它们的混合物取代。合适的卤代R基团可包括,例如,三卤代(优选三氟代)烷基,如-R1CF3,其中R1是C1-C3烷基。这样的聚硅氧烷的实施例包括但不限于聚甲基3,3,3-三氟丙基硅氧烷。
用于本发明洗发剂组合物的合适的R基团包括但不限于甲基、乙基、丙基、苯基、甲基苯基和苯基甲基。优选的硅氧烷的非限制性实施例包括聚二甲基硅氧烷、聚二乙基硅氧烷和聚甲基苯基硅氧烷。尤其优选的是聚二甲基硅氧烷。其它合适的R基团包括甲基、甲氧基、乙氧基、丙氧基和芳基氧基。在硅氧烷封端的三个R基团可代表相同或不同的基团。
可以被使用的非挥发性聚烷基硅氧烷流体包括,例如低分子量聚二甲基硅氧烷。这些硅氧烷可以购自General Electric Company的Viscasil R和SF 96系列,Dow Corning公司的DC 200系列。可以被使用的聚烷基芳基硅氧烷流体也包括,例如聚甲基苯基硅氧烷。这些硅氧烷可购自例如General ElectricCompany的SF 1075甲基苯基液体,或者购自Dow Corning公司的556化妆品级液体。可以被使用的聚醚硅氧烷共聚物包括,例如聚氧化丙烯改性的聚二甲基硅氧烷(例如Dow Corning DC-1248),尽管氧化乙烯或氧化乙烯与氧化丙烯的混合物也可被使用。氧化乙烯和聚氧化丙烯的浓度必须足够低以防止在水和本发明描述的组合物中的溶解度。
适用于本发明洗发剂组合物的烷基氨基取代的硅氧烷包括但不限于符合下面通式(IV)的那些:
其中x和y是整数。这个聚合物也称为“氨基封端的聚二甲基硅氧烷”。
b.
阳离子硅氧烷
适用于本发明洗发剂组合物的阳离子聚硅氧烷流体包括但不限于符合通式(V)的那些:
(R1)aG3-a-Si-(-OSiG2)n-(-OSiGb(R1)2-b)m-O-SiG3-a(R1)a
其中G是氢、苯基、羟基或C1-C8烷基,优选甲基;a是0或具有1至3的值的整数,优选0;b是0或1,优选1;n是0至1,999的数,优选49至149;m是1至2,000的整数,优选1至10;n和m的和是1至2,000的数,优选50至150;R1是符合通式CqH2qL的一价基团,其中q是具有2至8的值的整数,和L选自下列基团:
-N(R2)CH2-CH2-N(R2)2
-N(R2)2
-N(R2)3A-
-N(R2)CH2-CH2-NR2H2A-
其中R2是氢、苯基、苄基或饱和烃基,优选约C1至约C20烷基,和A-是卤离子。
尤其优选的对应式(V)的阳离子硅氧烷是称为“三甲基甲硅烷基氨代聚二甲基硅氧烷”的聚合物,其如下式(VI)所示:
可用于本发明洗发剂组合物的其它硅氧烷阳离子聚合物用通式(VII)表示:
其中R3是C1-C18的一价烃基,优选烷基或链烯基,如甲基;R4是烃基、优选C1-C18亚烷基或C10-C18亚烷氧基、更优选C1-C8亚烷氧基;Q-是卤离子,优选氯离子;r是2至20的平均统计值,优选2至8;s是20至200的平均统计值,优选20至50。这类的优选的聚合物称为UCARE SILICONE ALE56TM,得自Union Carbide。
c.硅氧烷树胶
其它适用于本发明洗发剂组合物的聚硅氧烷流体是不溶性硅氧烷树胶。这些树胶是聚有机硅氧烷物质,其具有的粘度在25℃测得为大于或等于1,000,000厘池。硅氧烷树胶描述于美国专利4,152,416;Noll和Walter,“硅氧烷的化学和技术”(Chemistry and Technology of Silicones),纽约:AcademicPress(1968);和General Electric Silicone Rubber Product Data Sheets SE 30、SE 33、SE 54和SE 76中,所有这些都引入本发明以供参考。硅氧烷树胶将典型地具有超过约200,000,优选约200,000至约1,000,000的重均分子量。具体的用于本发明洗发剂组合物的硅氧烷树胶的非限制性实施例包括聚二甲基硅氧烷、(聚二甲基硅氧烷)(甲基乙烯基硅氧烷)共聚物,聚(二甲基硅氧烷)(二苯基硅氧烷)(甲基乙烯基硅氧烷)共聚物以及它们的混合物。
d.高折射率硅氧烷
适用于本发明洗发剂组合物的其它非挥发性不溶性聚硅氧烷流体调理剂是称为“高折射率硅氧烷”的那些,其具有至少约1.46、优选至少约1.48、更优选至少约1.52、最优选至少约1.55的折射率。聚硅氧烷流体的折射率将通常低于约1.70,典型地低于约1.60。在这一上下文中,聚硅氧烷“流体”包括油以及树胶。
高折射率聚硅氧烷流体包括如上通式(III)表示的那些,以及环状的聚硅氧烷,如下面式(VIII)表示的那些:
其中R如上所定义,和n是约3至约7的数,优选约3至约5。
高折射率聚硅氧烷流体包含的包含芳基的R取代基的量足以将折射率提高到如上所述的期望水平。此外,R和n必须被选定以使该物质具有非挥发性。
包含芳基的取代基包括包含脂环烃和杂环的五元和六元芳环的那些和包含稠合的五元或六元环的那些。芳基环本身可以是被取代的或未被取代的。取代基包括脂族取代基,也可包括烷氧基取代基、酰基取代基、酮、卤素(例如Cl和Br)、胺等。包含芳基的基团的实施例包括但不限于取代的或未取代的芳烃,如苯基和苯基衍生物,如具有C1-C5烷基或链烯基取代基的苯基。具体的非限制性实施例包括烯丙基苯基、甲基苯基和乙基苯基、乙烯基苯基(例如苯乙烯基)和苯基炔烃(例如苯基C2-C4炔烃)。杂环芳基包括但不限于衍生自呋喃、咪唑、吡咯、吡啶等的取代基。稠合芳环取代基的实施例包括但不限于萘、香豆素和嘌呤。
一般地,高折射率聚硅氧烷流体将具有至少约15%、优选至少约20%、更优选至少约25%、甚至更优选至少约35%、最优选至少约50%的包含芳基的取代基程度。典型地,芳基取代度将低于约90%,更一般的低于约85%,优选为约55%至约80%。
高折射率聚硅氧烷流体也具有因它们的芳基取代导致的较高表面张力。一般地,聚硅氧烷流体将具有至少约24达因/cm2的表面张力,典型地至少约27达因/cm2。表面张力,为了在此之目的,依照Dow Corning公司测试方法CTM 0461(1971年11月23日)通过de Nouy环张力计测得。表面张力的改变可依照上述测试方法或依照ASTMmethod D 1331测得。
优选的高折射率聚硅氧烷流体具有苯基或苯基衍生物取代基(最优选苯基)与烷基取代基,优选C1-C4烷基(最优选甲基)、羟基或C1-C4烷基氨基(尤其是-R1NHR2NH2,其中每个R1和R2独立地为C1-C3烷基、链烯基和/或烷氧基)的组合。高折射率聚硅氧烷得自Dow Corning、Huls America和GeneralElectric。
当高折射率硅氧烷被用于本发明洗发剂组合物时,它们优选在具有铺展剂如硅氧烷树脂或表面活性剂的溶液中使用,以充分降低表面张力来提高铺展,和因此增强用该组合物处理的毛发的光泽(干燥之后)。一般地,铺展剂的用量足以将高折射率聚硅氧烷流体的表面张力降低至少约5%、优选至少约10%、更优选至少约15%、甚至更优选至少约20%、最优选至少约25%。聚硅氧烷流体/铺展剂混合物对表面张力的降低可改善毛发光泽。
