CN104530918A - Oil-based waterproof paint with calcium sulfate crystal whisker and preparation method thereof - Google Patents
Oil-based waterproof paint with calcium sulfate crystal whisker and preparation method thereof Download PDFInfo
- Publication number
- CN104530918A CN104530918A CN201510059385.3A CN201510059385A CN104530918A CN 104530918 A CN104530918 A CN 104530918A CN 201510059385 A CN201510059385 A CN 201510059385A CN 104530918 A CN104530918 A CN 104530918A
- Authority
- CN
- China
- Prior art keywords
- calcium sulfate
- sulfate crystal
- crystal whiskers
- waterproof paint
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
Abstract
The invention discloses an oil-based waterproof paint with calcium sulfate crystal whisker and a preparation method thereof. The oil-based waterproof paint is prepared from the following raw materials in parts by weight: 18-27 parts of calcium sulfate crystal whisker, 5-10 parts of ethylene perchloride resin, 14-20 parts of epoxy resin, 3-10 parts of dibutyl phthalate, 1-9 parts of thickener, 5-10 parts of butyl glycidyl ether, 1-5 parts of additive, 25-35 parts of xylene and 3-6 parts of pigment. The preparation method comprises the following steps: weighing, modifying and mixing. The oil-based waterproof paint with calcium sulfate crystal whisker has the advantages of hard coated film, high adhesive force, excellent water resistance, excellent corrosion resistance and low raw material cost. The method is simple to operate and convenient for production, has low requirements for equipment, and is suitable for industrialized large-scale production.
Description
Technical field
The invention belongs to building coating technical field, be specifically related to a kind of oiliness waterproof paint adding calcium sulfate crystal whiskers and preparation method thereof.
Background technology
Building coating has decoration functions, defencive function and livability and improves function.Proportion shared by various function is not quite similar because application target is different.Decoration functions is the function of beautifying the appearance value improving it by buildings.Defencive function refers to architecture protection thing not by the impact of environment and the function of destruction.The content that different types of protected body requires defencive function is also different.Facing type waterproof paint is a kind of new coating kind integrating decoration and water-proof function.When waterproof paint is coated on flammable base material; decoration function can be played at ordinary times; occur once fire; then fire spreading can be stoped; reach the object of protection base material; the facing type waterproof paint produced is expanded polystyrene veneer waterproof paint, and kind has oiliness waterproof paint, transparent watertight coating and solvent-type waterproofing paint, and waterproof agent used is substantially identical.
Waterproof paint is generally made up of base-material, intumescent system, filler and auxiliary agent.Base-material is the main film forming substance in swelling property waterproof paint, and its effect is that other components in waterproof paint are sticked into an entirety, makes coating curing postadhesion form even, continuous, tough and tensile protective layer at substrate surface.Intumescent system is made up of dehydration catalyst, whipping agent, char-forming agent, classical intumescent system selects ammonium polyphosphate/trimeric cyanamide/tetramethylolmethane system, when coating is heated, the first decomposes of ammonium polyphosphate generates phosphoric acid, phosphoric acid dewaters further and forms the strong dewatering agent such as metaphosphoric acid and poly-metaphosphoric acid, and tetramethylolmethane to react with strong dewatering agent after melting and impels the hydroxy groups on it to dewater carbonization, trimeric cyanamide produces a large amount of non-flammable gases and plays foaming effect simultaneously, makes carburization zone under the effect of non-flammable gases, form uniform foam carbonaceous layer.Meanwhile, polyphosphoric acid and poly-metaphosphoric acid form the surface that solid-phase layer covers foam layer, isolated air and heat, and in solid phase, it stops the effect of burning.But this system also to there is consumption many and affect the shortcomings such as material property, poor heat stability, water-soluble and ageing resistance be poor.
Summary of the invention
The object of the invention is to the shortcoming overcoming prior art, a kind of oiliness waterproof paint adding calcium sulfate crystal whiskers be provided, this coating film is hard, strong adhesion, water-fast, excellent corrosion resistance and raw materials cost is low;
Another object of the present invention is to provide this kind to add the preparation method of the oiliness waterproof paint of calcium sulfate crystal whiskers, the method is simple to operate, convenient for production, low to the requirement of equipment, is applicable to industrialization scale operation.
