WO2007075654A3 - Stabilization of polymers with zinc oxide nanoparticles - Google Patents

Stabilization of polymers with zinc oxide nanoparticles Download PDF

Info

Publication number
WO2007075654A3
WO2007075654A3 PCT/US2006/048387 US2006048387W WO2007075654A3 WO 2007075654 A3 WO2007075654 A3 WO 2007075654A3 US 2006048387 W US2006048387 W US 2006048387W WO 2007075654 A3 WO2007075654 A3 WO 2007075654A3
Authority
WO
WIPO (PCT)
Prior art keywords
polymers
composition
zinc oxide
polymer composite
zno
Prior art date
Application number
PCT/US2006/048387
Other languages
French (fr)
Other versions
WO2007075654A2 (en
Inventor
Nobuo Miyatake
Hung-Jue Sue
Yuntao Li
Katsumi Yamaguchi
Original Assignee
Texas A & M Univ Sys
Kaneka Corp
Nobuo Miyatake
Hung-Jue Sue
Yuntao Li
Katsumi Yamaguchi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Texas A & M Univ Sys, Kaneka Corp, Nobuo Miyatake, Hung-Jue Sue, Yuntao Li, Katsumi Yamaguchi filed Critical Texas A & M Univ Sys
Priority to JP2008547430A priority Critical patent/JP2009520870A/en
Priority to EP06845793A priority patent/EP1969046A4/en
Publication of WO2007075654A2 publication Critical patent/WO2007075654A2/en
Publication of WO2007075654A3 publication Critical patent/WO2007075654A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/14—Methods for preparing oxides or hydroxides in general
    • C01B13/32—Methods for preparing oxides or hydroxides in general by oxidation or hydrolysis of elements or compounds in the liquid or solid state or in non-aqueous solution, e.g. sol-gel process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G9/00—Compounds of zinc
    • C01G9/02—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer

Abstract

A composition and method of making a stabilizer for polymers. The composition has zinc oxide (ZnO) nanoparticles dispersed and having an average size of no more than about 15 nanometers, wherein the ZnO nanoparticles are provided as an additive to a polymeric material, thereby forming a stabilized polymer composite in which the ZnO nanoparticles remain dispersed and have an average size of no more than about 15 nanometers. The stabilized polymer composite is stabilized against heat and ultraviolet light. The polymeric material can be a (meth)acrylic resin, a styrenic resin, a pre-cure epoxy resin, or combinations thereof. In a concentrated form, the composition has ZnO nanoparticles that are typically less than 20% of the stabilized polymer composite. The stabilizer is polymerizable and may include additional additives.
PCT/US2006/048387 2005-12-20 2006-12-19 Stabilization of polymers with zinc oxide nanoparticles WO2007075654A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2008547430A JP2009520870A (en) 2005-12-20 2006-12-19 Stabilization of polymers by zinc oxide nanoparticles
EP06845793A EP1969046A4 (en) 2005-12-20 2006-12-19 Stabilization of polymers with zinc oxide nanoparticles

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/312,043 2005-12-20
US11/312,043 US20060194910A1 (en) 2004-05-19 2005-12-20 Stabilization of polymers with zinc oxide nanoparticles

Publications (2)

Publication Number Publication Date
WO2007075654A2 WO2007075654A2 (en) 2007-07-05
WO2007075654A3 true WO2007075654A3 (en) 2008-06-12

Family

ID=38218527

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/048387 WO2007075654A2 (en) 2005-12-20 2006-12-19 Stabilization of polymers with zinc oxide nanoparticles

Country Status (5)