铺展剂也会优选地将表面张力降低至少约2达因/cm2、优选至少约3达因/cm2、甚至更优选至少约4达因/cm2、最优选至少约5达因/cm2。
以最终产品中存在的比例,聚硅氧烷流体和铺展剂的混合物表面张力优选地小于或等于约30达因/cm2、更优选小于或等于约28达因/cm2、最优选小于或等于约25达因/cm2。典型地,表面张力将是约15达因/cm2至约30达因/cm2、更典型地为约18达因/cm2至约28达因/cm2、最通常地为约20达因/cm2至约25达因/cm2。
通常,高度芳基化聚硅氧烷流体与铺展剂的重量比率将是约1000∶1至约1∶1、优选约100∶1至约2∶1、更优选约50∶1至约2∶1、最优选约25∶1至约2∶1。当氟化的表面活性剂被使用时,尤其高的聚硅氧烷流体和铺展剂的比率由于这些表面活性剂的功效可以是有效的。因此,经设想可以使用显著高于1000∶1的比率。
适用于本发明洗发剂组合物的聚硅氧烷流体公开于美国专利2,826,551、美国专利3,964,500、美国专利4,364,837、英国专利849,433,和硅化合物(Silicon Compounds),Petrarch Systems,Inc.(1984)中,所有这些引入本发明以供参考。
e.硅氧烷树脂
硅氧烷树脂可被包括在本发明洗发剂组合物的硅氧烷调理剂中。这些树脂是高度交联的聚合物硅氧烷体系。交联是在制造硅氧烷树脂的过程中通过将三官能的和四官能化硅烷与一官能的或二官能的或两种硅烷掺合而引入。这对于本领域的普通技术人员将是显而易见的。获得硅氧烷树脂所需要的交联度将依照具体的掺入硅氧烷树脂的硅烷单元而变。一般地,具有足够含量的三官能的和四官能的硅烷单体单元(和因此,足够水平的交联)的硅氧烷物质,这样它们在干燥后成为刚性或硬的膜,被认为是硅氧烷树脂。氧原子与硅原子的比率是特定硅氧烷材料中交联水平的指标。适用于本发明洗发剂组合物的硅氧烷树脂通常具有至少约1.1个氧原子每个硅原子。优选地,氧与硅原子的比率为至少约1.2∶1.0。用于制造硅氧烷树脂的硅烷包括但不限于一甲基-、二甲基-、三甲基-、一苯基-、二苯基-、甲基苯基-、一乙烯基-和甲基乙烯基-氯硅烷,和四氯硅烷,其中甲基-取代的硅烷是最常用的。优选的树脂以GE SS4230和GE SS4267得自General Electric。可商购获得的硅氧烷树脂通常以在低粘度挥发性的或非挥发性的聚硅氧烷流体中溶解的形式提供。用于本发明的硅氧烷树脂应以这样的溶解的形式被提供并掺入本发明的组合物,这对本领域的普通技术人员将是显而易见的。
尤其是硅氧烷物质和硅氧烷树脂可依照本领域普通技术人员已知的称为“MDTQ”命名的速记命名体系而方便地被指认。在该体系下,根据所存在的组成聚硅氧烷的各种硅氧烷单体单元表示聚硅氧烷。简要地,符号M代表一官能单元(CH3)3SiO0.5;D代表二官能单元(CH3)2SiO;T代表三官能单元(CH3)SiO1.5;和Q代表四官能单元SiO2。基本单元符号(例如M′、D′、T′和Q′)表示甲基之外的取代基,并必须在每个出现处具体地定义。典型的交替取代基包括但不限于如乙烯基、苯基、胺、羟基等。各单元的摩尔比,或者以符号下标表示聚硅氧烷中每一类型单元的总数(或其平均数),或者以具体表示的比例并结合分子量表示,从而完成了按照MDTQ系统对聚硅氧烷物质的描述。硅氧烷树脂中更高相对摩尔量的T、Q、T′和/或Q′对D、D′、M和/或m′指示更高水平的交联。然而,如上所讨论的,总交联水平也能通过氧硅比率而指示。
用于本发明洗发剂组合物的优选的硅氧烷树脂包括但不限于MQ、MT、MTQ、MDT和MDTQ树脂。甲基是优选的硅氧烷取代基。尤其优选的硅氧烷树脂是MQ树脂,其中M∶Q比率是约0.5∶1.0至约1.5∶1.0,和硅氧烷树脂的平均分子量是约1000至约10,000。
折射率低于1.46的非挥发性聚硅氧烷流体与硅氧烷树脂组分(当使用时)的重量比率优选为约4∶1至约400∶1、更优选约9∶1至约200∶1、最优选约19∶1至约100∶1,尤其是当聚硅氧烷流体组分是如上所述的聚二甲基硅氧烷流体或聚二甲基硅氧烷流体和聚二甲基硅氧烷树胶的混合物时。因为硅氧烷树脂在本发明的组合物中形成与硅氧烷流体,即液体沉积助剂相同的相的一部分,在确定组合物中硅氧烷含量时,流体和树脂的总和应该被包括在内。
2.有机调理油
本发明洗发剂组合物的调理组分还包括按组合物重量计的约0.05%至约3%、优选约0.08%至约1.5%、更优选约0.1%至约1%的至少一种作为调理剂的有机调理油,该调理剂可单独使用,或与其它调理剂如硅氧烷(如本文所述)联合使用。
当与组合物的基本组分组合使用时,尤其是当与阳离子聚合物(如下所述)组合使用时,据信这些有机调理油提供洗发剂组合物以改善的条理性能。调理油可增加毛发的光泽和光亮。此外,它们也增强干梳理和干毛发感觉。多数或所有的这些有机调理油被相信可溶解于洗发剂组合物的表面活性剂胶束中。也据信这种在表面活性剂胶束中的溶解作用可以改善本文洗发剂组合物的毛发调理性能。
适合用作本发明调理剂的有机调理油优选是选自烃油、聚烯烃、脂肪族酯以及它们的混合物的低粘度水不溶性的液体。这样的有机调理油在40℃测得的粘度优选地为约1厘泊至约200厘泊、更优选为约1厘泊至约100厘泊、最优选为约2厘泊至约50厘泊。
a.
烃油
适合用作本发明洗发剂组合物中的调理剂的有机调理油包括但不限于具有至少约10个碳原子的烃油,如环状烃,直链脂族烃(饱和的或不饱和的),和支链脂族烃(饱和的或不饱和的),包括聚合物和其混合物。直链烃油优选地为约C12至约C19。支链烃油,包括烃聚合物,典型地将包含多于19个碳原子。
这些烃油的具体的非限制性实施例包括石蜡油、矿物油、饱和和不饱和十二烷、饱和和不饱和十三烷、饱和和不饱和十四烷、饱和和不饱和十五烷、饱和和不饱和十六烷、聚丁烯、聚癸烯以及它们的混合物。也可使用这些化合物的支链异构体以及更高级链长的烃,其实施例包括高度支化的、饱和或不饱和的烷烃,如高甲基取代的异构体,例如十六烷和二十碳烷的高甲基取代的异构体,如2,2,4,4,6,6,8,8-二甲基-10-甲基十一烷和2,2,4,4,6,6-二甲基-8-甲基壬烷,得自Permethyl Corporation。烃聚合物如聚丁烯和聚癸烯。优选的烃聚合物是聚丁烯,例如异丁烯和丁烯的共聚物。这类可商购获得的物质是L-14聚丁烯,得自Amoco Chemical Corporation。
b.
聚烯烃
用于本发明洗发剂组合物的有机调理油也可包括液体聚烯烃、更优选液体聚-α-烯烃、最优选氢化液体聚-α-烯烃。用于本发明的聚烯烃通过C4至约C14烯烃单体,优选约C6至约C12的聚合作用而制备。
用于制备本发明的聚烯烃的烯烃单体的非限制性实施例包括乙烯、丙烯、1-丁烯、1-戊烯、1-己烯、1-辛烯、1-癸烯、1-十二碳烯、1-十四烯,支链异构体如4-甲基-1-戊烯以及它们的混合物。也适合于制备聚烯烃液体的是包含烯烃的精炼厂原料或排放物。优选的氢化α-烯烃单体包括但不限于1-己烯至1-十六碳烯、1-辛烯至1-十四烯以及它们的混合物。
c.
