CN100457847C - Environmental protection type aqueous brightening agent for tyre - Google Patents

Environmental protection type aqueous brightening agent for tyre Download PDF

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Publication number
CN100457847C
CN100457847C CNB2006100601653A CN200610060165A CN100457847C CN 100457847 C CN100457847 C CN 100457847C CN B2006100601653 A CNB2006100601653 A CN B2006100601653A CN 200610060165 A CN200610060165 A CN 200610060165A CN 100457847 C CN100457847 C CN 100457847C
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CN
China
Prior art keywords
water
brightening agent
tyre
environmental protection
protection type
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB2006100601653A
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Chinese (zh)
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CN101050340A (en
Inventor
林峰
张武英
肖望东
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Shenzhen Polytechnic
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Shenzhen Polytechnic
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Priority to CNB2006100601653A priority Critical patent/CN100457847C/en
Publication of CN101050340A publication Critical patent/CN101050340A/en
Application granted granted Critical
Publication of CN100457847C publication Critical patent/CN100457847C/en
Expired - Fee Related legal-status Critical Current
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Abstract

This invention discloses an environmentally friendly waterborne tyre brightener, which comprises: starch derivative 3-50 wt.%, polyol 5-60 wt.%, waterborne wax emulsion 0-30 wt.%, waterborne silicone oil 0-30 wt.%, preservative 0.01-1 wt.%, defoaming agent 0.001-1 wt.%, and water as balance.