Object of the present invention is achieved through the following technical solutions: a kind of oiliness waterproof paint adding calcium sulfate crystal whiskers, and it is made up of the raw material of following weight parts:
Wherein, described additive is made up of dispersion agent, film coalescence aid, pH adjusting agent, defoamer, sterilant and mould inhibitor, and weight part is as follows:
Further, the average aspect ratio of described calcium sulfate crystal whiskers is 50 ~ 80, and diameter is 1 ~ 4 μm.
Further, described pigment is titanium dioxide.
Further, described pH adjusting agent to be concentration be 28% ammoniacal liquor.
Further, described defoamer is NXZ defoamer.
Further, described thickening material is thickening material MS-2.
Add a preparation method for the oiliness waterproof paint of calcium sulfate crystal whiskers, it comprises the following steps:
S1. weigh: take each raw material according to the above ratio, for subsequent use;
S2. modification: add aluminate coupling agent in aqueous ethanolic solution, calcium sulfate crystal whiskers is added after 800 ~ 1000r/min rotating speed stirs, be that 4 ~ 5,2300 ~ 2700r/min rotating speeds stir after 1h and carry out vacuum-drying by Glacial acetic acid regulator solution system pH, namely obtain the calcium sulfate crystal whiskers of modification;
S3. mix: by dimethylbenzene and dispersion agent, film coalescence aid, pH adjusting agent, sterilant and mould inhibitor mixing, the calcium sulfate crystal whiskers of pigment and modification is added after stirring 10 ~ 15min with 100 ~ 200r/min rotating speed, high speed dispersion is carried out with 800 ~ 1000r/min rotating speed, proceed to shredder after dispersion to grind, obtain slurry, the grain graininess of described slurry is 50 μm, superchlorination ethenoid resin is added successively in slurry, epoxy resin, dibutyl phthalate, butylglycidyl ether, defoamer, thickening material, mix, the obtained oiliness waterproof paint adding calcium sulfate crystal whiskers.
Further, described aqueous ethanolic solution is dehydrated alcohol and deionized water is the solution of the proportional arrangement of 3:1 by volume.
Further, the weight ratio of described aluminate coupling agent and calcium sulfate crystal whiskers is 1:20 ~ 30.
The present invention has the following advantages:
1. the main component of oiliness waterproof paint of the present invention is wastewaters with modified calcium sulfate whiskers, superchlorination ethenoid resin, epoxy resin, dimethylbenzene, butylglycidyl ether.Calcium sulfate crystal whiskers has larger specific surface area, therefore hard, the strong adhesion of film, water-fast, excellent corrosion resistance; And calcium sulfate crystal whiskers is compared with other staple fibres, there is excellent property, the advantage such as cheap.Therefore, waterproof paint of the present invention not only has excellent waterproof performance, and has the advantage of low cost of manufacture.
2. the preparation method of oiliness waterproof paint of the present invention has simple to operate, convenient for production, low to the requirement of equipment, is applicable to the characteristic of industrialization scale operation.
