CN1239879A - Conditioning shampoo composition containing emulsion polymerized polymers - Google Patents
Conditioning shampoo composition containing emulsion polymerized polymers Download PDFInfo
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/594—Mixtures of polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/60—Particulates further characterized by their structure or composition
- A61K2800/65—Characterized by the composition of the particulate/core
- A61K2800/654—The particulate/core comprising macromolecular material
Abstract
Disclosed are shampoo compositions which comprise from about 5 % to about 50 % by weight of an anionic detersive surfactant, from about 0.025 % to about 3 % by weight of an organic, cationic deposition polymer, from about 0.01 % to about 10 % by weight of an emulsion polymerized silicone wherein the polymer is derived from the polymerization of linear dimethylpolysiloxane monomers, and from about 20 % to about 94 % by weight water. The composition provides improved conditioning benefits such as wet and dry combing, and dry hair feel with minimal suppression of the shampoo lather.
Description
Invention field
The present invention relates to contain the conditioning shampoo composition of the selected polysiloxanes that obtains through emulsion polymerization, this polysiloxane polymer is obtained through emulsion polymerization by straight chain dimethyl polysiloxane monomer.
Background of invention
The conditioner shampoo that contains the various various combinations of detersive surfactant and hair conditioner is known.This class shampoo product generally contains anionic detersive surfactant and conditioner, as polysiloxanes, hydrocarbon ils, fatty acid ester or their mixture.Because only just can reach conditioning hair and hair washing effect simultaneously easily by a kind of hair products, this class shampoo is subjected to user's welcome all the more.
Although disclose the multiple shampoo that contains rinse additive, owing to various reasons, they can not be entirely satisfactory.Because cation opsonizing agent energy antistatic, the wet comb property of improvement also can make hair have a sensation that wets of silkiness, they are used for conditioning hair is very desirable.The problem that shampoo ran into is to have the consistency problem between the conventional cationic surfactant of the anion surfactant of good cleaning characteristics and the traditional conditioner of many conducts.By the adjustment form surface-active agent with improve cation opsonizing agent and reduce this disadvantageous interaction as possible.The cationic surfactant that has good abundant conditioning characteristic in the hair washing product is generally understood and anionic detersive surfactant generation mating reaction, makes the conditioning variation of described shampoo.Particularly, the employing soluble cation surfactant that can form the soluble ion coordination compound can not deposit on hair preferably.Can on hair, deposit though can form the soluble cation surfactant of insoluble ionic complex, the good hair opsonic action can not be provided, but also can make hair that sensation unclean and that smeared is arranged.Adopt insoluble cationic surfactant (for example, three cetyl ammonio methacrylates) that fabulous antistatic effect can be provided, but the good whole opsonic action can not be provided.Many cationic polymers can be piled up the sensation that causes undesirable " unclean " to be smeared on hair.Therefore, the consumption that generally will limit cationic polymer alleviates this problem.But this can limit the whole conditioning effect that will reach.In addition, cation opsonizing agent general (especially as a kind of composition of being discharged by shampoo composite time) can not reach best whole conditioning effect, particularly aspect " flexibility ".
The material that can improve hair soft is the nonionic siloxanes.In multiple different public publications, disclosed the polysiloxanes that can be used in the shampoo composite.These publications comprise USP 2,826,551 (Geen, on March 11st, 1958 authorized); USP 3,964,500 (Drakoff, on June 22nd, 1976 authorized); USP 4,364,837 (Pader, the mandates on the 21st of nineteen eighty-two December); And British patent 849,433 (Woolston, nineteen sixty JIUYUE 28 days).The compositions that contains siloxanes is disclosed in these patents, but owing to be difficult to make siloxanes in product, to keep fine dispersion and suspension, so these patents do not provide the product that is entirely satisfactory.In recent years, at USP 4,741,855 (Grote and Russell, on May 3rd, 1988 authorized) and USP 4,788, the hair conditioning shampoo compositions that contains stable insoluble silicone is disclosed among 066 (Bolich and the Williams, on November 29th, 1988 authorized).Although contain anionic detersive surfactant in these shampoo composites, concerning various hair qualitys, said composition still has fabulous whole conditioning effect in the fabulous cleaning characteristics of maintenance.
Recently, U.S.'s series application number 07/622,699 (Robert L.Wells, the application on the 5th of nineteen ninety December, now abandon) and continuation application series number 07/778, the conditioner shampoo that improves is provided in 765 (applications on October 21st, 1991), wherein discloses and contained anion surfactant, dispersive insoluble polysiloxanes in this shampoo, and the lower cationic polymer (being approximately higher than 0.4meq/gm) of some ionic strength.These compositionss have fabulous hair washing opsonic action to various hair qualitys, especially comprise having improved conditioning characteristic because of impaired hairs of factor such as hair dyeing processing, bleaching, hair-wavings.
Day disclosure special permission communique 56-72095 (on June 16th, 1981, people such as Hirota, Kao SoapCorp.) also discloses the shampoo that contains cationic polymer and silicone conditioning agent.Other patent application that relates to the shampoo of cation composition and polysiloxanes openly also comprises EP 0413417 (on February 20th, 1991 is open, people such as Harnett).
Other method that makes shampoo composite have the hair conditioning effect is to adopt the butyrous composition of feel.This constituents can improve the gloss and the brightness of hair.In shampoo formulation, oiliness composition and cation constituent can be used in combination.(on October 6th, 1979 is open for Japan characteristic communique 53-35902, Granted publication 54-129135, N.Uchino, Lion Yushi Co.) discloses hair care composition in, wherein contained cationic polymer, soap and at least 10% oily components of before or after hair washing, using.The oily components that is suitable for has hydro carbons, higher alcohol, fatty acid ester, glyceride and fatty acid.Japanese patent application 62[1987]-327266 (December in 1987 applications on the 25th, on July 4th, 1989 is open, publication number is put down [1987]-168612, composition of detergent is disclosed people such as Horie), wherein contain cationic surfactant and/or cationic polymer, anion surfactant, and suc as formula the specific ester shown in the RCOOR ', wherein R and R ' they are the straight or branched alkyl.
Attempt in order to the best of breed of cleaning characteristics and hair conditioning characteristic to be provided though carry out these, but still be desirable to provide shampoo composite with further improved conditioning performance.For example, still wish to improve the shampoo composite that its whole conditioning performance, especially Hair grooming contain polysiloxane and cation constituent: the aspects such as dry feeling of brightness after the processing and gloss, wet comb property and dried comb property, hair.For the shampoo that contains oiliness composition and cation constituent, still wish the dry feeling that improves its whole conditioning performance, particularly wet comb property and anti-entanglement, does comb property and hair.The content of one or both conditioners can cause unfavorable effect but only increase wherein, as makes the greasy and shortage full weight of hair.Need when promoting opsonic action, can not produce these troubles again.
Disclose a kind of trial among the WO 95/09599 (April 13 nineteen ninety-five is open, people such as Murray), be introduced into this paper as a reference.This patent disclosure a kind of shampoo composite, wherein contain the cationic polymer that is deposited in the solubility silicone oil (particularly dimethyl polysiloxane alcohol).When wherein polysiloxanes be particle mean size through emulsion polymerization and this Emulgating polymers be lower than 2 μ m, when preferably being lower than 1 μ m, this system is the most effective, for example can make conditioner be deposited on the hair equably.
The silicone oil that adds the aqueous emulsion form in conditioning shampoo composition is well known in the art.Conventional polysiloxanes emulsification method comprises the method for silicone oil through mechanical agitation formation emulsion, and emulsion polymerization method.Two kinds of methods all can obtain emulsion system, and the granularity of silicone oil is less than about 2 μ m in the emulsion, preferably are less than about 1 μ m, more preferably from about are lower than 0.5 μ m, especially preferably are less than about 0.3 μ m, also preferably are less than about 0.15 μ m, most preferably from about are lower than 0.1 μ m.Granularity through emulsive silicone oil generally is approximately higher than 0.01 μ m.