脂肪族酯
作为调理剂用于本发明洗发剂组合物的其它合适的有机调理油包括但不限于具有至少10个碳原子的脂肪族酯。这些脂肪族酯包括具有衍生自脂肪酸或醇的烃基链的酯(例如单酯、多元醇酯和二与三羧酸酯)。在此的脂肪族酯的烃基可包括或具有共价键合的另外的相容的官能团,如酰胺和烷氧基部分(例如乙氧基或醚键等)。
适合用于本发明洗发剂组合物的是具有约C10至约C22脂族链的脂肪酸的烷基和链烯基酯,和具有衍生自C10至约C22烷基和/或链烯基醇的脂族链的烷基和链烯基脂肪醇羧酸酯以及它们的混合物。优选的脂肪族酯的具体实施例包括但不限于异硬脂酸异丙酯、月桂酸己酯、月桂酸异己酯、十六烷酸异己酯、十六烷酸异丙酯、油酸癸酯、油酸异癸酯、硬脂酸十六烷基酯、硬脂酸癸酯、异硬脂酸异丙酯、己二酸二己基癸酯、乳酸月桂醇酯、乳酸十四烷醇酯、乳酸鲸蜡醇酯、硬脂酸油醇酯、油酸油醇酯、十四烷酸油醇酯、乙酸月桂醇酯、丙酸鲸蜡醇酯和己二酸油醇酯。
适用于本发明洗发剂组合物的其它脂肪族酯是如通式R′COOR的一羧酸酯,其中R’和R是烷基或链烯基,且R′和R中碳原子之和至少是10,优选至少20。一羧酸酯不必包含至少一个有至少10个碳原子的链;而脂族链碳原子的总数必须至少为10。一羧酸酯的具体的非限制性实施例包括肉豆蔻酸异丙酯、硬脂酸乙二醇酯和月桂酸异丙酯。
其它适用于本发明洗发剂组合物的脂肪族酯还有羧酸的二和三烷基和链烯基酯,如C4-C8二羧酸酯(例如琥珀酸、戊二酸、己二酸、己酸、庚酸和辛酸的C1-C22酯,优选C1-C6酯)。羧酸的二和三烷基和链烯基酯的具体非限制性实施例包括硬脂酰基硬脂酸异十六烷醇酯、己二酸二异丙酯和柠檬酸三硬脂醇酯。
其它适用于本发明洗发剂组合物的脂肪族酯是称为多元醇酯的那些。这样的多元醇酯包括亚烷基二醇酯,如乙二醇一和二脂肪酸酯、二甘醇一和二脂肪酸酯、聚乙二醇一和二脂肪酸酯、丙二醇一和二脂肪酸酯、聚丙二醇一油酸酯、聚丙二醇2000一硬脂酸酯、乙氧基化丙二醇一硬脂酸酯、甘油一和二脂肪酸酯、聚甘油聚脂肪酸酯、乙氧基化甘油一硬脂酸酯、1,3-丁二醇一硬脂酸酯、1,3-丁二醇二硬脂酸酯、聚氧乙烯多元醇脂肪酸酯、脱水山梨糖醇脂肪酸酯和聚氧乙烯脱水山梨糖醇脂肪酸酯。
其它适用于本发明洗发剂组合物的脂肪族酯还是甘油酯,包括但不限于甘油一酯、甘油二酯和甘油三酯,优选甘油二酯和甘油三酯,最优选甘油三酯。对于在本发明所述洗发剂组合物中的使用,甘油酯优选地为长链羧酸如C10-C22羧酸的甘油一酯、甘油二酯和甘油三酯。从植物和动物脂肪和油,例如蓖麻子油、红花油、棉籽油、玉米油、橄榄油、鳕鱼肝油、杏仁油、鳄梨油、棕榈油、芝麻油、羊毛脂和豆油可以获得这种材料。合成油包括但不限于甘油三油酸酯和三硬脂酸甘油基二月桂酸酯。
适用于本发明洗发剂组合物的其它脂肪族酯是水不溶性合成脂肪族酯。一些优选的合成酯符合如下通式(IX):
其中R1是C7-C9烷基、链烯基、羟基烷基或羟基链烯基,优选饱和烷基,更优选饱和、直链烷基;n是具有2至4的值的正整数,优选3;和Y是烷基、链烯基、羟基或羧基取代的烷基或链烯基,具有约2至约20个碳原子,优选约3至约14个碳原子。其它优选的合成酯符合如下通式(X):
其中R2是C8-C10烷基、链烯基、羟基烷基或羟基链烯基;优选饱和的烷基、更优选饱和、直链烷基;n和Y如上的式(X)所定义。
据信优选的当与本发明洗发剂组合物的基本组分组合使用时,尤其是当与阳离子聚合物组分(如下所述)组合使用时,合成酯提供改善的湿毛发感觉。这些合成酯通过降低糊状的或已被阳离子聚合物调理的湿毛发的过度调理感觉而改善湿毛发感觉。
用于本发明洗发剂组合物的合适的合成脂肪族酯的具体的非限制性实施例包括:P-43(三羟甲基丙烷的C8-C10三酯)、MCP-684(3,3二乙醇-1,5戊二醇的四酯)、MCP 121(己二酸的C8-C10二酯),所有的得自Mobil ChemicalCompany。
3.其它调理剂
也适用于本发明的组合物的是描述于宝洁公司的美国专利5,674,478和5,750,122中的调理剂,都全文引入本发明以供参考。也适用于本发明的是那些描述于美国专利:4,529,586(Clairol)、4,507,280(Clairol)、4,663,158(Clairol)、4,197,865(L’Oreal)、4,217,914(L’Oreal)、4,381,919(L’Oreal)和4,422,853(L’Oreal)中的调理剂,所有的其描述引入本发明以供参考。
一些其它优选得用于本发明的组合物得硅氧烷调理剂包括:Abil S 201(聚二甲基硅氧烷/钠PG-丙基二甲聚硅氧烷硫代硫酸盐共聚物),得自Goldschmidt;DC Q2-8220(三甲基甲硅烷基氨代聚二甲基硅氧烷)得自DowCorning;DC 949(氨基封端的聚二甲基硅氧烷,十六烷基三甲基氯化铵,和十三烷基聚氧乙烯醚-12),得自Dow Corning;DC 749(环二甲基硅酮和三甲基甲硅烷氧基硅酸酯),得自Dow Corning;DC2502(鲸蜡基二甲基硅氧烷),得自Dow Corning;BC97/004和BC 99/088(氨基官能化硅氧烷微乳),得自Basildon Chemicals;GE SME253和SM2115-D2__和SM2658和SF1708(氨基官能化硅氧烷微乳),得自通用电气;硅化meadowfoam种子油,得自Croda;和由GAF Corp.描述于美国专利4,834,767(季铵基内酰胺)、BiosilTechnologies描述于美国专利5,854,319(包含氨基酸的反应性硅氧烷乳液)和Dow Corning描述于美国专利4,898,585(聚硅氧烷)中的那些硅氧烷,所有其描述引入本发明以供参考。
去头屑活性物质
本发明洗发剂组合物也可包含去头屑活剂。合适的去头屑颗粒的非限制性实施例包括吡啶硫酮盐、硫化硒、颗粒硫以及它们的混合物。优选的是吡啶硫酮盐。这样的去头屑颗粒应该在物理或化学上与组合物中的基本组分相容,并且不应该不适当地损害产品的稳定性、美观性或性能。
1.吡啶硫酮盐
吡啶硫酮盐去头屑颗粒,尤其是1-羟基-2-吡啶硫酮盐是高度优选的用于本发明洗发剂组合物的去头屑剂。吡啶硫酮盐去头屑颗粒的浓度按组合物的重量计典型地为约0.1%至约4%、优选约0.1%至约3%、最优选约0.3%至约2%。优选的吡啶硫酮盐包括从重金属如锌、锡、镉、镁、铝和锆、优选锌形成的那些、更优选1-羟基-2-吡啶硫酮的锌盐(称为“锌吡啶硫酮盐”或“ZPT”)、最优选以小板颗粒的形式的1-羟基-2-吡啶硫酮盐,其中颗粒具有的平均尺寸为最高达约20μ、优选约5μ、最优选约2.5μ。由其它阳离子,如钠形成的盐也适用于本发明。吡啶硫酮去头屑剂例如公开在美国专利2,809,971;3,236,733;3,753,196;3,761,418;4,345,080;4,323,683;4,379,753和4,470,982中,所有这些文献均引入本文作为参考。可以认为,当将ZPT用作本发明的洗发剂组合物中的去头屑剂颗粒时,头发的生长或再生长可以得到加强或调节或两者,或者头发损失可以降低或受到抑制,或者头发将变厚或丰富。
2.硫化硒
硫化硒是适用于本发明洗发剂组合物的颗粒去头屑剂,其有效浓度按组合物的重量计为约0.1%至约4%、优选约0.3%至约2.5%、更优选约0.5%至约1.5%。硫化硒通常被认为是具有一摩尔硒和两摩尔硫的化合物,尽管它也可以是符合通式SexSy的环状结构,其中x+y=8。硫化硒的平均颗粒直径典型地低于15μm,由向前的激光散射装置测得(例如Malvern 3600仪器),优选低于10μm。硫化硒化合物例如公开在美国专利2,694,668;3,152,046;4,089,945;和4,885,107中,所有这些文献均引入本文作为参考。
3.硫
硫也可作为颗粒去头屑剂用于本发明的组合物中。颗粒硫的有效浓度约为该组合物重量的1%至约4%、优选约2%至约4%。
湿润剂
本发明的组合物可包含润湿剂。本发明的湿润剂选自多元醇、水溶性烷氧基化非离子聚合物,以及它们的混合物。当用于本发明时,润湿剂优选地以按组合物的重量计约0.1%至约20%的量、更优选约0.5%至约5%的量被使用。
可用于本发明的多元醇包括甘油、山梨醇、丙二醇、丁二醇、己二醇、乙氧基化葡萄糖、1,2-己二醇、己三醇、一缩二丙二醇、赤藓醇、海藻糖、双甘油、木糖醇、麦芽糖醇、麦芽糖、葡萄糖、果糖、软骨素硫酸钠、透明质酸钠、腺苷磷酸钠、乳酸钠、吡咯烷酮碳酸盐、葡糖胺、环糊精以及它们的混合物。