Description

Environmental protection type aqueous brightening agent for tyre
Technical field
The present invention is a kind of water-based brightening agent, particularly relates to a kind of water-based brightening agent of doughnut.
Background technology
Doughnut in use often is subjected to the erosion of various compositions such as oiliness dust of silt, the vehicle on natural rainwater, dust, road surface, makes tire lose original pure black and presents grey black, influences visual effect.Iff being that simple water cleans or washes tire with the water that contains sanitising agent, because water is attached to surface of tyre, tire can keep light at short notice, but the time is long slightly particularly behind running car, volatilization along with attached water, tire presents intensely dark grey black again, so the car detailing industry uses brightening agent for tyre in a large number, realizes tire light as new visual effect.Commercially available brightening agent for tyre product mainly contains solvent-borne type, emulsion-type and water-based three major types at present.The solvent-borne type product is owing to contain organic solvent, and burning brings potential safety hazard easily, and is not easy to clean after using for some time to remove, and makes surface of tyre seem bright and clean inadequately; The emulsion type products cost is higher, is fit to family oneself maintenance automobile, for numerous car detailing shops, is difficult to accept its high cost; There is the shortcoming of bright inadequately and persistence difference in commercially available aqueous product.For this reason, the present invention designs and improves prescription at these shortcomings exactly.
Summary of the invention
The purpose of this invention is to provide a kind of aqueous brightening agent for tyre, it can overcome, and surface of tyre is bright and clean inadequately, higher, the commercially available aqueous product of the emulsion type products cost problem of light and persistence difference inadequately.
For achieving the above object, the present invention proposes a kind of environmental protection type aqueous brightening agent for tyre, and it includes starch derivative, polyvalent alcohol, water-based wax emulsion, water-based silicone oil, sanitas and defoamer, and its content is as follows: by the quality percentage composition
Starch derivative 3~50%
Polyvalent alcohol 5~60%
Water-based wax emulsion 0~30%
Water-based silicone oil 0~30%
Sanitas 0.01~1%
Defoamer 0.001~1%
Surplus is a water.
The starch derivative that uses among the present invention is dextrin or dextrin derivative.Dextrin or dextrin derivative good water absorption, spread upon surface of tyre after, form aqueous coating and bring brightness effect, and after in a single day dextrin or dextrin derivative absorb moisture, can form gel structure, keep the ability of moisture stronger, can delay the volatilization of water, thereby keep light for a long time.Present commercially available aqueous product is because sticking power is bad, under the strong shear action that tire runs up, the composition of brightening agent is pulled out away from surface of tyre, make that the persistence of brightness effect is bad, and dextrin or dextrin derivative possess stronger cementability, can can not be pulled out away from attached to surface of tyre when galloping, make that the persistence of brightness effect is long.Dextrin or the dextrin derivative solubleness in water is big in addition, can be prepared into the high concentrated solution of content, is convenient to transportation.
The polyvalent alcohol that uses among the present invention is selected from the group that ethylene glycol, glycerol, glycol ether, triglycol, polyoxyethylene glycol or their mixture are formed.Polyvalent alcohol has water absorbability, can form the coating of light at surface of tyre, and the boiling point height is not volatile, makes that the persistence of light is long.Wherein use the different molecular weight polyethylene glycol also should be at the row of protection of the present invention.
The water-based wax emulsion of using among the present invention is selected from the group that aqueous polyethylene wax emulsion, water-based palm wax emulsion or their mixture are formed.Water-based wax emulsion possesses good brightness effect, and a small amount of in the present invention use can improve the luminance brightness of aquifer coating.
The water-based silicone oil that uses among the present invention belongs to the low not viscous liquid of the big surface tension of molecular weight, is difficult for sticking ash when bringing light.
The sanitas that uses among the present invention is selected from the group of forming as quaternary surfactant, Sodium Benzoate or their mixture.Because general dust all has negative charge, the quaternary surfactant that therefore an amount of interpolation belongs to cation compound can also hinder the electric charge of dust, plays the effect of antidusting.
Aqueous brightening agent for tyre can not add any defoamer among the present invention, also can add a certain amount of defoamer.As everyone knows, as defoamer, waterborne organic silicon defoamer, tributyl phosphate, polyether antifoam agent etc. can add.
The compound method of aqueous brightening agent for tyre of the present invention:
In a container, press the composition and the content preparation of foregoing.Add starch derivative in water, stirring and dissolving adds polyvalent alcohol, water-based wax emulsion, water-based silicone oil then respectively, adds sanitas again, adds defoamer at last, stirs, and promptly gets aqueous brightening agent for tyre of the present invention.
Advantage of the present invention:
Aqueous brightening agent for tyre of the present invention contains the composition of starch derivative, polyvalent alcohol, water-based wax emulsion, water-based silicone oil, sanitas and defoamer, can form light as new effect attached to surface of tyre by smearing, persistence is long, and still can keep the tire light when galloping.Said composition belongs to water-based system, has the feature of environmental protection, and dilute with water is with low cost easily, is convenient to the car detailing industry and uses on a large scale.Wherein used good water absorption to have the dextrin or the dextrin derivative of cementability again, made and when galloping, avoid the brightening agent component to be pulled out away from surface of tyre, so have persistent luminance brightness; The polyvalent alcohol that has wherein used good hygroscopicity, volatilization to have light slowly again makes surface of tyre have light as new visual effect; Use therein water-based wax emulsion, water-based silicone oil can improve luminance brightness more; Owing to used the quaternary ammonium type tensio-active agent to improve the antidusting of brightening agent.
Embodiment
A kind of environmental protection type aqueous brightening agent for tyre, it includes starch derivative, polyvalent alcohol, water-based wax emulsion, water-based silicone oil, sanitas and defoamer, and its content is as follows: by the quality percentage composition
Starch derivative 3~50%
Polyvalent alcohol 5~60%
Water-based wax emulsion 0~30%
Water-based silicone oil 0~30%
Sanitas 0.01~1%
Defoamer 0.001~1%
Surplus is a water.
This starch derivative is dextrin or dextrin derivative.
This polyvalent alcohol is selected from the group that ethylene glycol, glycerol, glycol ether, triglycol, polyoxyethylene glycol or their mixture are formed.
This water-based wax emulsion is selected from the group that aqueous polyethylene wax emulsion, water-based palm wax emulsion or their mixture are formed.
This sanitas is selected from the group of forming into quaternary surfactant, Sodium Benzoate or their mixture.
This defoamer is selected from the group that waterborne organic silicon defoamer, tributyl phosphate, polyether antifoam agent or their mixture are formed.
Embodiment 1
By the quality percentage composition, comprising in the present embodiment:
Water-soluble dextrin 30%
Glycerol 20%
Bromogeramine (1227) 0.05%
Defoamer 0.01%
Water surplus
Add water-soluble dextrin in water gradually, stirring and dissolving adds glycerol, stirs, and adds bromogeramine (1227) again, stirs, and adds defoamer at last, stirs, get final product aqueous brightening agent for tyre of the present invention.Bromogeramine (bromination dodecyl dimethyl benzyl ammonium) is a kind of sanitas.
Embodiment 2
By the quality percentage composition, comprising in the present embodiment:
Dextrin derivative 3%
Glycol ether 40%
Polyoxyethylene glycol (6000) 20%
Bromogeramine (1227) 0.02%
Sodium Benzoate 0.05%
Defoamer 1%
Water surplus
Preparation method with reference to above-mentioned first embodiment.Bromogeramine and Sodium Benzoate are sanitass.
Embodiment 3
By the quality percentage composition, comprising in the present embodiment:
Dextrin derivative 50%
Glycol ether 5%
Water-based palm wax emulsion 2%
Bromogeramine (1227) 0.3%
Sodium Benzoate 0.2%
Defoamer 0.01%
Pigment is a small amount of
Water surplus
Preparation method with reference to above-mentioned first embodiment.Bromogeramine and Sodium Benzoate are sanitass.
Embodiment 4
By the quality percentage composition, comprising in the present embodiment:
Dextrin 10%
Glycol ether 5%
Glycerol 5%
Water-based palm wax emulsion 30%
Water-based silicone oil 2%
Bromogeramine (1227) 0.05%
Sodium Benzoate 0.05%
Defoamer 0.01%
Water surplus
Preparation method with reference to above-mentioned first embodiment.Bromogeramine and Sodium Benzoate are sanitass.
Embodiment 5
By the quality percentage composition, comprising in the present embodiment:
Water-soluble dextrin 15%
Polyoxyethylene glycol (4000) 10%
Water-based silicone oil 30%
Bromogeramine (1227) 0.01%
Defoamer 0.001%
Water surplus
Preparation method with reference to above-mentioned first embodiment.Bromogeramine is a sanitas.