Embodiment
Below in conjunction with embodiment, the present invention will be further described, and protection scope of the present invention is not limited to the following stated:
Embodiment 1: a kind of oiliness waterproof paint adding calcium sulfate crystal whiskers, it is made up of the raw material of following weight parts:
The preparation method of the oiliness waterproof paint of above-mentioned interpolation calcium sulfate crystal whiskers, it comprises the following steps:
S1. weigh: take each raw material according to the above ratio, the average aspect ratio of calcium sulfate crystal whiskers is 50 ~ 80, and diameter is 1 ~ 4 μm, for subsequent use;
S2. modification: dehydrated alcohol and deionized water are the aqueous ethanolic solution of the proportional arrangement of 3:1 by volume, aluminate coupling agent is added in aqueous ethanolic solution, the weight ratio of aluminate coupling agent and calcium sulfate crystal whiskers is 1:20, calcium sulfate crystal whiskers is added after 800r/min rotating speed stirs, be 4 by Glacial acetic acid regulator solution system pH, 2300r/min rotating speed carries out vacuum-drying after stirring 1h, namely obtains the calcium sulfate crystal whiskers of modification;
S3. mix: by dimethylbenzene and dispersion agent, film coalescence aid, the ammoniacal liquor of 28%, sterilant and mould inhibitor mixing, the calcium sulfate crystal whiskers of titanium dioxide and modification is added after stirring 10min with 100r/min rotating speed, high speed dispersion is carried out with 800r/min rotating speed, proceed to shredder after dispersion to grind, obtain slurry, the grain graininess of described slurry is 50 μm, superchlorination ethenoid resin is added successively in slurry, epoxy resin, dibutyl phthalate, butylglycidyl ether, NXZ defoamer, thickening material MS-2, mix, the obtained oiliness waterproof paint adding calcium sulfate crystal whiskers.
Embodiment 2: a kind of oiliness waterproof paint adding calcium sulfate crystal whiskers, it is made up of the raw material of following weight parts:
The preparation method of the oiliness waterproof paint of above-mentioned interpolation calcium sulfate crystal whiskers, it comprises the following steps:
S1. weigh: take each raw material according to the above ratio, the average aspect ratio of calcium sulfate crystal whiskers is 50 ~ 80, and diameter is 1 ~ 4 μm, for subsequent use;
S2. modification: dehydrated alcohol and deionized water are the aqueous ethanolic solution of the proportional arrangement of 3:1 by volume, aluminate coupling agent is added in aqueous ethanolic solution, the weight ratio of aluminate coupling agent and calcium sulfate crystal whiskers is 1:30, calcium sulfate crystal whiskers is added after 1000r/min rotating speed stirs, be 5 by Glacial acetic acid regulator solution system pH, 2700r/min rotating speed carries out vacuum-drying after stirring 1h, namely obtains the calcium sulfate crystal whiskers of modification;
S3. mix: by dimethylbenzene and dispersion agent, film coalescence aid, the ammoniacal liquor of 28%, sterilant and mould inhibitor mixing, the calcium sulfate crystal whiskers of titanium dioxide and modification is added after stirring 15min with 200r/min rotating speed, high speed dispersion is carried out with 1000r/min rotating speed, proceed to shredder after dispersion to grind, obtain slurry, the grain graininess of described slurry is 50 μm, superchlorination ethenoid resin is added successively in slurry, epoxy resin, dibutyl phthalate, butylglycidyl ether, NXZ defoamer, thickening material MS-2, mix, the obtained oiliness waterproof paint adding calcium sulfate crystal whiskers.
Embodiment 3: a kind of oiliness waterproof paint adding calcium sulfate crystal whiskers, it is made up of the raw material of following weight parts:
The preparation method of the oiliness waterproof paint of above-mentioned interpolation calcium sulfate crystal whiskers, it comprises the following steps:
S1. weigh: take each raw material according to the above ratio, the average aspect ratio of calcium sulfate crystal whiskers is 50 ~ 80, and diameter is 1 ~ 4 μm, for subsequent use;
S2. modification: dehydrated alcohol and deionized water are the aqueous ethanolic solution of the proportional arrangement of 3:1 by volume, aluminate coupling agent is added in aqueous ethanolic solution, the weight ratio of aluminate coupling agent and calcium sulfate crystal whiskers is 1:22, calcium sulfate crystal whiskers is added after 900r/min rotating speed stirs, be 4.5 by Glacial acetic acid regulator solution system pH, 2500r/min rotating speed carries out vacuum-drying after stirring 1h, namely obtains the calcium sulfate crystal whiskers of modification;
S3. mix: by dimethylbenzene and dispersion agent, film coalescence aid, the ammoniacal liquor of 28%, sterilant and mould inhibitor mixing, the calcium sulfate crystal whiskers of pigment and modification is added after stirring 12min with 120r/min rotating speed, high speed dispersion is carried out with 850r/min rotating speed, proceed to shredder after dispersion to grind, obtain slurry, the grain graininess of described slurry is 50 μm, superchlorination ethenoid resin is added successively in slurry, epoxy resin, dibutyl phthalate, butylglycidyl ether, NXZ defoamer, thickening material MS-2, mix, the obtained oiliness waterproof paint adding calcium sulfate crystal whiskers.