可用于本发明的水溶性烷氧基化非离子聚合物包括聚具有分子量约1000的乙二醇和聚丙二醇,如那些CTFA名称为PEG-200、PEG-400、PEG-600、PEG-1000以及它们的混合物的那些。
适用于本发明的市售的湿润剂包括:商品名STARTM SUPEROLTM的甘油得自宝洁公司,CRODEROL GA7000TM得自Universal Ltd.,PRECERINTM系列得自Unichema,商品名与化学名相同得自NOF;商品名LEXOLPG-865/855TM的丙二醇得自Inolex,1,2-PROPYLENE GLYCOL USP得自BASF;商品名LIPONICTM系列的山梨醇得自Lipo,SORBOTM、ALEXTM、A-625TM和A-641TM得自ICI,和UNISWEET 70TM、UNISWEET CONCTM得自UPI;一缩二丙二醇以相同的商品名得自BASF;商品名DIGLYCEROLTM的双甘油得自Solvay GmbH;木糖醇以相同的商品名得自Kyowa and Eizai;麦芽糖醇以商品名MALBIT得自Hayashibara,软骨素硫酸钠以相同的商品名得自Freeman and Bioiberica,和商品名ATOMERGIC SODIUMCHONDROITIN SULFATE得自Atomergic Chemetals;透明质酸钠以商品名ACTIMOIST得自Active Organics,AVIAN SODIUM HYALURONATE系列得自Intergen,HYALURONIC ACID Na得自Ichimaru Pharcos;腺苷磷酸钠以相同的商品名得自Asahikasei,Kyowa,和Daiichi Seiyaku;乳酸钠以相同的商品名得自merck、Wako和Showakako,环糊精以商品名CAVITRON得自Americanmaize,RHODOCAP系列得自Rhone-Poulenc,和DEXPEARL得自Tomen;和聚乙二醇以商品名CARBOWAX系列得自联合碳化物公司。
悬浮剂
本发明洗发剂组合物可进一步包括悬浮剂,其在洗发剂组合物的分散形式中浓度可有效悬浮颗粒或其它水不溶性物质或用于调节组合物的粘度。这样的浓度按洗发剂组合物的重量计为约0.1%至约10%,优选约0.3%至约5.0%。
可用于本发明的悬浮剂包括阴离子聚合物和非离子聚合物。可用于本发明的是乙烯基聚合物如CTFA名为卡波姆的交联丙烯酸聚合物,纤维素衍生物和改性的纤维素聚合物如甲基纤维素、乙基纤维素、羟乙基纤维素、羟丙基甲基纤维素、硝基纤维素、纤维素硫酸钠、羧甲基纤维素钠、结晶纤维素、纤维素粉末、聚乙烯吡咯烷酮、聚乙烯醇、瓜耳胶、羟丙基瓜耳胶、黄原胶、阿拉伯胶、黄蓍胶、半乳聚糖、长豆角胶、瓜耳胶树脂、刺梧桐树胶、角叉菜胶、果胶、琼脂、温柏树籽(Cydonia oblonga Mill)、淀粉(水稻、玉米、马铃薯、小麦)、海藻胶(藻类提取物)、微生物聚合物如葡聚糖、琥珀酰葡聚糖、普鲁兰(pulleran),基于淀粉的聚合物如羧甲基淀粉、甲基羟丙基淀粉,基于藻酸的聚合物如藻酸钠、褐藻酸丙二醇酯,丙烯酸酯聚合物如聚丙烯酸钠、聚丙烯酸乙酯、聚丙烯酰胺、聚乙烯亚胺和无机水溶性物质如斑脱膨润土、硅酸铝镁、合成锂皂石、锂蒙脱石和无水硅酸。
分子量高于约1000的聚亚烷基二醇可用于本发明。可使用具有下式的物质:
式中R95选自H、甲基以及它们的混合物。当R95为H时,这些物质为环氧乙烷的聚合物,它们也被称为聚环氧乙烷、聚氧化乙烯和聚乙二醇。当R95为甲基时,这些物质为环氧丙烷的聚合物,它们也被称为聚环氧丙烷、聚氧化丙烯和聚丙二醇。当R95为甲基时,也可理解可以存在所得聚合物的各种位置的异构体。在上述结构中,x3具有约1500至约120,000的平均值、优选约3,000至约100,000,和更优选约5,000至约50,000。其它有益的聚合物包括聚丙二醇和混合的聚乙烯-聚丙二醇或聚氧乙烯-聚氧丙烯共聚物。可用于本发明的聚乙二醇聚合物是PEG-2M,其中R95等于H和x3具有约2,000的平均值(PEG-2M也称为Polyox WSRN-10,其以PEG-2,000得自Dow/Amerchol);PEG-5M,其中R95等于H和x3具有约5,000的平均值(PEG-5M也称为Polyox WSRN-35和PolYox WSRN-80,都以PEG-5,000和Polyethylene Glycol300,000得自Dow/Amerchol);PEG-7M,其中R95等于H和x3具有约7,000的平均值(PEG-7M也称为Polyox WSRN-750,得自Dow/Amerchol);PEG-9M,其中R95等于H和x3具有约9,000的平均值(PEG9-M也称为Polyox WSRN-3333,得自Dow/Amerchol);PEG-14m,其中R95等于H和x3具有约14,000的平均值(PEG-14M也称为Polyox WSRN-3000,得自Dow/Amerchol);PEG-45M,其中R95等于H和x3具有约45,000的平均值(PEG-45M也称为Polyox WSRN-60K,得自Dow/Amerchol);和PEG-90M,其中R95等于H和x3具有约90,000的平均值(PEG-90M也称为Polyox WSR-301,得自Dow/Amerchol)。
高度有益于本发明的可商购获得的粘度改性剂包括卡波姆,商品名为Carbopol 934、Carbopol 940、Carbopol 950、Carbopol 980、Carbopol 981、Carbopol ETD 2010、Carbopol ETD 2050、Carbopol Ultrez 10和Carbopol AquaSF-1,所有的得自Noveon,Inc.,丙烯酸盐/硬脂基聚氧乙烯醚-20异丁烯酸盐共聚物,商品名ACRYSOL 22,得自Rohm和Hass,壬氧基羟乙基纤维素,商品名AMERCELL POLYMER HM-1500,得自Amerchol,甲基纤维素,商品名BENECEL,羟乙基纤维素,商品名NATROSOL,羟丙基纤维素,商品名KLUCEL,鲸蜡基羟乙基纤维素,商品名POLYSURF 67,所有这些由赫尔克里提供,基于环氧乙烷和/或环氧丙烷的聚合物,商品名CARBOWAX PEGs、POLYOX WASRs和UCON FLUIDS,所有这些由Amerchol提供。
其它任选的悬浮剂包括微晶悬浮剂,其可被分类为酰基衍生物、长链胺氧化物以及它们的混合物。这些悬浮剂描述于美国专利4,741,855中,其描述引入本发明以供参考。这些优选的悬浮剂包括具有约16至约22个碳原子的脂肪酸乙二醇酯。更优选的是乙二醇硬脂酸酯,单酯和二硬脂酸酯,但尤其是包含低于约7%的单硬脂酸酯硬脂酸酯。其它合适的悬浮剂包括脂肪酸的链烷醇酰胺、优选具有约16至约22个碳原子的、更优选约16至18个碳原子,其优选的实施例包括硬脂酸一乙醇酰胺、硬脂酸二乙醇酰胺、硬脂酸一异丙醇酰胺和硬脂酸一乙醇酰胺硬脂酸酯。其它长链酰基衍生物包括长链脂肪酸的长链酯(例如硬脂酸硬脂醇酯、棕榈酸鲸蜡醇酯等);长链烷醇酰胺的长链酯(例如硬脂酰二乙醇胺二硬脂酸酯、硬脂酰一乙醇胺硬脂酸酯);和甘油酯(例如甘油二硬脂酸酯、三羟基硬脂精、tribehenin)其可商购获得实施例是Thixin R,得自Rheox,Inc.。除了上面列出的优选的物质外,长链酰基衍生物、长链羧酸乙二醇酯、长链胺氧化物和长链羧酸烷醇酰胺可作为悬浮剂使用。
适合作为悬浮剂使用的其它长链酰基衍生物包括N,N-二烃基酰氨基苯甲酸和其水溶性盐(例如Na、K),尤其是这类的N,N-二(氢化)C.sub.16、C.sub.18和牛油酰氨基苯甲酸类,其可商购自Stepan Company(Northfield,Ill.,USA)。
作为悬浮剂使用的合适的长链胺氧化物的实施例包括烷基(C.sub.16-C.sub.22)二甲基胺氧化物,即硬脂基二甲基胺氧化物。
其它合适的悬浮剂包括具有有至少16个碳原子的脂肪烷基部分的伯胺,其实施例包括棕榈胺或十八胺,和具有两个分别有至少12个碳原子的脂肪烷基部分的仲胺,其实施例包括二棕榈基胺或二(氢化牛油基)胺。其它合适的悬浮剂还包括二(氢化牛油基)邻苯二甲酸酰胺和交联的马来酸酐-甲基乙烯基醚共聚物。
其它任选组分
本发明的组合物也可包含维生素和氨基酸,如:水溶性维生素,如维生素B1、B2、B6、B12、C、泛酸、泛基乙基醚、泛醇、生物素和它们的衍生物;水溶性氨基酸,如天冬酰胺、丙氨酸、吲哚、谷氨酸和它们的盐;水不溶性维生素,如维生素A、D、E和它们的衍生物;水不溶性氨基酸,如酪氨酸、色胺和它们的盐。
