CN105931689A - Variable-wall-thickness glove preparation method and gloves prepared with method - Google Patents

Variable-wall-thickness glove preparation method and gloves prepared with method Download PDF

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Publication number
CN105931689A
CN105931689A CN201610379843.6A CN201610379843A CN105931689A CN 105931689 A CN105931689 A CN 105931689A CN 201610379843 A CN201610379843 A CN 201610379843A CN 105931689 A CN105931689 A CN 105931689A
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CN
China
Prior art keywords
glove
coagulator
rubber latex
wall thickness
aqueous solution
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CN201610379843.6A
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CN105931689B (en
Inventor
徐对功
廖益传
张鹏程
谭树刚
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Institute of Materials of CAEP
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Institute of Materials of CAEP
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    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21FPROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F3/00Shielding characterised by its physical form, e.g. granules, or shape of the material
    • G21F3/02Clothing
    • G21F3/035Gloves
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00Gloves
    • A41D19/04Appliances for making gloves; Measuring devices for glove-making

Abstract

The invention discloses a variable-wall-thickness glove preparation method and a pair of gloves prepared with the method, and belongs to the field of preparation of protective devices. A coagulant with different concentration is applied to different positions of a glove mold, and one-time total impregnation with rubber emulsion is performed, so that variable wall thickness is realized at any part of the gloves. Special processing of the glove mold is not needed, and local thickening can be realized with adoption of the conventional glove mold, so that the flexibility of the gloves is guaranteed on the premise that the protection requirements are met. The method has greatly high adaptability, the flexibility of the prepared gloves can be guaranteed on the premise that the protection requirements are met, and the operation feel of a user is improved. Radiation protective gloves prepared with the method can protect the hand back of a doctor in a interventional therapy environment or other environments and can particularly meet the requirements for protection against X-rays, gamma-rays and neutrons, and the gloves can integrate the characteristics of protection and flexibility in use on the premise that the hand back of the doctor under an interventional therapy is protected effectively.

Description

A kind of become wall thickness glove preparation method and the glove of preparation thereof
Technical field
The present invention relates to protective device preparation field, especially radiation protection product scope, be specially one and become wall thickness glove system Preparation Method and the glove of preparation thereof.The present invention can realize glove not by a mass-impregnation on the basis of existing mold Prepare with the change wall thickness at position.Use change wall thickness protective gloves prepared by the present invention, especially become wall thickness X-ray protection glove, Can be used in the protection to doctor's the back of the hand position in intervention operation and bone surgery, there is preferable protection effect and application prospect.
Background technology
In nuclear industry and the field of nuclear medicine, the radiation protection rubber gloves used is to wait wall thickness glove.Lead on wall thickness glove Frequently with general glove mould, it is prepared from by the way of mass-impregnation.In order to reach preferable protection effect, adopting When the wall thickness glove such as preparing by ordinary glove mould mass-impregnation method, need to add the wall thickness of large glove;Thus, prepared hands Set is the most thick and heavy, when using or perform the operation, can affect the operating handle of doctor, and then the corresponding operation of impact.
Chinese patent CN201010202804.1 discloses a kind of radiation-proof rubber protective gloves and preparation method thereof, and it can realize Decay to X-ray about 50%.But, practice have shown that: in order to reach preferable protection effect, this protective gloves needs That does is thicker.Therefore, this protective gloves is only suitable to simple operations, it is impossible to be used for getting involved the accurate operations such as operation, bone surgery.
In order to solve foregoing problems, inventor's one becomes wall thickness radiation protection glove (application number: 201520612087.8), its By the local of glove is repeatedly impregnated, thus realize becoming the preparation of wall thickness protective gloves.
Meanwhile, inventor also disclose a kind of for prepare become the female mold of wall thickness glove and preparation thereof glove (application number: 201510831861.9).This invention is mainly by the improvement of mould itself, thus realizes glove change wall thickness and prepare.It realizes The mechanism that glove become wall thickness is based primarily upon three aspects: one is owing to the groove of mould can accommodate more latex, it is achieved thicken;Two It is owing to the hydrophilic of groove surfaces is more preferable, more latex can be loaded;Three is owing to the hydrophilic of groove surfaces is more preferable, can bear Carry more coagulator, coagulator good water absorption, more latex after Dipped latex, can be loaded.
