CN102871868A - Massage mask-facial cleanser combination - Google Patents
Massage mask-facial cleanser combination Download PDFInfo
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- CN102871868A CN102871868A CN2012101780726A CN201210178072A CN102871868A CN 102871868 A CN102871868 A CN 102871868A CN 2012101780726 A CN2012101780726 A CN 2012101780726A CN 201210178072 A CN201210178072 A CN 201210178072A CN 102871868 A CN102871868 A CN 102871868A
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- washing composition
- massage pack
- pack face
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- face
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Abstract
The invention relates to a massage mask-facial cleanser combination which is characterized in that spreadability of foam is good, the foam is easy to wash away, the use feel is good and the foam is of good quality even at low temperature. The combination contains 92-97 weight percent water-solubility aerosol stoste and 3-8 weight percent liquefied petroleum gas; carbon dioxide is pressurized to 0.4-0.7MPa at a temperature of 25 degrees; and the water-solubility aerosol stoste contains 1-5 weight percent higher alcohol formed by docosyl alcohol and cetanol, 3-8 weight percent higher aliphatic acid formed by the docosyl alcohol and stearic acid, and 1-4 weight percent nonionic surfactant formed by Phytosterols and cithrol.
Description
Technical field
The present invention relates to massage face-washing composition, more specifically, the present invention relates to can be with the massage pack face-washing composition of blister injection.
Background technology
As the foam-form face-washing material, patent documentation 1 has proposed the material of washing one's face of the alveolar substance exquisiteness that is made of the aqueous solution that contains anion surfactant, liquefied petroleum gas, carbon dioxide.Patent documentation 2,3 has proposed to contain the blister facial film material of the polyhydric alcohol such as a large amount of Polyethylene Glycol or glycerol.
Patent documentation 1: Japanese Patent Application 2010-94476 number
Patent documentation 2: the clear 61-158909 of Japanese Patent Application number
Patent documentation 3: TOHKEMY 2005-2030 number
But, for patent documentation 1, although fine and smooth and sprawl well because of alveolar substance, be suitable as foaming mousse cleanser, so because alveolar substance is soft unsatisfactory with material as massage.For the technology of patent documentation 2 and 3, although owing to contain the polyhydric alcohol such as Polyethylene Glycol 50% or more or glycerol, good to the adhesion of skin, be not easy but then to wash off, need the large water gaging of use.
Summary of the invention
The inventor conducts in-depth research in order to address the above problem.Found that a kind of massage pack face-washing composition, said composition contains water solublity aerosol stock solution 92-97 % by weight and liquefied petroleum gas 3-8 % by weight, and be pressurized to 0.4-0.7MPa with carbon dioxide at 25 ℃, wherein water solublity aerosol stock solution contains the higher alcohol 1-5 % by weight that is made of behenyl alcohol and hexadecanol, the higher fatty acids 3-8 % by weight that behenic acid and stearic acid consist of, the non-ionic surface active agent 1-4 % by weight that polyoxyethylene sterol and cithrol consist of, this massage pack compositions can be injected into blister, spreadability to skin is good, and can simply wash off, thereby finished the present invention.
That is to say, the invention provides following massage pack face-washing composition.
1. massage pack face-washing composition, said composition contains water solublity aerosol stock solution 92-97 % by weight and liquefied petroleum gas 3-8 % by weight, and be pressurized to 0.4-0.7MPa with carbon dioxide at 25 ℃, wherein water solublity aerosol stock solution contains the non-ionic surface active agent 1-4 % by weight that higher fatty acids 3-8 % by weight, polyoxyethylene sterol and cithrol that the higher alcohol 1-5 % by weight, behenic acid and the stearic acid that are made of behenyl alcohol and hexadecanol consist of consist of.
2. massage pack face-washing composition, wherein, the proportioning of aforementioned behenyl alcohol and hexadecanol is 80: 20-60: 40
3. massage pack face-washing composition, wherein, aforementioned behenic acid and stearic proportioning are 80: 20-60: 40.
4. such as 1 described massage pack face-washing composition, wherein, the proportioning of polyoxyethylene sterol and cithrol is 20: 80-40: 60.
Below massage pack face-washing composition of the present invention is specifically described.
The higher alcohol that uses among the present invention can be enumerated behenyl alcohol and hexadecanol.Can mix and use these two kinds of alcohol, use level is the 1-5 % by weight of aqueous aerosol solution, is preferably the 2-4 % by weight.Proportioning is 80: 20-60: 40, be preferably 70: 30-65: 35.The proportioning of hexadecanol was steeped softly less than 20% the time, was difficult to obtain massage effect, and was in addition, if proportioning surpasses 40% then bubble is really up to the mark, unsatisfactory with material as massage pack.