本发明的组合物也可包含颜料物质,如无机的、亚硝基的、单偶氮、双偶氮、类胡萝卜素、三苯甲烷、三芳基甲烷、氧杂蒽;呫吨、喹啉、噁嗪、吖嗪、蒽醌、靛系、硫堇靛青类、二羟基喹啉并吖啶、酞菁、植物、天然颜料,包括:水溶性组分,如具有下列C.I.名称的染料:Acid Red 18、26、27、33、51、52、87、88、92、94、95,Acid Yellow 1、3、11、23、36、40、73,Food Yellow 3,Food Green 3,Food blue 2,Food Red 1、6,Acid Blue 5、9、74,Pigment Red 57-1、53(Na),Basic Violet 10,Solvent Red 49,Acid orange7、20、24,Acid Green 1、3、5、25,Solvent Green 7,Acid Violet 9、43;水不溶性组分,例如具有下列C.I.名称的染料:Pigment Red 53(Ba)、49(Na)、49(Ca)、49(Ba)、49(Sr)、57,Solvent Red 23、24、43、48、72、73,SolventOrange 2、7,Pigment Red 4、24、48、63(Ca)3、64,Vat Red 1,Vat blue 1、6,Pigment Orange 1、5、13,Solvent Yellow 5、6、33,Pigment Yellow 1、12,Solvent Green 3,Solvent Violet 13,Solvent Blue 63,Pigment Blue 15,二氧化钛、叶绿酸铜配合物、群青、铝粉、膨润土、碳酸钙、硫酸钡、三氢化铋、硫酸钙、碳黑、骨灰、铬酸、钴蓝、金、氧化铁、水合氧化铁、亚铁氰化铁、碳酸镁、磷酸镁、银和氧化锌。
本发明的组合物也可包括抗微生物剂,其作为化妆品杀虫剂和去头屑剂是有益的,包括水溶性组分如羟甲辛吡铜乙醇胺,水不溶性组分如3,4,4′-三氯二苯脲(三氯生)、三氯卡班和吡啶硫酮锌。
本发明的组合物也可包括螯合剂,如:2,2′-二吡啶胺;1,10-菲咯啉{邻菲咯啉};二-2-吡啶基酮;2,3-二(2-吡啶基)吡嗪;2,3-二(2-吡啶基)-5,6-二氢吡嗪;1,1′-羰基二咪唑;2,4-二(5,6-二苯基-1,2,4-三嗪-3-基)吡啶;2,4,6-三(2-吡啶基)-1,3,5-三嗪;4,4′-二甲基-2,2′-联吡啶(dipyridyl);2,2′-联喹啉;二-2-吡啶基乙二醛{2,2′-pyridil};2-(2-吡啶基)苯并咪唑;2,2′-联吡嗪;3-(2-吡啶基)-5,6-二苯基-1,2,4-三嗪;3-(4-苯基-2-吡啶基)-5-苯基-1,2,4-三嗪;3-(4-苯基-2-吡啶基)-5,6-二苯基-1,2,4-三嗪;2,3,5,6-四-(2′-吡啶基)-吡嗪;2,6-吡啶二羧酸;2,4,5-三羟基嘧啶;苯基2-吡啶基酮肟;3-氨基-5,6-二甲基-1,2,4-三嗪;6-羟基-2-苯基-3(2H)-哒嗪酮;2,4-蝶啶二醇{lumazine};2,2′-联吡啶;和2,3-二羟基吡啶。
摩擦测试
用本发明的组合物处理之后,毛发将优选地显示约1至约2的摩擦系数。更优选地,毛发将显示约1.05至约1.8的摩擦系数。还更优选地,毛发将显示约1.1至约1.7的摩擦系数。甚至更优选地,毛发将显示约1.2至约1.6的摩擦系数。摩擦系数依照如下方法确定:
该方法测定未处理的相对于处理过的毛发簇的摩擦改变。称过重的“滑车”(约4.6mm×3.1mm),重73g+/-5%,用约105微米孔径的尼龙网覆盖,其连接于测力装置,如Instron上,以恒定速度牵引通过20g的毛发簇(大约25cm(10英寸)长),其一端被夹住。
使用的毛发是白种人毛发,被形成20克毛发簇,25cm(十英寸)长,其被清洁以去除任何外来污垢。然后,该毛发簇被允许在恒温在75℃/50%相对湿度(RH)的房间平衡过夜。
毛发簇被按如下处理:发簇在流动的自来水下预湿润。过量的水被挤干并且发簇挂在衣架上。对于免洗型产品,1.5cc的测试产品然后施用到毛发簇表面并擦入发簇约30至40秒。对于洗去型产品,测试产品以0.1g/g的剂量施用于湿毛发并按摩/涂以肥皂泡约30秒,随后约在流速约5.7升/分钟(1.5加仑/分钟)下漂洗约30秒,重复该方法以完成一个处理循环。然后,发簇被干燥并且前述处理循环重复总共3个循环。处理之后,发簇重新挂在衣架上并放置于恒温房间(75℃/50%RH)平衡过夜。
该待测发簇在水平测试架上夹紧并梳理2至3次以给毛发确定方向和去除纠缠。然后将滑车连接并放置于毛发簇上。摩擦在三个单独的发簇上以向前的方向(朝着毛发的尖端)测得,通过以约1cm/秒的速度牵引滑车同时测量张力(典型地按克为单位测得)。每个力测量值是当“滑车”达到恒定速度后在至少5cm距离记录的至少10个值的平均数。每发簇最少测量三次。摩擦系数由被处理的毛发簇的摩擦除以未处理的毛发簇的摩擦的平均比率确定。
毛发感觉测试
经本发明的组合物处理后,毛发将优选地显示低于约8的“毛发感觉”。更优选地,毛发将显示低于约7的“毛发感觉”。还更优选地,毛发将显示低于约6的“毛发感觉”。甚至更优选地,毛发将显示低于约5的“毛发感觉”。“毛发感觉”依照如下方法确定:
处理过的毛发簇由至少5个培训过的专门小组成员评估,以感觉干发簇。20克,25cm(10英寸)长,白种人毛发簇如本发明描述的摩擦测试所述的被用本发明的组合物处理,和对于涂敷量的感觉被评估。A0至10等级被用于鉴定处理过的毛发簇的等级。等级“0”表示非常干净感觉的毛发。等级“10”表示对毛发的非常被涂敷的感觉。等级终点是基于按如下处理的毛发簇:
0=用PanteneTM Clarifying Shampoo处理
10=0.75cc的在毛发簇中摩擦30秒的包含2.0%二氧化硅(Sipernet22LS,Degussa)的Pemulen TR-1凝胶(得自B.F.Goodrich)颗粒。
每种待测试的组合物使用三个不同的发簇。专门小组成员评估每个处理过的发簇并且打分被平均以得出总的“毛发感觉”等级。
使用方法
本发明洗发剂组合物以清洁毛发或皮肤的常规方式使用,并提供增强的固体颗粒的沉积和本发明的其它有益效果。有效量的用于清洁毛发或皮肤的组合物涂敷于毛发或皮肤,其优选地已被水润湿,然后漂洗掉。这样的有效量通常为约1g至约50g,优选约1g至约20g。涂敷于毛发典型地包括揉搓组合物于毛发以使大部分或所有毛发与组合物接触。
这一清洁毛发和皮肤的方法包括如下步骤:
a)用水润湿毛发和/或皮肤,b)涂敷有效量的洗发剂组合物至毛发和/或皮肤,和c)用水从毛发或皮肤上漂洗组合物。这些步骤可如期望的重复多次直到获得期望的清洁和颗粒沉积有益效果。
下列实施例进一步描述和说明了在本发明范围内的优选实施方案。实施例仅是为了描述之目的,不应被解释为对本发明的限定条件,因为在不背离其范围下其许多改变是可能的。
实施例
如下实施例中描述的洗发剂组合物描述了本发明洗发剂组合物的具体实施方案,但不是旨在对其进行限制。在不背离本发明精神和范围的条件下,技术人员可以进行其它的改变。本发明洗发剂组合物的这些示例的实施方案提供增强的颗粒的沉积效率有益效果。
如下实施例中描述的洗发剂组合物通过常规配制和混合方法制备,其实施例如下所述。除非另外指明,所有列出的示例的量以重量百分比,并排除了微量组分,如稀释剂、防腐剂、有色溶液、假想成分、植物药物等。
本发明洗发剂组合物可通过常规配制和混合技术制备。当固体表面活性剂或蜡组分的熔化或溶解是必需的时,这些可被加入表面活性剂预混物,或某部分的表面活性剂,在例如约72℃下,混合并加热以熔化固体组分。然后混合物可任选地通过剪切研磨器加工并冷却,然后将剩余组分混合。固体颗粒组分可在经过高剪切研磨处理前或优选在冷却后加到最终的混合物中。组合物典型地具有约2000至约20,000cps的最终粘度。组合物的粘度可通过常规方法,包括按需要加入氯化钠或二甲苯磺酸铵来调节。因此,所列制剂包括所列组分和任何与该组分相关的微量组分。
实施例组合物 | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 |
表面活性剂 | |||||||||||
月桂基聚氧乙烯醚-3硫酸铵 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 |