In order to preferably simplify the preparation becoming wall thickness glove, inventor provides a kind of new change wall thickness glove preparation method and system thereof Standby glove.
Summary of the invention
Applicant is found by research, X-ray, gamma-rays, neutron radiation application in, X-ray, gamma-rays, neutron The most direct and serious to the irradiation damage at operator's the back of the hand position.And existing wait wall thickness protective gloves in use, flexibly Property poor, it is impossible to meeting the needs of doctor's finger flexible operating, therefore, doctor is often reluctant to wear and existing waits wall thickness lead to prevent Hand guard glove.Therefore, in the urgent need to exploitation one, there is preferable radiation protection effect, flexible accurate operation requirement can be met again Protective gloves, i.e. becomes wall thickness glove.
The goal of the invention of the present invention is: for the problem of above-mentioned existence, it is provided that a kind of change wall thickness glove preparation method and system thereof Standby glove.The present invention by coating the coagulator of variable concentrations at the different parts of glove mould, and is soaked by once overall Stain rubber latex such that it is able to realize becoming wall thickness to any position of glove.The present invention is without carrying out special adding to glove mould Work, uses existing glove mould can realize local and thickeies, thus on the premise of effectively protection, it is ensured that glove flexible Property.The present invention has extremely strong adaptability, and prepared glove can be on the premise of meeting requirement of shelter, it is ensured that glove Motility, improves the operating handle of user.The radiation protection gloves using the present invention to prepare disclosure satisfy that the rings such as intervention operation Protection to doctor's the back of the hand under border, enables in particular to meet the protection needs of X-ray, gamma-rays, neutron, and it can be to intervention Operative doctor the back of the hand effectively protect in advance under, it is ensured that finger manipulation operation motility, effectively take into account protection and use Feature flexibly.The present invention is reasonable in design, easy to use, uses a mass-impregnation can prepare change wall thickness glove, tool There is preferable application prospect, for becoming the preparation of wall thickness glove, there is important directive significance.
To achieve these goals, the present invention adopts the following technical scheme that
A kind of change wall thickness glove preparation method, comprises the steps: to coat the solidifying of variable concentrations at the different parts of fingerprint mould Gu agent, by mass-impregnation of fingerprint mould of coating coagulator in rubber latex, then shape, dry, post processing, i.e. Can.
Comprise the steps:
(1) by after clean for fingerprint mold clean, mass-impregnation the first coagulator, it is dried, obtains the first intermediate mold;
(2) on the first intermediate mold that step (1) obtains, topical application the second coagulator, it is dried, obtains in second Between mould;
(3) the second intermediate mold mass-impregnation is kept 5s~10min in rubber latex, then shape, dry, obtain the 3rd Intermediate;
(4) by the mould crimping of the 3rd intermediate, sulfuration, the demoulding, foam washing, it is dried, obtains glove finished product.
In described second coagulator, the mass percent of solute is more than the mass percent of solute in the first coagulator.
In described step (1), the first coagulator is CaCl2Aqueous solution, BaCl2Aqueous solution, Ca (NO3)2Aqueous solution, Ba (NO3)2 One or more in aqueous solution, and CaCl2Aqueous solution, BaCl2Aqueous solution, Ca (NO3)2Aqueous solution, Ba (NO3)2Water-soluble In liquid, the mass fraction of solute is 0.3~5%;
In described step (2), the second coagulator is CaCl2Aqueous solution, BaCl2Aqueous solution, Ca (NO3)2Aqueous solution, Ba (NO3)2 In one or more in aqueous solution, and the second coagulator, the mass fraction of solute is 5~80%.
In described second coagulator, the mass fraction of solute is 6%~60%.
Possibly together with starch and thickening agent in described first coagulator, the second coagulator.