In the preparation process of high viscosity fluid and micro emulsion, can control the granularity of itself better through the polysiloxanes emulsion of emulsion polymerization.Viscosity is higher than the extremely difficult preparation of submicron order machinery emulsion of the siloxanes of 60000 centistokes.Because the easier preparation viscosity of emulsion polymerization method is higher than the emulsion of 60000 centistokes, transfers to the employing emulsion polymerization method at industrial production emphasis and prepare high viscosity submicron order silicone emulsion.
Find to influence the foam performance of conditioning shampoo composition at present by the polysiloxane emulsion that cyclosiloxane forms through emulsion polymerization.But the polysiloxane emulsion that is made by the polymerization of straight chain dimethyl polysiloxane can be used in the conditioning shampoo composition, and it is extremely low that it presses down bubble property.To this, hypothesis is thought and is filtered mutually into the surfactant phase from remaining cyclosiloxane from emulsion, plays defoamer or dirt carrier, thereby has reduced the foam performance of product.
Also find in the polysiloxanes that emulsion polymerization obtains by the polymer that obtains through polymerization by straight chain dimethyl polysiloxane monomer shown in the following formula foaminess of conditioning shampoo composition is not had adverse effect: HO-[Si (R
1R
2)-O-]
n-H, wherein n is approximately higher than 10.This is because reaction is more complete, and dimethyl polysiloxane alcohol composition has enough molecular weight, can avoid taking place the phenomenon that the surfactant phase is gone in a small amount of filter.
Therefore, an object of the present invention is to provide a kind of hair or skin conditioning shampoo composite of being used for, said composition has improved conditioning performance, the present invention also provides a kind of compositions, wherein improved conditioner can uniform deposition on hair or skin, a kind of compositions also is provided, has wherein adopted the dimethyl polysiloxane emulsion that obtains through emulsion polymerization by straight chain dimethyl polysiloxane monomer.
Summary of the invention
The present invention relates to be used for the conditioning shampoo composition of hair, wherein contain:
(A) 5-50% (weight) surfactant, they are selected from anion surfactant, have the zwitterionic surfactant or the amphoteric surfactant that are anionic linking group under the pH of compositions condition, and their mixture;
(B) about 0.025-3 (weight) %, the preferred organic cation deposited polymer of about 0.1-2% (weight), its cationic charge density is about 0.2-7meq/gm, preferably is about 0.6-2.0meq/gm, and its molecular weight is about 5,000-10,000,000;
(C) about 0.005-10 (weight) % is through the polysiloxanes of emulsion polymerization, and wherein this polymer is to be obtained through polymerization by the straight chain dimethyl polysiloxane monomer that is shown below:
HO-[Si(R
1R
2)-O-]
n-H
(D) about 20-94 (weight) % water.
Detailed Description Of The Invention
Shampoo composite of the present invention can comprise the basis of the present invention having been carried out qualification, and other additional or selectivity composition, component or the present invention limit composition.
Except as otherwise noted, all percents used herein, umber and ratio are all in the gross weight of shampoo composite.All these about the weight of ingredients listed all based on active quantities, thereby, except as otherwise noted, do not comprise the carrier or the by-product that may be present in the commercially available material.
Term " solvable " is meant that material can fully be dissolved in the water under 25 ℃ herein, and when being formed on concentration and being 0.1wt%, bore hole is viewed as a kind of clear solutions basically.In contrast, term " soluble " is meant that material can not fully be dissolved in the water under 25 ℃, and in the time of can not being formed on concentration and being 0.1wt%, bore hole is viewed as a kind of clear solutions basically.
Term " non-volatile " is meant that material has very little or almost do not have vapour pressure under environmental condition herein, and the boiling point under 1 atmospheric pressure preferably is at least about 250 ℃.Under this condition and at 25 ℃ or more under the low temperature, vapour pressure is preferably less than about 0.2mmHg, preferably less than about 0.1mmHg.
Shampoo composite of the present invention comprises basis and some selectivity composition, below it is elaborated.
The anionic detersive surfactant composition
Shampoo composite of the present invention comprises a kind of anionic detersive surfactant composition, so that compositions has clean-up performance.This anionic detersive surfactant composition comprises anionic detersive surfactant, have be the zwitterionic surfactant of anionic linking group or amphoteric surfactant under the pH of compositions, and these surfactant mixtures, the preferred anionic detersive surfactant.This surfactant should with basis described below at physics and chemically compatible, perhaps, it should not damage the stability of product, aesthstic sense organ or performance inadequately.
The anionic detersive surfactant that is applicable to shampoo composite of the present invention comprises the known surfactant that can be used in hair nursing or other personal care cleansing compositions.In shampoo composite, with composition weight meter, the concentration of anion surfactant composition should be enough to provide needed cleaning and frothing capacity, be generally about 5-50 (weight) %, preferred about 8-30 (weight) %, more preferably 10-25 (weight) %, most preferably from about 12-18 (weight) %.
The anion surfactant that preferably is applicable to shampoo composite is alkyl and alkyl ether sulfate.These materials have general formula R OSO separately
3M and RO (C
2H
4O)
xSO
3M, wherein R is alkyl or the alkenyl with about 8-18 carbon atom, and x is the integer of 1-10, and M is a cation, as ammonium, alkanolamine such as triethanolamine, monovalence metal such as sodium and potassium, multivalent metal cation such as magnesium and calcium.It is water miscible should selecting cation M to make anionic detersive surfactant.The dissolubility of surfactant depends on concrete anionic detersive surfactant and selected cation.
In alkyl and alkyl ether sulfate, preferred R has about 8-18 carbon atom, more preferably from about 10-16 carbon atom, most preferably from about 12-14 carbon atom.Alkyl ether sulfate is normally prepared by oxirane and the condensation product with monohydric alcohol of 8-24 carbon atom.Alcohol is can be synthetic, or they can make described fat by fat, as Oleum Cocois, palm-kernel oil, Adeps Bovis seu Bubali.The preferred pure and mild straight chain alcohol of lauryl that obtains by Oleum Cocois or palm-kernel oil.This alcohol is with gaseous state and about 0-10, preferably about 2-5, and the oxirane of 3 mol ratios more preferably from about, every mol of alcohol contains 3 moles of ethylene oxide in the gained mixture, then with its sulfuration, neutralization.
The limiting examples that the present invention can be used for the alkyl ether sulfate of shampoo composite comprises the vitriolic sodium salt of cocos nucifera oil alkyl triethylene glycol ether and ammonium salt, the vitriolic sodium salt of tallow alkyl triethylene glycol ether and ammonium salt and vitriolic sodium salt of tallow alkyl hexaoxyethylene and ammonium salt.Preferred alkyl ether sulfate contains the mixture of single component, and the average chain length of the component in the mixture is a 10-16 carbon atom, and ethoxylation degree is the 1-4 mole ethylene oxide.
Other suitable anionic detersive surfactant is the water soluble salt that generates behind the organic sulfur acid reaction, and its general formula is [R
1-SO
3-M], R wherein
1Contain 8-24 carbon atom, preferably contain straight or branched, the representative examples of saturated aliphatic alkyl of 10-18 carbon atom; M is aforesaid cation.The limiting examples of these detersive surfactants is methane series hydro carbons and sulfonating agent such as SO
2, H
2SO
4According to resulting salt behind known method of sulfonating (comprising bleaching and hydrolysis) the organic sulfur acidification reaction, preferred C
10-C
18The alkali metal salt and the ammonium salt of sulfonation normal alkane.Described methane series hydro carbons comprises and contains 8-24 carbon atom, preferably contain 12-18 carbon atom different-, newly-, just-alkane.
