CN105542597A - Heat-reflection thermal-insulation high-lightness base material and preparation method thereof - Google Patents

Heat-reflection thermal-insulation high-lightness base material and preparation method thereof Download PDF

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Publication number
CN105542597A
CN105542597A CN201510973436.3A CN201510973436A CN105542597A CN 105542597 A CN105542597 A CN 105542597A CN 201510973436 A CN201510973436 A CN 201510973436A CN 105542597 A CN105542597 A CN 105542597A
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heat
parts
high brightness
minute
insulating high
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CN105542597B (en
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洪杰
周龙生
李祥文
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Skshu Paint Co Ltd
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Skshu Paint Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention relates to a heat-reflection thermal-insulation high-lightness base material and which is prepared from the following components, by weight: 20-30 parts of water, 0.3-0.38 parts of a thickening agent, 0.1-0.35 parts of a multifunctional aid, 0.4-0.7 parts of a dispersing agent, 0.1-0.3 parts of a sterilization antiseptic, 0.1-0.3 parts of a mould inhibitor, 0.3-0.5 parts of a wetting agent, 12-18 parts of micron-grade titanium white, 4-10 parts of a functional filler, 18-23 parts of a common filler, 0.2-0.6 parts of a defoaming agent, 2-3 parts of a co-solvent, 1.8-2.4 parts of a film-forming aid, and 30-40 parts of pure acrylic emulsion. The base material has the following advantages: the high-lightness base material prepared with the combination of the components and ratio provided by the invention has superior comprehensive performances such as excellent sunlight reflectivity, various colors, and the capability of substantially reducing indoor temperature.