The higher fatty acids that uses among the present invention can be enumerated behenic acid and stearic acid.Can mix and use these two kinds of acid, the use level in the water solublity aerosol solution is the 3-8 % by weight, is preferably the 4-6 % by weight.Proportioning is 80: 20-60: 40, be preferably 70: 30-65: 35.Stearic use level was steeped softly less than 20% the time, was difficult to obtain massage effect, and was in addition, if proportioning surpasses 40% then bubble is really up to the mark, unsatisfactory with material as massage.
The non-ionic surface active agent that uses among the present invention can be enumerated polyoxyethylene sterol and cithrol.More specifically, as the polyoxyethylene sterol, can enumerate PEG-5 soyasterol, PEG-10 soyasterol, PEG-20 soyasterol, PEG-30 soyasterol, particularly preferably the PEG-10 soyasterol.In addition, as cithrol, can enumerate polyethylene glycol laurate, Myrj 45, polyoxyethylene oleate, polyoxyethylene distearate, polyoxyethylene diisopstearate, particularly preferably Myrj 45.Can mix two kinds in these, use level is preferably the aerocolloidal 1-4 % by weight of water solublity, more preferably 2-3 % by weight.Proportioning is 20: 80-40: 60, be preferably 30: 70-35: 65.The use level of polyoxyethylene sterol is less than 20% the time, and it is large that foaming becomes, unsatisfactory with material as massage pack, and is in addition, if surpass 40% then bubble is really up to the mark, unsatisfactory with material as massage pack.
Liquefied petroleum gas among the present invention can be enumerated such as propane, normal butane, iso-butane, isopentane etc., wherein the mixture of preferably propane, normal butane, iso-butane.Preferred content is the 3-8 % by weight, more preferably the 4-6 % by weight.If content less than 3 % by weight then the alveolar substance variation, in addition, becomes large if surpass 8 % by weight then foam, can not form fine and smooth bubble.
Even cooperating the purpose of carbon dioxide among the present invention is to use as the auxiliary agent that also can spray content when low temperature, because excellent with respect to the dissolubility of aqueous stock solution, thus preferred.Preferred its content is to be pressurized to 0.4-0.7MPa under 25 ℃, more preferably is pressurized to 0.5-0.6MPa.If sometimes can not be injected into during less than 0.4MPa then at low temperature under 25 ℃ last, in addition, if surpass 0.7MPa then to spray intensity excessive, undesirable in the use.
The pH of water solublity aerosol stock solution of the present invention is preferably 4.0-7.0, more preferably 5.0-6.5.If pH is less than 4.0 then might corrode aerocolloidal canister, if surpass 7.0 then pH approaches alkalescence, skin is produced to stimulate.
In massage pack face-washing composition of the present invention, except above-mentioned necessary component, can also in the scope of not damaging effect of the present invention, suitably cooperate other conventional ingredients that use in the cosmetics, such as wetting agent, antiseptic, pH adjusting agent, viscosity modifier, antioxidant, freshener, antibacterial, essence, pigment etc.
The specific embodiment
Below, the embodiment of massage pack face-washing composition of the present invention is described, but the present invention is not limited to these embodiment.
Embodiment 1-2 and comparative example 1-5
According to the modulation of the composition shown in the following table 1 massage face-washing composition, be filled into respectively in the aluminum aerosol container.According to the hardness of following evaluation methodology evaluation (1) bubble, the spreadability of (2) bubble, (3) are the property washed off easily, the bubble hardness during (4) low temperature.Its evaluation result is as shown in table 1.Unit in embodiment and the comparative example is % by weight.