Other suitable anionic detersive surfactant be fatty acid with the isethionic acid esterification, again with in the sodium hydroxide and after product, fatty acid can be made by cocos nucifera oil or palm-kernel oil; The sodium salt of the fatty acid amide of methyl taurate or potassium salt, described fatty acid is made by Oleum Cocois or palm-kernel oil.USP2,486,921, USP 2,486,922 and USP 2,396,278 described other similar anion surfactant, be incorporated herein by reference.
Other is applicable to that the anionic detersive surfactant of shampoo composite is a succinate, example comprises N-disodium octadecyl sulfosuccinate, lauryl disodium sulfosuccinate, lauryl 2-Sulfosuccinic acid diammonium, N-(1,2-two carboxyethyls)-N-octadecyl succinic acid four sodium, sodium sulfosuccinate diamyl ester, sodium sulfosuccinate dihexyl and sodium sulfosuccinate dioctyl ester.
Other is applicable to that the anionic detersive surfactant of shampoo composite comprises the alkene sulfonate that contains 10-24 carbon atom.Term herein " alkene sulfonate " refers to the SO of alpha-olefin with non-complexation
3Sulfonation, under certain condition in and acidic mixture, make the sulfone hydrolysis that is generated in the reaction generate corresponding hydroxyl-paraffin sulfonate.SO
3Can be liquid state or gaseous state, usually but must not dilute with inert diluent.When using, use liquid SO with liquid form
2, dilution such as chlorinated hydrocabon, maybe when needs use gaseous state, with air, nitrogen, gaseous state SO
2Deng dilution.The alpha-olefin that can make alkene sulfonate is the monoolefine that contains 10-24 carbon atom, preferably contains 12-16 carbon atom.Preferred linear alkene.Except ideal alkene sulfonate and a part of hydroxyl-paraffin sulfonate, alkene sulfonate can contain a spot of other material such as alkene disulfonate, depends on reaction condition, reactant composition, the character of starting olefin and the side reaction in impurity in the raw material olefin and the sulfonating reaction process.The limiting examples of this alpha-alkene sulfonate mixture is seen USP 3,332,880, is incorporated herein by reference.
Another kind ofly be applicable to that the anion surfactant of shampoo composite is β-alkoxyl alkyl sulfonate.The general formula of these surfactants is:
Wherein, R
1For containing the straight chained alkyl of 6-20 carbon atom, R
2For containing the low alkyl group of 1-3 carbon atom, preferred 1 carbon atom, M is foregoing water-soluble cationic.
The anion surfactant that preferably is used for shampoo composite comprises: ammonium lauryl sulfate; lauryl polyethenoxy ether sodium sulfate; the lauryl sulfate triethylamine; laureth sulphuric acid triethylamine; triethanolamine lauryl sulfate; laureth sulphuric acid triethanolamine; lauryl sulfate monoethanolamine; laureth sulphuric acid monoethanolamine; lauryl sulfate diethanolamine; laureth sulphuric acid diethanolamine; glycerol monolaurate sodium sulfate; sodium lauryl sulfate; sodium laureth sulfate; lauryl potassium sulfate; the laureth potassium sulfate; sodium lauryl sarcosinate; sodium lauroyl sarcosine; the lauryl sarcosine; the cocoyl sarcosine; the cocoyl sarcosine; lauroyl ammonium sulfate; cocoyl sodium sulfate; lauroyl sodium sulfate; the cocoyl potassium sulfate; lauryl potassium sulfate; triethanolamine lauryl sulfate; triethanolamine lauryl sulfate; cocoyl sulphuric acid monoethanolamine; lauryl sulfate monoethanolamine; triethanolamine lauryl sulfate; cocoyl sulphuric acid monoethanolamine; lauryl sulfate monoethanolamine; the tridecyl benzene sulfonic acid sodium salt; dodecylbenzene sodium sulfonate and their mixture.
The amphion or the amphoteric detersive surfactants that are applicable to shampoo composite of the present invention comprise those known materials that can be used for hair nursing or other personal care cleansing compositions.With composition weight meter, the concentration of this amphoteric detersive surfactants is preferably about 0.5-20 (weight) %, preferably about 1-10 (weight) %.Suitable amphion or amphoteric surfactant are stated in following patent documentation: USP5,104,646 (Bolich Jr etc.), USP 5,106,609 (Bolich Jr etc.) are incorporated herein by reference.
The amphoteric detersive surfactants that is applicable to shampoo composite is well known in the art, the surfactant that comprises those aliphatic secondary amines and tertiary amines derived thing, wherein aliphatic group can be the straight or branched group, and, one of aliphatic series substituent group comprises about 8-18 carbon atom, and another substituent group comprises the water-soluble group of a kind of anion such as carboxyl, sulfonic group, sulfate radical, phosphate radical or phosphonate radical.
The zwitterionic detersive surfactants that is applicable to shampoo composite is well known in the art, comprise those be aliphatic quaternary ammonium, quaternary phosphine and season sulfonium compound the surfactant of derivant, wherein aliphatic group can be the straight or branched group, and, one of aliphatic series substituent group comprises about 8-18 carbon atom, and another comprises a kind of anionic group such as carboxyl, sulfonic group, sulfate radical, phosphate radical or phosphonate radical.Preferred zwitterionic surfactant such as betanin.
Shampoo composite of the present invention also can comprise additional surfactant, and these surfactants and aforesaid anionic detersive surfactant composition are used in combination.Suitable selective meter's surface-active agent comprises non-ionic surface active agent, cationic surfactant and its compositions.Can use any surfactant that is used for hair or personal-care supplies well known in the art, as long as the basis of this selectivity additional surfactants and shampoo composite is at physics and chemically compatible, perhaps, it should not damage stability, aesthetic feeling or the performance of product inadequately.The concentration of the selectivity additional surfactants in the shampoo composite can change according to other composition that exists in required cleaning or foam performance, selected surfactant, required product concentration, the compositions and other factors as known in the art.
The non-limiting example that is applicable to other aniones, amphion, both sexes or selectivity additional surfactants in the shampoo composite can be referring to following document: McCutcheon ' s, Emulsifiers andDetergents.1989 Annual is published by M.C.Publishing Co.; USP 3,929, and 678, USP2,658,072, USP 2,438,091, US 2,528,378, be incorporated herein by reference.
Deposited polymer
Deposited polymer is a basis of the present invention.Its consumption generally is about 0.01-5 (weight) %, preferably about 0.05-1 (weight) %, more preferably 0.08-0.5 (weight) %.This polymer can be a homopolymer, or is made of two or more monomers.Its molecular weight is about 5,000～10,000,000, preferred about 50,000～5,000,000.Most preferably from about 100,000～2,000,000 preferred deposition polymer is a cationic polymer, and preferably comprises nitrogen-containing group, as comprises quaternary ammonium salt or protonated amino, or their mixture.
Its cationic charge density should be at least about 0.1meq/g, preferably is approximately higher than 0.5meq/g, more preferably from about is higher than 0.8meq/g or higher.Cationic charge density should not surpass 5meq/g, preferably is less than 3meq/g, more preferably less than 2meq/g, can adopt the Kjeldahl method to measure charge density, and charge density should meet above-mentioned qualification under the pH condition in use.Described pH value is generally about 3-9, preferably about 4-8.
Cation nitrogen-containing group part exists with the form as the replacement of the part of the whole monomeric unit of cationic polymer usually.Therefore, when cationic polymer is not homopolymer, can comprise non-cationic monomeric unit at interval.These polymer are stated in following document: CTFA CosmeticIngredient Dictionary, the 3rd edition.