Description

A kind of heat-reflecting heat-insulating high brightness base-material and preparation method thereof
Technical field
The present invention relates to technical field of coatings, particularly a kind of heat-reflecting heat-insulating high brightness base-material and preparation method thereof.
Background technology
Heat-reflecting insulating coating can make coated article produce thermoregulator effect under solar light irradiation, comprises solar energy shielding coating, solar heat reflection paint, space thermal insulating coating, energy-saving and heat-insulating paint, temperature reduction IR camouflage paint etc.Wherein, sun reflective coating be by the sunlight of reflecting part wavelength to reach the object of heat insulation and heat control, be also called reflectivity energy-saving coatings.The type coating uses simple, and energy-saving effect is obvious, is widely applied to the multiple fields such as building, oil, transport, is the focus of current thermal insulating coating research.
Traditionally, high-reflectivity titanium dioxide is for optimizing the reflection of visible ray, if add color paste toning, sunlight reflectivity will decline to a great extent.In order to enable coloured surface keep nice and cool under sunlight, to the reflection of near infrared (IR) light sightless in solar spectrum becomes most important because the heat of this part spectrum generation is maximum.
At present, the heat-reflecting insulating coating that market is sold mostly is white, and utilize cenosphere and high-reflectivity titanium white to be major function color stuffing, sunlight reflectivity is higher, but color is single, can not meet the various requirement of exterior coating color of building field.Colored heat reflection coatings is because of the high-absorbable at visible light wave range, and it uses and popularization is restricted.
Summary of the invention
The invention provides a kind of heat-reflecting heat-insulating high brightness base-material and preparation method thereof, heat-reflecting heat-insulating high brightness base-material of the present invention be applied in excellent to the reflecting effect of near infrared (IR) light sightless in solar spectrum on colored heat reflection coatings, significantly can reduce room temp, make heat reflection coatings color no longer single, adjustable polychrome.
A kind of heat-reflecting heat-insulating high brightness base-material, formulated according to following ratio of weight and number by following component:
Described thickening material is Natvosol.
Described multifunctional assistant is be alkaline pH adjusting agent.
Described dispersion agent is polycarboxylate sodium.
Described fungicidal preservative is isothiazolinone biocide agent.
Described mould inhibitor is octylisothiazolinone class mould inhibitor.
Described wetting agent is nonionogenic tenside.
Described micron order titanium white is the Rutile type Titanium Dioxide material of size distribution in 1000 ~ 1200nm, a kind of high infrared reflection rate obtained by change TiO2 crystallographic dimension and the filler of high-weatherability.
Described functional filler is that hollow nano microballoon and far infrared ceramic powder mix according to 1:0.8-1.
Described hollow nano microballoon is the spheroid that a kind of hollow is airtight, pulverous Ultralight packing material, effectively can completely cut off heat; Described far infrared ceramic powder for by inorganic mineral, nonmetal oxide and metal oxide synthesize calcining and obtain a kind of white powder, radiation-curable go out far ir ray more more than normal object.
Described common fillers is that titanium dioxide, calcined kaolin and coarse whiting mix according to 1:0.8-1:3.5-4.
Described defoamer is mineral oil defoaming agent.
Described solubility promoter is propylene glycol.
Described film coalescence aid is alcohol ester 12.
Described pure-acrylic emulsion is acrylate and alkylmethacrylate polymer.
A preparation method for heat-reflecting heat-insulating high brightness base-material, comprises the step of sequentially carrying out as follows:
(1) water of 20-30 part is added in dispersion cylinder, under speed, added the thickening material of 0.3-0.38 part at 300-600r/ minute, stir 15-20 minute, thickening material is dissolved completely;
(2) then keep above-mentioned rotating speed, add the defoamer of 0.1-0.35 part multifunctional assistant, 0.4-0.7 part dispersion agent, 0.1-0.3 part fungicidal preservative, 0.1-0.3 part mould inhibitor, 0.3-0.5 part wetting agent and 0.1-0.3 part, stir 10-15 minute;
(3) then keep above-mentioned rotating speed to add 12-18 part micron order titanium white, 4-10 part functional filler and 18-23 part common fillers, improve rotating speed afterwards to 1300-1800r/ minute, stir 10-15 minute;
(4) finally reduce rotating speed to 300-600r/ minute, add 0.1-0.3 part defoamer, 2-3 part solubility promoter, 1.8-2.4 part film coalescence aid and 30-40 part pure-acrylic emulsion successively, stir 10-15 minute, obtain product of the present invention.
Principle of the present invention: adopt the graceful Altiris550 titanium white of Hensel as heat reflection function of tonic chord pigment in the present invention, by changing the crystallographic dimension of rutile type, can reflect near infrared light effectively, realize the possibility of colored heat reflection coatings.In addition, add cenosphere and far infrared ceramic powder in formula, the former can reduce the thermal conductivity of film, and the latter can improve the hemispherical reflectance of film.Three with the use of, significantly can reduce room temp, make heat reflection coatings color no longer single, adjustable polychrome.
Beneficial effect of the present invention: a kind of heat-reflecting heat-insulating high brightness base-material tool prepared by the present invention has the following advantages: adopt component of the present invention and proportioning to combine the high brightness base-material over-all properties prepared superior, there is excellent sunlight reflectivity, adjustable polychrome, significantly can reduce room temp.Base-material of the present invention also has excellent weathering resistance, water-alkali resistance.
Embodiment
In following product, described thickening material is preferably NATROSOL (sub-to dragon) the 250HBR Natvosol that Ashland company of the U.S. produces;
Described multifunctional assistant is preferably the AMP-95 that LG-DOW company produces;
Described dispersion agent is preferably the OROTANCA2500 that LG-DOW is produced;
Described fungicidal preservative is preferably the production of Sol company of Britain rS;
Described mould inhibitor is preferably the production of Sol company of Britain ePW;
Described wetting agent is preferably the SN-WET996 that Japanese Nuo Puke produces;