Country Link
US (1) US20060194910A1 (en)
EP (1) EP1969046A4 (en)
JP (1) JP2009520870A (en)
TW (1) TW200728373A (en)
WO (1) WO2007075654A2 (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8344054B2 (en) 2007-07-24 2013-01-01 The Texas A & M University System Polymer nanocomposites including dispersed nanoparticles and inorganic nanoplatelets
JP2011509312A (en) * 2007-09-25 2011-03-24 ザ テキサス エー アンド エム ユニバーシティ システム Water-soluble nanoparticles with controlled aggregate size
DE102008038295B4 (en) * 2008-08-18 2013-11-28 Eads Deutschland Gmbh Granulation and stabilization of resin systems for use in the manufacture of fiber composite components
TWI366421B (en) * 2008-08-22 2012-06-11 Nanya Plastics Corp High thermal conductivity, high glass transition temperature (tg) resin composition and its pre-impregnated and coating materials for printed circuit boards
WO2010066768A2 (en) 2008-12-12 2010-06-17 Basf Se Dispersions comprising functionalized oxidic nanoparticles
WO2010080400A1 (en) * 2009-01-06 2010-07-15 Dow Global Technologies Inc. Metal stabilizers for epoxy resins and advancement process
US8580879B2 (en) 2009-01-06 2013-11-12 Nan Ya Plastics Corporation Resin composition of high thermal conductivity and high glass transition temperature (Tg) and for use with PCB, and prepreg and coating thereof
US20110224329A1 (en) * 2009-01-06 2011-09-15 Dow Global Technologies Llc Metal stabilizers for epoxy resins and dispersion process
JP5886629B2 (en) * 2009-01-06 2016-03-16 ブルー キューブ アイピー エルエルシー Metal compounds in non-brominated flame retardant epoxy resins
GB201207997D0 (en) * 2012-05-04 2012-06-20 Imp Innovations Ltd Process
MX2015003082A (en) * 2012-09-10 2015-11-09 Basf Se Precipitating nanoparticles in monomers for producing hybrid particles.
US10316171B2 (en) * 2013-09-23 2019-06-11 Agienic, Inc. Thermal stabilization of polymers using functionalized particles of transition metal compounds
JP2014208839A (en) * 2014-07-02 2014-11-06 ダウ グローバル テクノロジーズ エルエルシー Metal compound in non-brominated frame retardant epoxy resin
US20160168440A1 (en) * 2014-09-15 2016-06-16 Energy Bank Inc. Synthetic polymerization heat sink and shield enclosure
CN104389156A (en) * 2014-11-04 2015-03-04 东华大学 Preparation method of durable zinc oxide loaded textile
KR101776413B1 (en) 2015-11-20 2017-09-19 현대자동차주식회사 Nano zinc oxide filled weather strip rubber composition and weather strip for car using the same
WO2018084484A2 (en) * 2016-11-02 2018-05-11 롯데첨단소재(주) Thermoplastic resin composition and molded product manufactured therefrom
WO2019135857A1 (en) * 2018-01-08 2019-07-11 Dow Global Technologies Llc Epoxy resin adhesive compositions

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6599631B2 (en) * 2001-01-26 2003-07-29 Nanogram Corporation Polymer-inorganic particle composites
US20030172845A1 (en) * 2002-03-15 2003-09-18 Thiemo Marx Process for the preparation of nano-zinc oxide dispersions stabilized by hydroxyl group-containing inorganic polymers
US20040176187A1 (en) * 2000-12-21 2004-09-09 Bissonnette Laurent C. Golf balls including solution blended polymeric composite and method of making same
US20050045031A1 (en) * 2002-06-07 2005-03-03 Shyamala Rajagopalan Air-stable metal oxide nanoparticles
US20050255629A1 (en) * 2004-04-15 2005-11-17 Mingyong Han Biomimetic approach to low-cost fabrication of complex nanostructures of metal oxides by natural oxidation at low-temperature