Suitable cationic polymer comprises vinyl monomer with cationic amine or quaternary ammonium functional group and the water solublity spacer monomers copolymer as (methyl) acrylamide, Methacrylamide, alkyl and dialkyl group (methyl) acrylamide, alkyl (methyl) acrylates, vinyl caprolactone and ethenyl pyrrolidone.The monomer that alkyl and dialkyl group replace preferably has C
1-C
7Alkyl group, more preferably C
1-C
3Alkyl group.Other suitable spacer monomers comprises vinyl esters, vinyl alcohol, maleic anhydride, propylene glycol and ethylene glycol.
Cationic amine can be primary amine, secondary amine or tertiary amine, decides on the pH of its kind and shampoo.General preferred primary amine and secondary amine, special preferred tertiary amine.
Vinyl monomer that amine replaces and amine can amine the form polymerization, then through the quaternized ammonium salt that changes into.
Suitable cationic amine and quaternary ammonium monomer comprise: use propenoic acid dialkyl aminoalkyl ester, the methacrylic acid dialkyl aminoalkyl ester, acrylic acid alkyl monosubstituted amino Arrcostab, methacrylic acid alkyl monosubstituted amino Arrcostab, trialkyl methacryloxy alkylammonium salt, trialkyl acryloxyalkyl ammonium salt, the vinyl compound that the diallyl quaternary ammonium salt replaces, with have ring-type and contain azo-cycle such as pyridine, the vinyl quaternary ammonium monomer of imidazoles and quaternized pyrrolidine, for example alkyl vinyl imidazoles and quaternized pyrrolidine are as the alkyl vinyl imidazoles, alkylvinylpyridines, alkyl vinyl ketopyrrolidine salt.These monomeric moieties are preferably low alkyl group such as C
1-C
3Alkyl, more preferably C
1And C
2Alkyl.
The vinyl monomer that suitable amine replaces comprises propenoic acid dialkyl aminoalkyl ester, methacrylic acid dialkyl aminoalkyl ester, dialkyl aminoalkyl acrylamide and dialkyl aminoalkyl Methacrylamide.Wherein, the preferred C of alkyl
1-C
7Alkyl, more preferably C
1-C
3Alkyl.
Cationic polymer of the present invention can contain the mixture of the monomeric unit that is obtained by amine and/or quaternary ammonium-substituted monomer and/or compatible spacer monomer.
Suitable cationic deposition polymer comprises 1-vinyl-2-pyrrolidine and 1-vinyl-3-methylimidazole salt (as chloride salt) (also being referred to as quaternized hydroxyethylcellulos-16 by " CTFA " industrial), as from the BASF Wyandotte (Parsippany of company, NJ, the commodity that U.S.A.) are purchased are called the copolymer of LUVIQUAT (as LUVIQUAT FC 370); 1-vinyl-2-pyrrolidine and dimethylaminoethyl acrylate methyl base amino-ethyl ester (also being referred to as quaternized hydroxyethylcellulos-11) by " CTFA " industrial, as from (the Wayne of ISP company, New Jersey, the commodity that U.S.A.) are purchased are called the copolymer of GAFQUAT (as GAFQUAT 755N); Cation contains the polymer of diallyl quaternary ammonium, comprise, for example: the copolymer of dimethyl diallyl ammonium chloride homopolymer and acrylamide and dimethyl diallyl ammonium chloride is referred to as quaternized hydroxyethylcellulos-6 and 7 by " CTFA " respectively industrial; And as the inorganic acid salt of the amino-Arrcostab of the homopolymer of the described unsaturated carboxylic acid that contains 3-5 carbon atom of US patent 4,009,256 and copolymer, this patent documentation also is incorporated herein by reference.
Other suitable cationic polymer comprises polysaccharide polymer, as cationic cellulose derivative and cationic starch derivative.Suitable cationic polysaccharide polymer comprises those polymer with following formula:
Wherein, A is the anhydroglucose residue, as starch or cellulose anhydroglucose residue; R is alkylidene oxygen base alkylidene, polyoxyalkylene or hydroxy alkylidene group, or its combination; R
1, R
2And R
3Be alkyl, aryl, alkaryl, aralkyl, alkoxyalkyl or alkoxy aryl independently of one another, each group comprises about at the most 18 carbon atoms, and the total carbon atom number of each cationic moiety (is R
1, R
2And R
3In the total number of carbon atoms) be preferably about 20 or still less; X is foregoing anionic counter-ion.
Cationic cellulose polymer can be from Amerchol Corp. (Edison, NJ, USA) Polymer JR that is purchased and LR series polymer, as reacting the salt that generates, also be referred to as quaternized hydroxyethylcellulos-10 by " CTFA " industrial with epoxide that replaces with trimethyl ammonium and hydroxyethyl-cellulose.Another type cationic cellulose comprises the epoxide of lauryl dimethyl ammonium-replacement and the polymeric quaternary ammonium salts that is generated of hydroxy ethyl fiber reaction, and " CTFA " is referred to as quaternized hydroxyethylcellulos-24 at industrial quilt.These materials can (USA), its trade name Polymer LM-200 be purchased for Edison, NJ from Amerchol Corp..
Other suitable cationic polymer comprises the cationic guar gum derivant, and as Rhaball Gum CG-M 8M, its instantiation comprises Jaguar series, can be purchased from Celanese Corporation.Other suitable cationic polymer comprises quaternized nitrogen-containing fiber ether, and its some example is stated in US patent 3,962,418, is incorporated herein by reference.Other suitable cationic polymer comprises the copolymer of etherified cellulose and starch, and the example is stated in US patent 3,958,581, is incorporated herein by reference.
Deposited polymer needn't be dissolved in the shampoo composite, but preferred cationic polymer or dissolve in the shampoo composite, perhaps preferably be dissolved in the complex coacervation mutually of shampoo composite, described condensed phase is formed by aforesaid cationic polymer and anionic detergent surfactant component.The complex coacervation of cationic polymer also can form (for example kayexalate) by the anion surfactant in the shampoo composite or other chosen anion composition that can add in the compositions mutually.
Various factors is depended in the formation of condensed phase, as charge density, pH and the temperature of the ratio of molecular weight, concentration, interactional ion component, ionic strength (comprising the change of ionic strength, for example by adding salt), cation and anion component.Coacervated system and acting in the following document of these parameters are stated: J Caelles etc., " anion in the mixed system and cation mixt (Anionic andCationic Compounds in Mixed Systems) ", " cosmetics and toilet articles " Cosmetics ﹠amp; Toiletries, 106 volumes, in April, 1991, pp 49-51; C.J.van Oss, " cohesion; compound reaction and flocculation reaction (Coacervation; Complex-Coacervation and Flocculation) ", J.DispersionScience and Technology, the 9th volume (5,6), 1988-89, pp 561-573 and D.J.Burgess, " actual analysis of complex coacervation system (Practical Analysis of Complex Coacervate Systems) ", J.of Colloid and Interface Science, the 14th the 1st phase of volume, November nineteen ninety, pp 227-238 all is incorporated herein by reference.
Cationic polymer is present in shampoo composite in the condensed phase, the shampoo on the perhaps coated or rinsing hair or to form condensed phase when hair rinses shampoo be very useful.Complex coacervation is easier to be deposited on the hair mutually.Therefore, usually the preferred cationic polymer exists with condensed phase in shampoo composite or form a kind of condensed phase when dilution.If in shampoo composite, do not form condensed phase, then preferably when dilute with water, cationic polymer will exist with complex coacervation phase form in shampoo, and wherein the amount ratio of water and shampoo composite is about 20: 1, be more preferably 10: 1, be more preferably 8: 1.