Described defoamer is preferably the DispelairCF246 that England Blackburn is produced;
Described micron order titanium white is preferably the Altiris550 that Hensel Man produces;
Described cenosphere is preferably the novel ultra-light cenosphere that Ge Run sub-company in Shanghai produces;
Described far infrared ceramic powder is preferably the nano-scale far infrared ceramic powder that Hebei Zhen Chuan company produces;
Described ordinary titanium powder is preferably the R668 titanium dioxide that Guangdong Hui Yuntai industry company produces;
Described calcined kaolin is preferably the white calcined kaolin of the ultra-fine height of MXK201 that Meng Xigao ridge, Inner Mongol powder company produces;
Described coarse whiting is preferably the SN-1083800 order water-ground limestone that Fujian agriculture-countryside-farmer's calcium carbonate company produces;
Described solubility promoter is preferably the propylene glycol that Depew, Shandong chemical science and technology company produces;
Described film coalescence aid is preferably the TEXANOL that Yi Si Man of the U.S. produces;
Described pure-acrylic emulsion is preferably BASF Aktiengesellschaft's production dS6266.
Concrete case study on implementation 1
Prepare a kind of heat-reflecting heat-insulating high brightness base-material, by following component and ratio of weight and number formulated:
Described functional filler is that hollow nano microballoon and far infrared ceramic powder mix according to 1:0.9.
Described common fillers is that titanium dioxide, calcined kaolin and coarse whiting mix according to 1:1:4.
A preparation method for heat-reflecting insulating coating, it comprises the step of sequentially carrying out as follows:
(1) water of 19.24 parts is added in dispersion cylinder, added the thickening material of 0.36 part under speed at 300r/ minute and stir 15 minutes, thickening material is dissolved completely.
(2) add 0.2 part of multifunctional assistant, 0.6 part of dispersion agent, 0.2 part of fungicidal preservative, 0.2 part of mould inhibitor, 0.3 part of wetting agent, the defoamer of 0.2 part, stir 15 minutes.
(3) 16 parts of modification titanium whites, 6 parts of functional fillers and 20 parts of common fillers are added, with 1300r/ minute high-speed stirring 10 minutes.
(4) reduce rotating speed, add 0.2 part of defoamer, 2.5 parts of solubility promoters, 2 parts of film coalescence aid, 32 parts of pure-acrylic emulsions successively, stir and namely obtain product of the present invention in 10 minutes.
Concrete case study on implementation 2
Prepare a kind of heat-reflecting heat-insulating high brightness base-material, by following component and ratio of weight and number formulated:
Described functional filler is that hollow nano microballoon and far infrared ceramic powder mix according to 1:1.
Described common fillers is that titanium dioxide, calcined kaolin and coarse whiting mix according to 1:1:4.
A preparation method for heat-reflecting insulating coating, it comprises the step of sequentially carrying out as follows:
(1) water of 16.23 parts is added in dispersion cylinder, added the thickening material of 0.32 part under speed at 300r/ minute and stir 15 minutes, thickening material is dissolved completely.
(2) add 0.15 part of multifunctional assistant, 0.7 part of dispersion agent, 0.2 part of fungicidal preservative, 0.2 part of mould inhibitor, 0.4 part of wetting agent, the defoamer of 0.3 part, stir 10 minutes.
(3) 14 parts of modification titanium whites, 4 parts of functional fillers and 24 parts of common fillers are added, with 1300r/ minute high-speed stirring 10 minutes.
(4) reduce rotating speed, add 0.2 part of defoamer, 2.5 parts of solubility promoters, 2 parts of film coalescence aid, 34 parts of pure-acrylic emulsions successively, stir and namely obtain product of the present invention in 10 minutes.
Specific embodiment 3
Described functional filler is that hollow nano microballoon and far infrared ceramic powder mix according to 1:0.9.
Described common fillers is that titanium dioxide, calcined kaolin and coarse whiting mix according to 1:0.9:3.7.
(1) water of 20 parts is added in dispersion cylinder, under speed, added the thickening material of 0.3 part at 300r/ minute, stir 15 minutes, thickening material is dissolved completely;
(2) then keep above-mentioned rotating speed, add the defoamer of 0.1 part of multifunctional assistant, 0.4 part of dispersion agent, 0.1 part of fungicidal preservative, 0.1 part of mould inhibitor, 0.3 part of wetting agent and 0.1 part, stir 10 minutes;
(3) then keep above-mentioned rotating speed to add 12 parts of micron order titanium whites, 4 parts of functional fillers and 18 parts of fillers, improve rotating speed afterwards to 1300r/ minute, stir 10 minutes;
(4) finally reduce rotating speed to 300r/ minute, add 0.1 part of defoamer, 2 parts of solubility promoters, 1.8 parts of film coalescence aid and 30 parts of pure-acrylic emulsions successively, stir 10 minutes, obtain product of the present invention.
Specific embodiment 4
Described functional filler is that hollow nano microballoon and far infrared ceramic powder mix according to 1:0.8.
Described common fillers is that titanium dioxide, calcined kaolin and coarse whiting mix according to 1:0.8:3.5.
(1) water of 30 parts is added in dispersion cylinder, under speed, added the thickening material of 0.38 part at 600r/ minute, stir 20 minutes, thickening material is dissolved completely;
(2) then keep above-mentioned rotating speed, add the defoamer of 0.35 part of multifunctional assistant, 0.7 part of dispersion agent, 0.3 part of fungicidal preservative, 0.3 part of mould inhibitor, 0.5 part of wetting agent and 0.3 part, stir 10 minutes;
(3) then keep above-mentioned rotating speed to add 18 parts of micron order titanium whites, 10 parts of functional fillers and 23 parts of fillers, improve rotating speed afterwards to 1800r/ minute, stir 15 minutes;
(4) finally reduce rotating speed to 600r/ minute, add 0.3 part of defoamer, 3 parts of solubility promoters, 2.4 parts of film coalescence aid and 40 parts of pure-acrylic emulsions successively, stir 15 minutes, obtain product of the present invention.
Compared with prior art, the mixing of the high brightness base-material that the present invention prepares and 0.01-1.2 part mill base, can obtain the high brightness colored paint of multiple color.By testing the high brightness colored paint of multiple color, the sunlight reflectivity of colored paint is about 0.7, near infrared sun reflectivity is about 0.85, be greater than the standard regulation in JGT235-2014, the sunlight reflectivity that the high brightness colored paint obtained can keep higher is described.
Test with further reference to GB/T9755-2014, show that this base-material also has the weathering resistance, the water-alkali resistance that there are excellence.