In described step (2), on the first intermediate mold that step (1) obtains, topical application the second coagulator, it is dried, Repeat aforementioned second coagulator coating, dry run several times, obtain the second intermediate mold.
In described step (3), rubber latex uses rubber latex, compounding ingredient, radiation protection material to mix, described in join Mixture includes vulcanizing agent, vulcanization accelerator, age resistor, reinforcing agent, ammonia, soft water.
Described rubber latex is water based emulsion, and described rubber latex includes natural rubber latex, Neoprene latex, butyronitrile rubber Glue latex, styrene butadiene rubber latex, polyurethane rubber latex, butadiene rubber latex, acrylate rubber latex, chlorinated polyethylene One or more in alkene rubber latex, CSM latex.
Described radiation protection material include the one in X-ray protection material, NEUTRON PROTECTION material, gamma-rays protective material or Multiple.
Use glove prepared by preceding method, including glove bulk, the thickening layer arranged on glove bulk, described glove bulk Use one-body molded with thickening layer.
The thickness of described thickening layer is 0.05~50 times of glove bulk thickness.
The thickness of described glove bulk is 0.1~0.3mm, and the thickness of described thickening layer is 0.2~2.5mm.
Described glove bulk, described glove bulk includes metacarpus, thumb parts, forefinger parts, middle finger, the third finger Parts, little finger parts, described metacarpus include centre of the palm part, the palm back piece, described palm back piece is provided with thickening layer, described in add Thick-layer uses one-body molded with palm back piece.
On described thumb parts, the area of thickening layer is 0.1~0.7 times that thumb parts are positioned at palm back piece side area, described On forefinger parts, the area of thickening layer is 0.1~0.7 times that forefinger parts are positioned at palm back piece side area.
On described thumb parts, the area of thickening layer is 0.1~0.7 times that thumb parts are positioned at palm back piece side area, described On forefinger parts, the area of thickening layer is 0.1~0.7 times that forefinger parts are positioned at palm back piece side area, and described middle finger adds The area of thick-layer is 0.1~0.7 times that middle finger is positioned at palm back piece side area, the area of thickening layer on described nameless parts Be positioned at 0.1~0.7 times of palm back piece side area for nameless parts, on described little finger parts, the area of thickening layer is little finger Parts are positioned at 0.1~0.7 times of palm back piece side area.
On the basis of previous experiments, applicant, in reality research and development, production process, finds not transform mould itself, Also the method for the present invention can be used to realize the change wall thickness of glove different parts.The present invention is coated with by the different parts at fingerprint mould Cover the coagulator of variable concentrations, by mass-impregnation of fingerprint mould of coating coagulator in rubber latex, then shape, dry Dry, post processing, to realize present invention purpose.
Further, the mechanism that the present invention realizes locally thickening is as follows: owing to the second coagulator is higher than the first coagulant concentration, Coagulator has water absorption, and after dipping rubber latex, the mold potential energy being coated with the second coagulator loads more latex. The present invention can preferably realize the local of glove and thicken, and prepares that protection effect is good, the change wall thickness glove of flexible operation.Adopt When preparing glove by the present invention, single-steeping molding can be realized, be effectively simplified production procedure, reduce production cost.
In sum, using the method for the present invention can prepare change wall thickness glove, prepared protective gloves has protection effect The best, the feature of flexible operation, enables in particular to meet the protection needs of X-ray.Use the present invention can prepare change wall thickness Protective gloves, especially prepares the X-ray protection glove becoming wall thickness, and prepared glove can be used for getting involved operation and orthopaedics hands Protection to doctor's the back of the hand position in art, has preferable protection effect and application prospect.Protective gloves prepared by the present invention During for getting involved operation and bone surgery, both can guarantee that the motility of glove, and can effectively protect again, thus be vast Medical worker provides practical, is effectively protected.
Accompanying drawing explanation
Examples of the present invention will be described by way of reference to the accompanying drawings, wherein:
Fig. 1 is the production technological process of embodiment 2,3,4,5.