Family Cites Families (65)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3603091A (en) * 1969-06-26 1971-09-07 Bernhardt Stahmer Internal combustion engine
US4053577A (en) * 1972-02-18 1977-10-11 Tioxide Group Limited Process for the gaseous phase production of metal oxide particles
IT1161200B (en) * 1983-02-25 1987-03-18 Montedison Spa PROCESS AND APPARATUS FOR THE PREPARATION OF SINGLE-DISPERSED METAL OXIDE PARTICLES, SPHERICAL, NOT AGGREGATED AND OF LESS THAN MICRON
JPS61122106A (en) * 1984-11-19 1986-06-10 Ube Ind Ltd Production of metal oxide fine powder
EP0214308B1 (en) * 1985-03-05 1993-07-28 Idemitsu Kosan Company Limited Method for preparing super-fine spherical particles of metal oxide
US4575522A (en) * 1985-03-07 1986-03-11 Hydril Company Rubber composition for geothermal application
EP0234816B1 (en) * 1986-02-12 1993-08-11 Catalysts & Chemicals Industries Co., Ltd. Processes for preparing mono-dispersed particles
US4778671A (en) * 1986-07-14 1988-10-18 Corning Glass Works Preparation of unagglomerated metal oxide particles with uniform particle size
US4927560A (en) * 1987-02-25 1990-05-22 Nippon Shokubai Kagaku Kogyo Co., Ltd. Method for production of inorganic minute globular particles
US4764357A (en) * 1987-03-09 1988-08-16 Akzo America Inc. Process for producing finely divided powdery metal oxide compositions
US4871790A (en) * 1987-11-25 1989-10-03 Minnesota Mining And Manufacturing Company Colloidal metals in monomers or polymers
US4931427A (en) * 1988-01-15 1990-06-05 Academy Of Applied Science, Inc. Process for producing metal oxide superconductor-polymer composites and composites thereby formed
US5047174A (en) * 1988-11-21 1991-09-10 Akzo America Inc. Production of stable metal oxide sols
US5207973A (en) * 1989-11-27 1993-05-04 Martin Marietta Energy Systems, Inc. Method and apparatus for the production of metal oxide powder
JP3047110B2 (en) * 1990-06-15 2000-05-29 株式会社東北テクノアーチ Method for producing metal oxide fine particles
US5409683A (en) * 1990-08-23 1995-04-25 Regents Of The University Of California Method for producing metal oxide aerogels
DE4033417A1 (en) * 1990-10-20 1992-04-23 Basf Ag METHOD FOR THE PRODUCTION OF ZINCOXIDE PIGMENTS DOPED WITH METAL OXIDS
EP0599643B1 (en) * 1992-11-26 1996-05-15 Sumitomo Rubber Industries Ltd. Rubber compositions of tyre tread
CA2113501C (en) * 1993-02-08 2007-09-18 James P. Mason Transparent polycarbonate pet blends
WO1994025966A1 (en) * 1993-04-28 1994-11-10 Mark Mitchnick Conductive polymers
JP3733599B2 (en) * 1993-08-11 2006-01-11 住友化学株式会社 Metal oxide powder and method for producing the same
JPH07218463A (en) * 1994-02-04 1995-08-18 Figaro Eng Inc Method for forming silica mask on surface of metal oxide
DE69531705T2 (en) * 1994-06-06 2004-03-18 Nippon Shokubai Co. Ltd. Fine zinc oxide particles, process for their preparation and their use
FR2721615A1 (en) * 1994-06-24 1995-12-29 Rhone Poulenc Chimie Process for the preparation of organophilic metal oxide particles
JPH10502494A (en) * 1994-07-07 1998-03-03 チロン ダイアグノスティクス コーポレーション Highly dispersible magnetic metal oxides, their production and use
JP3229174B2 (en) * 1995-08-21 2001-11-12 日本アエロジル株式会社 Surface modified metal oxide fine powder and method for producing the same
US5753373A (en) * 1995-12-21 1998-05-19 Minnesota Mining And Manufacturing Company Coating composition having anti-reflective and anti-fogging properties
US5856254A (en) * 1996-02-15 1999-01-05 Vaw Silizium Gmbh Spherical metal-oxide powder particles and process for their manufacture
US5637258A (en) * 1996-03-18 1997-06-10 Nanocrystals Technology L.P. Method for producing rare earth activited metal oxide nanocrystals
DE19630100A1 (en) * 1996-07-25 1998-01-29 Inst Neue Mat Gemein Gmbh Process for producing a shaped body suitable for optical purposes
US6169119B1 (en) * 1997-02-14 2001-01-02 Reliance Electric Technologies, Llc Metal oxide sols and process for making the same
US5780525A (en) * 1997-02-14 1998-07-14 Reliance Electric Industrial Company Photocurable composition for electrical insulation
US5928723A (en) * 1997-04-09 1999-07-27 Cabot Corporation Progress for producing surface modified metal oxide compositions
US6071486A (en) * 1997-04-09 2000-06-06 Cabot Corporation Process for producing metal oxide and organo-metal oxide compositions