Claims (9)

1, a kind of environmental protection type aqueous brightening agent for tyre is characterized in that, comprises dextrin, polyvalent alcohol, water-based wax emulsion, water-based silicone oil, sanitas and defoamer, and its content is as follows: by the quality percentage composition
Dextrin 3 ~ 50%
Polyvalent alcohol 5 ~ 60%
Water-based wax emulsion 0 ~ 30%
Water-based silicone oil 0 ~ 30%
Sanitas 0.01 ~ 1%
Defoamer 0.001 ~ 1%
Surplus is a water.
2, environmental protection type aqueous brightening agent for tyre according to claim 1 is characterized in that, the quality percentage composition of this dextrin is 10 ~ 30%.
3, environmental protection type aqueous brightening agent for tyre according to claim 1 is characterized in that, the quality percentage composition of this polyvalent alcohol is 5 ~ 20%.
4, environmental protection type aqueous brightening agent for tyre according to claim 1 is characterized in that, the quality percentage composition of this sanitas is 0.02 ~ 0.5%.
5, environmental protection type aqueous brightening agent for tyre according to claim 1 is characterized in that, the quality percentage composition of this defoamer is 0.001 ~ 0.01%.
According to claim 1 or 3 described environmental protection type aqueous brightening agent for tyre, it is characterized in that 6, this polyvalent alcohol is selected from the group that ethylene glycol, glycerol, glycol ether, triglycol, polyoxyethylene glycol or their mixture are formed.
7, environmental protection type aqueous brightening agent for tyre according to claim 1, it is characterized in that, this water-based wax emulsion is selected from the group that aqueous polyethylene wax emulsion, water-based palm wax emulsion or their mixture are formed, and this water-based wax emulsion adopts the alkylphenol polyoxyethylene phosphate ester salt to make emulsifying agent.
According to claim 1 or 4 described environmental protection type aqueous brightening agent for tyre, it is characterized in that 8, this sanitas is selected from the group of forming into quaternary surfactant, Sodium Benzoate or their mixture.
9, environmental protection type aqueous brightening agent for tyre according to claim 1 or 5 is characterized in that, this defoamer is selected from the group that waterborne organic silicon defoamer, tributyl phosphate, polyether antifoam agent or their mixture are formed.
CNB2006100601653A 2006-04-03 2006-04-03 Environmental protection type aqueous brightening agent for tyre Expired - Fee Related CN100457847C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2006100601653A CN100457847C (en) 2006-04-03 2006-04-03 Environmental protection type aqueous brightening agent for tyre