月桂基硫酸铵 | 6.00 | 6.00 | 6.00 | 6.00 | 7.00 | 7.00 | 7.00 | 7.00 | 6.00 | 6.00 | 6.00 |
辅助表面活性剂 | |||||||||||
鲸蜡醇 | 0.90 | ||||||||||
椰油酰胺MEA | 0.80 | ||||||||||
阳离子/聚合物 | |||||||||||
Polyquat 10(2) | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 |
稳定剂 | |||||||||||
乙二醇二硬脂酸酯 | 1.50 | ||||||||||
聚二甲基硅氧烷(17) | 0.25 | 2.00 | |||||||||
聚二甲基硅氧烷(18) | 0.50 | ||||||||||
环二甲基酮(20) | 0.50 | ||||||||||
壬基氟丁基/壬基氟异丁基甲基醚(21) | 0.50 | ||||||||||
Mobil P43合成油(22) | 0.10 | ||||||||||
Puresyn 6(MCP-1812)(23) | 0.30 | ||||||||||
三羟基硬脂精(24) | 0.25 | ||||||||||
粘度/pH/防腐剂 | |||||||||||
香料溶液 | 0.55 | 0.55 | 0.55 | 0.55 | 0.55 | 0.55 | 0.55 | 0.55 | 0.55 | 0.55 | 0.55 |
柠檬酸钠 | 0.45 | 0.45 | 0.45 | 0.45 | 0.45 | 0.45 | 0.45 | 0.45 | 0.45 | 0.45 | 0.45 |
柠檬酸 | 0.04 | 0.04 | 0.04 | 0.04 | 0.04 | 0.04 | 0.04 | 0.04 | 0.04 | 0.04 | 0.04 |
氯化钠 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 |
颗粒 | |||||||||||
沉淀二氧化硅(7) | 1.00 | 2.00 | |||||||||
聚甲基倍半硅氧烷(8) | 2.00 | 5.00 | 2.00 | 2.00 | |||||||
聚甲基倍半硅氧烷(9) | 1.00 | ||||||||||
聚二甲基硅氧烷/乙烯基聚二甲基硅氧烷交聚物粉末(10) | 2.00 | ||||||||||
聚乙烯(11) | 2.00 | ||||||||||
PTFE(12) | 1.00 | ||||||||||
Expancel DE091(13) | 0.25 | 1.00 | |||||||||
水和微量组分(适量至100%) |
(2)聚合物KG30M,得自Amerchol[电荷密度=1.9meq/g,分子量约1,250,000]
(7)Sipernat 22LS,得自Degussa
(8)Tospearl 240,得自GE Silicones
(9)Tospearl 3120,得自GE Siljcones
(10)9506化妆品颗粒,得自Dow Corning
(11)microsilk 419,得自MicroPowders,Inc。
(12)PTFE-20聚四氟乙烯粉末,得自Presperse,Inc。
(13)得自Expancel Corp。
(17)Viscasil 330M,得自通用电气Silicones
(18)60,000csk粒径约300nm的聚甲基硅氧烷的乳液,以DC1664得自Dow Corning
(20)SF1202十五烷基甲基硅氧烷,得自通用电气Silicones
(21)HFE7100,得自3M
(22)P43合成油,得自Mobil
(23)Puresyn 6(MCP-1812),得自Mobil Chemical Company,Edison,N.J.,U.S.A
(24)Thixin R,得自Rheox,Inc.。
实施例组成 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 | 20 | 21 |
表面活性剂 | ||||||||||
月桂基聚氧乙烯醚-3硫酸铵 | 10.00 | 10.00 | 10.00 | 10.00 | 9.00 | 9.00 | 10.00 | 6.50 | 6.50 | 10.00 |
月桂基硫酸铵 | 6.00 | 6.00 | 6.00 | 6.00 | 3.00 | 3.00 | 6.00 | 7.50 | 7.50 | 6.00 |
N-月桂酰胺基乙基-N-羟乙基乙酸钠 | 5.00 | 5.00 | ||||||||
辅助表面活性剂 | ||||||||||
椰油酰胺MEA | 1.20 | 1.20 | ||||||||
阳离子/聚合物 | ||||||||||
Polyquat 10(1) | 0.50 | 0.10 | 0.10 | |||||||
Polyquat 10(2) | 0.50 | 0.50 | ||||||||
瓜耳胶羟丙基三甲基氯化铵(3) | 0.50 | |||||||||
瓜耳胶羟丙基三甲基氯化铵(4) | 0.50 | |||||||||
瓜耳胶羟丙基三甲基氯化铵(5) | 0.30 | 0.15 | 0.15 | |||||||
聚(异丁烯酰氨基丙基三甲基氯化铵)(6) | 0.40 | 0.75 | 0.75 | 0.40 | ||||||
稳定剂 | ||||||||||
乙二醇二硬脂酸酯 | 0.36 | 0.36 |
PEG 14M(16) | 0.30 | 0.30 | 0.17 | 0.17 | ||||||
Varisoft 550(25) | 0.15 | 0.15 | ||||||||
Varisoft CB110(25) | 4.28 | 4.28 | ||||||||
聚二甲基硅氧烷(17) | 0.25 | 0.25 | 0.20 | |||||||
聚二甲基硅氧烷(18) | ||||||||||
异十二烷(19) | 1.80 | 1.80 | ||||||||
三羟基硬脂精(24) | 0.15 | 0.15 | ||||||||
粘度/pH/防腐剂 | ||||||||||
香料溶液 | 0.55 | 0.55 | 0.55 | 0.55 | 0.85 | 0.85 | 0.55 | 0.70 | 0.70 | 0.55 |
柠檬酸钠 | 0.45 | 0.45 | 0.45 | 0.45 | 0.45 | 0.45 | 0.45 | 0.45 | ||
柠檬酸 | 0.04 | 0.04 | 0.04 | 0.04 | 0.90 | 0.90 | 0.04 | 0.04 | 0.04 | 0.04 |
氯化钠 | 3.50 | 3.50 | 3.50 | 3.50 | 0.45 | 0.45 | 0.50 | 0.92 | 0.92 | 0.50 |
颗粒 | ||||||||||
沉淀二氧化硅(7) | 2.25 | 1.00 | ||||||||
聚甲基倍半硅氧烷(8) | 2.00 | 2.00 | 2.00 | 2.25 | ||||||
氧化铁(14) | 0.50 | |||||||||
Flamenco Velvet Pearl(TiO2/云母)(15) | 2.00 | |||||||||
Cloisonne Satin Bronze(氧化铁/云母)(15) | 2.00 | 4.00 | ||||||||
水和微量组分(适量至100%) |
(1)聚合物JR30M,得自Amerchol[电荷密度=1.25meq/g,分子量约900,000]
(2)聚合物KG30M,得自Amerchol[电荷密度=1.9meq/g,分子量约1,250,000]
(3)阳离子瓜耳胶,Aqualon提供[电荷密度=1.8meq/g,分子量约2,400,000]
(4)阳离子瓜耳胶,Aqualon提供[电荷密度=1.8meq/g,分子量约450,000]
(5)阳离子瓜耳胶Jaguar C17,得自Aqualon[电荷密度=0.9meq/g,分子量约2,200,000]
(6)Polycare 133,得自Rhodia[电荷密度=4.5meq/g,分子量约110,000]
(7)Sipernat 22LS,得自Degussa
(8)Tospearl 240,得自GE Silicones
(14)氧化铁红70101,得自Cardre,Inc.