The technology whether the analysis complex coacervation forms mutually also is known in the art.For example, shampoo composite carries out microscopic analysis and all can be used for differentiating whether formed condensed phase under optional dilute strength.Use dyestuff to help to distinguish condensed phase and be scattered in mutually insoluble in the shampoo composite with other.
Preferred deposited polymer is selected from hydroxyalkyl cellulose ether and cationic guar derivative.Particularly preferred deposited polymer is Jaguar C13S, Jaguar C17, Jaguar C16 and JaguarC162.Other preferred cellulose ether comprises polymer JR400, JR30M and JR125.
Polysiloxane polymer through emulsion polymerization
Shampoo composite of the present invention contains non-volatile polysiloxanes Emulgating polymers, and this polymer is obtained through emulsion polymerization by straight chain dimethyl polysiloxane monomer.Concentration through emulsive polysiloxanes generally is about 0.005-10% (weight), preferably is about 0.05-5% (weight), is more preferably 0.1-4% (weight), is most preferably 0.2-3% (weight).Shampoo composite preferably contains dimethyl silica alkanol (dimethiconol).Dimethyl silica alkanol polysiloxanes can directly be used, or adopts the form through methyl blocking.Polysiloxanes through emulsion polymerization also can contain organo-functional group (amine, ester, quaternized thing etc.).Polysiloxanes through emulsion polymerization is known in the art, and at USP 2,891, states in 920,3,294,7225 and 3,360,491, as a reference.Dimethyl polysiloxane micro emulsion through emulsion polymerization is seen EP 268,982, and its full content is in conjunction with being incorporated herein by reference.
Being used for prevailing method that emulsion polymerization prepares polysiloxanes comprises the ring organopolysiloxane shown in the following formula is carried out emulsifying:
Wherein n is about 3-7, below is about 3-5.Then emulsive organopolysiloxane polymerization is formed the high viscosity polysiloxane fluid.This method is actually equilibrium step, wherein leaves about 10-15% (weight) cyclopolysiloxane in emulsion in mutually.
Shampoo composite of the present invention does not preferably contain substantially by the deutero-emulsion polymerization siloxanes of cyclopolysiloxane.Here the term of Cai Yonging " do not contain substantially " be meant contain in the compositions be less than about 1% (weight), more preferably from about be lower than 0.5% (weight), more preferably from about be lower than 0.2% (weight), more preferably from about be lower than 0.1% (weight), and most preferably from about be lower than the polysiloxanes that 0.05% (weight) is obtained through emulsion polymerization by the ring organopolysiloxane.
Other emulsion polymerization method that is used to prepare the high viscosity polysiloxane emulsion also comprises carries out emulsifying to the low molecular weight linear organopolysiloxane shown in the following formula:
HO-[Si(R
1R
2)O]
n-H
R wherein
1And R
2Can be identical or different, and can be selected from CH
3, organic functions alkyl peace treaty contains the straight or branched alkyl of 1-22 carbon atom; N is approximately greater than 10-100, preferably approximately greater than 15-100, more preferably from about greater than 20-75, more preferably from about greater than 20-50.Through this straight chain organopolysiloxane of condensation reaction polymerization, obtain the high viscosity polysiloxane polymer then.
Although in theory also unrestricted, the applicant believes that the employing cyclopolysiloxane can have a negative impact to the foaminess of conditioning shampoo composition through the polysiloxane emulsion that emulsion polymerization obtains.And can add in the conditioning shampoo composition by the polysiloxane emulsion that the straight chain dimethyl polysiloxane obtains through polymerization, it is very weak that it presses down bubble property.Although do not wish to exist in theory any restriction, the applicant believes that also remaining cyclopolysiloxane can filter into the surfactant phase mutually from emulsion, and the effect of defoamer and dirt carrier is arranged.Thereby can reduce the foaminess of product.Because the reaction of the polysiloxanes emulsified body that is obtained through polymerization by the straight chain dimethyl polysiloxane is more complete, and raw material has enough molecular weight and can avoid being filtered into the surfactant phase, so its foaminess to conditioning shampoo composition does not have adverse effect.
Can make the shampoo composite uniform deposition by low-molecular-weight straight chain organopolysiloxane through the polysiloxanes of the present invention that emulsion polymerization obtains, thereby make hair have the good conditioning effect as wet comb property and dried comb property, and dry and comfortable sensation.In addition, the polysiloxanes that is obtained through emulsion polymerization by low-molecular-weight straight chain organopolysiloxane can add in the conditioning shampoo composition, and it is very weak that it presses down bubble property.The granularity of the polysiloxanes that is obtained through emulsion polymerization by low-molecular-weight straight chain organopolysiloxane preferably is lower than 2 μ m, preferably be less than about 1 μ m, more preferably from about be lower than 0.5 μ m, more preferably from about be lower than 0.31 μ m, more preferably from about be lower than 0.15 μ m, most preferably from about be lower than 0.1 μ m.
Water
Shampoo composite of the present invention is an Aquo System, with composition weight meter, and the about 20-94 of its water content (weight) %, preferably about 50-90 (weight) %, more preferably from about 60-85 (weight) %.
The selectivity composition
Remove above-mentioned basis, also can contain one or more known selectivity compositions that is used for hair nursing or personal-care supplies in the shampoo composite of the present invention, as long as these selectivity compositions and basis as herein described are at physics and chemically compatible, perhaps, it should not damage stability, aesthetic feeling or the performance of product inadequately.The non-limiting example of these selectivity compositions sees " international cosmetic composition handbook (Intemational Cosmetic Ingredient Dictionary) the 5th edition (1993), and CTFA " cosmetic composition handbook the 2nd edition (1992) is all introduced in full as a reference.The non-limiting example of these selectivity compositions sees below.
Poly alkylene glycol
Also contain in the shampoo composite to be useful on and improve the foaminess poly alkylene glycol.The concentration of poly alkylene glycol accounts for the 0.01-5% (weight) of compositions, preferred about 0.05-3% (weight) in the shampoo composite, is more preferably 0.1-2% (weight).
Optionally the feature of poly alkylene glycol is shown in following general formula:
Wherein R is selected from H, methyl and their mixture.When R was H, these compositions were ethylene oxide polymer, are also referred to as polyethylene glycol oxide, Polyethylene Glycol.When R was methyl, these compositions were propylene oxide polymers, were also referred to as polypropylene oxide, polypropylene glycol.When R is methyl, can contain all places isomeric compound in the resulting polymers.
In the said structure formula, the meansigma methods of n is about 1500-25, and 000.Preferably be about 2500-20,000, be more preferably 3500-15,000.
The polyethylene glycol polymer that is suitable for has PEG-2M, and wherein R is H, and the meansigma methods of n is about 2000 (PEG-2M is also referred to as Polyox WSR N-10, available from Union Carbide, is also referred to as PEG-2000); PEG-5M, wherein R is H, n is about 5000 (PEG-5M is also referred to as PolyoxWSR N-35 and Polyox WSR N-80, all available from Union Carbide, is also referred to as PDG-5M and Polyethylene Glycol 30,0000); PEG-7M, wherein R is H, n is about 7000 (PEG-7M is also referred to as Polyox WSR N-750, available from Union Carbide), PEG-9M, wherein R is H, n is about 9000 (PEG-9M is also referred to as Polyox WSR N-3333, available from Union Carbide); And PEG-14M, wherein R is H, n is about 14000 (PEG-14M is also referred to as PolyoxWSR N-3000, available from Union Carbide).
Other remaining polymer comprises polypropylene glycol and polyethylene/polypropylene glycol mixture.
Suspending agent
Shampoo composite of the present invention also can comprise a kind of suspending agent, and its valid density can suspend selectivity silica alkane hair conditioner or other water-insoluble material in shampoo composite with discrete form.In shampoo composite weight, described concentration should be about 0.1-10 (weight) %, preferably about 0.3-5.0 (weight) %.