Table 1
| Embodiment 1 | Embodiment 2 | Comparative example 1 | Comparative example 2 | Comparative example 3 | |
| Behenyl alcohol | 2 | 1.6 | 2 | 4 | 2 |
| Hexadecanol | 1 | 0.4 | 0.2 | 2 | 1 |
| Stearic acid | 1.5 | 1.2 | 1.5 | 1.5 | 0.5 |
| Behenic acid | 3 | 4.8 | 3 | 3 | 3 |
| The PEG-10 soyasterol | 1 | 0.4 | 1 | 1 | 1 |
| Stearic acid PEG-25 | 2 | 1.6 | 2 | 2 | 2 |
| Potassium hydroxide | 0.5 | 0.6 | 0.5 | 0.5 | 0.5 |
| Water | 89 | 89.4 | 89.8 | 86 | 90 |
| Liquefied petroleum gas | 5 | 4 | 5 | 5 | 5 |
| With carbon dioxide pressurization (MPa) | 0.6 | 0.5 | 0.6 | 0.6 | 0.6 |
| (1) result | ○ | ○ | △ | × | △ |
| (2) result | ○ | ○ | △ | × | △ |
| (3) result | ○ | ○ | ○ | △ | △ |
| (4) result | ○ | ○ | △ | △ | △ |
| Comparative example 4 | Comparative example 5 | Comparative example 6 | Comparative example 7 | Comparative example 8 | |
| Behenyl alcohol | 2 | 2 | 2 | 2 | 2 |
| Hexadecanol | 1 | 1 | 1 | 1 | 1 |
| Stearic acid | 5 | 1.5 | 1.5 | 1.5 | 1.5 |
| Behenic acid | 3.5 | 3 | 3 | 3 | 3 |
| The PEG-10 soyasterol | 1 | 0.5 | 2.5 | 1 | 1 |
| Stearic acid PEG-25 | 2 | 2.5 | 2.5 | 2 | 2 |
| Potassium hydroxide | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
| Water | 86 | 89 | 87 | 89 | 89 |
| Liquefied petroleum gas | 5 | 5 | 5 | 2 | 5 |
| With carbon dioxide pressurization (MPa) | 0.6 | 0.6 | 0.6 | 0.6 | 0.2 |
| (1) result | × | △ | × | △ | × |
| (2) result | × | △ | △ | × | △ |
| (3) result | × | ○ | × | ○ | ○ |
| (4) result | × | △ | △ | △ | × |
Evaluation methodology:
Following the carrying out of key property evaluation experimental that massage pack is washed one's face and expected: use 10 experimenters to carry out actual massage pack and wash one's face, then estimate the hardness of bubble, the spreadability of when whole face is sprawled, steeping, the easiness of washing off.Calculated by the following minute standard of each getting, average mark is zero being evaluated as more than 2.1, and average mark is evaluated as △ at 1.1-2.0, average mark is being evaluated as below 1.0 *.Test temperature is 25 ± 2 ℃ room temperature.In addition, also estimated blister attitude (range estimation) under 5 ℃ of low temperature.
(1) hardness of bubble
3: good
2: general
1: undesirable (crossing soft or really up to the mark)
(2) spreadability of bubble
3: good
2: general
1: undesirable
(3) the easy property washed off
3: good
2: general
1: undesirable
(4) the bubble hardness of test chamber temperature under 5 ℃
3: good
2: general
1: undesirable
Massage pack face-washing composition of the present invention be the bubble spreadability and easily the property washed off make with a good sense, even also good massage pack face-washing composition of alveolar substance at low temperatures.
Claims (19)
1. massage pack face-washing composition, said composition contains water solublity aerosol stock solution 92-97 % by weight and liquefied petroleum gas 3-8 % by weight, and be pressurized to 0.4-0.7MPa with carbon dioxide at 25 ℃, wherein water solublity aerosol stock solution contains the non-ionic surface active agent 1-4 % by weight that higher fatty acids 3-8 % by weight, polyoxyethylene sterol and cithrol that the higher alcohol 1-5 % by weight, behenic acid and the stearic acid that are made of behenyl alcohol and hexadecanol consist of consist of.
2. massage pack face-washing composition as claimed in claim 1, wherein, the proportioning of described behenyl alcohol and hexadecanol is 80: 20-60: 40.
3. massage pack face-washing composition as claimed in claim 2, wherein, the proportioning of described behenyl alcohol and hexadecanol is 70: 30-65: 35.
4. such as the arbitrary described massage pack face-washing composition of claim 1-3, wherein, described behenic acid and stearic proportioning are 80: 20-60: 40.
5. such as each described massage pack face-washing composition among the claim 1-4, wherein, described behenic acid and stearic proportioning are 70: 30-65: 35.
6. massage pack face-washing composition as claimed in claim 5, wherein, the proportioning of described polyoxyethylene sterol and cithrol is 20: 80-40: 60.
7. massage pack face-washing composition as claimed in claim 6, wherein, the proportioning of described polyoxyethylene sterol and cithrol is 30: 70-35: 65.
8. such as each described massage pack face-washing composition among the claim 1-7, wherein, water solublity aerosol stock solution contains the higher alcohol 2-4 % by weight that is made of behenyl alcohol and hexadecanol.
9. such as each described massage pack face-washing composition among the claim 1-8, wherein, the higher fatty acids that water solublity aerosol stock solution contains behenic acid and stearic acid formation is the 4-6 % by weight.
10. such as each described massage pack face-washing composition among the claim 1-9, wherein, described polyoxyethylene sterol is selected from PEG-5 soyasterol, PEG-10 soyasterol, PEG-20 soyasterol, PEG-30 soyasterol.
11. massage pack face-washing composition as claimed in claim 10, described polyoxyethylene sterol is the PEG-10 soyasterol.