Fig. 2 is the prepared structural representation becoming wall thickness glove of embodiment.
Labelling in figure: 1 is thumb parts, 2 is forefinger parts, and 3 is middle finger, and 4 is nameless parts, and 5 is little thumb Finger, 6 is palm back piece, and 7 is thickening layer.
Detailed description of the invention
All features disclosed in this specification, or disclosed all methods or during step, except mutually exclusive feature And/or beyond step, all can combine by any way.
Any feature disclosed in this specification, unless specifically stated otherwise, all can be by other equivalences or the replacement spy with similar purpose Levy and replaced.I.e., unless specifically stated otherwise, an example during each feature is a series of equivalence or similar characteristics.
Embodiment 1
The step that the present embodiment preparation becomes wall thickness natural emulsion glove is as follows.
(1) ordinary glove mold clean is dried, mass-impregnation the first coagulator, then it is dried.In the present embodiment, the One coagulator uses mass fraction to be the CaCl of 0.5%2Aqueous solution.
(2) in locally sprayed second coagulator in the glove mould back of step (1), the dash area of Fig. 2 is seen at spraying position, Then it is dried.This step can be repeated several times.In the present embodiment, the second coagulator uses mass fraction to be the CaCl of 10%2Water Solution.In the present embodiment, glove bulk include metacarpus, thumb parts, forefinger parts, middle finger, nameless parts, Little finger parts, metacarpus includes centre of the palm part, palm back piece, the palm back piece, thumb parts, forefinger parts is respectively arranged with and adds Thick-layer, thickening layer uses one-body molded with palm back piece.
(3) by 4kg vulcanizing agent sulfur, 4kg activating agent ZnO, 4kg vulcanization accelerator ZDC, 1kg antioxidant D, 0.1kg After Nekal BX, 0.5kg ammonia mix with 15kg soft water, carry out ball milling, obtain fluid,matching.Described Nekal BX chemistry Entitled nekal.
(4) natural rubber latex after being filtered with 100kg by the fluid,matching of step (3) mixes, and filters, maturation 2 days, De-bubble, obtains dipping rubber latex.
(5) the mould entirety of step (2) is immersed in rubber latex prepared by step (4), and keeps 30s~10min, Then hang down drip, shape, dry, crimping.
(6) by the mold releasability of step (5), decocting in water sulfuration, foam washing, it is dried, wall thickness glove finished product must be become.
Change the dipping number of times of step (2), the retention time of step (5) respectively, prepare the change wall thickness glove of respective thickness, Measurement result is as shown in table 1 below.
The change wall thickness glove of table 1 embodiment 1 preparation
Step (2) dipping number of times Step (5) retention time Do not thicken part thickness Thicken part thickness
Condition 1 2 30s 0.10mm 0.31mm
Condition 2 2 1min 0.13mm 0.53mm
Condition 3 3 90s 0.14mm 0.85mm
Condition 4 1 2min 0.16mm 0.62mm
Condition 5 3 5min 0.19mm 1.30mm
Condition 6 5 8min 0.30mm 1.35mm
Pass through experimental data, it will thus be seen that it is 0.31~1.35mm that glove prepared by the present embodiment thicken the thickness at position, not The thickness thickening position is 0.1~0.30mm.Use the present invention can successfully prepare change wall thickness glove, there is preferably effect Really.
Embodiment 2
The step that the present embodiment prepares natural emulsion material change wall thickness radiation protection glove is as follows.
(1) ordinary glove mold clean is dried, mass-impregnation the first coagulator, then it is dried.In the present embodiment, the One coagulator uses mass fraction to be the CaCl of 5%2Aqueous solution.
(2) in locally sprayed second coagulator in the glove mould back of step (1), the dash area of Fig. 2 is seen at spraying position, Then it is dried.This step can be repeated several times.In the present embodiment, the second coagulator uses mass fraction to be the CaCl of 60%2Water Solution.In the present embodiment, glove bulk include metacarpus, thumb parts, forefinger parts, middle finger, nameless parts, Little finger parts, metacarpus includes centre of the palm part, palm back piece, the palm back piece, thumb parts, forefinger parts is respectively arranged with and adds Thick-layer, thickening layer uses one-body molded with palm back piece.