The selectivity suspending agent comprises the crystal type suspending agent, and it can range acyl derivative, long-chain amine oxide or its compositions, and in shampoo composite weight, its concentration is about 0.1-5.0 (weight) %, preferably about 0.5-3.0 (weight) %.These suspending agents are at USP 4,741, state in 855, are incorporated herein by reference.These preferred suspending agents comprise the glycol ester of fatty acid, and preferably it has about 16-22 carbon atom.More preferably glycol stearate comprises monoesters and diester, particularly comprises the stearic acid diester that is less than about 7% monoesters.Other suitable suspending agent comprises Marlamid, preferred its has about 16-22 carbon atom, more preferably have about 16-18 carbon atom, its preferred embodiment comprises: stearic acid monoethanolamide, Stearic acid diethanolamine salt, stearic acid list isopropanol amide and stearic acid monoethanolamide stearate.Other long acyl derivant comprises the long-chain ester (as stearoyl stearyl, palmityl cetyl ester etc.) of long-chain fatty acid; The long-chain ester of glyceride (as glycerol distearate) and long-chain alkanolamide (as stearmide diglycollic amide distearate, stearmide single ethanol amide stearate).Except preferred substance listed above, long acyl derivant, long-chain carboxylic acid's glycol ester, long chain amine oxide and long-chain carboxylic acid's alkanolamide also can be used as suspending agent.For example, can consider that use has C
8-C
22The suspending agent of long chain hydrocarbon groups.
Other is applicable to that the long acyl derivant as suspending agent comprises N, N-dialkyl amide groups benzoic acid and its soluble-salt (as sodium salt and potassium salt), the particularly N of this gang, N-two (hydrogenation) C
16, C
18With Adeps Bovis seu Bubali amide groups benzoic acid, it can (Northfield, Illinois USA) be purchased from Stepan Company.
Be applicable to that the example as the long chain amine oxide of suspending agent comprises alkyl (C
16-C
22) dimethyl oxidation amine, as stearoyl dimethyl oxidation amine.
Other suspending agent that is suitable for comprises xanthan gum, and in shampoo composite weight, its concentration is about 0.3-3 (weight) %, preferably about 0.4-1.2 (weight) %.In containing the shampoo composite of siloxanes, use xanthan gum for example to descend USP 4,788, state in 006, be incorporated herein by reference as suspending agent.The compositions of long acyl derivant and xanthan gum also can be used as suspending agent in shampoo composite.This USP4 that is combined in states in 704,272, is incorporated herein by reference.
Other suitable suspending agent comprises carboxy vinyl polymer.Wherein, preferred polymer is acrylic acid and polyene propyl group sucrose crosslinked copolymers, and as USP 2,798,053 is described, is incorporated herein by reference.The example of these polymer comprises Carbopol 934,940,941 and 956, can be purchased from B.F.Goodrich Company.
Other suspending agent that is suitable for comprises that aliphatic alkyl partly has the primary amine at least about 16 carbon atoms, the example comprises Petiolus Trachycarpi acid amide or Stearyl Amine, each alkyl has the secondary amine at least about 12 carbon atoms in two aliphatic alkyl parts that have, and the example comprises two palmitamides or two (hydrogenant Adeps Bovis seu Bubali) amine.Other suspending agent that is suitable for comprises two (h-tallow) phthalic acid amide and crosslinked maleic anhydride-methyl ethylene ether copolymer.
Other is applicable to that suspending agent in the shampoo composite comprises that those can give the material of compositions with gel sample viscosity, as water solublity or colloidal state water-soluble polymer sample cellulose ether (as methylcellulose, hydroxy butyl methyl cellulose, hydroxypropyl cellulose, hydroxypropyl emthylcellulose, hydroxyethyl ethylcellulose and hydroxyethyl-cellulose), guar gum, polyvinyl alcohol, polyvinylpyrrolidone, hydroxypropyl guar gum, starch and starch derivatives and other thickening agent, viscosity modifier, gellant etc.Also can use the mixture of these materials.
Other selectivity composition
The selectivity composition that is used for shampoo composite is including, but not limited to antiseptic such as benzyl alcohol, benzoic acid, methyl parahydroxybenzoate, propyl p-hydroxybenzoate, imidazolidinyl urea, iodo propine butyl carbamate, Methylisothiazolinone, methylchloroisothiazandnone; Salt and electrolyte such as sodium chloride, potassium chloride and sodium sulfate; Ammonium xylene sulfonate; Propylene glycol; Polyvinyl alcohol; Ethanol; PH regulator agent such as citric acid, succinic acid, phosphoric acid, sodium hydroxide, and sodium carbonate; Be used to improve the spice and the coloring agent of compositions aesthetic property; Hydrogen peroxide; Sunscreen; Hair dye; Wetting agent such as glycerol and other polyhydric alcohol; Moisturizing agent; Antioxidant; Chelating agen such as EDTA; Antiinflammatory; Steroid; Composition is beautified in the part; Salubrious agent of scalp such as menthol, but be not limited only to this.Cationic conditioning polymer also is applicable to shampoo composite.
Synthetic ester also is applicable to shampoo composite of the present invention, is used to improve and shampoo basis of the present invention, the wet soapy feeling of hair that particularly produces when shared with above-mentioned organic conditioning oil.The concentration of synthetic ester accounts for the 0.01-1.0% (weight) of compositions in the shampoo composite, preferably is about 0.05-0.5% (weight), is more preferably 0.08-0.3% (weight).
Also can adopt dandruff removing agent in the shampoo composite.These compositions comprise dandruff removing agent microgranule such as thiol pyridine (pyridinethione) salt, selenium compound such as selenium sulfide and solubility dandruff removing agent.The concentration of dandruff removing agent accounts for the 0.1-4% (weight) of compositions, preferably is about 0.2-2% (weight) in the shampoo composite.
Also can adopt lousicide to be used to the infection that prevents that louse from causing in the shampoo composite of the present invention.The lousicide that is suitable for is well known in the art, as cinerins, sees USP 4,668,666, is incorporated herein by reference.
Using method
Shampoo composite of the present invention can be according to conventional method with cleaning and conditioning hair or skin.Conventional method comprises that the product with effective dose is coated on hair or the skin, and preferred water makes its moistening, then it is rinsed.Effective dose is generally about 1-50 gram, preferably about 1-20 gram.Shampoo composite is coated on to generally include on the hair compositions is smeared on hair so that most of hair or all hairs contact with compositions.
The method of this cleaning and conditioning hair or skin comprises the steps:
A) use the water-wet hair; B) shampoo composite with effective dose is coated on the hair; C) cleaning hair with compositions, and d) water rinses shampoo composite from hair.As required, these steps can be repeatedly used, to reach needed cleaning and conditioning effect.
Embodiment
Adopt following examples to further specify the interior specific embodiments of the scope of the invention.Embodiment only is used for explanation, and the present invention is not constituted any limitation, and under the prerequisite that does not deviate from the spirit and scope of the present invention, may have a lot of different situations.The concrete scheme of the shampoo composite of the present invention of being given an example can clean hair and improve the conditioning characteristic of hair.Following compositions is named with chemical name, trade (brand) name and CTFA.
Preparation
Can adopt conventional mixing and preparation technique to prepare shampoo composite of the present invention.Prepare the described shampoo composite of following example I-XV by the following method.