US6235270B1 (en) * 1997-04-18 2001-05-22 Showa Denko K.K. Cosmetics, silica-coated metal oxide powder and production method therefor
US6139816A (en) * 1997-06-09 2000-10-31 Merck Kanto Advanced Chemical Ltd Process for the preparation of ultra-fine powders of metal oxides
US5777001A (en) * 1997-08-04 1998-07-07 Kerr Mcgee Chemical Corp. Graft polymerized metal oxide compositions and methods
JP4184487B2 (en) * 1997-08-15 2008-11-19 昭和電工株式会社 Method for producing titanium dioxide fine particles
KR100580133B1 (en) * 1997-11-18 2006-05-16 가부시키가이샤 시세이도 Ultraviolet-screening zinc oxide excellent in transparency and composition containing the same
JPH11209695A (en) * 1998-01-27 1999-08-03 Jsr Corp Coating composition and cured article
KR100265202B1 (en) * 1998-02-05 2000-09-15 김순택 A composite of organic and inorganic compounds
DE69935769T2 (en) * 1998-05-11 2007-12-27 Nippon Aerosil Co., Ltd. Fine, hydrophobic metal oxide powder, process for its preparation and toner composition for electrophotography
AUPP355798A0 (en) * 1998-05-15 1998-06-11 University Of Western Australia, The Process for the production of ultrafine powders
JP3953649B2 (en) * 1998-07-17 2007-08-08 オリヱント化学工業株式会社 Organic-inorganic hybrid component gradient polymer material and method for producing the same
US6036886A (en) * 1998-07-29 2000-03-14 Nanocrystals Technology L.P. Microemulsion method for producing activated metal oxide nanocrystals
US6329058B1 (en) * 1998-07-30 2001-12-11 3M Innovative Properties Company Nanosize metal oxide particles for producing transparent metal oxide colloids and ceramers
DE19907704A1 (en) * 1999-02-23 2000-08-24 Bayer Ag Nano-scale precipitating zinc oxide used e.g. for protecting UV-sensitive organic polymers consists of particles having an average specified primary particle diameter
JP4214203B2 (en) * 1999-05-18 2009-01-28 オリヱント化学工業株式会社 Organic-inorganic composite material and method for producing the same
JP4473364B2 (en) * 1999-06-03 2010-06-02 Ｊｓｒ株式会社 Photocurable resin composition and optical member
US6797760B1 (en) * 1999-10-15 2004-09-28 Alphagary Corporation Non-dripping, flame retardant, fluoroelastomer insulative compositions for telecommunication cables
US6327825B1 (en) * 2000-04-24 2001-12-11 Charles Pankow Builders Ltd. Method and apparatus for use in positioning high-strength cables within a precast moment resisting frame
BR0105083A (en) * 2000-11-17 2002-06-25 Goodyear Tire & Rubber Light rubber composition containing clay
US6586096B2 (en) * 2000-12-22 2003-07-01 Eastman Kodak Company Polymethylmethacrylate nanocomposite optical article and method of making same
US6919395B2 (en) * 2002-01-04 2005-07-19 Acushnet Company Golf ball compositions comprising nanoparticulates
US20050215718A1 (en) * 2002-01-04 2005-09-29 Murali Rajagopalan Nanocomposite ethylene copolymer compositions for golf balls
US20030176551A1 (en) * 2002-03-06 2003-09-18 Rediske James E. Stabilized pigmented polymer compositions
US6759446B2 (en) * 2002-05-02 2004-07-06 The Ohio State University Research Foundation Polymer nanocomposite foams
JP2004292282A (en) * 2003-03-28 2004-10-21 Mitsubishi Chemicals Corp Zinc oxide nanoparticle and method for manufacturing the same, zinc oxide nanoparticle-containing composition and laminate using the same
US7342065B2 (en) * 2003-09-18 2008-03-11 The Goodyear Tire & Rubber Company Preparation of nanocomposite of elastomer and exfoliated clay platelets, rubber compositions comprised of said nanocomposite and articles of manufacture, including tires
US7482382B2 (en) * 2004-05-19 2009-01-27 The Texas A&M University System Process for preparing nano-sized metal oxide particles
US8052918B2 (en) * 2004-07-21 2011-11-08 Nissin Kogyo Co., Ltd. Carbon-based material and method of producing the same, and composite material and method of producing the same
US7119140B2 (en) * 2004-07-22 2006-10-10 Ronald Basham Transparent films, compositions, and method of manufacture thereof
WO2007023919A1 (en) * 2005-08-24 2007-03-01 Kaneka Corporation Stabilizer composition for synthetic resin
US8163830B2 (en) * 2006-03-31 2012-04-24 Intel Corporation Nanoclays in polymer compositions, articles containing same, processes of making same, and systems containing same
US7498381B1 (en) * 2006-08-02 2009-03-03 Exxonmobil Chemical Patents Inc. Low permeability elastomeric-metal phosphate nanocomposites