(15)得自Engelhard,Corp
(16)Polyox WSR N-3000,得自Amerchol/Dow Chemical Company
(17)Viscasil 330M,得自通用电气Silicones
(18)60,000csk粒径约300nm的聚甲基硅氧烷的乳液,以DC1664得自Dow Corning
(19)Isopar G,得自Exxon Chemical
(24)Thixin R,得自Rheox,Inc.
(25)得自Witco
实施例组成 | 22 | 23 | 24 | 25 | 26 | 27 | 28 | 29 | 30 | 31 |
表面活性剂 | ||||||||||
月桂基聚氧乙烯醚-3硫酸铵 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | ||||
月桂基硫酸铵 | 7.00 | 7.00 | 7.00 | 7.00 | 7.00 | 7.00 | ||||
月桂基聚氧乙烯醚硫酸钠 | 10.00 | 10.00 | 10.00 | 10.00 | ||||||
月桂基硫酸钠 | 7.00 | 7.00 | 7.00 | 7.00 | ||||||
阳离子/聚合物 | ||||||||||
聚季铵盐-10(2) | 0.25 | 0.25 | 0.13 | 0.13 | 0.25 | 0.50 | 0.50 | 0.25 | ||
聚季铵盐-10(30) | 0.25 | |||||||||
聚季铵盐-10(31) | 0.25 | |||||||||
稳定剂 | ||||||||||
PEG 90M(29) | 0.10 | |||||||||
卡波姆(28) | 1.00 | |||||||||
三羟基硬脂精(24) | 0.25 | 0.25 | 0.50 | 0.25 | ||||||
粘度/pH/防腐剂 | ||||||||||
香料溶液 | 0.70 | 0.55 | 0.55 | 0.55 | 0.55 | 0.85 | 0.85 | 0.55 | 0.55 | 0.55 |
柠檬酸钠 | 0.45 | 0.45 | 0.23 | 0.23 | 0.45 | 0.23 | 0.23 | 0.45 | 0.45 | 0.45 |
柠檬酸 | 0.04 | 0.04 | 0.18 | 0.18 | 0.04 | 0.18 | 0.18 | 0.04 | 0.04 | 0.04 |
氯化钠 | 0.50 | 0.20 | 0.50 | 0.50 | 0.45 | 0.45 | 0.45 | 0.50 | 0.50 | 0.50 |
颗粒 | ||||||||||
沉淀二氧化硅(7) | 1.00 | 0.50 | 1.00 | 1.00 | 1.00 | |||||
聚甲基倍半硅氧烷(8) | 0.50 | |||||||||
聚甲基倍半硅氧烷(9) | 1.00 | |||||||||
球状二氧化硅MSS-500/H(26) | 1.00 | 1.00 | ||||||||
球状二氧化硅MSS-500/3N(27) | 0.50 | |||||||||
水和微量组分(适量至100%) |
(2)聚合物KG30M,得自Amerchol[电荷密度=1.9meq/g,分子量约1,250,000]
(7)Sipernat 22LS,得自Degussa[粒径约4微米,具体的表面积约175平方米/克]
(8)Tospearl 240,得自GE Silicones[粒径约4微米,具体的表面积约35平方米/克]
(9)Tospearl 3120,得自GE Silicones[粒径约12微米,具体的表面积约18平方米/克
(24)Thixin R,得自Rheox,Inc.
(26)得自KOBO Products Inc.[粒径约12微米,具体的表面积约750平方米/克
(27)得自kOBO Products Inc,[粒径约3微米,具体的表面积约60平方米/克
(28)Carbopol Ultrez 10,得自Noveon,Inc.
(29)Polyox WSR-301,得自Dow Chemical Company
(30)阳离子纤维素,Amerchol提供[电荷密度约2.4meq/g,分子量约2,000,000]
(31)阳离子纤维素,Amerchol提供[电荷密度约2.4meq/g,分子量约350,000]
实施例组成 | 32 | 33 | 34 | 35 | 36 | 37 | 38 | 39 | 40 | 41 |
表面活性剂 | ||||||||||
月桂基聚氧乙烯醚硫酸钠 | 0.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 8.00 | 8.00 |
月桂基硫酸钠 | 7.00 | 7.00 | 7.00 | 7.00 | 7.00 | 7.00 | 7.00 | 6.00 | 7.00 | 8.00 |
阳离子/聚合物 | ||||||||||
聚季铵盐-10(2) | 0.25 | 0.25 | 0.10 | 0.10 | ||||||
聚季铵盐-10(30) | 0.25 | 0.10 | ||||||||
聚季铵盐-10(31) | 0.50 | 0.10 | ||||||||
瓜耳胶羟丙基三甲基氯化铵(32) | 0.25 | 0.25 | ||||||||
稳定剂 | ||||||||||
PEG 90M(29) | 0.20 | 0.10 | ||||||||
卡波姆(28) | 0.50 | 0.20 | ||||||||
三羟基硬脂精(24) | 0.25 | 0.25 | 0.30 | 0.10 | ||||||
粘度/pH/防腐剂 | ||||||||||
香料溶液 | 0.55 | 0.55 | 0.70 | 0.55 | 0.55 | 0.85 | 0.85 | 0.55 | 0.55 | 0.55 |
柠檬酸钠 | 0.23 | 0.45 | 0.23 | 0.23 | 0.23 | 0.23 | 0.23 | 0.23 | 0.23 | 0.23 |
柠檬酸 | 0.18 | 0.04 | 0.18 | 0.18 | 0.18 | 0.18 | 0.18 | 0.18 | 0.18 | 0.18 |
氢氧化钠50% | 1.00 | 0.50 | ||||||||
氯化钠 | 0.50 | 0.20 | 0.50 | 0.50 | 0.45 | 0.45 | 0.45 | 0.50 | 0.50 | 0.50 |
颗粒 | ||||||||||
沉淀二氧化硅(7) | 1.00 | 1.00 | 1.00 | |||||||
沉淀二氧化硅(33) | 1.00 | |||||||||
球状二氧化硅mSS-500/H(26) | 0.50 | |||||||||
聚乙烯(34) | 2.00 | 0.50 | ||||||||
聚甲基倍半硅氧烷(8) | 1.00 | |||||||||
尼龙-12(35) | 1.00 | |||||||||
聚四氟乙烯(36) | 2.00 | |||||||||
水和微量组分(适量至100%) |
(2)聚合物KG30M,得自Amerchol[电荷密度=1.9meq/g,分子量约1,250,000]
(7)Sipernat 22LS,得自Degussa[粒径约4微米,具体的表面积约175平方米/克]
(8)Tospearl 240,得自GE Silicones[粒径约4微米,具体的表面积约35平方米/克]
(24)Thixin R,得自Rheox,Inc.