(3) by 4kg vulcanizing agent sulfur, 4kg activating agent ZnO, 4kg vulcanization accelerator ZDC, 1kg antioxidant D, 0.1kg After Nekal BX, 0.5kg ammonia mix with 15kg soft water, carry out ball milling, obtain fluid,matching 1.
(4), after 20kg bismuth oxide powder, 0.1kg Nekal BX, 0.5kg ammonia being mixed with 10kg soft water, ball is carried out Mill, obtains fluid,matching 2.
(5) natural rubber latex after the fluid,matching 2 of the fluid,matching 1 of step (3), step (4) being filtered with 100kg Mixing, filters, maturation 2 days, de-bubble, obtains dipping rubber latex.
(6) the mould entirety of step (2) is immersed in the rubber latex of step (5), and keep 30s~10min, then Hang down drip, shape, dry, crimping.
(7) by the mold releasability of step (6), decocting in water sulfuration, foam washing, it is dried, wall thickness glove finished product must be become.
Change the dipping number of times of step (2), the retention time of step (6) respectively, prepare the change wall thickness glove of respective thickness, Measurement result is as shown in table 2 below.
The change wall thickness glove of table 2 embodiment 2 preparation
Step (2) dipping number of times Step (6) retention time Do not thicken part thickness Thicken part thickness
Condition 1 2 30s 0.14mm 0.42mm
Condition 2 2 1min 0.19mm 0.95mm
Condition 3 3 90s 0.21mm 1.35mm
Condition 4 1 2min 0.23mm 1.27mm
Condition 5 3 5min 0.27mm 1.92mm
Condition 6 5 8min 0.30mm 2.45mm
Pass through experimental data, it will thus be seen that it is 0.42~2.45mm that glove prepared by the present invention thicken the thickness at position, does not adds The thickness at thick position is 0.14~0.3mm.Use the present invention can successfully prepare change wall thickness glove, there is preferable effect.
Through actual application verification, radiation-resistant gloves prepared by the present embodiment has preferable protection effect, it is possible to anti-meeting On the premise of protecting requirement, it is ensured that the motility of glove, improve the operating handle of user.Through getting involved the reality of operative doctor etc. Application, it is possible to meet the requirement of accurate operation, there is preferable effect.
Embodiment 3
The step that the present embodiment prepares butyronitrile material change wall thickness radiation protection glove is as follows.
(1) ordinary glove mold clean is dried, mass-impregnation the first coagulator, then it is dried.In the present embodiment, the Ca (the NO that one coagulator uses mass fraction to be 3%3)2Aqueous solution.
(2) in locally sprayed second coagulator in the glove mould back of step (1), the dash area of Fig. 2 is seen at spraying position, Then it is dried.This step can be repeated several times.In the present embodiment, the Ca (NO that the second coagulator uses mass fraction to be 20%3)2 Aqueous solution.
(3) by 3kg vulcanizing agent sulfur, 5kg activating agent ZnO, 3kg vulcanization accelerator ZDC, 1kg antioxidant D, 5kg After reinforcing agent white carbon black, 0.1kg Nekal BX, 0.5kg ammonia mix with 15kg soft water, carry out ball milling, obtain fluid,matching 1.
(4), after 20kg gadolinium oxide powders, 0.1kg Nekal BX, 0.5kg ammonia being mixed with 10kg soft water, ball is carried out Mill, obtains fluid,matching 2.
(5) the nitrile rubber latex after the fluid,matching 2 of the fluid,matching 1 of step (3), step (4) being filtered with 100kg Mixing, filters, maturation 2 days, de-bubble, obtains dipping rubber latex.
(6) the mould entirety of step (2) immersed in the rubber latex of step (5) and keep 30s~10min, then hanging down Drip, shape, dry, crimping.
(7) by the mold releasability of step (6), hot-air cure, foam washing, it is dried, wall thickness glove finished product must be become.