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040176187A1 (en) * 2000-12-21 2004-09-09 Bissonnette Laurent C. Golf balls including solution blended polymeric composite and method of making same
US6599631B2 (en) * 2001-01-26 2003-07-29 Nanogram Corporation Polymer-inorganic particle composites
US20030172845A1 (en) * 2002-03-15 2003-09-18 Thiemo Marx Process for the preparation of nano-zinc oxide dispersions stabilized by hydroxyl group-containing inorganic polymers
US20050045031A1 (en) * 2002-06-07 2005-03-03 Shyamala Rajagopalan Air-stable metal oxide nanoparticles
US20050255629A1 (en) * 2004-04-15 2005-11-17 Mingyong Han Biomimetic approach to low-cost fabrication of complex nanostructures of metal oxides by natural oxidation at low-temperature

Also Published As

Publication number Publication date
EP1969046A2 (en) 2008-09-17
TW200728373A (en) 2007-08-01
WO2007075654A2 (en) 2007-07-05
JP2009520870A (en) 2009-05-28
EP1969046A4 (en) 2010-11-17
US20060194910A1 (en) 2006-08-31

Similar Documents

Publication Publication Date Title
WO2007075654A3 (en) Stabilization of polymers with zinc oxide nanoparticles
WO2007076990A3 (en) Agglomerate particles, method for producing nanocomposites, and the use thereof
EP2295513A3 (en) Improved structural adhesive materials
WO2007144576A3 (en) Uv absorbing composition
EP1803778A3 (en) Hydrotalcite-based compound particles, resin stabilizer using the same, halogen-containing resin composition and anion scavenger using the same
CN107200952A (en) A kind of tasteless environment-friendly type PVC edge band and preparation method thereof
WO2005072680A3 (en) Surface-doped particles of ti02 or zno and their use
MY155060A (en) Composed element, multi-layered board and panel-shaped element for forming this composed element
TW200708522A (en) Polyacrylic acid (salt) water-absorbent resin, production process thereof, and acrylic acid used in polymerization for production of water-absorbent resin
WO2007074167A3 (en) Production of a water-absorbing resin to which a particulate additive is admixed
WO2006130604A3 (en) Self-extinguishing polymer composition
WO2008021033A3 (en) Polymers filled with highly expanded graphite
WO2008096713A1 (en) Granular water absorber and method of producing the same
WO2009071332A3 (en) Nanoparticulate composition and method for the production thereof
WO2008048693A3 (en) Magnesium hydroxide nanoparticles, methods of making same and compositions incorporating same
WO2009036862A3 (en) Compositions with an antimicrobial action
WO2008152417A3 (en) Antimicrobial polymer nanocomposites
WO2008142983A1 (en) Crosslinked fluorine-containing elastomer fine particle, method for producing the same, and composition
WO2009080974A3 (en) Method of preparing a transparent polymer material comprising a thermoplastic polycarbonate and mineral nanoparticles
WO2006069285A3 (en) Curable polyester resin compositions
WO2010041834A3 (en) Pigment consisting of photonic crystals for a paint composition, and method for producing same
WO2010035258A3 (en) Discrete metallic copper nanoparticles
WO2009004250A3 (en) Glass fibre structure for reinforcing agglomerated abrasive objects
WO2005109515A3 (en) System and method for making nanoparticles with controlled emission properties
WO2009036295A3 (en) A drawing process for the continuous fabrication of nanofibers made of a variety of materials

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2008547430

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2006845793

Country of ref document: EP