Embodiment 4: a kind of oiliness waterproof paint adding calcium sulfate crystal whiskers, it is made up of the raw material of following weight parts:
The preparation method of the oiliness waterproof paint of above-mentioned interpolation calcium sulfate crystal whiskers, it comprises the following steps:
S1. weigh: take each raw material according to the above ratio, the average aspect ratio of calcium sulfate crystal whiskers is 50 ~ 80, and diameter is 1 ~ 4 μm, for subsequent use;
S2. modification: dehydrated alcohol and deionized water are the aqueous ethanolic solution of the proportional arrangement of 3:1 by volume, aluminate coupling agent is added in aqueous ethanolic solution, the weight ratio of aluminate coupling agent and calcium sulfate crystal whiskers is 1:28, calcium sulfate crystal whiskers is added after 950r/min rotating speed stirs, be 5 by Glacial acetic acid regulator solution system pH, 2600r/min rotating speed carries out vacuum-drying after stirring 1h, namely obtains the calcium sulfate crystal whiskers of modification;
S3. mix: by dimethylbenzene and dispersion agent, film coalescence aid, the ammoniacal liquor of 28%, sterilant and mould inhibitor mixing, the calcium sulfate crystal whiskers of titanium dioxide and modification is added after stirring 13min with 150r/min rotating speed, high speed dispersion is carried out with 900r/min rotating speed, proceed to shredder after dispersion to grind, obtain slurry, the grain graininess of described slurry is 50 μm, superchlorination ethenoid resin is added successively in slurry, epoxy resin, dibutyl phthalate, butylglycidyl ether, NXZ defoamer, thickening material MS-2, mix, the obtained oiliness waterproof paint adding calcium sulfate crystal whiskers.
Embodiment 5: a kind of oiliness waterproof paint adding calcium sulfate crystal whiskers, it is made up of the raw material of following weight parts:
The preparation method of the oiliness waterproof paint of above-mentioned interpolation calcium sulfate crystal whiskers, it comprises the following steps:
S1. weigh: take each raw material according to the above ratio, the average aspect ratio of calcium sulfate crystal whiskers is 50 ~ 80, and diameter is 1 ~ 4 μm, for subsequent use;
S2. modification: dehydrated alcohol and deionized water are the aqueous ethanolic solution of the proportional arrangement of 3:1 by volume, aluminate coupling agent is added in aqueous ethanolic solution, the weight ratio of aluminate coupling agent and calcium sulfate crystal whiskers is 1:20, calcium sulfate crystal whiskers is added after 1000r/min rotating speed stirs, be 4 by Glacial acetic acid regulator solution system pH, 2400r/min rotating speed carries out vacuum-drying after stirring 1h, namely obtains the calcium sulfate crystal whiskers of modification;
S3. mix: by dimethylbenzene and dispersion agent, film coalescence aid, the ammoniacal liquor of 28%, sterilant and mould inhibitor mixing, the calcium sulfate crystal whiskers of titanium dioxide and modification is added after stirring 10min with 180r/min rotating speed, high speed dispersion is carried out with 950r/min rotating speed, proceed to shredder after dispersion to grind, obtain slurry, the grain graininess of described slurry is 50 μm, superchlorination ethenoid resin is added successively in slurry, epoxy resin, dibutyl phthalate, butylglycidyl ether, NXZ defoamer, thickening material MS-2, mix, the obtained oiliness waterproof paint adding calcium sulfate crystal whiskers.
According to national building material industry standard JC/T984-2005, impermeability test is done to the waterproof utilizing the present invention to make, preservative coat, test after shaping by 6.3cm, 6.4cm, 6.5cm, oiliness waterproof paint prepared by embodiment 1-5 carries out performance test, and experimental result is as shown in table 1.