Change the dipping number of times of step (2), the retention time of step (6) respectively, prepare the change wall thickness glove of respective thickness, Measurement result is as shown in table 3 below.
The change wall thickness glove of table 3 embodiment 3 preparation
Step (2) dipping number of times Step (6) retention time Do not thicken part thickness Thicken part thickness
Condition 1 2 40s 0.11mm 0.36mm
Condition 2 2 75s 0.15mm 0.85mm
Condition 3 3 90s 0.16mm 1.26mm
Condition 4 1 200s 0.21mm 1.50mm
Condition 5 3 5min 0.23mm 1.71mm
Condition 6 5 8min 0.25mm 2.31mm
It is 0.3~2.5mm that the glove of preparation thicken the thickness at position, and the thickness not thickening position is 0.1~0.3mm.
Applying through reality, the present invention has preferable protection effect, and disclosure satisfy that the requirement of accurate operation etc..
Embodiment 4
The step that the present embodiment prepares neoprene material change wall thickness radiation protection glove is as follows.
(1) ordinary glove mold clean is dried, mass-impregnation the first coagulator, then it is dried.In the present embodiment, the One coagulator uses mass fraction to be the CaCl of 4.5%2Aqueous solution.
(2) in locally sprayed second coagulator in the glove mould back of step (1), the dash area of Fig. 2 is seen at spraying position, Then it is dried.This step can be repeated several times.In the present embodiment, the second coagulator uses mass fraction to be the CaCl of 40%2Water Solution.
(3) by 4kg vulcanizing agent sulfur, 4kg activating agent ZnO, 4kg vulcanization accelerator ZDC, 1kg antioxidant D, 5kg After reinforcing agent white carbon black, 0.1kg Nekal BX mix with 15kg soft water, carry out ball milling, obtain fluid,matching 1.
(4), after 20kg tungsten oxide powder, 0.1kg Nekal BX being mixed with 10kg soft water, carry out ball milling, joined Close liquid 2.
(5) Neoprene latex after the fluid,matching 2 of the fluid,matching 1 of step (3), step (4) being filtered with 100kg Mixing, filters, maturation 2 days, de-bubble, obtains dipping rubber latex.
(6) the mould entirety of step (2) immersed in the rubber latex of step (5) and keep 30s~10min, then hanging down Drip, shape, dry, crimping.
(7) by the mold releasability of step (6), hot-air cure, foam washing, it is dried, wall thickness glove finished product must be become.
Change the dipping number of times of step (2), the retention time of step (6) respectively, prepare the change wall thickness glove of respective thickness, Measurement result is as shown in table 4 below.
The change wall thickness glove of table 4 embodiment 4 preparation
Step (2) dipping number of times Step (6) retention time Do not thicken part thickness Thicken part thickness
Condition 1 2 30s 0.12mm 0.39mm
Condition 2 2 1min 0.17mm 0.91mm
Condition 3 3 90s 0.20mm 1.30mm
Condition 4 3 2min 0.22mm 1.53mm
Condition 5 3 5min 0.25mm 1.88mm
Condition 6 3 8min 0.27mm 2.42mm
Pass through experimental data, it will thus be seen that it is 0.39~2.42mm that glove prepared by the present invention thicken the thickness at position, does not adds The thickness at thick position is 0.12~0.27mm.Use the present invention can successfully prepare change wall thickness glove, there is preferable effect.
Embodiment 5
The step that the present embodiment prepares natural emulsion material change wall thickness NEUTRON PROTECTION glove is as follows.
(1) ordinary glove mold clean is dried, mass-impregnation the first coagulator, then it is dried.In the present embodiment, the One coagulator uses mass fraction to be the CaCl of 5%2Aqueous solution.
(2) in locally sprayed second coagulator in the glove mould back of step (1), the dash area of Fig. 2 is seen at spraying position, Then it is dried.This step can be repeated several times.In the present embodiment, the second coagulator uses mass fraction to be the CaCl of 15%2Water Solution, this CaCl2Aqueous solution is the alginic acid of 1% possibly together with the carboxymethyl starch sodium that mass fraction is 2% and mass fraction Sodium.
(3) 4kg (weight kg) vulcanizing agent sulfur, 4kg activating agent ZnO, 4kg vulcanization accelerator ZDC, 1kg are prevented After old agent D, 0.1kg Nekal BX, 0.5kg ammonia mix with 15kg soft water, carry out ball milling, obtain fluid,matching 1.
(4), after 20kg boron carbide powder, 0.1kg Nekal BX, 0.5kg ammonia being mixed with 10kg soft water, ball is carried out Mill, obtains fluid,matching 2.
(5) natural rubber latex after the fluid,matching 2 of the fluid,matching 1 of step (3), step (4) being filtered with 100kg Mixing, filters, maturation 2 days, de-bubble, obtains dipping rubber latex.
(6) the mould entirety of step (2) immersed in the rubber latex of step (5) and keep 30s~10min, then hanging down Drip, shape, dry, crimping.
(7) by the mold releasability of step (6), decocting in water sulfuration, foam washing, it is dried, wall thickness glove finished product must be become.
Change the dipping number of times of step (2), the retention time of step (6) respectively, prepare the change wall thickness glove of respective thickness, Measurement result is as shown in table 5 below.
The change wall thickness glove of table 5 embodiment 5 preparation
Step (2) dipping number of times Step (6) retention time Do not thicken part thickness Thicken part thickness
Condition 1 2 30s 0.13mm 0.32mm
Condition 2 2 1min 0.18mm 0.77mm
Condition 3 3 90s 0.21mm 1.19mm
Condition 4 1 2min 0.25mm 1.40mm
Condition 5 3 5min 0.28mm 1.83mm
Condition 6 5 8min 0.30mm 2.04mm
Pass through experimental data, it will thus be seen that it is 0.32~2.04mm that glove prepared by the present invention thicken the thickness at position, does not adds The thickness at thick position is 0.13~0.3mm.Use the present invention can successfully prepare change wall thickness glove, there is preferable effect.
The invention is not limited in aforesaid detailed description of the invention.The present invention expands to any new spy disclosed in this manual Levy or any new combination, and the arbitrary new method that discloses or the step of process or any new combination.

Claims (10)

1. one kind becomes wall thickness glove preparation method, it is characterized in that, comprise the steps: that the different parts at fingerprint mould coats the coagulator of variable concentrations, by mass-impregnation of fingerprint mould of coating coagulator in rubber latex, shape again, dry, post processing,.
Become wall thickness glove preparation method the most according to claim 1, it is characterised in that comprise the steps:
(1) by after clean for fingerprint mold clean, mass-impregnation the first coagulator, it is dried, obtains the first intermediate mold;
(2) on the first intermediate mold that step (1) obtains, topical application the second coagulator, it is dried, obtains the second intermediate mold;
(3) the second intermediate mold mass-impregnation is kept 5s ~ 10min in rubber latex, then shape, dry, obtain the 3rd intermediate;
(4) by the mould crimping of the 3rd intermediate, sulfuration, the demoulding, foam washing, it is dried, obtains glove finished product.
Become wall thickness glove preparation method the most according to claim 2, it is characterised in that in described step (1), the first coagulator is CaCl2Aqueous solution, BaCl2Aqueous solution, Ca (NO3)2Aqueous solution, Ba (NO3)2One or more in aqueous solution, and CaCl2Aqueous solution, BaCl2Aqueous solution, Ca (NO3)2Aqueous solution, Ba (NO3)2In aqueous solution, the mass fraction of solute is 0.3~5%;
In described step (2), the second coagulator is CaCl2Aqueous solution, BaCl2Aqueous solution, Ca (NO3)2Aqueous solution, Ba (NO3)2In one or more in aqueous solution, and the second coagulator, the mass fraction of solute is 5~80%.
Become wall thickness glove preparation method the most according to claim 2, it is characterised in that possibly together with starch and thickening agent in described first coagulator, the second coagulator.
Become wall thickness glove preparation method the most according to claim 2, it is characterised in that in described step (2), on the first intermediate mold that step (1) obtains, topical application the second coagulator, it is dried, repeat aforementioned second coagulator coating, dry run several times, obtain the second intermediate mold.
6. according to becoming wall thickness glove preparation method described in any one of claim 2 ~ 5, it is characterized in that, in described step (3), rubber latex uses rubber latex, compounding ingredient, radiation protection material to mix, and described compounding ingredient includes vulcanizing agent, vulcanization accelerator, age resistor, reinforcing agent, ammonia, soft water.
Become wall thickness glove preparation method the most according to claim 6, it is characterized in that, described rubber latex is water based emulsion, and described rubber latex includes one or more in natural rubber latex, Neoprene latex, nitrile rubber latex, styrene butadiene rubber latex, polyurethane rubber latex, butadiene rubber latex, acrylate rubber latex, chlorinated polyethylene rubber latex, CSM latex.
8. according to becoming wall thickness glove preparation method described in claim 6 or 7, it is characterised in that described radiation protection material includes one or more in X-ray protection material, NEUTRON PROTECTION material, gamma-rays protective material.
9. use glove prepared by preceding method, it is characterised in that include that glove bulk, the thickening layer arranging on glove bulk, described glove bulk and thickening layer use one-body molded.
The glove that the most according to claim 9, prepared by method, it is characterised in that the thickness of described thickening layer is 0.05 ~ 50 times of glove bulk thickness.
CN201610379843.6A 2016-05-31 2016-05-31 A kind of gloves for becoming wall thickness gloves preparation method and its preparation Active CN105931689B (en)

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CN106418819A (en) * 2016-11-15 2017-02-22 中国工程物理研究院材料研究所 Method for forming latex gloves without baking
WO2017028748A1 (en) * 2015-08-14 2017-02-23 中国工程物理研究院材料研究所 Thickness-variable radiation protection gloves
CN106566013A (en) * 2016-11-10 2017-04-19 哈尔滨汉盾辐射防护技术开发有限公司 Anti-X, gamma ray and neutron radiation shielding material and preparation method thereof
CN107361439A (en) * 2017-09-08 2017-11-21 中国工程物理研究院材料研究所 A kind of gloves for the method and its preparation for preparing Varying-thickness gloves
WO2018049645A1 (en) * 2016-09-18 2018-03-22 Institute Of Materials, China Academy Of Engineering Physics Preparation method of latex gloves for neutron shielding and the gloves
CN109393607A (en) * 2018-12-06 2019-03-01 天长市恒生医疗器械有限公司 A kind of antibacterial sweat-absorbing medical rubber glove and preparation method thereof
CN111201576A (en) * 2017-09-21 2020-05-26 奥马尔·奥马尔-帕夏 Protective glove for blocking penetrating radiation
WO2021110804A1 (en) 2019-12-05 2021-06-10 Universität Rostock Medical protective glove
CN113001848A (en) * 2021-02-24 2021-06-22 桂林恒保健康防护有限公司 Preparation method of medical gloves with uniform thickness

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WO2017028748A1 (en) * 2015-08-14 2017-02-23 中国工程物理研究院材料研究所 Thickness-variable radiation protection gloves
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CN107361439A (en) * 2017-09-08 2017-11-21 中国工程物理研究院材料研究所 A kind of gloves for the method and its preparation for preparing Varying-thickness gloves
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CN111201576A (en) * 2017-09-21 2020-05-26 奥马尔·奥马尔-帕夏 Protective glove for blocking penetrating radiation
CN109393607A (en) * 2018-12-06 2019-03-01 天长市恒生医疗器械有限公司 A kind of antibacterial sweat-absorbing medical rubber glove and preparation method thereof
WO2021110804A1 (en) 2019-12-05 2021-06-10 Universität Rostock Medical protective glove
CN113001848A (en) * 2021-02-24 2021-06-22 桂林恒保健康防护有限公司 Preparation method of medical gloves with uniform thickness

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