With total alkyl sulfate surfactant (lauryl polyethenoxy ether sodium sulfate, add and/or ammonium lauryl sulfate with 25% solution form, add with 25% solution form) about 1/3 add the jacket type reactor, and, form surfactant solution through slowly being stirred and heated to about 74 ℃.In still, add coconut monoethanol amide and aliphatic alcohol, and make its dispersion.In mixing kettle, add the glycol distearate (EGDS) that is suitable for then, and make its fusing.EGDS if necessary, can add Polyethylene Glycol and antiseptic and make its mixing after fully disperseing (generally needing 5-20 minute approximately).Make this mixture by cools down to 35 ℃, and be collected in the finished product jar.Because this cooling step, glycol distearate forms the crystallization network structure in product.In the finished product jar, add remaining lauryl polyethenoxy ether sodium sulfate, lauryl sulfate and comprise other composition of polysiloxane emulsion, fully stir to guarantee to obtain uniform mixture.The polysiloxane emulsion that adds capacity is so that the polydimethylsiloxane in the final products reaches the content of expection.Before water dispersible polymers adding final mixture, general elder generation is scattered in the solution of making 1-10% (weight) in the water with it.After whole compositions all add, ammonium xylene sulfonate or additional sodium chloride be can add and thickening or diluted mixture thing are used for, make its viscosity reach desired value.Preferably under 25 ℃, range of viscosities is about 2500-9000CS (adopt Well-Brookfield cone-plate and plate viscometer to measure, rotating speed is 15 revolutions per seconds).Component embodiment number
--------adds water to the 100%--------component embodiment number to I II III IV V Texapon Special 24454 laureth-3 ammonium sulfate 86 12 10 12 cocoamidopropyl 00 2.5 0 1Jaguar C17 (5) 0.05 0.05 0.05 0.30 0.15 coconut monoethanol amides 0.5 0.5 0.80 0.80 0 cetanols 00 0.42 0.42 0.42 stearyl alcohols 00 0.18 0.18 0.18 glycol distearates 1.50 1.50 1.50 1.50 1.50EP polysiloxanes (1) 3.0 2.5 3.0 2.0 3.0 spice solution 0.70 0.70 0.70 0.70 0.70DMDM hydantoins, 0.37 0.37 0.37 0.37 0.37 colourant solutions (ppm) 64 64 64 64 64 water and impurity in right amount
VI VII VIII IX X laureth-3 ammonium sulfate 9.00 9.00 14.0 14.85 12.50 cocoamidopropyl 1.70 1.70 2.70 1.85 4.20 season hydroxyethylcellulose-10 (3) 0.05 0.02 0.15 0.15 0.15 coconut monoethanol amides 0.80 0.80 0.80 0.80 0 cetanol 00 0.42 0.42 0.42 stearyl alcohols, 00 0.18 0.18 0.18 glycol distearate 1.50 1.50 1.50 1.50 1.50EP polysiloxanes (4) 3.0 2.5 3.0 2.0 3.0 spice solution 0.70 0.70 0.70 0.70 0.70DMDM hydantoins, 0.37 0.37 0.37 0.37 0.37 colourant solution (ppm) 64 64 64 64 64 water and impurity-------in right amount add water to the 100%-------component embodiment number
Uride 0.37 0.37 0.37 0.37 0.37 colourant solution, 64 64 64 64 64 water and impurity-------in right amount add water to 100%------in XIO XII XIII XIV XV laureth-3 ammonium sulfate 14.0 14.00 14.00 9.00 9.00 cocoamidopropyl 2.70 2.70 2.70 1.70 1.70 season hydroxyethylcellulose-10 (6) 0 0.15 0.15 0.05 0.02 coconut monoethanol amides 0.80 0.80 0 0.80 0.80 cetanol 0 0.42 000 stearyl alcohols 0 0.18 000 glycol distearates 000 1.50 1.50Carbopol 981 (2) 0.50 0.50 0.50 0 0EP polysiloxanes (1) 3.0 2.5 3.0 2.0 3.0 essence solution 0.70 0.70 0.70 0.70 0.70DMDM
(1) the EP polysiloxanes is experiment that viscosity the is about 97000csk polydimethylsiloxane through emulsion polymerization, and its granularity is about 300nm, and it is by available from Dow Coming (2-1520; Straight chain raw material 13556-24) is made.
(2) Carbopol 981 is the Acusol772 Acusol771s available from B.F.Goodrich.
(3) Polyquatemium-10 is JR30M, available from the cationic cellulose derived polymer of Amerchol.
(4) the EP polysiloxanes is experiment that viscosity the is about 335000csk polydimethylsiloxane through emulsion polymerization, and its granularity is about 500nm, by available from Dow Corning (2-1520; PE106004) straight chain raw material is made.
(5) Jaguar C17 is available from the cationic polymer of Rhone-Poulenc.
(6) Polyquaternium-10 is JR 400, available from the cationic cellulose derived polymer of Amerchol.
The described shampoo composite of embodiment 1-XV all is embodiment of the present invention, has fabulous cleaning, foaming, gentleness, anti-dandruff (if necessary) and hair conditioning effect, the sensation after particularly having fabulous opsonic action and nursing one's health.
Claims (9)
1. conditioning shampoo composition, wherein contain:
(A) 5-50% (weight) anion surfactant, they are selected from anion surfactant, have the zwitterionic surfactant or the amphoteric surfactant that are anionic linking group under the pH of compositions condition, and their mixture;
(B) about 0.025-3 (weight) %, the preferred organic cation deposited polymer of about 0.1-2% (weight), its cationic charge density is about 0.2-5meq/gm, preferably is about 0.8-2.0meq/gm, and its mean molecule quantity is about 5,000-10,000,000;
(C) about 0.005-10 (weight) % is through the polysiloxanes of emulsion polymerization, and wherein this polymer is to be obtained through polymerization by the straight chain dimethyl polysiloxane monomer that is shown below:
HO-[Si (R
1R
2)-O-]
n-H is R wherein
1And R
2Can be identical or different, and be CH
3, or organic functions alkyl or contain the straight or branched alkyl of 1-22 carbon atom, n is 10-100, is preferably greater than 15-50; Know
(D) about 20-94 (weight) % water.
2. the compositions of claim 1, wherein the organic cation deposited polymer is selected from: cationic cellulose derivative, cationic starch derivative, cationic guar derivative, and their mixture.
3. the compositions of arbitrary claim during aforesaid right requires wherein contains in the said composition and is lower than 0.5% (weight), preferably is lower than the polysiloxanes that is obtained through emulsion polymerization by the ring organopolysiloxane of 0.2% (weight).
4. the compositions of arbitrary claim during aforesaid right requires, wherein the particle mean size through the polysiloxanes of emulsion polymerization is 0.01-2 μ m, preferred 0.01-0.5 μ m.
5. the preparation method of a conditioning shampoo composition, wherein said method comprises:
(a) preparation is through the polysiloxanes of emulsion polymerization, and wherein this polymer is to be obtained through polymerization by the straight chain dimethyl polysiloxane monomer that is shown below:
HO-[Si (R
1R
2)-O-]
n-H is R wherein
1And R
2Can be identical or different, and be CH
3, or organo-functional group alkyl or contain the straight or branched alkyl of 1-22 carbon atom, n is 10-100, is preferably greater than 15-50; With
(b) 0.005-10% is mixed with following component through the polysiloxanes of emulsion polymerization:
(i) about 5-50% (weight), preferred 8-30% anion surfactant,
(ii) about 20-94% (weight) water and
(iii) 0.025-3% (weight) organic cation deposited polymer.
6. the compositions in the claim 5, wherein the cationic charge density of organic cation deposited polymer is about 0.8-2.0meq/g.
7. claim 5 or 6 compositions, wherein the organic cation deposited polymer is selected from: cationic cellulose derivative, cationic starch derivative, cationic guar derivative, and their mixture.
8. the compositions in the claim 5,6 or 7 wherein contains in the compositions and is lower than 0.5% (weight), preferably is lower than the polysiloxanes that is obtained through emulsion polymerization by the ring organopolysiloxane of 0.2% (weight).