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2006100601653A CN100457847C (en) 2006-04-03 2006-04-03 Environmental protection type aqueous brightening agent for tyre

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Publication Number Publication Date
CN101050340A CN101050340A (en) 2007-10-10
CN100457847C true CN100457847C (en) 2009-02-04

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Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102226062B (en) * 2011-04-08 2013-12-11 龚有林 Water-soluble nano bright grease
CN104710881B (en) * 2015-02-13 2017-06-13 中山市优贝科技股份有限公司 Solid wax of vehicle glazing protection containing active component and preparation method thereof
CN105238266B (en) * 2015-10-23 2018-10-09 颜军科 The lasting brightener of nano self-cleaning type tire and its manufacturing method
CN105219279A (en) * 2015-11-14 2016-01-06 华玉叶 A kind of brightening agent for tyre
CN105219278A (en) * 2015-11-14 2016-01-06 华玉叶 A kind of brightening agent for tyre
CN105219277A (en) * 2015-11-14 2016-01-06 华玉叶 A kind of brightening agent for tyre
CN105295738A (en) * 2015-11-14 2016-02-03 华玉叶 Tyre brightener
CN105505232A (en) * 2015-12-11 2016-04-20 上海飞尔实业有限公司 Tire brightener
CN106566410A (en) * 2016-11-04 2017-04-19 广西钱隆投资管理有限公司 Car wax and preparation method thereof
CN115584166A (en) * 2022-11-08 2023-01-10 江苏巨能橡塑科技有限公司 Heavy-load solid tire tread protective agent and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3137949A1 (en) * 1981-09-24 1983-04-21 Andreas 7320 Göppingen Mozzi Brightener for rubber goods, in particular car tyres, and preparation thereof
JPH0873815A (en) * 1994-09-09 1996-03-19 Kyowa Shoko Kk Tire wax composition containing pearl pigment
CN1119206A (en) * 1994-09-21 1996-03-27 钟世昌 New-functional multipurpose brightening agent for washing hard surface
JP2002201413A (en) * 2000-12-28 2002-07-19 Health Chemical:Kk Coating material for rubber product
US20040131787A1 (en) * 2002-11-26 2004-07-08 Pennzoil-Quaker State Company Aqueous based tire dressing compositions and methods of making
US20050250668A1 (en) * 2004-05-05 2005-11-10 Serobian Ashot K Rheologically stabilized silicone dispersions

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3137949A1 (en) * 1981-09-24 1983-04-21 Andreas 7320 Göppingen Mozzi Brightener for rubber goods, in particular car tyres, and preparation thereof
JPH0873815A (en) * 1994-09-09 1996-03-19 Kyowa Shoko Kk Tire wax composition containing pearl pigment
CN1119206A (en) * 1994-09-21 1996-03-27 钟世昌 New-functional multipurpose brightening agent for washing hard surface
JP2002201413A (en) * 2000-12-28 2002-07-19 Health Chemical:Kk Coating material for rubber product
US20040131787A1 (en) * 2002-11-26 2004-07-08 Pennzoil-Quaker State Company Aqueous based tire dressing compositions and methods of making
US20050250668A1 (en) * 2004-05-05 2005-11-10 Serobian Ashot K Rheologically stabilized silicone dispersions

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Granted publication date: 20090204

Termination date: 20120403