12. such as arbitrary described massage pack face-washing composition among the claim 1-11, wherein, described cithrol is selected from polyethylene glycol laurate, Myrj 45, polyoxyethylene oleate, polyoxyethylene distearate, polyoxyethylene diisopstearate.
13. massage pack face-washing composition as claimed in claim 12, wherein, described cithrol is selected from Myrj 45.
14. such as arbitrary described massage pack face-washing composition among the claim 1-13, wherein, described water solublity aerosol stock solution contains the non-ionic surface active agent 2-3 % by weight of polyoxyethylene sterol and cithrol formation.
15. such as arbitrary described massage pack face-washing composition among the claim 1-14, wherein, described liquefied petroleum gas is selected from propane, normal butane, iso-butane, isopentane or its mixture.
16. such as arbitrary described massage pack face-washing composition among the claim 1-15, wherein, compositions contains liquefied petroleum gas 4-6 % by weight.
17. such as arbitrary described massage pack face-washing composition among the claim 1-16, wherein, described compositions is pressurized to 0.5-0.6MPa with carbon dioxide under 25 ℃.
18. such as arbitrary described massage pack face-washing composition among the claim 1-16, wherein, the pH of water solublity aerosol stock solution is 4.0-7.0.
19. massage pack face-washing composition as claimed in claim 18, wherein, the pH of water solublity aerosol stock solution is 5.0-6.5.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011169634A JP2013023493A (en) | 2011-07-15 | 2011-07-15 | Composition for facial massage pack cleanser |
| JP2011-169634 | 2011-07-15 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102871868A true CN102871868A (en) | 2013-01-16 |
| CN102871868B CN102871868B (en) | 2014-04-02 |
Family
ID=47473548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210178072.6A Active CN102871868B (en) | 2011-07-15 | 2012-05-24 | Massage mask-facial cleanser combination |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP2013023493A (en) |
| CN (1) | CN102871868B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108430452A (en) * | 2015-09-30 | 2018-08-21 | 株式会社爱茉莉太平洋 | It prevents hair loss or promotes the aerosol type composition of hair tonic |
| CN109095419A (en) * | 2018-06-21 | 2018-12-28 | 上海西西艾尔启东日用化学品有限公司 | A kind of carbon dioxide-containing mist agent manufacture system and technique |
| CN110214001A (en) * | 2017-05-30 | 2019-09-06 | 株式会社漫丹 | Foam-like skin cleaner |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7427742B2 (en) | 2021-10-29 | 2024-02-05 | 株式会社長寿乃里 | Composition for skin pack and method for using the same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040241105A1 (en) * | 2001-09-07 | 2004-12-02 | Beiersdorf Ag | Self-foaming or foamy preparations containing inorganic gel formers, organic hydrocolloids and particulate hydrophobic, hydrophobicized or oil-absorbing solid-body substances |
| US20080031908A1 (en) * | 2006-07-25 | 2008-02-07 | L'oreal | Oily cosmetic composition in aerosol form |
| CN101554356A (en) * | 2008-04-11 | 2009-10-14 | 花王株式会社 | A spumous skin coating agent |
-
2011
- 2011-07-15 JP JP2011169634A patent/JP2013023493A/en not_active Withdrawn
-
2012
- 2012-05-24 CN CN201210178072.6A patent/CN102871868B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040241105A1 (en) * | 2001-09-07 | 2004-12-02 | Beiersdorf Ag | Self-foaming or foamy preparations containing inorganic gel formers, organic hydrocolloids and particulate hydrophobic, hydrophobicized or oil-absorbing solid-body substances |
| US20080031908A1 (en) * | 2006-07-25 | 2008-02-07 | L'oreal | Oily cosmetic composition in aerosol form |
| CN101554356A (en) * | 2008-04-11 | 2009-10-14 | 花王株式会社 | A spumous skin coating agent |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108430452A (en) * | 2015-09-30 | 2018-08-21 | 株式会社爱茉莉太平洋 | It prevents hair loss or promotes the aerosol type composition of hair tonic |
| CN108430452B (en) * | 2015-09-30 | 2021-03-09 | 株式会社爱茉莉太平洋 | Aerosol composition for preventing hair loss or promoting hair growth |
| CN110214001A (en) * | 2017-05-30 | 2019-09-06 | 株式会社漫丹 | Foam-like skin cleaner |
| CN109095419A (en) * | 2018-06-21 | 2018-12-28 | 上海西西艾尔启东日用化学品有限公司 | A kind of carbon dioxide-containing mist agent manufacture system and technique |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2013023493A (en) | 2013-02-04 |
| CN102871868B (en) | 2014-04-02 |
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