(26),得自KOBO Products Inc.[粒径约12微米,具体的表面积约750平方米/克
(28)Carbopol Ultrez 10,得自Noveon,Inc.
(29)Polyox WSR-301,得自Amerchol/Dow Chemical Company
(30)阳离子纤维素,Amerchol提供[电荷密度约2.4meq/g,分子量约2,000,000]
(31)阳离子纤维素,Amerchol提供[电荷密度约2.4meq/g,分子量约350,000]
(32)阳离子纤维素,Aqualon提供[电荷密度约2.4meq/g,分子量约600,000]
(33)Sipernat 360,得自Degussa Corp.[粒径约15微米,具体的表面积约50平方米/克
(34)microthene FN51000,得自Quantum Chemical
(35)SP-10,得自KOBO Products,Inc[粒径约10微米]
(36)FluroPURE 103C,得自Shamrock Technologies,Inc[粒径约5微米]
应该理解,本发明所述的实施例和具体实施方案仅仅是说明性的,在不背离本发明范围的情况下,本领域的普通技术人员可以对其进行各种修改和变化。
Claims (10)
1.洗发剂组合物,所述组合物包括:
a)约5至约50重量百分比的去污表面活性剂,
b)至少约0.1重量百分比的颗粒,所述颗粒的平均粒径小于约300微米,
c)至少约0.05重量百分比的阳离子聚合物,所述阳离子聚合物具有约10,000至约10,000,000的分子量和约0.9meq/gm至约7.0meq/gm的电荷密度,和
d)至少约20.0重量百分比的含水载体;
其中所述颗粒选自中空颗粒、固体颗粒以及它们的组合。
2.如权利要求1所述的组合物,其中所述阳离子聚合物的分子量为约100,000至约3,000,000。
3.如前述任一项权利要求所述的组合物,其中所述阳离子聚合物的电荷密度为约1.2meq/gm至约7meq/gm。
4.如前述任一项权利要求所述的组合物,其中所述阳离子聚合物的电荷密度为约1.5meq/gm至约5meq/gm。
5.如前述任一项权利要求所述的组合物,所述组合物包括约0.05重量百分比至约3重量百分比的所述阳离子聚合物。
6.如前述任一项权利要求所述的组合物,其中所述阳离子聚合物与所述颗粒的重量比率为约2∶1至约1∶30。
7.如前述任一项权利要求所述的组合物,其中所述阳离子聚合物与所述颗粒的重量比率为约1∶2至约1∶10。
8.如前述任一项权利要求所述的组合物,其中所述颗粒的平均粒径为约1微米至约80微米。
9.如前述任一项权利要求所述的组合物,其中所述颗粒的平均粒径为约3微米至约80微米。
10.通过施用安全有效量的如前述任一项权利要求所述的组合物来护理毛发的方法。
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US32684801P | 2001-10-03 | 2001-10-03 | |
US60/326,848 | 2001-10-03 | ||
US32838301P | 2001-10-10 | 2001-10-10 | |
US60/328,383 | 2001-10-10 | ||
US38688402P | 2002-06-07 | 2002-06-07 | |
US60/386,884 | 2002-06-07 |
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EP (1) | EP1434551A1 (zh) |
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Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US547660A (en) * | 1895-10-08 | Charles f | ||
DE4420880A1 (de) * | 1994-06-15 | 1995-12-21 | Wella Ag | Festigendes Haarreinigungsmittel |
FR2722092B1 (fr) * | 1994-07-11 | 1996-08-14 | Oreal | Composition capillaire solide contenant un agent structurant particulaire |
US5624666A (en) * | 1995-01-20 | 1997-04-29 | The Procter & Gamble Company | Anti-dandruff shampoos with particulate active agent and cationic polymer |
WO1997009031A1 (en) * | 1995-09-01 | 1997-03-13 | The Procter & Gamble Company | Hair styling shampoos containing organic oil |
KR100234547B1 (ko) * | 1995-12-26 | 1999-12-15 | 손경식 | 유성물질이 충진된 캡슐을 함유하는 샴푸 조성물 |
KR100296167B1 (ko) * | 1997-01-20 | 2001-08-07 | 조지안느 플로 | 막형성가능고분자입자및막형성불가능입자로이루어진막형성혼합물을케라틴섬유코팅제로서함유하는화장용조성물 |
US5985294A (en) * | 1997-11-05 | 1999-11-16 | The Procter & Gamble Company | Personal care compositions |
GB9725013D0 (en) * | 1997-11-26 | 1998-01-28 | Unilever Plc | Washing composition |
FR2773990A1 (fr) * | 1998-01-28 | 1999-07-30 | Rhodia Chimie Sa | Utilisation, dans les compositions cosmetiques, de polymeres cationiques pour vectoriser des oxydes mineraux par precipitation a la dilution. |
US6149898A (en) * | 1998-06-22 | 2000-11-21 | The Procter & Gamble Company | Hair styling compositions containing silicone microemulsions and cationic non-polymeric liquids |
US6451300B1 (en) * | 1999-05-03 | 2002-09-17 | The Procter & Gamble Company | Anti-dandruff and conditioning shampoos containing polyalkylene glycols and cationic polymers |
DE10050782A1 (de) * | 2000-10-13 | 2002-04-25 | Goldwell Gmbh | Haarpflegemittel |
FR2819411B1 (fr) * | 2001-01-18 | 2003-02-21 | Oreal | Composition cosmetique irisee et ses utilisations |
-
2002
- 2002-10-03 CN CNA028187938A patent/CN1558747A/zh active Pending
- 2002-10-03 JP JP2003532016A patent/JP2005504822A/ja active Pending
- 2002-10-03 US US10/263,531 patent/US20030108501A1/en not_active Abandoned
- 2002-10-03 CA CA002459919A patent/CA2459919A1/en not_active Abandoned
- 2002-10-03 MX MXPA04003009A patent/MXPA04003009A/es unknown
- 2002-10-03 WO PCT/US2002/031672 patent/WO2003028683A1/en active Application Filing
- 2002-10-03 EP EP02766482A patent/EP1434551A1/en not_active Withdrawn
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US8349300B2 (en) | 2007-04-19 | 2013-01-08 | The Procter & Gamble Company | Personal care compositions containing at least two cationic polymers and an anionic surfactant |
CN101686902B (zh) * | 2007-04-19 | 2013-08-21 | 宝洁公司 | 包含至少两种阳离子聚合物和一种阴离子表面活性剂的个人护理组合物 |
CN101716128B (zh) * | 2009-12-11 | 2012-07-11 | 广东名臣有限公司 | 一种透明调理洗发组合物及其制备方法 |
CN103458871A (zh) * | 2011-04-07 | 2013-12-18 | 宝洁公司 | 具有增强的聚丙烯酸酯微胶囊的沉积的调理剂组合物 |
CN103458871B (zh) * | 2011-04-07 | 2015-05-13 | 宝洁公司 | 具有增强的聚丙烯酸酯微胶囊的沉积的调理剂组合物 |
CN105102071A (zh) * | 2013-04-10 | 2015-11-25 | 宝洁公司 | 包含聚有机倍半硅氧烷颗粒的口腔护理组合物 |
CN105120960A (zh) * | 2013-04-10 | 2015-12-02 | 宝洁公司 | 包含聚有机倍半硅氧烷颗粒的口腔护理组合物 |
CN105120960B (zh) * | 2013-04-10 | 2018-06-22 | 宝洁公司 | 包含聚有机倍半硅氧烷颗粒的口腔护理组合物 |
CN108601953A (zh) * | 2015-10-29 | 2018-09-28 | 荷兰联合利华有限公司 | 个人清洁组合物 |
Also Published As
Publication number | Publication date |
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WO2003028683A1 (en) | 2003-04-10 |
JP2005504822A (ja) | 2005-02-17 |
MXPA04003009A (es) | 2004-07-15 |
CA2459919A1 (en) | 2003-04-10 |
EP1434551A1 (en) | 2004-07-07 |
US20030108501A1 (en) | 2003-06-12 |
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