Table 1: performance test experimental result
As shown in Table 1: coating of the present invention has excellent water resistance.
Claims (9)
1. add an oiliness waterproof paint for calcium sulfate crystal whiskers, it is characterized in that, it is made up of the raw material of following weight parts:
Calcium sulfate crystal whiskers: 18 ~ 27; Superchlorination ethenoid resin: 5 ~ 10;
Epoxy resin: 14 ~ 20; Dibutyl phthalate: 3 ~ 10;
Thickening material: 1 ~ 9; Butylglycidyl ether: 5 ~ 10;
Additive: 1 ~ 5; Dimethylbenzene: 25 ~ 35;
Pigment: 3 ~ 6;
Wherein, described additive is made up of dispersion agent, film coalescence aid, pH adjusting agent, defoamer, sterilant and mould inhibitor, and weight part is as follows:
Dispersion agent: 1 ~ 2; Film coalescence aid: 2 ~ 5;
PH adjusting agent: 0.5 ~ 1; Defoamer: 0.2 ~ 0.5;
Sterilant: 0.5 ~ 1; Mould inhibitor: 0.5 ~ 1.
2. a kind of oiliness waterproof paint adding calcium sulfate crystal whiskers as claimed in claim 1, is characterized in that, the average aspect ratio of described calcium sulfate crystal whiskers is 50 ~ 80, and diameter is 1 ~ 4 μm.
3. a kind of oiliness waterproof paint adding calcium sulfate crystal whiskers as claimed in claim 1, it is characterized in that, described pigment is titanium dioxide.
4. a kind of oiliness waterproof paint adding calcium sulfate crystal whiskers as claimed in claim 1, is characterized in that, described pH adjusting agent to be concentration be 28% ammoniacal liquor.
5. a kind of oiliness waterproof paint adding calcium sulfate crystal whiskers as claimed in claim 1, it is characterized in that, described defoamer is NXZ defoamer.
6. a kind of oiliness waterproof paint adding calcium sulfate crystal whiskers as claimed in claim 1, it is characterized in that, described thickening material is thickening material MS-2.
7. a kind of preparation method adding the oiliness waterproof paint of calcium sulfate crystal whiskers according to any one of claim 1-6, it is characterized in that, it comprises the following steps:
S1. weigh: take each raw material according to the above ratio, for subsequent use;
S2. modification: add aluminate coupling agent in aqueous ethanolic solution, calcium sulfate crystal whiskers is added after 800 ~ 1000r/min rotating speed stirs, be that 4 ~ 5,2300 ~ 2700r/min rotating speeds stir after 1h and carry out vacuum-drying by Glacial acetic acid regulator solution system pH, namely obtain the calcium sulfate crystal whiskers of modification;
S3. mix: by dimethylbenzene and dispersion agent, film coalescence aid, pH adjusting agent, sterilant and mould inhibitor mixing, the calcium sulfate crystal whiskers of pigment and modification is added after stirring 10 ~ 15min with 100 ~ 200r/min rotating speed, high speed dispersion is carried out with 800 ~ 1000r/min rotating speed, proceed to shredder after dispersion to grind, obtain slurry, the grain graininess of described slurry is 50 μm, superchlorination ethenoid resin is added successively in slurry, epoxy resin, dibutyl phthalate, butylglycidyl ether, defoamer, thickening material, mix, the obtained oiliness waterproof paint adding calcium sulfate crystal whiskers.
8. preparation method as claimed in claim 7, is characterized in that, described aqueous ethanolic solution is dehydrated alcohol and deionized water is the solution of the proportional arrangement of 3:1 by volume.