Claims (9)

1. a heat-reflecting heat-insulating high brightness base-material, is characterized in that: formulated according to following ratio of weight and number by following component:
Described common fillers is that titanium dioxide, calcined kaolin and coarse whiting mix according to 1:0.8-1:3.5-4.
2. a kind of heat-reflecting heat-insulating high brightness base-material according to claim 1, is characterized in that: described functional filler is that hollow nano microballoon and far infrared ceramic powder mix according to 1:0.8-1.
3. a kind of heat-reflecting heat-insulating high brightness base-material according to claim 1, is characterized in that: described micron order titanium white is the Rutile type Titanium Dioxide material of particle diameter in 1000 ~ 1200nm.
4. a kind of heat-reflecting heat-insulating high brightness base-material according to claim 1, is characterized in that: described multifunctional assistant is alkaline pH adjusting agent; Described thickening material is Natvosol.
5. a kind of heat-reflecting heat-insulating high brightness base-material according to claim 1, is characterized in that: described dispersion agent is polycarboxylate sodium.
6. a kind of heat-reflecting heat-insulating high brightness base-material according to claim 1, is characterized in that: described mould inhibitor is octylisothiazolinone class mould inhibitor; Described fungicidal preservative is isothiazolinone biocide agent.
7. a kind of heat-reflecting heat-insulating high brightness base-material according to claim 1, is characterized in that: described wetting agent is nonionogenic tenside.
8. a kind of heat-reflecting heat-insulating high brightness base-material according to claim 1, is characterized in that: described defoamer is mineral oil defoaming agent; Described solubility promoter is propylene glycol; Described film coalescence aid is alcohol ester 12; Described pure-acrylic emulsion is acrylate and alkylmethacrylate polymer.
9. according to the preparation method of a kind of heat-reflecting heat-insulating high brightness base-material in claim 1-8 described in any one, it is characterized in that: comprise the step of sequentially carrying out as follows:
(1) water of 20-30 part is added in dispersion cylinder, under speed, added the thickening material of 0.3-0.38 part at 300-600r/ minute, stir 15-20 minute, thickening material is dissolved completely;
(2) then keep above-mentioned rotating speed, add the defoamer of 0.1-0.35 part multifunctional assistant, 0.4-0.7 part dispersion agent, 0.1-0.3 part fungicidal preservative, 0.1-0.3 part mould inhibitor, 0.3-0.5 part wetting agent and 0.1-0.3 part, stir 10-15 minute;
(3) then keep above-mentioned rotating speed to add 12-18 part micron order titanium white, 4-10 part functional filler and 18-23 part common fillers, improve rotating speed afterwards to 1300-1800r/ minute, stir 10-15 minute;
(4) finally reduce rotating speed to 300-600r/ minute, add 0.1-0.3 part defoamer, 2-3 part solubility promoter, 1.8-2.4 part film coalescence aid and 30-40 part pure-acrylic emulsion successively, stir 10-15 minute, obtain product of the present invention.
CN201510973436.3A 2015-12-22 2015-12-22 A kind of heat-reflecting heat-insulating high brightness base-material and preparation method thereof Active CN105542597B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106554685A (en) * 2016-11-30 2017-04-05 江苏特丰新材料科技有限公司 A kind of reflective heat-insulation paint and preparation method thereof
CN114507466A (en) * 2022-03-15 2022-05-17 青岛金光鸿智能机械电子有限公司 Low-temperature self-drying low-VOC camouflage functional heat-insulation cooling coating and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5998525A (en) * 1996-12-02 1999-12-07 Fmc Corporation Coating and composition for transportation and sign surfaces and method of preparing and applying same
CN101818013A (en) * 2009-02-26 2010-09-01 北京东方雨虹防水技术股份有限公司 Reflecting thermal insulating paint
CN104861805A (en) * 2015-05-21 2015-08-26 紫荆花涂料(上海)有限公司 Water-borne architectural color coating with light reflection function and preparation method of coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5998525A (en) * 1996-12-02 1999-12-07 Fmc Corporation Coating and composition for transportation and sign surfaces and method of preparing and applying same
CN101818013A (en) * 2009-02-26 2010-09-01 北京东方雨虹防水技术股份有限公司 Reflecting thermal insulating paint
CN104861805A (en) * 2015-05-21 2015-08-26 紫荆花涂料(上海)有限公司 Water-borne architectural color coating with light reflection function and preparation method of coating

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106554685A (en) * 2016-11-30 2017-04-05 江苏特丰新材料科技有限公司 A kind of reflective heat-insulation paint and preparation method thereof
CN114507466A (en) * 2022-03-15 2022-05-17 青岛金光鸿智能机械电子有限公司 Low-temperature self-drying low-VOC camouflage functional heat-insulation cooling coating and preparation method and application thereof

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