9. the compositions in the claim 5,6,7 or 8, wherein the particle mean size through the polysiloxanes of emulsion polymerization is 0.01-2 μ m, preferred 0.01-0.5 μ m.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US73821196A | 1996-10-25 | 1996-10-25 | |
| US08/738,211 | 1996-10-25 |
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| Publication Number | Publication Date |
|---|---|
| CN1239879A true CN1239879A (en) | 1999-12-29 |
Family
ID=24967040
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97180295A Pending CN1239879A (en) | 1996-10-25 | 1997-10-23 | Conditioning shampoo composition containing emulsion polymerized polymers |
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| Country | Link |
|---|---|
| EP (1) | EP0955990A1 (en) |
| JP (1) | JP2001503057A (en) |
| CN (1) | CN1239879A (en) |
| AR (1) | AR011001A1 (en) |
| AU (1) | AU4918597A (en) |
| BR (1) | BR9712678A (en) |
| CA (1) | CA2269822A1 (en) |
| CO (1) | CO4920202A1 (en) |
| IL (1) | IL129570A0 (en) |
| PE (1) | PE8599A1 (en) |
| WO (1) | WO1998018434A1 (en) |
| ZA (1) | ZA979572B (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7622294B2 (en) | 1997-03-14 | 2009-11-24 | Trustees Of Tufts College | Methods for detecting target analytes and enzymatic reactions |
| GB9726970D0 (en) * | 1997-12-19 | 1998-02-18 | Unilever Plc | Shampoo compositions |
| US6627183B1 (en) | 1998-07-30 | 2003-09-30 | The Procter & Gamble Company | Hair care compositions |
| AU8760598A (en) * | 1998-07-30 | 2000-02-21 | Procter & Gamble Company, The | Hair care compositions |
| US6451300B1 (en) | 1999-05-03 | 2002-09-17 | The Procter & Gamble Company | Anti-dandruff and conditioning shampoos containing polyalkylene glycols and cationic polymers |
| US6974569B2 (en) | 1999-05-03 | 2005-12-13 | The Procter & Gamble Company | Shampoos providing a superior combination anti-dandruff efficacy and condition |
| WO2001008643A1 (en) * | 1999-07-02 | 2001-02-08 | The Procter & Gamble Company | Hair conditioning compositon comprising cationic silicone emulsion |
| US6808701B2 (en) | 2000-03-21 | 2004-10-26 | Johnson & Johnson Consumer Companies, Inc. | Conditioning compositions |
| US6514918B1 (en) | 2000-08-18 | 2003-02-04 | Johnson & Johnson Consumer Companies, Inc. | Viscous, mild, and effective cleansing compositions |
| CN1658824A (en) | 2002-06-04 | 2005-08-24 | 宝洁公司 | Conditioning shampoo composition containing select cationic conditioning polymers |
| DE10234262A1 (en) * | 2002-07-27 | 2004-02-19 | Beiersdorf Ag | Hair shampoo for fine and oily hair |
| EP1587487A1 (en) * | 2003-01-27 | 2005-10-26 | The Procter & Gamble Company | Personal cleansing composition containing irregularly shaped particles and spherical particles |
| WO2004083251A2 (en) * | 2003-03-17 | 2004-09-30 | Wyeth Holdings Corporation | Mutant cholera holotoxin as an adjuvant and an antigen carrier protein |
| US8623341B2 (en) | 2004-07-02 | 2014-01-07 | The Procter & Gamble Company | Personal care compositions containing cationically modified starch and an anionic surfactant system |
| US20060293197A1 (en) * | 2005-06-24 | 2006-12-28 | The Procter & Gamble Company | Conditioning compositions comprising coacervate and conditioning agent |
| US7470651B2 (en) * | 2005-06-24 | 2008-12-30 | The Procter & Gamble Company | Clear conditioning compositions comprising coacervate |
| CN101217998A (en) | 2005-07-07 | 2008-07-09 | 宝洁公司 | Conditioning compositions comprising coacervate and gel matrix |
| US9427391B2 (en) | 2006-01-09 | 2016-08-30 | The Procter & Gamble Company | Personal care compositions containing cationic synthetic copolymer and a detersive surfactant |
| CN100543037C (en) * | 2006-09-30 | 2009-09-23 | 广州天赐高新材料股份有限公司 | The preparation method of hydrophobic modified cation cellulose ether |
| US9376648B2 (en) | 2008-04-07 | 2016-06-28 | The Procter & Gamble Company | Foam manipulation compositions containing fine particles |
| JP5683295B2 (en) * | 2011-01-31 | 2015-03-11 | ライオン株式会社 | Method for producing surfactant composition |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8912391D0 (en) * | 1989-05-30 | 1989-07-12 | Unilever Plc | Shampoo composition |
| ES2060070T5 (en) * | 1989-12-04 | 2005-03-16 | Unilever N.V. | COMPOSITION FOR HAIR TREATMENT. |
| GB9016100D0 (en) * | 1990-07-23 | 1990-09-05 | Unilever Plc | Shampoo composition |
| GB9117740D0 (en) * | 1991-08-16 | 1991-10-02 | Unilever Plc | Cosmetic composition |
| ATE141784T1 (en) * | 1991-10-29 | 1996-09-15 | Procter & Gamble | HAIR SHAMPOO FORMULATION WITH SILICONE, CATIONIC POLYMER AND LIQUID, OILY CONDITIONING AGENTS |
| WO1995009600A1 (en) * | 1993-10-01 | 1995-04-13 | The Procter & Gamble Company | Hair care compositions containing low melting point fatty alcohol and crosslinked polymeric thickener |
| CN1184415A (en) * | 1995-04-21 | 1998-06-10 | 普罗克特和甘保尔公司 | Shampoos with insoluble silicone conditioning agent and cationic polymer |
| BR9708281A (en) * | 1996-03-27 | 1999-08-03 | Procter & Gamble | Conditioning containing polyalphaolefins conditioner |
| US5932203A (en) * | 1996-03-27 | 1999-08-03 | Proctor & Gamble Company | Conditioning shampoo compositions containing select hair conditioning esters |
-
1997
- 1997-10-23 JP JP10520616A patent/JP2001503057A/en active Pending
- 1997-10-23 CA CA002269822A patent/CA2269822A1/en not_active Abandoned
- 1997-10-23 CN CN97180295A patent/CN1239879A/en active Pending
- 1997-10-23 CO CO97062280A patent/CO4920202A1/en unknown
- 1997-10-23 IL IL12957097A patent/IL129570A0/en unknown
- 1997-10-23 BR BR9712678-0A patent/BR9712678A/en not_active Application Discontinuation
- 1997-10-23 AU AU49185/97A patent/AU4918597A/en not_active Abandoned
- 1997-10-23 WO PCT/US1997/019273 patent/WO1998018434A1/en not_active Application Discontinuation
- 1997-10-23 EP EP97911919A patent/EP0955990A1/en not_active Withdrawn
- 1997-10-23 AR ARP970104891A patent/AR011001A1/en not_active Application Discontinuation
- 1997-10-24 ZA ZA9709572A patent/ZA979572B/en unknown
- 1997-10-27 PE PE1997000957A patent/PE8599A1/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AR011001A1 (en) | 2000-08-02 |
| IL129570A0 (en) | 2000-02-29 |
| CO4920202A1 (en) | 2000-05-29 |
| EP0955990A1 (en) | 1999-11-17 |
| CA2269822A1 (en) | 1998-05-07 |
| BR9712678A (en) | 1999-10-26 |
| ZA979572B (en) | 1998-05-21 |
| PE8599A1 (en) | 1999-03-10 |
| AU4918597A (en) | 1998-05-22 |
| JP2001503057A (en) | 2001-03-06 |
| WO1998018434A1 (en) | 1998-05-07 |
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