9. preparation method as claimed in claim 7, it is characterized in that, the weight ratio of described aluminate coupling agent and calcium sulfate crystal whiskers is 1:20 ~ 30.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510059385.3A CN104530918B (en) | 2015-02-05 | 2015-02-05 | Oil-based waterproof paint with calcium sulfate crystal whisker and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510059385.3A CN104530918B (en) | 2015-02-05 | 2015-02-05 | Oil-based waterproof paint with calcium sulfate crystal whisker and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104530918A true CN104530918A (en) | 2015-04-22 |
| CN104530918B CN104530918B (en) | 2017-05-17 |
Family
ID=52846561
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510059385.3A Expired - Fee Related CN104530918B (en) | 2015-02-05 | 2015-02-05 | Oil-based waterproof paint with calcium sulfate crystal whisker and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104530918B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112795284A (en) * | 2021-01-06 | 2021-05-14 | 日照中意华坤金属制造有限公司 | Coating for spraying iron art guardrail and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5998525A (en) * | 1996-12-02 | 1999-12-07 | Fmc Corporation | Coating and composition for transportation and sign surfaces and method of preparing and applying same |
| CN103059689A (en) * | 2012-12-26 | 2013-04-24 | 大连金洁建筑材料科技发展有限公司 | Fluorescent paint |
-
2015
- 2015-02-05 CN CN201510059385.3A patent/CN104530918B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5998525A (en) * | 1996-12-02 | 1999-12-07 | Fmc Corporation | Coating and composition for transportation and sign surfaces and method of preparing and applying same |
| CN103059689A (en) * | 2012-12-26 | 2013-04-24 | 大连金洁建筑材料科技发展有限公司 | Fluorescent paint |
Non-Patent Citations (2)
| Title |
|---|
| 郝文莉等: ""硫酸钙晶须的表面改性研究"", 《化工矿物与加工》 * |
| 黄明杰等: ""硫酸钙晶须在涂料中的应用综述"", 《现代涂料与涂装》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112795284A (en) * | 2021-01-06 | 2021-05-14 | 日照中意华坤金属制造有限公司 | Coating for spraying iron art guardrail and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104530918B (en) | 2017-05-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104559679A (en) | Water-based waterproof coating added with calcium sulfate whiskers and preparation method of coating | |
| CN104945997B (en) | A kind of outer wall flexible waterproof putty powder | |
| CN105272017A (en) | Polymer cement waterproof coating | |
| CN104129950B (en) | A kind of high flexibility fiber reinforced type polymer cement waterproof paint | |
| WO2014090105A1 (en) | Water-based expandable fireproof coating for steel structure and preparation method therefor | |
| CN102408220A (en) | All-in-one water-borne inorganic-organic hybrid architectural coating and preparation method thereof | |
| CN103232260A (en) | Waterproof insulation lightweight high-strength gypsum sheet material and preparation method thereof | |
| CN103642337A (en) | Water-based high-elasticity environment-friendly waterproof paint and preparation method thereof | |
| CN103923541A (en) | Preparation method for universal alkali-resistant seal primer | |
| CN104194534A (en) | Waterproof heat preservation coating for building external wall and preparation method of waterproof heat preservation coating | |
| CN103756475A (en) | Waterproof exterior wall coating and preparation method thereof | |
| CN104650714A (en) | Flame-retardant waterproof coating for interior wall of building and preparation method thereof | |
| CN104446187A (en) | Universal glue for tile | |
| CN109135460A (en) | A kind of high strength and waterproof polymer emulsion building water-proof paint and preparation method thereof | |
| CN104710906A (en) | Calcium sulfate whisker-containing oily fireproof coating and preparation method thereof | |
| CN104530918A (en) | Oil-based waterproof paint with calcium sulfate crystal whisker and preparation method thereof | |
| CN104449384A (en) | Water-based sound-insulating coating | |
| CN104263127A (en) | Insulating crack-resistant coating for exterior wall | |
| CN104263125A (en) | Polymer exterior wall paint | |
| CN104496389A (en) | Artificial granite inorganic dry powder composite slice coating | |
| CN104263122A (en) | Stable paint | |
| CN103086658B (en) | Production method of three-dimensional skeleton composite board for building | |
| CN104650717A (en) | High-weather resistance low-discoloration-tendency waterproof paint and preparation method thereof | |
| CN104773985A (en) | Lightweight composite building energy-saving heat-insulation material | |
| CN102212281A (en) | Environmentally-friendly water-resistant scrub-resistant interior wall paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170517 Termination date: 20190205 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |